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(11) | EP 0 120 533 B1 |
| (12) | EUROPEAN PATENT SPECIFICATION |
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| (54) |
Aqueous alkaline liquid detergent composition Wässrige alkalische flüssige Waschmittelzusammensetzung Composition détergente aqueuse alcaline liquide |
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| Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention). |
[0001] The invention relates to built liquid detergent compositions. More in particular the invention relates to aqueous alkaline built liquid detergent compositions with improved rheologic properties.
[0002] Aqueous alkaline built liquid detergent compositions for use in fabric- or dishwashing machines are well known. They are often considered to be more convenient to the user than the equivalent dry powdered or particulate products, as they are easier to dose, dissolve more readily, are non-dusting and usually occupy less storage space. Their formulation, however, is difficult since, on the one hand, considerable quantities of builder salts and alkaline agents should be incorporated to provide consumer-satisfactory detergency and, on the other hand, liquid products should be stable under a wide range of storage conditions and should have good pourability for consumer convenience.
[0003] In the prior art the problem of incorporating adequate quantities of e.g. inorganic builder salts in a liquid detergent has been approached by providing liquid suspending media, which are able to support the undissolved part of the builder salt in the liquid in a semi-permanent way.
[0004] In US―A―4,226,736 a dishwashing detergent composition in the form of a gel is disclosed, comprising a nonionic surfactant, an alkaline agent, a builder and carboxy methylcellulose as a structuring polymeric agent.
[0005] In US-A-3,060,124 similar detergent compositions in the form of gels are described, which are stabilized by means of cross-linked polyelectrolytes.
[0006] Although by internal or external structuring it has been possible to formulate liquid media capable of suspending adequate amounts of such undissolved or less soluble builders, hitherto it has proved difficult to formulate compositions of high alkanility, which results from the use of alkaline builder salts or alkaline agents, such as silicates or sodium hydroxide, without a very negative effect on the viscosity behaviour and physical or chemical stability.
[0007] Accordingly it is an object of the invention to provide stable suspending built liquid detergent compositions of high alkalinity, which have a good pourability and viscosity behaviour.
[0008] It is a further object of the present invention to provide such compositions in which the surface-active system is primarily based on nonionic detergents.
[0009] In the German Patent Application No. 3.006.333 such alkaline liquid detergent composition is disclosed comprising a nonionic detergent and a suspending system on the basis of a combination of sodium polyacrylate and modified polyacrylic acid. It was observed that compositions formulated according to the above disclosure without careful selection of the nonionic detergent in general showed unacceptably high viscosity and therefore poor pourability.
[0010] It has now been found that a highly alkaline liquid detergent composition can be formulated which comprises considerable levels of detergency builders and alkaline agents, comprising an alkoxylated fatty alcohol nonionic detergent or mixture of such nonionic detergents having an overall ratio between the number of ethylene-oxide units and propylene- and/or butylene oxide units of greater than 0 and less than 9, and essentially one single type of structuring agent selected from the class of the cross-linked polyacrylates.
[0011] By way of the invention compositions are obtained which combine the advantages of high alkalinity, stability, good viscosity and pourability and easy formulating.
[0012] Accordingly, the present invention provides an alkaline built liquid detergent composition which comprises in an aqueous medium:
a) at least 2% by weight of an ethoxylated and propoxylated and/or butoxylated fatty alcohol nonionic detergent or mixture thereof whereby the overall ratio in the alkylene oxide radical between the number of ethylene-oxide units and the number of propylene- and/or butylene-oxide units is from greater than 0 to less than 9;
b) from 0 to 5% by weight of an anionic surfactant;
c) from 2 to 30% by weight of an alkaline agent;
d) from 5 to 35% by weight of a detergency builder; and
e) from 0.1 to 1.0% by weight of essentially one single type of structuring agent selected from the class of the cross-linked polyacrylates, the composition having a pH value of 11 or above and a viscosity of from 0.3 to 3.0 Pa - s at 20°C and 20 S-1.
[0013] An essential feature of the present invention is the specific selection of the nonionic detergent, which is of the fatty alcohol type being condensed with a mixture of ethylene-oxide and propylene-oxide and/or butylene-oxide. It is necessary to select the alkoxylated fatty alcohol or mixture thereof such that the overall ratio between the number of ethylene-oxide units and the number of propylene- and/or butylene-oxide units is from greater than 0 to less than 9, preferably less than 2.5 or even 1.8. The term "overall ratio" refers to the fact that either a single alkoxylated alcohol may be used having in its alkylene-oxide radical a suitable ratio of ethylene-oxide to propylene- and/or butylene-oxide units or a mixture of alkoxylated alcohols may be used having a suitable ratio only on an average.
[0014] The nonionic detergent is present in an amount of at least 2% and in particular of at least 5% by weight, the amount preferably ranging from 5 to 15% by weight of the total composition.
[0015] Nonionic detergents for use in compositions of the present invention can be readily obtained commercially, such as e.g. those sold under the trade names Lutensol LF 400 to 1300 (ex BASF AG) and Plurafac RA 30 to 343 (ex Produits Chimiques Ugine-Kuhlmann).
[0016] The nonionic detergent can be used as sole detergent but other detergent-active ingredients, such as e.g. the water-soluble anionic sulphate or sulphonate detergents, can be tolerated provided their amount does not exceed 5% by weight, preferably 3% by weight or even 1% by weight of the total composition.
[0017] The alkaline agent is present in an amount of from 2% to 30% by weight, preferably 10 to 25% by weight of the total composition. Examples of suitable agents are the alkalimetal hydroxides and silicates, such as alkalimetal orthosilicates, metasilicates and disilicates, sodium metasilicate being preferred. Also mixtures of alkaline agents may be used, such as a combination of sodium silicate and sodium hydroxide.
[0018] The compositions of the invention contain 5% to 35%, in particular 10% to 30% and preferably 10% to 25% by weight of a detergency builder. Typical examples of suitable detergency builders are the phosphate builders such as the alkalimetal salts of triphosphoric acid, pyrophosphoric acid, orthophosphoric acid, polymetaphosphoric acid and mixtures thereof. Sodium and potassium triphosphates are preferred. Other suitable builders include carbonates, zeolites and organic builders such as citrates and polycarboxylates such as nitrilotriacetate, and mixtures thereof.
[0019] The present compositions are externally structured and for this purpose they contain essentially one single type of structuring or thickening polymeric agent selected from the class of the cross-linked polyacrylates. Suitable agents are alkali-stable polymers. Especially suitable are the water-soluble polymers of acrylic acid, cross-linked with about 1% of a polyallyl ether of sucrose having an average of about 5.8 allyl groups for each sucrose molecule, the polymer having a molecular weight in excess of 1.000.000. Examples of such polymers are Carbopol 934, 940 and 941. Carbopol is the Registered Trademark of B.F. Goodrich Co. Ltd., the manufacturers of these polymers. The preferred polymer is Carbopol 941. Depending on the viscosity which is desired they are included in the range of from 0.1 % to 1 % by weight, but preferably their amount varies from 0.2% to 0.8% by weight, and in particular from 0.2 to 0.6% by weight of the total composition.
[0020] The liquid detergent compositions of the invention may further contain any of the adjuvants normally used in fabric-washing detergent compositions, e.g. sequestering agents such as ethylenediaminetetraacetate and diethylenetetraamine methylene phosphoric acid; soil-suspending and anti-redeposition agents such as carboxymethylcellulose, polyvinylpyrrolidone and the maleic anhydride/vinylmethylether copolymer; fluorescent agents; hydrotropes; conditioning agents; lather boosters; perfumes, germicides and colourants.
[0021] Further the addition of lather-depressors such as liquid polysiloxane anti-foam compounds; alkaline stable enzymes; bleaches, such as e.g. sodium sulphite, and potassium dichlorocyanurate, may be necessary or desirable to formulate a complete heavy-duty detergent composition suitable for use in machine washing operations. These ingredients can be employed in the liquid detergent without the risk of undue decomposition during storage, especially if a proper protective coating is applied.
[0022] Compositions of the present invention have viscosities within the range of 0.3 to 3.0 Pa - s (at 20°C and 20 S-1), in particular within the range of 0.5 to 3.0 Pa - s and preferably within the range of 0.6―1.2 Pa - s.
[0023] Compositions of the present invention have pH-values within the high alkaline region, equal to or above 11, but preferred are pH-values above 12 or even above 13.
[0024] The invention will be further illustrated in the following examples. All percentages used therein are by weight unless otherwise specified.
Examples 1-5
a) at least 2% by weight of an ethoxylated and propoxylated and/or butyoxylated fatty alcohol nonionic detergent or mixture thereof whereby the overall ratio in the alkylene oxide radical between the number of ethylene-oxide units and the number of propylene- and/or butylene-oxide units is from greater than 0 to less than 9;
b) from 0 to 5% by weight of an anionic surfactant;
c) from 2 to 30% by weight of an alkaline agent;
d) from 5 to 35% by weight of a detergency builder; and
e) from 0.1 to 1.0% by weight of essentially one single type of structuring agent selected from the class of the cross-linked polyacrylates, the composition having a pH value of 11 or above and a viscosity of from 0.3 to 3.0 Pa - s at 20°C and 20 s-1.
a) mindestens 2 Gew.-% eines ethoxylierten und propoxylierten und/oder butoxylierten Fettalkohol - nicht-ionischen Waschmittels oder einer Mischung daraus, wobei das Gesamtverhältnis zwischen der Anzahl der Ethylenoxydeinheiten und der Anzahl der Propylen- und/oder Butylenoxydeinheiten in dem Alkylenoxydrest zwischen größer als 0 und weniger als 9 liegt;
b) 0 bis 5 Gew.-% eines anionischen oberflächenaktiven Mittels;
c) 2 bis 30 Gew.% eines alkalischen Mittels;
d) 5 bis 35 Gew.-% eines Detergens - Aufbaustoffes; und
e) 0,1 bis 1,0 Gew.-% eines Strukturierungsmittels aus im wesentlichen einem einzigen Typ, ausgewählt aus der Klasse quervernetzter Polyacrylate, wobei die Zusammensetzung einen pH-Wert von 11 oder darüber aufweist und eine Viskosität von 0,3 bis 3,0 Pa . s bei 20°C und 20 S-1.
(a) au moins 2% en poids d'un détergent non ionique du type alcool gras éthoxylé et propoxylé et/ou butoxylé ou un mélange de ceux-ci, de sorte que le rapport global dans le radical oxyde d'alkylène entre le nombre de motifs d'oxyde d'éthylène et le nombre de motifs d'oxyde de propylène et/ou de butylène est supérieur à 0, mais inférieur à 9;
(b) de 0 à 5% en poids d'un surfactif anionique;
(c) de 2 à 30% en poids d'un agent alcalin;
(d) de 5 à 35% en poids d'un adjuvant de détergence; et
(e) de 0,1 à 1,0% en poids d'un agent structurant essentiellement d'un seul type choisi parmi les polyacrylates réticulés, la composition ayant un pH de 11 ou supérieure et une viscosité comprise entre 0,3 et 3,0 Pa-s s à 20°C et 20 S-1.