[0001] This invention relates to electrostatic spraying. One form of electrostatic spraying
apparatus, for example for agricultural or horticultural use, comprises a portable
spray gun including a spray nozzle, means for applying a high potential to said nozzle,
and means for supplying to said nozzle the liquid to be sprayed from a container of
the liquid mounted on the spray gun. Examples of such electrostatic spraying apparatus
are described in, inter alia, US-A-4356528.
[0002] It has been proposed in USP-A-3212211 to produce the necessary high voltage for a
portable electrostatic spraying device from a low voltage power supply, e.g. batteries,
by means of a high voltage generator producing rectified high voltage pulses which
charge a capacitor connected across the generator output. The charge on the capacitor
is used to maintain the requisite potential at the spraying nozzle.
[0003] Clearly, to obtain electrostatic atomisation, the potential at the nozzle has to
be maintained at above a certain minimum voltage, but should not be so high that corona
discharge takes place. Generally, to effect electrostatic atomisation, the potential
at the nozzle will need to be in an excess of 5 k7, and often above 10 kV, although
the precise minimum value required will depend, inter alia, on the nozzle design.
The maximum voltage required is generally not more than 25 kV.
[0004] In low cost generators it is generally necessary to employ a switching system in
the generator which produces rapid changes of current in the primary of a step-up
transformer. The manitude and rapidity of the current changes in the primary determine
the magnitude and shape of the high voltage pulses: the magnitude is restricted by
the need to avoid excessive voltages at the nozzle which would give rise to corona
discharge. The rapid change of current in the transformer primary is conveniently
achieved by periodically effecting the rapid discharge of a capacitor in the primary
circuit through the transformer primary. Such rapid discharge may be effected by means
of a triggering unit connected, in series with the transformer primary, across the
primary circuit capacitor. The triggering unit is arranged to discharge the primary
circuit capacitor, via the transformer primary, typically through a thyristor or a
gas gap discharge tube, when the voltage across the primary circuit capacitor, and
hence across the triggering unit, reaches a predetermined value.
[0005] The frequency of operation of the triggering unit, and hence the frequency with which
the high voltage pulses are generated, thus depends on the rate of charging of the
primary circuit capacitor.
[0006] This rate of charging will of course depend on the capacitance of the primary circuit
capacitor and the current supplied thereto. In order to obtain high voltage pulses
of adequate magnitude to achieve the desired nozzle potential under load, the primary
circuit capacitor will generally need to have a fairly large capacitance. Consequently
to keep the current drain on the low voltage power source small, the charging rate
of the primary circuit capacitor and hence the rate of actuation of the triggering
device, and thus the frequency of the high voltage pulses must be relatively low.
[0007] As mentioned hereinbefore, the high voltage pulses are rectified and used to charge
a capacitor in the high voltage circuit to maintain the required potential at the
spray nozzle. If the capacitance of this capacitor in the high voltage circui: is
sufficient, there will be little variation of the potential at the nozzle between
pulses since the load represented by the transfer of charge at the nozzle to the liquid
to effect electrostatic atomisation, together with leakage currents, will represent
dissipation of only a small proportion of the charge on the capacitor.
[0008] However, if the capacitor has a high capacitance, the high voltage circuit will have
a high stored energy. A high stored energy is undesirable as it may present safety
hazards, for example electric shocks to the operator from accidental contact with
the nozzle. Desirably the stored energy is below 10 mJ. The stored energy is given
by

where V is the voltage and C is the capacitance. Hence to achieve a stored energy
below 10 mJ the capacitance must be below

where 7 is the voltage expressed in kilovolts, i.e. below 50 pF when the voltage
is 20 kV.
[0009] The load current, represented by the transfer of charge to the liquid at the nozzle,
required to effect atomisation is relatively small and, provided that the leakage
currents are small, it would be possible to use a high voltage circuit having a stored
energy below 10 mJ.
[0010] However, not only are capacitors capable of operation at high voltages expensive,
but, even those capacitors of the relatively low capacitance required, exhibit considerable
leakage currents at such high voltages.
[0011] At these relatively low values of capacitance the charge dissipated as a result of
the leakage currents represents a significant proportion of the charge on the capacitor
with the result that, between the pulses applied to the capacitor, the voltage at
the nozzle is liable to drop to below that required for spraying.
[0012] While this could be counteracted by increasing the frequency of the high voltage
pulses applied to the capacitor in the high voltage circuit, as explained hereinbefore,
increasing the frequency results in an increase in the current drain on the power
supply. Consequently to maintain the current drain at an acceptable level, e.g. to
give an adequate life where dry batteries are employed as the low voltage power source,
the frequency with which the pulses can be applied to the high voltage capacitor is
limited, generally to below about 50 Hz.
[0013] We have now devised an arrangement, having a low stored energy high voltage circuit,
that can be operated at a frequency that gives an acceptable current drain on the
power source.
[0014] Aacording to the present invention we provide a portable electrostatic spraying apparatus
including
(a) a spray nozzle,
(b) means to supply liquid to be sprayed to said spray nozzle,
(c) a low voltage power source,
(d) a high voltage generator powered by said low voltage power source, whereby rectified
high voltage pulses may be produced across its output,
(e) a capacitor connected to said nozzle and to one side of said generator output,
whereby said capacitor may be charged by said rectified high voltage pulses so that
said nozzle may be maintained at a sufficiently high potential, with respect to the
other side of said generator output, to cause electrostatic atomis- ation of said liquid at said nozzle,
characterised in that capacitor has a value below

, where V is the average voltage, expressed in kilovolts, that said generator is capable
of maintaining at said nozzle, and in that said capacitor is formed by the capacitance
between a lead connecting said one side of the generator output to said nozzle and
a lead connected to said other side of the generator output,
said generator being capable of producing said high voltage pulses of such magnitude
and frequency that the potential at said nozzle may be maintained at a sufficient
value to cause electrostatic atomisation of the liquid but without corona discharge.
[0015] By the use of the lead from one side of the generator output to the nozzle, in conjunction
with a second lead connected to the other side of the generator output as the capacitor,
sufficient capacitance can be obtained with negligible leakage current. The two leads
should be in sufficiently close proximity to give the requisite capacitance which
is generally within the range

to

(where V is in kV).
[0016] The capacitance is preferably within the range 10 to 50pF.
[0017] For example two separate insulated wires each having a length of about 0.5 m may
be twisted together as necessary to give the requisite capacitance. The leads may
of course be longer but spaced sufficiently far apart over some or all of their length
that the capacitance is at the requisite level. Alternatively a suitable length of
a twin core or coaxial cable may be employed.
[0018] Since a capacitor formed by two such leads will give negligible leakage current,
the leakage current between pulses will be markedly reduced, enabling sufficient potential
to be maintained at the nozzle.
[0019] As mentioned hereinbefore the average potential at the nozzle will depend on the
frequency and magnitude of the high voltage pulses applied to the capacitor: the magnitude
is restricted by the need to avoid voltages that would give rise to corona discharge.
The frequency of the pulses is typically in the range 10- 40 Bz, and preferably is
in the range 15 - 30 Hz. The requisite frequency will depend on the load applied by
the liquid being sprayed which in turn will depend on the properties, e.g. resistivity,
of the liquid and on the volumetric flow rate. The latter is preferably below 0.25,
particularly below 0.1 ml/s. A rate of 0.05 ml/s typically represents a load of less
than 100 nA.
[0020] If desired the generator may be provided with means for varying the frequency and/or
magnitude, i.e. peak voltage, of the high voltage pulses as the volumetric flow rate
is varied.
[0021] Although, as a result of using the leads from the high voltage generator to form
the capacitor, the leakage current through the capacitor is virtually eliminated,
leakage of charge from the capacitor will occur between pulses, inter alia, as a result
of the reverse leakage current of the rectifier. The rectifier reverse current may
be significant in relation to the load presented by transfer of charge to the liquid
being sprayed and will affect the minimum frequency required of the generator. We
prefer to employ as the rectifier a high voltage diode rated at a leakage current
of less than 1 µA at 37 kV at 20°C. Such a diode will have a reverse leakage current
of less than about 100 nA at 20 kV at 20°C.
[0022] The spraying apparatus preferably comprises an elongated member intended to be held
in the hand with the low voltage power supply, e.g. batteries, and high voltage generator
in one end thereof with the spray nozzle at the other end. The leads forming the high
voltage circuit capacitor thus can extend along the elongated member to connect the
nozzle to the generator.
[0023] In a preferred arrangement one lead is connected to the nozzle while the other is
connected to, or provides, an electrically conductive member adjacent to but spaced
from the nozzle. In assessing the lead capacitance, the capacitance between the nozzle
and such an electrically conductive member should be taken into account. The electrically
conductive member is preferably maintained substantially at earth potential, for example
by praciding a connection to earth from that lead via the operator. Such an earthed
electrically conductive member can then act as a fiold adjusting electrode as described
in aforementiored US-A-4356528.
[0024] In one form of the apparatus an elongated holder having the high voltage generator
and a receptacle for receipt of the low voltage power source, e.g. batteries, at one
end is provided, at the other end, with a receptacle for receipt of a canister of
the liquid to be sprayed. The nozzle may form part of the bolder or may be attached
to the canister. In the latter case meams are provided in the holder for making electrical
connection. between the lead from the one side of the high voltage generator and the
nozzle.
[0025] The apparatus is of particular utility for the spraying of liquids, such as pesticides,
polishes, and the like at low volumetric flow rates. The liquid preferably has a resistivity
of
107 to 1
0 11 ohm. cm.
[0026] The liquid may be supplied to the spray nozzle by simple gravity feed. However this
is disadvantageous in many cases since it restricts the spatial orientations of the
nozzle that can be used. This problem can be overcome by supplying the liquid to the
nozzle from a pressurised container; in particular the liquid can be supplied from
a container containing the liquid and a compressed pressurising agent.
[0027] It is preferred that the container is arranged so that the pressurising agent is
not dispensed through the nozzle with the liquid to be sprayed. In this way the atomisation
of the liquid by the electrostatic forces is not affected by the emergence of the
pressurising agent. In one preferred arrangement the container comprises a barrier
pack with the liquid to be sprayed contained within a collapsible inner container
located within the outer container with the pressurising agent fluid in the space
between the inner and outer containers.
[0028] The rate of delivery of the liquid to the spray nozzle will depend on the pressure
exerted by the pressurisiug agent (which is often a gas at ambient temperatures and
atmospheric pressure, but is liquid at the pressure prevailing within the container).
We have found that the pressure exerted by the pressurising agent is liable to considerable
fluctuation as the ambient temperature varies, with the result that the liquid supply
rate to the nozzle is also liable to considerable fluctuation: indeed over the range
of ambient temperatures liable to be encountered in use of the spray gun, particularly
where such use is outdoor, the pressure exerted by the pressurising agent, and consequently
the flow rate, may vary, in some cases, by a factor of four or more.
[0029] Variations in flow rate will affect the size, and size distribution, of the liquid
droplets formed by electo- static atomisation. Such variation in droplet size is undesirable
since for any given liquid there is an optimum droplet size, or size range, for the
intended use of the liquid.
[0030] For example, when spraying plants with a pesticide fomulation, if the droplets are
too large, the amount of "wrap-round", giving coating on the underside of plant leaves,
is reduced; whereas if the droplets are too small, they are liable to be unduly affected
by factors such as wind strength and so may drift onto plants other than those intended
and/or on to the operator.
[0031] As a further feature of the invention we have devised a way of overcoming these difficulties
by varying the nozzle potential to control the droplet size.
[0032] Accordingly the present invention further provides, in electrostatic spraying apparatus
of the type hereinbefore described for spraying a liquid as droplets from a nozzle
supplied with said liquid from a pressurised container by applying a high voltage
to said nozzle, the improvement comprising means to monitor the ambient temperature
and to vary the average voltage applied to said nozzle in response to said monitored
temperature to maintain the average droplet size within a predetermined range.
[0033] The average voltage at the spraying nozzle can be varied by variation of the amplitude,
frequency and/or shape of the high voltage pulses. Such variations can be brought
about by appropriate variation in the low voltage circuit, e.g. of the magnitude and/or
frequency of the current chaages in the transformer primary winding and/or the rate
of change thereof.
[0034] By incorporating a temperature sensitive electrical component, e.g. a thermistor,
into the spray apparatus and using the variation in the electrical properties of this
component with temperature to modify the transformer primary current changes, the
average high voltage applied to the nozzle can be varied.
[0035] The average nozzle voltages required to give a specified droplet size or size distribution
at various flow rates of a given liquid can readily be determined by experiment. Typically
for a given liquid at a given flow rate, an average voltage of 15 kV may be required
at the nozzle. If the flow rate is increased by a factor of two, the average voltage
required to obtain the same, or a similar, droplet size is typically increased to
20 k
y.
[0036] Likewise variation in pressurising agent pressure, and hence liquid flow rate, with
temperature can also be readily determined.
[0037] From this data, and from the temperature characteristics of the temperature sensitive
component, the appropriate circuitry can be devised to provide the necessary variation
in nozzle voltage to maintain the droplet size within the desired range.
[0038] The invention is illustrated by reference to the accompanying drawings wherein:
Figure 1 is an elevation of one form of the apparatus,
Figure 2 is a longitudinal section of the sprayhead part of the apparatus,
Figure 3 is a longitudinal section of the handle part of the apparatus,
Figure 4 is a cirsuit diagram,
Figure 5 shows a modification of part of the circuit depicted in Figure 4.
[0039] Referring first to Figure 1, the apparatus comprises an elongated member 1 having
a handle portion 2 incorporating a trigger 3 and a sprayhead assembly 4 comprising
a sleeve 5 in which a cartridge containing the liquid to be sprayed is inserted. The
cartridge has a mechanically actuated valve and a nozzle to which a high voltage can
be applied. When the cartridge valve is open and a high voltage is applied to the
nozzle, the liquid is electrostatically atomised as a spray through an orifice at
the lever end of the sprayhead assembly 4. To enhance the spray there is disposed
around the sleeve 5, but insulated from the nozzle, an annular conductor 6 constituting
a field intensifying electrode e.g. as described in aforementioned USP 4356528.
[0040] The shaft of the elongated member 1 comprises a casing formed by two shell mouldings
of an electrically insulating material.
[0041] Referring now to Figure 2 one of the shell mouldings is indicated by reference numeral
7. The sleeve 5 is moulded from an electrically insulating material and is of generally
cylindrical configuration. Sleeve 5 is located on the shell mouldings by means of
an integrally moulded, open-sided, box structure 8 which engages with a hollow projection
9 on moulding 7 and a corresponding projection on the other shell moulding. Sleeve
5 is provided with integrally moulded projections 10 in which one end 11 of a valve-actuating
member 12 is pivotally mounted.
[0042] Sleeve 5 is also provided with an opening 13 through its wall, through which the
other end 14 of the valve-actuating member 12 passes, and integral flanges 15, 16
which act as a guide for the end 14 of the valve-actuating member 12.
[0043] Screw mounted on the end of the sleeve 5 is a nose cone 17 having an opening 18 through
which the end of the cartridge nozzle can project.
[0044] The cartridge 19, which is shown partly in section in Figure 2, is a metal can 20
provided with a closure 21 incorporating a valve assembly, typically of the type commonly
employed in aerosol canisters.. Inside can 20 a flexible bag 22 is mounted on the
inlet 23 to the valve assembly. The liquid to be sprayed is contained within bag 22
while the space between bag 22 and the walls of the can 20 is charged with a volatile
liquid pressurising agent, e.g. a fluorocarbon such as dichlorodifluoromethane. The
cartridge 19 also has a nozzle 24 having a fine bore (not shown) extending longitudinally
therethrough. The nozzle 24 is formed integrally with a flange 25 forming part of
the valve assembly. Movement of flange 25 axially towards the base 26 of cartridge
19 effects opening of the valve to permit liquid to flow from the reservoir out of
the cartridge via the fine bore extending through nozzle 24. The bore is typically
of 1 mm diameter while the tip of the nozzle 24 is typically of hemispherical configuration
of 3 - 5 mm diameter.
[0045] Cartridge 19 is held in place by a rib 27 on a cap 28 engaging with the base 26 of
the cartridge and holding the flange 25 against the valve actuating member 12. The
cap 28 is moulded from an electrically insulating plastics material and is pivotally
mounted in a boss 29 in shell mould 7 and a corresponding boss in the other shell
mould. Cap 28 has an integral latch 30 engaging with a projection 31 moulded integrally
with sleeve 5.
[0046] Extending through an opening 32 in sleeve 5 is a spring metal contact strip 33 which
is held in place between the shell mouldings and the wall of sleeve 5. Electrically
connected, e.g. soldered, to strip 33 is a high voltage lead 34 from a generator located
in the handle portion of the apparatus. On application of a high voltage to lead 34,
the high voltage is applied, via contact strip 32, to the metal can cartridge 19 and
hence, via conduction through the cartridge and its contents, to the nozzle 24.
[0047] The valve-actuating member 12 is a moulding of an electrically insulating plastics
material of such cross section that the portion in the vicinity of nozzle 24, flange
25, and mounting 10 is relatively rigid but the free end 14 is relatively flexible.
The valve-actuating member 12 is provided with an opening 35 through which nozzle
24 projects, and projections 36 which engage with flange 25 on either side of nozzle
24. It is then seen that longitudinal movement of the free end 14 of the valve-actuating
member 12 away from mounting 10 causes flange 25 to be depressed thus opening the
valve. The free end 14 of the valve-actuating member 12 is provided with a slot 37
which engages with a hook 38 of a metal wire 39 which extends along the shaft of the
elongated member to the trigger 3.
[0048] As mentioned hereinbefore, extending round sleeve 5 is a metal wire 6 acting as a
field adjusting electrode. A flexible extension 40 of wire 6 passes through a groove
(shown dotted in Figure 2) in shell moulding 7 and is electrically connected, e.g.
soldered, to wire 39.
[0049] Wires 39 and 40 thus provide an electrical connection from the trigger 3 to the field
adjusting electrode 6 and wire 39 also provides a mechanical connection from trigger
3 to the valve actuating member 12.
[0050] The handle portion 2 of the apparatus is shown in Figure 3.
[0051] Provided within the handle portion 2 of the casing is a compartment 41 for receipt
of a series train of two dry cell batteries 42; a high voltage generator assembly
43; and a trigger assembly 44.
[0052] The generator assembly comprises a printed circuit board 45 on which are mounted
the various components shown in Figure 4 as enclosed within the dotted box. For siimplicity
these components are not shown in Figure 3. Board 45 is mounted in a moulding 46 of
electrically insulating plastics material. Also mounted in moulding 46 is an output
step-up transformer 47 which is connected to board 45 by leads 48, 49. The high voltage
output from transformer 47 is fed, via a high voltage diode 50, (not shown in Figure
3), to the high voltage lead 34 via a contact within sleeve 51 attached to transformer
47. The generator assembly 43 is located by projections 52, 53, 54 and 55 integral
with shell moulding 7 and by corresponding projections (not shown) in the other shell
moulding.
[0053] Board 45 is provided with two electrical contacts 56, 57. Contact 56 is a spring
metal strip which extends round moulding 46 to the trigger assembly 44 while contact
57 projects into the battery compartment 41 wherein it contacts the positive terminal
of the train of batteries 42. Extending the length of compartment 41 is a wire 58.
At the rear end of compartment 41, wire 58 is formed as a coil spring contact 59 which
urges the trains of batteries 42 into engagement with contaxt 57. Wire 58 also serves
to connect the negative contact of the battery train to the trigger assembly 44.
[0054] The trigger assembly 44 comprises a trigger lever 3 made of an electrically conductive
plastics material pivotably mounted on bosses 60 in the shell mouldings. The free
end of wire 58 from the battery compartment extends through a hole in lever 3 to form
a contact pin 61. Also mounted in lever 3 is a pin 62 formed from an electrically
insulating material. Pin 62 engages with the spring contact strip 56 from board 45
to hold the strip 56 out of engagement with pin 61 when the trigger lever 3 is in
the "off" position. Strip contact 56 is laterally spaced from lever 3, and hence insulated
therefrom when the trigger is in the "off" position. Rotation of lever 3 from the
"off" position causes the contact pin 61 to engage with strip contact 36 thus completing
the circuit to supply power from the batteries 42 to the generator.
[0055] Hooked round an integral extension 63 to trigger lever 3 is the connecting wire 39.
A return spring (not shown) is provided to bias lever 3 to the "off" position.
[0056] In use the operator's finger contacting trigger lever 3 provides a connection, through
the operator, to earth thus earthing the field intensifying electrode 6 and the negative
side of the battery train.
[0057] Referring now to Figure 4, the low voltage part of the high voltage generator circuit
consists of a conventional tran- sistorised saturation oscillator formed by the primary
64 of a first step-up transformer 65, resistor 66 and a transistor 67. Typically this
oscillator has a frequency of the order of 10 to 100 kHz. The secondary of transformer
65 is connected, via a diode 68, to a capacitor 69. Connected in parallel with capacitor
69 is a gas-gap discharge tube 70 connected in series with the primary of the output
step-up transformer 47. Shown dotted in the high voltage output circuit of Figure
4 is a capacitor 71. This capacitor is not a discrete component but represents the
capacitance between the high voltage lead 34, the cartridge 19, and the nozzle 24
and the adjacent "earthed" components, e.g. wires 39 and 40, and the field intensifying
electrode 6.
[0058] To ensure that the capacitor 71 has the desired value, typically 20 - 40 pF, guides
(not shown) may be provided in the shell mouldings to hold wire 39 in the desired
spatial relationship to the high voltage lead 34.
[0059] In operation the saturation oscillator gives rise to current pulses in the secondary
of transformer 65 which charge capacitor 69 via diode 68. When the voltage across
capacitor 69 reaches the striking voltage of gas-gap discharge tube 70, the latter
conducts, discharging capacitor 69 through the primary of output transformer 47, until
the voltage across the gas-gap discharge tube falls to the extinguishing voltage.
Typically the striking voltage is 150 - 250 V and the extinguishing voltage is less
than 10 V.
[0060] The discharge of capacitor 69 through the primary of transformer 47 produces high
voltage pulses in the secondary thereof: these high voltage pulses charge capacitor
71 via diode 50 and thus maintain a sufficiently high potential between nozzle 24
and the field intensifying electrode 6 for electrostatic atomisation of the liquid
from nozzle 24.
[0061] The frequency with which the high voltage pulses are produced is determined by the
value of capacitor 69, the impedance of the secondary of transformer 65 and the magnitude
and frequency of the pulses produced by the saturation oscillator.
[0062] In an example a pesticide composition of resistivity 8 x 10
7 ohm. cm was sprayed from apparatus of the type shown in Figures 1 to 4. The voltage
at nozzle 24 was about 18 kV, the liquid flow rate 1 ml/min, the frequency of the
high voltage pulses about 25 Ez. The capacitance of capacitor 71 was about 20 pF and
primarily formed by the capacitance between wires 34 and 39 which were each about
0.9 m long and spaced apart by an average of about 2 cm. The series train of batteries
42 gave a voltage of 3.1 V and the current drain thereon was about 150 mA.
[0063] In the modified circuit of Figure 5 the arrangement of the generator is modified
by the replacement of the gas-gap discharge tube 70 by a thyristor 72 and by the incorporation
of a temperature dependent triggering circuit 73, the output of which is applied to
the gate of thyristor 72.
[0064] This temperature dependent triggering circuit incorporates a temperature sensitive
component, e.g. a thermistor, and is arranged such that as the temperature increases,
thyristor 72 is triggered to conduct, thus discharging capacitor 69 through the primary
of output transformer 47, at increasing voltages across capacitor 69. Although this
results in a reduction of the frequency of discharge of capacitor 69, the rate of
transfer of energy to the high voltage circuit is increased thus giving an increased
voltage at the nozzle 24.
[0065] As the temperature increases the pressure exerted by the volatile liquid in can 20
increases, thus increasing the liquid flow rate through nozzle 24. The characteristic
of the temperature dependent triggering circuit 73 is arranged so that the voltage
at the nozzle 24 is increased, as the flow rate through nozzle 24 increases, so as
to give the desired droplet size spectrum.
1. Portable electrostatic spraying apparatus including
(a) a spray nozzle,
(b) means to supply liquid to be sprayed to said spray nozzle,
(c) a low voltage power source,
(d) a high voltage generator powered by said low voltage power source, whereby rectified
high voltage pulses may be produced across its output,
(e) a capacitor connected to said nozzle and to one side of said generator output,
whereby said capacitor may be charged by said rectified high voltage pulses so that
said nozzle may be maintained at a sufficiently high potential, with respect to the
other side of said generator output, to cause electrostatic atomisation of said liquid
at said nozzle,
characterised in that capacitor has a value below

, where V is the average voltage, expressed in kilovolts, that said generator is capable
of maintaining at said nozzle, and in that said capacitor is formed by the capacitance
between a lead connecting said one side of the generator output to said nozzle and
a lead connected to said other side of the generator output,
said generator being capable of producing said high voltage pulses of such magnitude
and frequency that the potential at said nozzle may be maintained at a sufficient
value to cause electrostatic atomisation of the liquid but without corona discharge.
2. Apparatus according to claim 1 wherein said capacitor has a value above

.
3. Apparatus according to claim 1 or claim 2 wherein said capacitor has a value between
10 and 50 pF.
4. Apparatus according to any one of claims 1 to 3 wherein said generator is capable
of maintaining a voltage between 10 and 25 kV at said nozzle.
5. Apparatus according to any one of claims 1 to 4 wherein said high voltage pulses
are rectified in said generator by a diode having a leakage current of less than 1
pA at 37 kV and 20°C.
6. Apparatus according to any one of claims 1 to 5 wherein said generator includes
a capacitor that can be discharged through the primary of a step-up transformer via
a triggering device whereby discharge of said capacitor through said primary produces
high voltage pulses in the secondary of said transformer.
7. Apparatus according to any one of claims 1 to 6 wherein said generator produces
said high voltage pulses at a frequency below 50 Hz.
8. Apparatus according to any one of claims 1 to 7 wherein an electrically conductive
member is positioned adjacent to, but spaced from. said nozzle and connected to said
other side of the generator output, and said capacitor of value below

is formed by the lead connecting said one side of the generator output to said nozzle
and the lead connecting said other side of the generator output to said electrically
conductive member.
9. Apparatus according to any one of claims 1 to 8 wherein said means to supply liquid
to said spray nozzle includes a mechanically operated valve actuated by a trigger
remote from said valve and said capacitor of value below

pF is formed by the lead connecting said one side of the generator output to said
nozzle and an electrically conductive member forming part of the mechanical connection
from said trigger to said valve, said electrically conductive member being electrically
connected to said other side of the generator output.
10. Apparatus according to any one of claims 1 to 9 wherein said means to supply liquid
to said nozzle includes a pressurised container and means are provided to monitor
the ambient temperature and to vary the average voltage applied to the nozzle in response
to said monitored temperature to maintain the average droplet size of the liquid sprayed
from said nozzle within a predetermined range.