| (19) |
 |
|
(11) |
EP 0 182 658 A3 |
| (12) |
EUROPEAN PATENT APPLICATION |
| (88) |
Date of publication A3: |
|
13.01.1988 Bulletin 1988/02 |
| (43) |
Date of publication A2: |
|
28.05.1986 Bulletin 1986/22 |
| (22) |
Date of filing: 20.11.1985 |
|
|
| (84) |
Designated Contracting States: |
|
DE FR GB |
| (30) |
Priority: |
23.11.1984 GB 8429677
|
| (71) |
Applicants: |
|
- EASTMAN KODAK COMPANY (a New Jersey corporation)
()
- Kodak Limited
()
|
|
| (72) |
Inventor: |
|
- Simons, Michael J. Dr.
()
|
|
| |
|
| (54) |
Photographic coupler dispersions |
(57) @ The dark stability of a photographic dye image formed by reaction between a coupler,
dispersed in admixture with an involatile solvent, and oxidized p-phenylenediamine
colour developing agent is impaired by the presence of a compound comprising a phenolic
(or naphtholic moiety in which the acidity of the phenolic hydroxyl group is enhanced
by at least one electron-withdrawing substituent in ortho and/or para positions relative
to that group. Such a compound may be the coupler itself of the involatile solvent
used for its incorporation. This loss in stability can be reduced by introducing into
the dispersion a lipophilic anionic surfactant which comprises a sulphate or sulphonate
group as the sole hydrophilic group and either a single aliphatic hydrocarbon group
having at least 1 carbon atoms or two or more aliphatic hydrocarbon groups which together
contain at least 17 carbon atoms. A conventional, i.e. less lipophilic, anionic surfactant
may also be used in preparing the coupler dispersion.
