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(11) | EP 0 032 811 A3 |
(12) | EUROPEAN PATENT APPLICATION |
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(54) | A process for the beneficiation of coal and beneficiated coal product |
(57) An improved beneficiated coal products is disclosed comprising coal particles which
have been rendered hydrophobic and oleophilic by forming a polymer coating thereon.
According to the process an aqueous slurry containing the coal particles is admixed
with a fuel oil and a polymerisation mixture preferably containing one or more long
chain carboxylic acids which are polymerised in situ on the coal particles. The hydrophobic
coal particles are then separated from the aqueous medium by froth flotation preferably
in several steps by atomising the flocculated coal particles onto the surface of a
mass of wash water. Hydrophilic ash particles separate into the wash water whilst
the flocculated hydrophobic, oleophilic coal particles are recovered. Following recovery
the flocculated particles are de-watered mechanically. Additional but optional treatments
include neutralisation and admixing with oil to form coal-in-oil mixtures, and subjecting
the particles to a second graft polymerisation procedure. |