[0001] The invention concerns the lining of containers for molten metal.
[0002] Containers for molten metal commonly comprise a metal casing lined with refractory
brickwork or a monolithic refractory lining and this lining is often termed the permanent
lining. The permanent lining is subject to damage and is expensive and time-consuming
to repair or replace. In particular, after use, a residue (skull) of solidified molten
metal and slag may adhere to the lining, and require removal before re-use of the
container, and may be difficult to remove and its removal may damage the lining.
[0003] In view of the above problems, it has been proposed to protect the permanent lining
by an inner layer or layers, which may also serve other purposes. In particular U.K.
patent specification 1477632 discloses application of two layers over the permanent
lining. The first layer is a parting layer comprising particulate carbonaceous material
e.g. coke dust and is free or substantially free of permanent binding agent. The first
layer may be applied as a liquid or paste composition by, for example, spraying or
trowelling. The second,i.e. inner, layer is of bonded particulate refractory material
and may be applied by, for example, trowelling on a coating composition. The combination
of the two layers protects the permanent lining and in particular enables clean stripping
of skull e.g. from a tundish without damage to the permanent lining. The layers are
re-applied before each re-use of the container.
[0004] According to the present invention a container for molten metal has a permanent refractory
lining, an inner, refractory lining and, in at least one place separating the permanent
and inner linings, a layer substantially consisting of heat-carbonisable sheet material.
[0005] When the container contains molten metal, sufficient heat is conducted from the metal
through the inner lining to the sheet material to carbonise the latter to yield a
carbonaceous residue. Alternatively, the inner lining may be pre-heated before molten
metal in introduced into the container and pre-heating may suffice to carbonise the
sheet material to yield a carbonaceous residue. The carbonaceous residue provides
a valuable parting layer facilitating removal of skull and the inner lining and without
damage to the permanent lining.
[0006] The heat-carbonisable sheet material may be, for example, newsprint, kraft paper,
cardboard (e.g. laminated corrugated cardboard), wallpaper, hessian, straw matting
or woven polyethylene or polypropylene.
[0007] The heat-carbonisable sheet material is flexible and this is of value in positioning
it as desired, especially if the permanent lining has irregularities at its surface
e.g. cavities or areas of adhering extraneous matter. Moreover suitable sheet materials
are available as large pieces and can easily be cut to size. Accordingly the layer
of heat-carbonisable sheet material can be provided quickly and easily. To hold the
sheet material against the permanent lining before the inner lining is applied, clips
or an adhesive can be used if desired, for example at places where the permanent lining
is generally upright and if the sheet material is very flexible e.g. newsprint rather
than less flexible e.g. cardboard. In the case of newsprint even water will provide
sufficient adhesion and in general a variety of widely available inexpensive adhesives
e.g. starch-based ones are suitable.
[0008] If the sheet material used is thin e.g. newsprint it may be desirable to use a number
of pieces of it superimposed to form the layer whereas with thicker sheet materials'
e.g. cardboard a single thickness may suffice. Preferably the thickness of the layer
is from 0.1 mm to 2 mm.
[0009] In containers for molten metal having an inner lining and a permanent lining, the
tendency for the inner lining (with adhering skull) to become fused to the permanent
lining may only be significant at certain parts of the container. For example, in
the case of tundishes the above tendency for fusion to occur is most marked at the
floor of the tundish and at the slag line i.e. the usual level of slag on the top
surface of the molten metal in the tundish. Accordingly, in a container according
to the invention the heat-carbonisable sheet material may be provided only at those
places where there is a significant risk of the inner lining becoming fused to the
permanent lining.
[0010] The inner lining keeps the carbonaceous residue in place to serve its eventual function
as a parting layer. The inner lining and the carbonaceous residue also protect the
permanent lining from attack by molten metal and slag in the container.
[0011] The inner lining may be provided by a set of slabs of refractory heat-insulating
material as described in relation to tundishes in U.K. patent specification 1364665.
In accordance with the invention it is however sometimes preferred that the inner
lining should be of a unitary construction, preferably formed in situ. The inner lining
may be formed by applying a refractory, coating composition and this may be done,
for example, by trowelling but it is preferred to apply the composition by spraying.
[0012] Coating compositions for forming the inner lining are preferably based on one or
more particulate refractory materials and an inorganic binding agent. Examples of
suitable particulate refractory materials include silica, chamotte, olivine, sillimanite,
zircon, magnesia, alumina and zirconia. Examples of suitable inorganic binding agents
include silicates, phosphates and aluminates of alkali or alkaline earth metals, colloidal
oxide hydrosols and clays. In order to enhance the initial strength or cohesion of
the applied coating composition a proportion preferably 0.5 to 5% by weight, of fibre
may be included in the composition. The fibres may also serve to enhance the heat-insulation
provided by the composition. It is usually preferred that the inner lining should
be heat-insulating. The fibre content may be organic and/or inorganic and an example
of organic fibre is chopped straw whilst an example of an inorganic fibre is glass
fibre. Organic binder may also be present in the composition.
[0013] The thickness of the inner lining is preferably from 10 to 50 mm.
[0014] If the inner lining is provided by use of a coating composition containing a significant
proportion of moisture or a binder that requires heating to harden, the composition
after application can be heated to drive off moisture or harden the binder.
[0015] If the inner lining is provided by pre-formed articles e.g. slabs, when the container
is in use or during any pre-heating, certain consitituents of the lining e.g. soda
may tend to migrate to the back of the lining under the influence of the heat and,
in the absence of the parting layer cause the inner lining to adhere to the permanent
lining. Likewise, in the case of an inner lining provided by a coating composition
any water-soluble binder e.g. sodium silicate in the composition may tend to migrate
to the back of the lining during use or any pre-heating. In such cases the parting
layer present in accordance with the invention is particularly valuable.
[0016] The invention is of particular value where the container is a tundish but it is also
of use in the case of other containers for molten metal e.g. ladles. The invention
is particularly useful in the case of containers for molten ferrous metals e.g. steel.
[0017] The method of lining the container forms a part of the invention.
[0018] An example of a container according to the invention is a tundish (for use in the
continuous casting of steel) having an outer, metal shell, a monolithic permanent
lining of cast refractory material adjacent the shell, a parting layer overlying the
permanent lining and provided by laminated corrugated cardboard (thickness about 1.5
mm) on the floor of the tundish and a number of layers (total thickness about 0.2
mm) of newsprint on the walls of the tundish, and, overlying the parting layer, a
layer applied by spraying a composition of particulate refractory material and inorganic
binder.
1. A container for molten metal having a permanent refractory lining and an inner,
refractory lining characterised in that, in at least one place, there is separating
the permanent and inner linings, a layer substantially consisting of heat-carbonisable
sheet material.
2. A container according to Claim 1 characterised in that the heat-carbonisable sheet
material is at least one of newsprint, kraft paper, cardboard, wallpaper, hessian,
straw matting, woven polyethylene or polypropylene.
3. A container according to Claim 1 or Claim 2 characterised in that the layer of
heat-carbonisable sheet material is formed of a plurality of thin sheets.
4. A container according to any one of the preceding claims characterised in that
the layer of heat-carbonisable sheet material has a thickness of from 0.1 to 2 mm.
5. A container according to any one of the preceding claims characterised in that
the inner, refractory lining is formed from a set of slabs.
6. A container according to any one of Claims 1 to 4 characterised in that the inner
lining is of a unitary construction.
7. A container according to Claim 6 characterised in that the unitary lining has been
formed in situ.
8. A container according to Claim 7 characterised in that the unitary lining has been
formed by means of trowelling or spraying.
9. A container according to any one of Claims 6 to 8 characterised in that the inner
lining is formed from one or more particulate refractory materials and an inorganic
binding agent.
10. A container according to Claim 9 characterised in that the particulate refractory
material is one or more of silica, chamotte, olivine, sillimanite, zircon, magnesia,
alumina or zirconia.
11. A container according to Claim 9 characterised in that the inorganic binding agent
is one or more of alkali or alkaline earth metal silicates, phosphates or aluminates,
colloidal oxide hydrosols and clays.
12. A container according to any one of Claims 9 to 11 characterised in that the inner
lining includes a proportion of fibre.
13. A container according to Claim 12 characterised in that the fibre is organic fibre
or inorganic fibre or an admixture of fibres.
14. A container according to Claim 12 or Claim 13 characterised in that the proportion
of fibre is from 0.5 to 5% by weight.
15. A container according to any preceding Claim characterised in that the container
is a ladle or a tundish.