BACKGROUND OF THE INVENTION
[0001] This invention relates to the determination of the . characteristics of substances
in gaseous form, and more specifically to determination of heating value, or heat
of combustion, density, and humidity or moisture content of a gas or vaporized liquid.
HEATING VALUE
[0002] Fuels in liquid or gaseous form are burned to produce heat for a plethora of applications.
These fuels may vary in composition from primarily single carbon hydrocarbons to hydrocarbons
having many carbon atoms arranged in branched chain or ring structures or may be mixtures
of many hydrocarbons. Often a fuel contains compounds which are inert with respect
to normal combustion. It is useful to know the heating value of a fuel, that is, the
amount of heat which a certain quantity of a fuel will produce when it is burned under
a certain set of conditions. While the heating values of most pure substances capable
of being used as fuels are readily available in the literature, that a myriad number
of mixtures of compounds are used as fuels results in a continuing need for making
heating value determinations. Apparatus and methods for determining heating values
are used both in laboratories and in industrial operations outside the laboratory.
It is often desirable to monitor heating value of a flowing stream on a continuous
basis. Following are several exemplary applications for heating value monitoring.
[0003] Since the value of a fuel depends in large part upon the amount of heat it is capable
of producing, it is more appropriate to set fuel price in accordance with heating
value and quantity, rather than quantity alone. Natural gas is a prime example; in
the USA it is almost always sold on the basis of dollars per thousand BTU instead
of the previously used basis of dollars per SCF. This is primarily the result of the
price increases of recent years. Imprecision in the number of BTU's transferred is
now too expensive to tolerate. Another factor necessitating transfer of custody on
the basis of heat quantity is that natural gas heating values tend to vary more, as
gases from different locations are pipelined around the country and gas is imported.
[0004] A gas stream which is a by-product of operation of a factory, or plant, is often
piped to a nearby plant to be burned as fuel. As in the above natural gas example,
the payment made for the gas will probably be based on its heating value as well as
the quantity burned. Average heating value may be determined by periodic laboratory
analysis or the heating value may be continuously measured as the gas enters the user's
plant. Further, heating values of the by-product gas must be determined, before its
actual use begins, for reasons other than pricing. Design and control of the burner,
furnace, and other equipment involved in handling and burning the gas depends in part
on the range of heating values which can be expected. Heating value of a by-product
gas would normally vary over a fairly large range, compared to natural gases, and
the average heating value would be different from that of natural gases.
[0005] In certain manufacturing processes, temperature and/or furnace atmosphere must be
maintained in a relatively narrow range in order to assure product-quality. Changes
in heating value of the fuel supplied to the furnace may necessitate corrective action
to avoid an excursion from the acceptable range. An increase in heating value of a
fuel indicates that more oxygen is required to combine with it. Where a furnace atmosphere
is required to be rich in oxygen, an increase in rate of oxygen depletion in the furnace
caused by an increased heating value may create quality problems. The solution is
often to increase oxygen flow as soon as an increase in heating value is detected
by a heating value monitor and thereby avoid significant depletion.
[0006] Fuel savings can be realized by using a heating value monitor in a combustion zone
control system. The amount of air supplied to the combustion zone can be adjusted
by reference to the heating value monitor so that the excess air quantity is small,
thus saving fuel used for heating unneeded air and so that use of extra fuel as a
result of incomplete combustion is avoided.
[0007] There are many applications, such as mentioned above, where an apparatus and method
for determining heating value on an instantaneous and continuous basis is required.
The most usual method of determining heating value in a laboratory is by use of a
calorimeter in which the fuel is burned under precisely controlled conditions and
rise in temperature of a water bath heated by the burned fuel is measured. While accurate,
this method is time- consuming and cannot be adapted to provide a continuous read-out
of heating value for a continuous flow of sample to the calorimeter. Also, as mentioned
above, there are many applications where a series of laboratory determinations of
heating value need to be made quickly and not necessarily with the accuracy of a primary
standard. The instant invention is expected to be significant in meeting these applications.
[0008] For purposes of comparison to the present invention, a continous reading on-line
calorimeter device available from Fluid Data, Inc. of Merrick, New York is described.
In this instrument, variations in heat produced by a test burner are offset by adjustment
of air flow to the burner, in a null balance fashion, and air flow rate is related
to heating value. A sample of gas is piped from a stream to be tested to the test
burner and gas flow rate is held constant. The flame heats a thermal expansion element
whose movement adjusts air flow to the burner through a mechanical and pneumatic linkage.
Air flow is independently measured by means of an orifice meter and displayed on a
scale which is marked in terms of heating value.
[0009] Several recently issued patents show the interest in methods for determining heating
value. In U.S. Patent 4,337,654, a fixed amount of gas is burned with a measured quantity
of air and hydrogen or oxygen supplied by an electrolytic cell. The amount of hydrogen
or oxygen added is controlled by an oxygen sensor and related to the heating value
of the gas burned. U.S. Patent 4,355,533 describes a method of determining heating
value where information developed by use of a gas chromatograph is correlated with
heating value. U.S. Patent Nos. 4,329,873 and 4,329,874 describe another calorimeter
in which gas is oxidized.
[0010] A recent article by Van Rossum which points up the need for the present invention
can be found in Oil and Gas Journal of January 3, 1983 (p. 71, Part 1) and January
10, 1983 (p. 85, Part 2).
[0011] For background information on different gases and liquids used as fuels and on combustion,
reference may be made to the Fuels section of Perry's Chemical Engineers Handbook,
published by McGraw-Hill, and in particular to pages 9-1 to 9-33 of the fourth edition.
DENSITY
[0012] It is important to know the density of a gas in many industries, in particular, in
the area of petroleum and petrochemical processing. A typical application is a mass
flow meter, where volumetric flow rate is combined with the density of the flowing
stream to produce mass flow rate. One seeking to measure density, particularly on
a continuous on-line basis, has a limited choice of apparatus. One commercially available
density meter utilizes an oscillating element in the fluid whose density is measured.
Oscillation is caused by an electromagnetic field. The frequency of oscillation depends
on the density of the fluid. The sensing element is contained in a housing having
one-inch flanges for installation in a pipeline. A standard reference, Process Instruments
and Controls Handbook, 2nd ed., 1974, edited by Considine, lists only three techniques
for measuring density, none of which are well suited for use outside the laboratory.
The listed methods (p. 6-152) are as follows.
[0013] In a gas specific gravity balance, a tall column of gas is measured by a floating
bottom fitted to the gas containment vessel. A mechanical linkage displays movement
of the bottom on a scale. A buoyancy gas balance consists of a vessel containing a
displacer mounted on a balance beam and with a manometer connected to it. Displacer
balance is established with the vessel filled with air and then filled with gas, the
pressure required to do so being noted from the manometer in both cases. The pressure
ratio is the density of the gas relative to air. In a viscous drag density instrument,
an air stream and a stream of the gas under test are passed through separate identical
chambers, each containing a rotating impeller. The two streams are acted upon by the
rotating impellers and in turn each acts upon a non-rotating impeller mounted in the
opposite end of the chamber. The non-rotating impellers are coupled together by a
linkage and measure the relative drag shown by the tendency of the impellers to rotate,
which is a function of relative density.
HUMIDITY
[0014] This invention also relates to determination of humidity, or moisture content, of
a gas or vaporized liquid. It is primarily useful for analyzing gases where the moisture
content is large and there is a small difference between the molecular weight of water
and the average molecular weight of the other components of the gas or where there
is a large difference between the molecular weight of water and the average molecular
weight of the other components.
[0015] There are a variety of methods for measuring water content, each of which involves
at least one significant disadvantage which disqualifies it for use in certain applications.
Thus the choice of a method must be made in light of the application. A survey of
methods and apparatus can be found in Process Instruments and Controls Handbook, edited
by Considine, 2nd ed., McGraw-Hill, 1974, p. 10-3 and following. The applications
for which the instant invention is suited will become apparent upon reading this specification,
as will the gap in the area of humidity measurement which is filled by the instant
invention.
STATEMENT OF ART
[0016] In an article in Oil and Gas Journal of April 5, 1982 entitled "Acoustic Measurement
for Gas BTU Content", Watson and White suggest a method and apparatus which utilize
the dependence of sound speed and BTU content on molecular weight and which utilize
some of the same basic scientific principles as this invention. LeRoy and Gorland
have explored the use of a fluidic oscillator as a molecular weight sensor of gases
and reported their work in an article entitled "Molecular Weight Sensor" published
in Instruments and Control Systems of January, 1971, and in National Aeronautics and
Space Administration Technical Memoranda TMX-52780 (circa 1970) and TMX-1939 (January
1970). In Fossil Energy I & C Briefs, Nov. 1981, prepared for the U.S. Dept. of Energy
by Jet Propulsion Laboratory of California Institute of Technology, Sutton of The
Garrett Corp., referred to the use of a fluidic oscillator to measure gas compositions,
mass flow and the heating value of natural gas.
[0017] In a paper entitled "Thermal Energy Measurements", presented at the 55th International
School of Hydrocarbon Measurement in 1980 at the University of Oklahoma, W. A. Fox
of Consolidated Gas Supply Corp. of Clarksburg, West Virginia, suggests that specific
gravity methods may be used for determining heating values. The use of a fluidic oscillator
in measuring composition in a methanol-water system is discussed in an article on
page 407 of Ind. Eng. Chem. Fundam., Vol. 11, No. 3, 1972. U.S. Patent No. 3,273,377
(Testerman) shows the use of two fluidic oscillators in analyzing fluid streams. A
fluidic device for measuring the ratio by volume of two known gases is disclosed in
U.S. Patent No. '3,554,004 (Rauch et al.). In U.S. Patent No. 4,150,561, Zupanick
claims a method of determining the constituent gas proportions of a gas mixture which
utilizes a fluidic oscillator.
[0018] In National Aeronautics and Space Administration Technical Memorandum TMX-1269 (August
1966), Prokopius reports on the use of a fluidic oscillator in a humidity sensor developed
for studying a hydrogen-oxygen fuel cell system. In NASA TMX-3068 (June 1974), Riddlebaugh
describes investigations into the use of a fluidic oscillator in measuring fuel-air
ratios in hydrocarbon combustion processes. NASA Report No. L0341 (April 16, 1976),
written by Roe and Wright of McDonnell Douglas under Contract No. NAS 10-8764 at the
Kennedy Space Center, reports on work done to develop a fluidic oscillator as a detector
for hydrogen leaks from liquid hydrogen transfer systems. U.S. Patent No. 3,756,068
(Villarroel et al.) deals with a device using two fluidic oscillators to determine
the percent concentration of a particular gas relative to a carrier gas.
[0019] Previously cited U.S. Patent Nos. 4,337,654 (Austin et al.), 4,329,873 (Maeda), 4,329,874
(Maeda), and 4,355,533 (Muldoon), disclose methods of determining heating value. The
previously cited article in the Oil and Gas Journal (January 3 and 10, 1983) presents
a survey of methods used in Europe.
BRIEF SUMMARY OF THE INVENTION
[0020] It is an object of this invention to provide methods and apparatus for determining
unknown properties of gases and liquids, which are capable of use both in the laboratory
and in the field. Also, it is an object that such apparatus be relatively inexpensive,
have a minimum of moving mechanical parts, and be compact, so as to facilitate transportation
and installation. It is a further object of this invention that such methods and apparatus
have high accuracy and reliability while providing results essentially instantaneously.
[0021] In one of its broad embodiments, the invention comprises (a) a fluidic oscillator;
(b) means for establishing flow of the sample through said oscillator
' (c) means for measuring or controlling the pressure at which the sample passes through
said oscillator and for providing a signal representative of the pressure when pressure
is not controlled in a previously established range; (d) means for measuring the temperature
of the sample at said oscillator and for providing a signal representative of the
temperature; (e) means for measuring the frequency of oscillation at said oscillator
and for providing a signal representative of the frequency; (f) computing means for
reading said signals and for calculating the unknown property of the sample using
equations and data stored in said computing means and data supplied by said means
for providing a pressure signal when pressure is not controlled in a previously established
range; and, (g) means for communicating information contained in said computing means.
BRIEF DESCRIPTION OF THE DRAWINGS
[0022] The invention will now be further described, by way of example, with reference to
the accompanying draw-Lngs, in which:
Figure 1 is a schematic diagram of a fluidic oscillator,
Figure 2 is a schematic diagram of an embodiment of the invention comprising a heating
value monitor where-Ln the heating value of gas flowing in a pipeline is neasured
on a continuous basis and displayed in a remote Location,
Figure 3 is a schematic diagram of an embodiment of the invention comprising a density
monitor wherein the density of gas flowing in a pipeline is measured In a continuous
basis and displayed in a remote location,
Figure 4 is a schematic diagram of an embodiment of the invention comprising a humidity
monitor using two oscillators in parallel wherein the moisture content of gas flowing
in a pipeline is measured on a continuous basis and displayed in a remote location,
and
Figure 5 is an expansion, in block diagram form, of the portions of Figures 2, 3 and
4 labelled "Field Electronics" and "Control Room Electronics".
DETAILED DESCRIPTION OF THE INVENTION
[0023] A device known as a fluidic oscillator is used in this invention. This is one of
a class of devices which are utilized in the field of fluidics. A fluidic oscillator
may have any of a number of different configurations in addition to that depicted
in FIGURE 1. The publications mentioned under the heading "Statement of Art" describe
fluidic oscillators and their governing principles in detail and therefore it is unnecessary
to present herein more than the following simple description.
[0024] A fluidic oscillator may be described as a set of passageways, in a solid block of
material, which are configured in a particular manner. If the passageways are centered
in the block and the block is cut in half in the appropriate place, a view of the
cut surface would appear as the schematic diagram of FIGURE 1. Referring to FIGURE
1, a gas stream enters the inlet, flows through nozzle 109, and "attaches" itself
to one of two stream attachment walls 105 and 106 in accordance with the principle
known as the Coanda effect. Gas flows through either exit passage 107 or exit passage
108, depending on whether the stream is attached to wall 105 or wall 106. Exit passages
107 and 108 can be considered as extending to the outside of the block of material
in a direction perpendicular to the plane in which the other passages lie. Consider
a gas stream which attaches to wall 105 and flows through exit passage 107. A pressure
pulse is produced that passes through delay line 104. The pressure pulse impinges
on the gas stream at the outlet of nozzle 109, forcing it to "attach" to wall 106
and flow through exit passage 108. A pulse passing through delay line 103 then causes
the stream to switch back to wall 105. It is in this manner that an oscillation is
established. The frequency of the oscillation is a function of the pressure propagation
time through the delay line and time lag involved in the stream switching from one
attachment wall to the other. For a delay line of given length, the pressure propagation
time is a function of the characteristics of the gas, as shown in the above mentioned
publications and also by the equations which are presented herein. The frequency of
oscillation can be sensed by a pressure sensor or microphone located in one of the
passages, such as shown by sensing port 102. A differential sensing device connected
to both passages can also be used. Sensing port 101 is shown to indicate one potential
location for a temperature sensor.
[0025] The invention can be most easily described by initial reference to Figures 2, 3,
4 and 5, which represent particular embodiments of the invention. Reference will also
be made to a particular prototype heating value monitor which was fabricated and tested.
Referring to Figures 2, 3 and 4, gas is flowing through pipeline 50. A sample flow
loop 51 is formed by means of conduit, such as 3/4-inch (19 mm) diameter pipe, connected
to pipeline 50 upstream and downstream of pressure drop element 53. The purpose of
pressure drop element 53 is to cause a loss of pressure in pipeline 50 which is the
same as the pressure drop in flow loop 51 when a sufficient amount of gas is passing
through flow loop 51. Gas flow through flow loop 51 is sufficient when gas composition
at sample point 54 is substantially the same as that in pipeline 50 at any given instant.-
Normally pressure drop element 53 is a device present in the pipeline for a primary
purpose unrelated to taking a sample, for example, a control valve. A sufficient length
of pipeline 50 can serve as pressure drop element 53 or an orifice plate can be installed
in pipeline 50 to serve the purpose. Valves 52 are used to isolate flow loop 51 from
pipeline 50.
[0026] With regard to Figure 3 only, pressure and temperature of the gas flowing in pipeline
50 are provided by pressure transmitter 75 and temperature transmitter 76. These are
located close to pipeline 50, so that differences in pressure and temperature between
their locations and pipeline 50 are not significant. Pipeline 50 is covered with thermal
insulation of a type commonly used on pipelines. The location shown in Figure 3 has
the advantage of allowing the density monitor to be a self-contained package. However,
if the pressure and temperature differences are significant, transmitters 75 and 76
can be located directly on pipeline 50. The measured pressure and temperature are
referred to herein as T
1 and P
l.
[0027] Figure 4 represents one alternative embodiment of the present invention wherein it
is desired to determine the moisture content of a gas sample. Flow of a gas sample
is provided in parallel through first fluidic oscillator 56 and second fluidic oscillator
78 with means for adjusting the water content of a portion of the sample before it
passes through the second oscillator 78.
[0028] In all three embodiments as depicted in Figures 2, 3 and 4, sample lines 55 carry
samples of gas from sample points 54 to fluidic oscillators 56. Sample line 77 branches
off to supply a sample of gas to fluidic oscillator 78 in the embodiment of Figure
4. Filters 57 are provided to remove particles which might be present in the sample,
so that the narrow passages of fluidic oscillators 56 and 78 or other flow paths will
not become plugged. Pressure regulators 58, of the self-contained type with an integral
gauge, are provided so that gas flowing through oscillators 56 and that flowing through
oscillator 78 is at a substantially constant pressure. The frequency of oscillation
at the oscillators may vary with pressure, depending on the particular oscillators
used and the actual pressure at the oscillators. As will be seen, frequencies are
correlated with humidity moisture content and density, so variation for any other
reason is unacceptable. Any pressure regulating means capable of maintaining flow
through the oscillators at a substantially constant value may be used. Under certain
circumstances, sufficient pressure regulation will exist by virtue of system configuration
and pressure level, so that no separate pressure regulation device is needed.
[0029] Orifices 60 are provided for the purpose, in conjunction with pressure regulators
58, of maintaining a constant flow of gas through each oscillator. Pressure gauges
59 indicate the pressures downstream of orifices 60. Normally it is not necessary
to install orifices 60, as the sample lines or the inlet ports of the oscillators
serve the same purpose. Conduits 71 (Figures 2, 3, 4) and 79 (Figure 4) carry the
samples away from oscillators 56 (Figure 2, 3, 4) and 78 (Figure 4), to the atmosphere
in a location where discharge of the gas will cause no harm or to a process vessel
where it can be utilized. However, the quantity of gas is sufficiently small that
it may not be economical to do more than discharge it to the atmosphere. Pressure
transmitters 61 are switch devices which provide signals for actuation of alarms if
the pressures do not remain in previously established ranges. Thus communication that
inaccurate results may be obtained is accomplished. With reference to Figure 4 only,
d'ryer 80 is provided to remove substantially all water from the gas which passes through
oscillator 78. There are many commercially available devices to accomplish this. A
typical device contains two beds of a desiccant material so that gas to be desiccated
passes through one bed while the other bed is being regenerated by applied heat.
[0030] Obtaining a representative sample stream from a pipeline, providing it to the inlet
port of a fluidic oscillator, removing it from the outlet port of the oscillator,
and maintaining a substantially constant pressure drop across the oscillator can be
accomplished by a variety of different means and methods for each given set of conditions,
such as desired flow rate through the oscillator and pipeline pressure. These means
and methods, which can be applied as alternatives to those shown in Figures 2, 3 and
4, are well known to those skilled in the art.
[0031] A fluidic oscillator can be designed and fabricated upon reference to the literature,
such as that mentioned under the heading "Statement of Art" or may be purchased. In
test work applicable to this invention, an oscillator supplied by Garrett Pneumatic
Systems Division of Phoenix, Arizona was used. This oscillator is of a different configuration
than that shown in FIGURE 1 in that the "loops" formed by delay lines 103 and 104
are open such that the "loops" define cavities and in that there is only one exit
passage. Drawings of this configuration can be found in the cited references. The
flow rate through this oscillator when testing natural gas is approximately 250 cm
3/min when upstream pressure is approximately 20 psig (a gauge pressure of 1.4 kg/cm
2) and the oscillator is vented directly to atmosphere. A flow rate range of 200 to
500 cm
3/min is considered to be reasonable for commercial use and sufficient to provide acceptable
humidity results.
[0032] Temperature transmitters 67 (Figures 2, 3, 4) and 81 (Figure 4) provide the temperature
of the gas at each oscillator. Any of the well known means of sensing temperature
may be used, such as a thermister, thermocouple, or solid state semiconductor sensor.
The sensor may be located in a passage of the oscillator, such as shown in FIGURE
1 (sensing port 101), or in the sample line or conduit adjacent to the oscillator.
Microphones 66 (Figures 2, 3, 4) and 82 (Figure 4) sense the frequency of oscillation
at each oscillator. A microphone is located in a position to sense when the gas stream
attaches itself to one of the walls, such as the position shown in FIGURE 1 (sensing
port 102). There are a wide variety of sensors which can be used, for example, a piezoceramic
transducer, in which pressure induces a voltage change, or a piezo-resistance transducer,
in which pressure induces a resistance change. Used in test work applicable to this
invention was a Series EA 1934 microphone supplied by Knowles Electronics of Franklin
Park, 111.
[0033] Signals from microphones 66 and 82, temperature transmitters 67 and 81, and pressure
transmitters 61 are processed by equipment denoted field electronics 68 and control
room electronics 69. Field electronics are located adjacent to the oscillators while
control room electronics are in a central control room some distance away from the
oscillators. This equipment processes the signals to obtain humidities of the gas
and performs other functions which will be described herein. Display unit 70 receives
signals from control room electronics 69 and communicates humidities of the sample
gas and other information in human-readable form. It may be, for example, a liquid
crystal display. The information may be communicated to other equipment, such as a
strip chart recorder for making a permanent record or a computer for further manipulation.
[0034] Two containers of calibration gas, 64 and 65, are provided to check that the monitor
is operating properly. Normally one of the calibration gases has properties in the
lower part of the range of values expected of the gas flowing in pipeline 50 and one
has properties in the higher part of that range. The monitor is placed in the appropriate
calibration mode by means of one of input switches 18 (Figure 5). By mani- puiating
valves 63, 72 and 73, the calibration gases are allowed to flow, in turn, through
calibration conduit 62 and sample line 55 to oscillator 56. The monitor may be arranged
so that properties of the calibration gases are displayed and a human technician must,
if necessary, adjust the monitor to the known calibration gas property values, or
may be arranged so that the monitor is capable of adjusting itself. For example, the
monitor could re-calculate the values of constants stored in it which are used in
calculating sample humidities or densities or heating values. Periodic calibration
must be accomplished to check for malfunctions and changes which might take place
in the apparatus such as electronic drift, corrosion, and substances accumulating
in the apparatus.
[0035] Since the pressure and temperature of the calibration gases will vary as conditions
such as ambient temperature change, the calibration gas densities calculated by the
monitor must be adjusted to a pressure and temperature at which the calibration gas
densities are known. For example, if pressure transmitter 61 measures a pressure of
20 psig (140 kPa gauge) and temperature transmitter 67 measures a temperature of 30°F
(-1.1°C) when calibration gas from container 64 is flowing and the density of container
64 gas is known to be 0.0448 lb/ft
3 (0.718 kg/m3) at 0°C and 1 atmosphere (101 kPa gauge), the density communicated by
the monitor must be at 0°C and 1.0 atmosphere (101 kPa). If the communicated density
is significantly different from 0.0448 lb/ft
3 (0.718 kg/m
3), the monitor is not operating properly. Adjustment of a density value from one pressure
and temperature to another is easily accomplished by means of the equation of state
presented herein. The monitor may be arranged so that densities of the calibration
gases are displayed and a human technician must, if necessary, adjust the monitor
to the known calibration gas densities, or may be arranged so that the monitor is
capable of adjusting itself. For example, as was done in the prototype device, the
monitor could re-calculate the values of constants stored in it which are used in
calculating sample densities.
[0036] The procedure just described does not accomplish calibration of pressure transmitter-75
and temperature transmitter 76 (see Figure 3). These items can be calibrated separately
by standard means. If desired, the calibration gases can be introduced into flow loop
51 upstream of these items in order to include them in the calibration. It is also
possible to compare a value determined by the monitor to the density of a calibration
gas by manual means. Pressure, temperature, and density could be communicated by the
monitor and an operator could refer to a standard chart or tables to compare the communicated
results to the actual density of the calibration gas. Another method is to provide
apparatus in line 55 to adjust pressure and temperature of calibration gas entering
the oscillator to particular preestablished values. However, this method would be
used only in rare circumstances, since it is less costly to manipulate numbers than
to manipulate the physical condition of the calibration gases.
[0037] Partial calibrations, or operation checks, can be accomplished in a number of different
ways. Use of a calibration gas can be combined with operation checks accomplished
electronically. A totally electronic operational check can be made. For example, means
for generating appropriate oscillating tones can be provided at microphones 66 (Figures
2,3,4) and 82 (Figure 4) so that new values of Kland K
2 can be calculated. Of course, this procedure checks only the electronics and not
the oscillator. In another simple check, tuning forks are used to generate tones at
microphones 66 and 82 and the synthetic "value" resulting from the tone inputs is
compared to the expected proper value in computing means. Operational checks can be
performed by switchingflow form one oscillator to the other in the embodiment of Figure
4. Temperature changes can be used to perform operational checks. This can be done
by using heating means, such as electrical resistance coils, to heat gas flowing into
the oscillators and comparing values of properties for heated and unheated gas. If
the gas used in the check is from a changing process source, provision must be made
to prevent changes during the checking period. This can be accomplished by providing
a container to collect a sufficient quantity of gas to do the check or recycling gas
from the outlet of the oscillators back through the system Given a particular objective
to be accomplished, other checks will become apparent.
[0038] An assembly of electronics devices for processing signals from the transmitters and
microphones (variables) and providing signals to the display unit can be fabricated
from standard components by one skilled in the art. FIGURE 5 shows one such design
in simplified form. Line 19 indicates which items are located in the field and which
are located in the control room. For ease of understanding, FigureS is drawn for the
cases in which only one oscillator is used. It can easily be seen that certain items
would need to be duplicated so data relating to two oscillators can be provided to
the computing means. Though the following description mentions only oscillators 56
and associated items, operation of oscillator 78 (Figure 4) and associated items is
the same as for oscillators 56. A signal from microphone 66 is provided to amplifier
1, passed through filter 2, and converted to a -square wave pulse in square wave shaper
3. The output of square wave shaper 3 is provided to counter 6 by means of transmitter
4 and receiver 5. Counter 6 counts the number of cycles occurring in oscillator 56
in a unit of time, thus generating frequency information. The signals from pressure
transmitter 61 and temperature transmitter 67 are selected one at a time by analog
switching device 7 and sent sequentially to analog-to-digital converter 8, where they
are converted to digital form. Serial input/output device 9 converts the output of
analog-to-digital converter 8 to a serial pulse train, which is provided by means
of transmitter 10 and receiver 11 to serial input/output device 12, located in the
control room.
[0039] Memory device 15, a random access memory chip (RAM), is used to store the variables.
A program for control of the electronics devices and performing computations is stored
in memory device 14, a programmable read-only memory chip (PROM). Constants needed
for the computation are stored in memory device 16, an electronically erasable programmable
read-only memory chip (EEPROM). Central processing unit 13 performs the necessary
computations and provide output signals to display unit 70 (Figures 2, 3,4). Input
switches 18 are used to provide human input to the electronic components. These are
rotary click-stop switches which can be set to any digit from 0 to 9. One of the switches
is the mode switch and the others are used to enter numerical values. The position
of the mode switch "instructs" the apparatus what to do. In the calculate mode, the
apparatus displays the humidity of a sample. When the mode switch is placed in the
"constant load" position, numerical values of constants can be manually set on the
other switches and loaded into the system by depressing a button. Another position
of the mode switch allows values of variables to be displayed in sequence on display
70. When it is desired to calibrate the apparatus, still other positions are used.
Additional positions are used as required. Parallel input/output device 17 provides
a means of transmitting information from input switches 18 and also controlling counter
6. It will be clear to one skilled in the art that certain of the electronics devices
may be collectively referred to as a computer or computing means or may be contained
within a computer or computing means.
[0040] The basic equation used in the practice of this invention which describes the operation
of a fluidic oscillator is

where
M = molecular weight of the gas flowing through oscillator,
G = specific heat ratio of the gas flowing through oscillator,
T = temperature of the gas flowing through oscillator,
F = frequency of oscillator output signal, and
K1 and K2 = constants.
[0041] The quantity 6 can be provided as a constant stored in computer memory or can be
calculated by means of a correlation, such as the eauation

where K
3, K
4, K
5 and K
6 are constants.
[0042] The computer is programmed to solve these equations for each oscillator, using values
of F and T provided as described above, and values of constants which exist in computer
memory. It can be readily seen that these molecular weights can be used to obtain
the moisture content of the sample by means of the equations

where
X = weight fraction,
Xw = X of water present in the sample,
Xb = X of all components of the sample other than water,
Ms = M of the sample before water content adjustment,
Mb = M of the sample components other than water (average), and
Mw = M of water.
Ms is calculated by means of the basic equation applied to data from oscillator 56 and
Mb is derived from data from oscillator 78 in the same manner. Thus there are two equations
and two unknowns, so Xw can be calculated in the computer.
[0043] The heating value of the gas can be calculated by use of an equation such as

where C
1 and C
2 are constants and H = heating value.
[0044] The computer is programmed to solve these equations to obtain H, using values of
F and T provided as described above, and values of constants which exist in computer
memory.
[0045] The density of the gas can be calculated by use of the equation

where
D = density,
m = mass,
V = volume,
P1 = pressure at the point of density measurement,
T1 = temperature at the point of density measurement,
Z = compressibility factor, and
R = universal gas constant.
[0046] This equation is derived from the familiar equation of state

where n = number of moles. Z can be easily expressed by means of equations which depend
on M and data available in the literature, as explained herein.
[0047] The computer is programmed to solve these equations to obtain D, using values of
F, T, T,, and P
1 provided as described above, and values of constants which exist in computer memory.
[0048] The equation for G used in the prototype unit was developed by a standard curve-fitting
method using values of G available in the literature for gases such as methane, ethane,
etc. As can be appreciated by those skilled in the art, there are other ways to develop
and express G and to store it in the computer. The most appropriate method is dependent
on the particular application.
[0049] An approach to developing a basic oscillator equation on a theoretical basis is as
follows. Reference is made to Figure 1 as an example. A pressure pulse which passes
through delay line 103 or 104, described above, travels at the local speed of sound,
u. Denoting the length of each delay line as L, the time required for the pulse to
traverse a delay line is L/u. The time for a complete cycle of oscillation includes
that required for a pulse to travel through each delay line. An equation for the local
speed of sound is

where
u = speed of sound,
g = gravitational constant, and
R = universal gas constant.
Thus the time required for the pulse to traverse the two delay lines is 2 L/u or

As explained above, the total time for a cycle of oscillation also depends on switching
time, the time required for switching of the stream from one attachment wall to another,
or the period between arrival of a pulse propagated through a delay line at nozzle
109 and the start of a pulse through the other delay line. Switching time can be expressed
as inversely proportional to u, that is as

Since L is a constant for any given oscillator and the inverse of time is frequency,
the following equation can be written

Solving the equation for M and making g, L, and R a part of the constant, the equation
becomes

If the above constant is designated as K
1, and K
2 is added to the right-hand side, the basic equation presented above is obtained.
It has been found necessary to add the constant K
2 to the equation in order to accurately describe the oscillator. It is not possible
to use a purely theoretical equation, in part as a result of the imperfections of
hardware and measuring equipment. For example, no two fluidic oscillators will perform
in an identical manner. In a particular oscillator, which was used in a natural gas
application, K
l and K
2 were empirically established by flowing gases such as methane, ethane, propane, butane,
and pentane through the monitor. The values of K
1 and K
2 thus established were 7.538 x 10
6 and 1.58, respectively. This calibration procedure must be followed for each monitor
which is fabricated, using gases similar to the gas for which the monitor is to be
used. However, only two calibration gases are required to define K
1 and K2.
[0050] The compressibility factor, Z, from the equation of state to calculate density, is
a measure of the deviation of the sample gas from ideality and is added to the expression
commonly known as the ideal gas law in order to make the ideal gas law applicable
to real gases. Since compressibility factors are covered by a vast quantity of literature
which includes a number of different methods of computing them, there is no need to
explain the basic theory herein. For further information and references to the literature,
refer to Basic Principles and Calculations in Chemical Engineering, 2nd edition, 1967,
Prentice-Hall, Inc., by Himmelblau, p. 149 and following. Also useful are Chemical
Process Principles, 2nd edition, 1954, John Wiley & Sons, by Hougen et al, p. 87,
and Perry's Chemical Engineers' Handbook, 4th edition, McGraw-Hill, p. 4-49.
[0051] In the prototype device, Z is calculated by means of the equation

where

for M between 16 and 21.75, or

for M between 21.76 and 27.55, and
[0052] Z
B = 0.999287 + 9.25222 x 10-
5 M - 1.06605 x 10-
5 M
2, where
Zg = Z at particular base conditions,
S = supercompressibility factor,
P1 = pounds per square inch gauge (P1x0.07 kg/cm2 gauge), and
T1 = oR.
The equations for S are empirically derived. These and the equation for Z can be found
in Principles and Practices of Flow Meter Engineering, 9th edition, 1967, by Spink,
published by Foxboro Co. and Plimpton Press of Norwood, Massachusetts. The expression
for Z
B was derived by means of correlating values of Zg for gases of different molecular
weights. This was done by converting values of base temperatures and pressures for
various gases, using criticaT temperatures and pressures obtained from the literature,
to reduced pressure and temperature and then using charts prepared by Nelson and Obert
to obtain Z
B.
[0053] The equation for heating value'presented above can be found in Report No. 5 of the
Transmission Measurement Committee of the American Gas Association (Arlington, Virginia,
Catalog No. XQ 0776). When H is expressed in BTU per standard cubic feet of gas, C
1 = 54.257 and C
2 = 144. If it is desired to express H in BTU per pound of fuel gas, Report No. 5 indicates
that C
1 and C
2 assume different values and 1/M is substituted for M. Of course, it is possible to
use other correlations for calculating H of natural gas in the practice of this invention.
And a different correlation is needed for determining H of substances other than hydrocarbons
having one to approximately six carbon atoms. This correlation would likely be developed
by empirical methods.
[0054] It is possible to present information derived from the practice of this invention
in several different forms. For example, H may be provided in metric units by appropriately
programming the computer or the Wobbe Index of the sample gas may be presented. Wobbe
Index is a parameter used in the gas industry. One method of expressing it is

where k = the square root of the molecular weight of air.
[0055] The sample gas may contain compounds which are non-combustible. The concentrations
and molecular weights of these compounds must be provided to the computer in order
to produce an accurate heating value. This may be done by means of an analyzer through
which the sample gas is passed and which is arranged to automatically provide appropriate
signals to the computer. A variety of analyzer apparatus is available for use, such
as a gas chromatograph. Alternatively, average values of concentrations and molecular
weights of the non-combustible components may be manually entered into the computer.
For example, natural gas often contains carbon dioxide and nitrogen and their concentrations
do not vary greatly from hour to hour. It will often be satisfactory to analyze for
these once a day and enter values by use of the input switches mentioned above. The
equation for H must be modified to account for these constituents which add to the
volume of gas but not the heating value. For example, if there are two non-combustible
constituents whose concentrations are expressed by volume fractions X
1 and X
2 and having molecular weights M
l and M
2, the equation presented above becomes

The derivation of this and similar forms is easily accomplished by algebraic manipulation.
[0056] In some applications it may be desirable to provide to the computer concentrations
and molecular weights of combustible constituents in the same manner as non-combustible
constituents in order to improve accuracy. The equation used to calculate H can easily
be modified for these applications. An example is the measurement of heating value
of off-gas from a hydrogen-producing hydrogen recycle process, such as catalytic reforming
or dehydrogenation. For background in this area, U.S. Patent No. 3,974,064 (Bajek
et al.) may be consulted. The off-gas is often used in whole or part as a fuel. It
is comprised of both hydrogen and various hydrocarbon compounds. Since the heating
value of hydrogen is not accurately represented by many correlations used for hydrocarbons,
it can be seen that use of exact hydrogen concentrations and a correlation for hydrocarbons
yields greater accuracy than use of a correlation which accounts for both hydrogen
and hydrocarbons. Also, because hydrogen concentration in hydrogen recycle processes
is often measured for other purposes, the improvement in accuracy may be available
without purchase of another analyzer.
[0057] Use of a heating value monitor.in control of a combustion zone may be highly desirable
or necessary to achieve acceptable control. Consider a process in which temperature
in a furnace must be maintained in a relatively narrow range. A typical control arrangement
is to measure furnace temperature and adjust fuel flow to maintain it constant. When
the amount of heat absorbed by the process increases, the temperature drops and more
fuel is burned to increase temperature to the proper value. Also, changes in fuel
heating value will cause furnace temperature changes for which the control system
must compensate. Since the performance of a control system degrades as the number
of factors for which it must compensate increases, it is desirable to eliminate fluctuations
in temperature resulting from changes in fuel heating value. This can be accomplished
by measuring fuel flow and heating value, establishing a signal representative of
their product, and adjusting fuel flow by reference to this product. The product is
representative of rate of heat flow to the process. The rate of heat flow is adjusted
with reference to process temperature. Expressing the system in terms of standard
analog control apparatus, a temperature controller receiving a signal representative
of furnace temperature would supply the set point, in cascade fashion, to a controller
which receives a signal representative of the heat content of the fuel and adjusts
the fuel flow control valve.
[0058] A heating value monitor may be applied to improve fuel economy. Consider a combustion
zone where fuel flow is adjusted to maintain a constant zone temperature. Combustion
air flow rate is normally established by measuring fuel flow and combining a signal
representative of fuel flow with a previously established ratio value to obtain a
signal used to adjust air rate. This control method is incapable of responding to
changes in fuel heating value, so normal practice is to set up the system so that
excess air is supplied to the combustion zone. Excess air is that quantity of air
which is not needed to combine with the fuel. It is desirable to keep excess air at
a minimum as the amount of fuel used to heat it represents a total loss. As the fuel
heating value increases, more combustion air is required. If insufficient combustion
air is supplied, fuel is wasted as a result of incomplete combustion. A signal representative
of fuel gas heating value can be used to adjust air flow rate, usually by means of
adjusting the ratio value, so that the excess air quantity is small, thus saving fuel
for heating unneeded air and avoiding use of extra fuel.
[0059] In the simple examples above, reference is made to objectives of close control, or
control in a narrow range, and control to improve fuel economy. Of course, these objectives
are not mutually exclusive. Control systems can be designed to achieve both objectives
by adjusting both fuel and air flows. These systems may utilize standard analog control
instrumentation or more sophisticated apparatus, such as that incorporating digital
computing devices. Further, there are other objectives, such as mentioned herein,
which may need to be achieved in control of a particular combustion zone. While it
is not possible to present herein all of the variations in objectives and methods
of achieving same, the usefulness of the present invention in doing so will be seen
by those skilled in the art upon consideration of particular situations.
[0060] FIGURE 2 shows an embodiment of the invention where a continuous flow of sample through
the oscillator is established in order to obtain a continuous heating value for gas
flowing in a process pipeline. An embodiment of the invention for use in a laboratory
would not require the flow loop shown in FIGURE 2. Sample can be collected in an evacuated
pressure-resistant container, commonly called a sample bomb, which is then connected
to sample line 55. In applications where the heating values of liquids are to be determined,
a means for vaporizing the liquids is required. This can be accomplished, for example,
by use of electric resistance heating elements surrounding a portion of conduit through
which the sample passes. The term "gas" is frequently used herein; it should be understood
to include vapors resulting from fuels which are initially in liquid form. For example,
it may be desired to determine the heating value of a sample of No. 2 fuel oil, which
is liquid at normal ambient temperatures.
[0061] In a relatively simple embodiment of the invention, the sample loop shown in Figure
3 omitted. Sample is collected-in an evacuated pressure-resistant container, which
is then connected to sample line 55, either upstream or downstream of filter 57. The
density communicated by the apparatus is that at the temperature and the pressure
measured by pressure transmitter 61 and temperature transmitter 67. There is no need
to divide the electronics into two packages at two different locations. This embodiment
might be used in a laboratory. It might be desired to add to this embodiment the feature
that the apparatus is capable of calculating a density value for sample gas at pressures
and temperatures different from those measured by transmitters 61 and 67 and which
are provided to the apparatus as follows. A temperature and a pressure can be manually
entered into the apparatus by means such as input switches 18 or they can be provided
by apparatus which measures temperature and pressure at some point of interest and
transmits appropriate signals to the computing means of the invention.
[0062] Figure 3 shows a more complex embodiment of the invention where a continuous flow
of sample through the oscillator (at temperature T) is established in order to obtain
a continuous density value for gas flowing in a process pipeline (at temperature T
1 and pressure Pi). In this embodiment, the apparatus is arranged to provide a density
representative of the sample gas at a point upstream of the pressure controlling means
represented by item 58 of Figure 3 further arranged so that the upstream point is
representative of the main stream from which the sample is taken.
[0063] As noted earlier, a variation in the pressure at which gas passes through the oscillator
may affect the accuracy of the monitor. This is true even though the pressure is a
variable used in calculating density; that is, a calculated density value may be incorrect
if the pressure value used in the calculation is correct but outside a particular
range. Therefore, it is desirable to monitor the pressure and communicate any departure
from a previously established range. This can be accomplished by several means, including
adding a primary sensor, such as a pressure switch, in the appropriate location, such
as line 55 of Figure 3, or adding the appropriate means in the electronics portion
of the apparatus to utilize the pressure signal provided for use in the equation,
such as the signal transmitted by pressure transmitter 61 of Figure 3. This monitoring
provision is not depicted in Figure 3.
[0064] The present invention may be embodied in apparatus for determining the mass flow
rate of gas in a pipeline. This can be done by combining apparatus such as that shown
in Figure 3 with apparatus for measuring the volumetric flow rate of the gas in the
pipeline and multiplying density times volumetric flow rate in apparatus such as the
computing means of Figure 3. If the apparatus for measuring volumetric flow rate comprises
a calibrated obstruction to flow, such as an orifice plate, and means to measure the
pressure drop across the obstruction, such as a differential pressure cell, the pressure
drop can be provided to the computing means for calculation of mass flow rate instead
of calculating the volumetric rate outside the computing means.
[0065] An alternative to the use of dryer 80 of Figure 4 is to use apparatus to saturate
the sample portion passing through oscillator 78.- This apparatus is readily available.
For example, saturating apparatus may comprise a small chamber into which a fine spray
of water is introduced through a nozzle. After gas passes through this saturating
chamber, it is passed through another chamber for removal of any water droplets which
might exist in the stream. The equations used in practicing this embodiment of the
invention are similar to those presented above. An example is as follows. For the
oscillator through which sample is flowing before adjustment of water content

For the oscillator through which saturated sample is flowing

Previously undefined terms are
Ma = M of sample after saturation,
Xaw = X of.water in sample after saturation,
Xab = X of all components of the sample other than water after saturation.
It can be seen that there are five unknowns and only four equations, so that it is
necessary to know one more quantity when practicing this embodiment of the invention
than when using drying apparatus as described above. However, this information is
often available. Equations for other cases can easily be written.
[0066] Figure 4 shows an embodiment of the invention when a continuous flow of sample through
the oscillators is established-in order to obtain a continuous humidity value for
gas flowing in a pipeline. An embodiment of the invention for use in a laboratory
would not require the sample loop shown in Figure 4. Sample could be collected in
an evacuated pressure-resistant container, commonly called a sample bomb, which is
then connected to sample line 55. In applications where the moisture contents of liquids
are to be determined, a means for vaporizing the liquids is required. This can be
accomplished, for example, by use of electric resistance heating elements surrounding
a portion of the conduit through which the sample passes. The term "gas" is frequently
used herein; it should be understood to include vapors resulting from substances which
are initially in liquid form.
[0067] In the parallel flow arrangement shown in Figure 4, the sample is split into two
portions and each portion is passed through a different oscillator. The water content
of one of the portions is adjusted before passage through the oscillator and the humidity
of the sample is calculated by reference to differences in signals obtained from the
transmitters associated with each oscillator. An alternate flow arrangement involves
series flow, where the entire sample is passed through one oscillator and then through
another. The means for moisture adjustment is located such that the sample passes
through the first oscillator, has its moisture content adjusted, and then passes through
the second oscillator.. This can easily be visualized by altering Figure 4 so that
sample line 77 connects to vent line 71 instead of sample line 55; thus the flow sequence
would be oscillator 56 to dryer 80 to oscillator 78. In this embodiment of the invention,
the moisture content of the sample is calculated in the same manner, that is, by reference
to the differences at each oscillator. However, it should be noted that when a continuous
flow of sample is provided, a rapidly changing sample humidity could result in inaccuracies,
since there is a time lag between measurement of a "particle" of sample in the first
oscillator and measurement of the same moisture-adjusted "particle" in the second
oscillator. Compensation for this time lag can easily be accomplished in the electronics
portion of a monitor to remove any inaccuracy. One of the methods of compensating
involves simply placing the same time lag in the signal path associated with the appropriate
oscillator just before the signal differences are noted.
[0068] In another embodiment of the invention, only one oscillator is used. Means for adjusting
the water content of the sample are provided along with means for periodically bypassing
the sample flow around the water content adjustment means. For example, if a dryer
is used, the stream continuously passing through the oscillator alternately contains
water and does not contain water. This can be easily visualized by altering Figure
4 to eliminate the sample line branch for oscillator 56, placing a three-way valve
in sample line 77 just ahead of dryer 80, and placing a length of conduit between
the valve and sample line 77 just downstream of dryer 80; then the three-way valve
is periodically cycled to route sample flow "around" dryer 80. The moisture content
of the sample is calculated by reference to differences in signals received from the
transmitters associated with the oscillator for each condition, that is, when dried
sample is flowing and when non-dried sample is flowing. The same time lag problem
as noted above exists when the sample humidity is rapidly changing. Compensation can
be accomplished in the same manner.
[0069] The use of the examples set forth herein is not intended to be exhaustive and further
applications of the principles of the invention will occur to those skilled in the
art. Mixtures of gases not including water can be analyzed by applications of the
principles of this invention. The term "gas" is frequently used herein; it should
be understood to include vapors.
1. Apparatus for determining an unknown property of a sample of gas characterised
by (a) a fluidic oscillator (56); (b) means (55) for establishing flow of the sample
through said oscillator (56); (c) means (59) for measuring or controlling the pressure
at which the sample passes through said oscillator (56) and means (61) for providing
a signal representative of the pressure when pressure is not controlled in a previously
established range; (d) means (67) for measuring the temperature of the sample at said
oscillator and for providing a signal representative of the temperature; (e) means
(66) for measuring the frequency of oscillation at said oscillator and for providing
a signal representative of the frequency; (f) computing means (68, 69) for reading
said signals and for calculating the unknown property of the sample using equations
and data stored in said computing means and data supplied by said means (67, 66) for
providing temperature and frequency signals and by said means (61) for providing a
pressure signal when pressure is not controlled in a previously established range;
and (g) means (70) for communicating information contained in said computing means.
2. The apparatus of claim 1, characterised in that means (64, 65) is provided for
establishing a flow of one or more calibration gases, in sequence, through said oscillator
(56) and means for adjusting the apparatus so that the property calculated by the
apparatus for the calibration gases is substantially identical to the known property
of the calibration gases.
3. The apparatus of claim 1 or claim 2, characterised in that means (71)is provided
for establishing a continuous flow of sample through said oscillator.
4. The apparatus of any preceding claim, characterised in that a flow loop (51) is
provided which is comprised of an inlet connection and an outlet connection communicating
by means of a first conduit, in that the inlet and outlet connections are connected
to a process pipeline (50) so that process fluid can flow continuously through the
flow loop, and in that a second conduit (55) is provided through which the sample
can flow continuously from the flow loop to the oscillator (56).
5. The apparatus of claim 1, characterised in that means for vaporizing a sample in
liquid form is provided to create a gaseous sample.
6. The apparatus of claim 1, characterised in that means (59) for monitoring the pressure
of the sample flowing through said oscillator (56) and communicating any departure
of the pressure from a previously established pressure range, is provided.
7. The apparatus of claim 1,characterised in that the unknown property is heating
value and in that component (c) is a means for controlling pressure of the sample
in a previously established range.
8: The apparatus of claim 1,characterised in that the unknown property is density
and in that component (c) is a means for measuring the pressure and for providing
a pressure signal to said computing means.
9. The apparatus of claim 8, characterised in thdt means for providing values of pressure
and temperature to said computing means and calculating a density value for sample
gas at the provided values of pressure and temperature is provided.
10. The apparatus of claim 8, characterised in that means is provided for measuring
and transmitting the pressure and temperature of the sample at a point upstream of
said pressure controlling means to said computing means and calculating a density
value for sample gas at said upstream point.
11. The apparatus of claim 8, further characterised in that said upstream point is
located such that the measured pressure and temperature are representative of the
main stream from which the sample is taken.
12. The apparatus of claim 1, characterised in that the unknown property is moisture
content, in that component (c) is a means for controlling pressure of the sample in
a previously established range and in that the apparatus includes means for adjusting
the water content of the gas sample before it passes through said oscillator and means
for periodically by-passing flow of the sample around the water content adjustment
means and for providing a signal to said computing means that the water content adjustment
means is being by-passed.
13. The apparatus of claim 1, characterised in that the unknown property is moisture
content, in that component (c) is a means for controlling pressure of the sample in
a previously established range and in that the apparatus includes a second fluidic
oscillator (78) with means essentially identical to that of the first-mentioned fluidic
oscillator (56) and means for adjusting the water content of the gas sample before
it passes through said second oscillator (78).
14. The apparatus of claim 13 further characterised in that said oscillators (56,
78) are arranged in series, so that the sample flows initially through said first
oscillator and then through said second oscillator, and in that said means for adjusting
water content act upon the sample before it passes through said second oscillator,
but after it passes through said first oscillator.
15. The apparatus of claim 13 further characterised in that said oscillators (56,
78) are arranged in parallel, such that a first portion of the sample passes through
said first oscillator and a second portion of the sample passes through said second
oscillator, and in that said means for adjusting water content act only upon the second
portion.
16. The apparatus of claim 12 or 13 further characterised in that said means for adjusting
water content removes substantially all water from gas passing through said means.
17. The apparatus of claim 12 or 13 further characterised in that said means for adjusting
water content substantially saturates gas passing through said means.