[0001] The present invention relates to a composite netal anchor member suitable for securing
a castable refractory to structural supporting member, such as the interior wall of
a high temperature reaction vessel.
[0002] There are many metal components, such as reaction vessels and piping, used in the
petroleum and petrochemical industries which are employed in corrosive or erosive
environments, or both, at elevated temperatures and pressures. Because such environments
are deleterious to the surfaces of metal components, the metal surfaces are generally
protected with one or more layers of refractory materials. The refractory material
is conventionally held in place by metal anchoring members which are usually butt
welded to the metal surfaces. The refractory material is then applied, usually gunned,
over the surface of the metal of sufficient thickness to cover the anchoring members.
[0003] Examples of refractory anchoring members conventionally employed can be found in
U.S. Patent No. 2,525,821, as well as the following publications:
Cut Installed Cost With Stud Welded Refractory Anchors, by H. A. Chambers, Hydrocarbon
Processing, December 1971; and Metal Anchors For Refractory Concrete by M. S. Crowley,
Ceramic Bulletin, Vol. 45 No. 7, 1966.
[0004] Although some of the conventional refractory metal anchoring members have met with
various degrees of success, all such anchoring members are subject to corrosion at
sections which are closest to the front, or hot face, of the refractory lining. That
is, the temperature at the hot face area of the lining is generally very high and
corrosive moieties of the process stream will diffuse through the refractory material
and attack the metal anchoring member. Consequently, the anchoring system is weakened,
leaving the refractory layer subject to spalling.
[0005] In accordance with the present invention, there is provided composite Y-shaped metal
anchor members for anchoring castable refractory material to a structural supporting
member. The anchor members are constructed such that their tine section, and at least
some upper portion of their shank section, are comprised of an oxide dispersion strengthened
alloy which may be butted to a lower shank section, this section comprising an austenitic
or ferritic alloy.
[0006] In one preferred embodiment of the present invention, the Y-shaped metal anchor members
are of circular cross-section and the oxide dispersion strengthened alloy is an iron,
nickel, or cobalt based alloy containing yttria as its dispersed oxide.
[0007] In other preferred embodiments of the present invention, the anchor members are employed
for securing a castable refractory to a high temperature reaction vessel or high temperature
piping.
[0008] In the drawing:
Figure 1 is a vertical, cross-section view of a typical reaction vessel embodying
the invention;
Figure 2 is a vertical plan view of a preferred embodiment of metal anchoring member
in accordance with the invention.
[0009] Referring to the drawings, particularly Figure 1, a reaction vessel generally indicated
at 10 includes an outer metal shell 12 having an inlet flange 14 and an outlet flange
16. The inner wall of the metal vessel includes a plurality of the Y-shaped metal
anchor members 22 of the present invention. The anchor members are typically butt
welded at the ends of their outer shank to the inner wall of the vessel. Contiguous
to the inner wall of the vessel and superimposed over the anchoring members is a refractory
insulating layer 18 which is of a sufficient thickness to completely cover the anchoring
members. The refractory insulating layer 18 may be comprised of any conventional castable
refractory material suitable for thermal insulation purposes. These are usually materials
having a relatively low density.
[0010] Referring more particularly to Figure 2, a composite Y-shaped metal anchor member
generally indicated at 22 includes a tine section 24 which also includes a shank section
which is butted to a lower shank section 26. The tine section 24 is comprised of an
oxide dispersion strengthened alloy based on a metal selected from iron, nickel, and
cobalt. Such alloys are dispersion strengthened by the uniform dissemination of a
relatively large number of discrete sub-micron sized refractory particles throughout
the metal matrix. The refractory particles, in this case oxides, serve to stabilize
the matrix microstructure at elevated temperatures, thereby increasing its tensile
strength and stress rupture life at elevated temperatures. These alloys, as well as
their preparation, are described in U.S. Patent No. 3,591,362 issued July 6, 1971
to Inco and incorporated herein by reference.
[0011] By employing an oxide dispersion strengthened alloy in the tine section of the anchor
members of the present invention, the anchor members will have a substantially greater
life expectancy when used for securing castable refractory materials to metal support
members when such support members are subjected to high temperature corrosive environments.
That is, the tine section being the upper
mst section of the anchor member, will be more resistant to corrosion in the event
that corrosive moieties diffuse through the protective refractory layer.
[0012] The tine section 24 of the Y-shaped composite metal anchor members of the present
invention includes a shank section comprised of the same alloy as that of the tine
section and is of course molded or machined from the same material. This tine section
is attached to a lower shank section 26 which is comprised of an austenitic or ferritic
alloy which is preferably weldable to the metal support member and which preferably
has substantially the same coefficient of expansion as the metal support member. Of
course, other suitable means for attaching the anchor members to the metal support
member may also be employed herein. Such other suitable means would include mechanical
coupling.
[0013] Any suitable conventional joining method may be used for joining the tine section
to the lower shank section of the anchors of the present invention. Nonlimiting joining
methods which may be used herein include brazing, friction welding and mechanical
coupling (threaded). Preferred is friction welding.
[0014] Non-limiting examples of refractory materials which may be used in the practice of
the present invention include various fire clays, diatomaceous earths, magnesite,
concrete, mixtures of metallic oxides and cement, diatomaceous earths and cement,
and the like. The refractory material, and water, are prepared and pressure sprayed,
gunned, or troweled into place over the anchor members and allowed to dry in situ.
Enough refractory material is applied so that the anchor members are completely covered.
Preferably, enough refractory material is applied such that the upper portion of the
tines of the anchor members are at least about 1/2 inch from the hot face surface
of the refractory layer.
[0015] Non-limiting examples of metal support members to which the composite anchoring members
of the present invention may be butted include reaction vessels, piping, furnace tube
sheets, and burner linings.
[0016] Although specific embodiments of the present invention have been shown and described
in detail to illustrate the application of the inventive principles, it will be understood
that the invention may be embodied or practised otherwise without departing from such
principles.
1. A corrosion resistant composite Y-shaped metal anchor for anchoring a castable
refractory material to a structural supporting member, in which anchor (i) the tine
section comprises an oxide dispersion strengthened alloy; and (ii) the shank section
comprises an austenitic or ferritic alloy.
2. An anchor according to claim 1 wherein the tine section comprises an iron, nickel,
or cobalt based oxide dispersion strengthened alloy and the lower shank section comprises
an austenitic alloy.
3. A method for anchoring a refractory material to a structural supporting member
comprising the steps of fastening a plurality of Y-shaped metallic anchors according
to either of claims 1 and 2 to the interior surface of the supporting member, spraying
a castable layer of refractory material onto said interior surface of sufficient thickness
to cover the metallic anchors.
4. A method according to claim 3 wherein the anchors are welded to the structural
support member.