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EP 0 092 109 B1 |
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EUROPEAN PATENT SPECIFICATION |
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Mention of the grant of the patent: |
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14.01.1987 Bulletin 1987/03 |
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Date of filing: 06.04.1983 |
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International Patent Classification (IPC)4: H01K 3/02 |
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Method for increasing the life of a tungsten filament for an incandescent lamp
Verfahren zum Verlängern der Lebensdauer eines Wolframleuchtdrahtes für eine Glühlampe
Méthode pour prolonger la durée de vie d'un filament en tungstène pour une lampe à
incandescence
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Designated Contracting States: |
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BE DE FR GB NL |
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Priority: |
15.04.1982 US 368543
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Date of publication of application: |
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26.10.1983 Bulletin 1983/43 |
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Applicant: GTE Products Corporation |
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Wilmington, DE 19801 (US) |
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Inventor: |
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- Shaffer, John W.
Williamsport, Pa. 17701 (US)
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Representative: Lemke, Jörg-Michael, Dipl.-Ing. |
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Schmiedstrasse 1,
Hausen 86447 Aindling 86447 Aindling (DE) |
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
|
Technical Field
[0001] This invention relates to incandescent lamps and more particularly to a method for
increasing the life of tungsten filaments.
[0002] The use of tungsten filaments in incandescent lamps is well established. Also well
established is the fact that tungsten filaments do not heat to a uniform temperature
upon passage of an electric current therethrough. Rather, localized hot spots are
generally observed. Such hot spots are the filament life-determining factor in a well-made
lamp because of their higher rate of tungsten evaporation. A runaway condition thereby
exists, with evaporation promoted thinning of the wire and consequent increased ohmic
heating and ever higher localized temperatures.
[0003] Hot spots on a filament may arise because of nonuniform wire cross sectional area,
nonuniform cross sectional shape, variations in wire surface smoothness, nonuniformly
spaced turns or segments of turns in a coiled or coiled coil geometry, and other reasons.
While good lamp manufacturing practice strives to reduce all such contributing factors,
the presence of hot spots is nevertheless ubiquitous.
[0004] It is well known to those skilled in the art that a halogen cycle based on fluorine
or its compounds differs from those based on bromine and the other halogens in that
with fluorine evaporated tungsten is redeposited back onto the filament in a rate
that increased with filament temperature. This is because of the relatively greater
thermal stability of tungsten hexafluoride as compared to the other tungsten halides.
In effect, the fluorine cycle renders the fialment much more stable because the hot
spots, which are more prone to evaporation, are also significantly more effective
in thermally breaking down tungsten hexafluoride and thereby depositing tungsten back
onto the filament. In practice, it is found that, at hot spots, tungsten deposition
occurs at a higher rate than does evaporation, and the net effect is for a fluorine-cycle
lamp to continually repair its filament.
[0005] The attractiveness of the fluorine cycle in incandescent lamps is somewhat offset
by the toxicity of fluorine compounds (either initially or after operation of the
lamp) and the technical difficulty of providing a lamp vessel and lead wires that
are resistant to fluorine attack. U.S. Patent No. 4,256,988, e.g., addresses the problems
of how to protect a lamp envelope and the filament supporting structure from attack
by fluorine in a tungsten- fluorine lamp. The suggested method involves coating the
interior of the lamp envelope and the internal structure with fluorine resistant compounds.
[0006] While this approach is interesting, it would certainly be expensive; and, it does
not solve the problems occasioned by leaving in the hands of consumers a vessel loaded
with toxic fluorine or fluoride compounds.
[0007] It is, therefore, an object of the invention to obviate the disadvantages of the
prior art and to enhance the life of tungsten filaments.
[0008] These objects are accomplished by the provision of a method for increasing the life
of tungsten filaments employed as a light emitting element in a lamp. The method comprises
the steps of forming a filament from a length of tungsten wire; placing said filament
in a closed environment; providing said closed environment with a gas fill which includes
tungsten hexafluoride; applying sufficient electrical energy to said filament to cause
said filament to incandesce; maintaining said filament at incandescence for a sufficient
period of time to substantially remove hot spots from said filament; withdrawing said
electrical energy and removing said filament from said closed environment; and subsequently
operatively sealing said filament in a lamp envelope having an atmosphere free of
fluorine and fluorine compounds.
[0009] This process allows the use of the advantageous fluorine regenerative cycle under
closely controlled manufacturing conditions while keeping the ultimate lamp delivered
to the general public fluorine-free.
Best Mode for Carrying Out the Invention
[0010] For a better understanding of the present invention, together with other and further
objects, advantages and capabilities thereof, reference is made to the following disclosure
and appended claims.
[0011] The method is accomplished by first forming a filament from a length of tungsten
wire. The filament can remain as cut; or it can be formed into a coil; a coiled coil;
or any other desired configuration. The filament is then placed in closed environment
which can be the final lamp vessel but preferably is a separate chamber formed of
monel
@ or other suitable fluorine resistant material.
[0012] The closed environment is then provided with a gas fill which includes tungsten hexafluoride
(WF
6). Electrical energy is then applied to the filament to cause the filament to incandesce.
The time and operating conditions should be sufficient to allow substantial repair
of hot spots, wherever located or regardless of cause. This fluorine treatment, as
noted above, renders the filament more stable.
[0013] After the treatment the filament is removed from the closed environment and subsequently
is assembled into a lamp. The treated filament is effective in vacuum incandescent
lamps, inert gas filled incandescent lamps such as, for example, lamps containing
an argon-nitrogen fill, and tungsten-halogen lamps containing a halogen other than
fluorine.
[0014] The gas fill for the closed environment is preferably a mixture of an inert gas,
such as nitrogen, and up to about 50% WF
6.
[0015] Employment of this process thus provides the benefits of the fluorine cycle on initial
filament repair while allowing the sale to the public of lamps which do not contain
fluorine.
1. In a method of increasing the life of tungsten filaments employed as a light emitting
element in a lamp, the steps comprising: forming a filament from a length of tungsten
wire; placing said filament in a closed environment; providing said closed environment
with a gas fill which includes tungsten hexafluoride; applying sufficient electrical
energy to said filament to cause said filament to incandesce; maintaining said filament
at incandescence for a sufficient period of time to substantially remove hot spots
from said filament; withdrawing said electrical energy and removing said filament
from said closed environment; and subsequently operatively sealing said filament in
a lamp envelope having an atmosphere free of fluorine and fluorine compounds.
2. The method of Claim 1 wherein said gas fill includes also nitrogen.
3. The method of Claim 2 wherein said gas fill comprises up to about 50% tungsten
hexafluoride.
4. The method of Claim 1 wherein said lamp envelope is evacuated.
5. The method of Claim 1 wherein said lamp envelope contains an inert gas.
6. The method of claim 1 wherein said lamp envelope contains a halogen selected from
chlorine, bromine and iodine.
1. Verfahren zur Verlängerung der Lebensdauer von als Licht aussendendes Element in
einer Lampe dienenden Wolframräden, bestehend aus den folgenden Schritten: Bilden
eines Fadens aus einem Stück Walframdraht; Anordnen dieses Fadens in einer abgeschlossenen
Umgebung; Versehen dieser abgeschlossenen Umgebung mit einer Wolfram-Hexafluorid enthaltenden
Gasfüllung; Beaufschlagen des Fadens mit einer ausreichenden Menge elektrischer Energie,
um denselben zum Glühen zu bringen; Aufrechterhalten des Glühzustands des Fadens für
eine ausreichende Zeitspanne, um überhitzte Stellen bzw. Aufblasestellen im wesentlichen
zu entfernen; Abschalten der elektrischen Energie und Entfernen des Fadens aus der
abgeschlossenen Umgebung; und schließlich betriebsmäßiges Einsiegeln des Fadens in
eine Lampenhülle, die eine von Fluor und Fluorverbindungen freie Atmosphäre aufweist.
2. Verfahren nach Anspruch 1, bei welchem die Gasfüllung auch Stickstoff aufweist.
3. Aufweise nach Anspruch 2, bei welchem die Gasfüllung bis etwa 50% Wolfram-Hexafluorid
aufweist.
4. Verfahren nach Anspruch 1, bei welchem die Lampenhülle evakuiert ist.
5. Verfahren nach Anspruch 1, bei welchem die Lampenhülle ein inertes Gas aufweist.
6. Verfahren nach Anspruch 1, bei welchem die Lampenhülle ein aus Chlor, Brom und
Jod ausgewähltes Halogen enthält.
1. Procédé pour augmenter la durée de vie des filaments au tungstène utilisés en tant
que composant émettant de la lumière dans une lampe, comprenant les étapes suivantes:
- mise en forme d'un filament à partir d'une longueur d'un fil de tungstène;
- mise en place du dit filament dans un environnement clos;
- emplir le dit environnement clos d'un gaz de remplissage comprenant de l'hexafluorure
de tungstène;
- appliquer au dit filament une quantité d'énergie électrique suffisante pour obtenir
son incandescence;
- maintenir en incandescence le filament pendant un temps suffisant pour éliminer
les point chauds du dit filament;
- arrêter la dite énergie électrique et ôter le dit filament du dit environnement
clos; puis
- sceller pour son fonctionnement le dit filament dans une ampoule de lampe enfermant
un gaz libre de fluor et de composés de ce dernier.
2. Procédé selon la revendication 1 caractérisé en ce que le dit gaz de remplissage
contient en outre de l'azote.
3. Procédé selon la revendication 2 caractérisé en ce que le gaz de remplissage contient
jusqu'à 50 % environ d'hexafluorure de tungstène.
4. Procédé selon la revendication 1 caractérisé en ce qu l'on fait le vide dans la
dite ampoule de lampe.
5. Procédé selon la revendication 1 caractérisé en ce que la dite ampoule de lampe
enferme un gaz inerte.
6. Procédé selon la revendication 1 caractérisé en ce que la dite ampoule de lampe
enferme un halogène choisi parmi le chlore, le brome et l'iode.