(19)
(11) EP 0 131 355 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
29.05.1985 Bulletin 1985/22

(43) Date of publication A2:
16.01.1985 Bulletin 1985/03

(21) Application number: 84303208

(22) Date of filing: 11.05.1984
(84) Designated Contracting States:
AT BE CH DE FR GB IT LI NL SE

(30) Priority: 12.05.1983 US 493916
03.02.1984 US 576602

(71) Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
 ()

(72) Inventors:
  • Cescon, Lawrence Anthony
     ()
  • Millet, Nolan Joseph, Jr.
     ()

   


(54) Stable ammonium nitrate-emulsion explosives and emulsion for use therein


(57) Explosives that are sensitized blends of a water-in-oil emulsion and AN particles, such as AN or ANFO prills, have improved stability when their structure hinders the loss of water from the aqueous emulsion phase and transportation of such water across the oil phase to the AN particles. Use of an anionic emulsifying agent comprising a fatty acid salt, e.g., as formed in situ during the formation of the emulsion, is the preferred way of forming such a blend-stabilizing structure. Emulsion/ANFO and emulsion/AN blends stabilized in this manner make satisfactory storage-stable packaged products. Emulsion/AN blends made with a new low-viscosity emulsion containing essentially all of the oil required to oxygen-balance the blend and a proportionately larger amount of anionic emulsifying agent to stabilize the emulsion structure constitute preferred bulk products owing to their greater adaptability to pumping. Pumping the stabilized blends through an annular stream of aqueous lubricating liquid is advantageous.







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