(19)
(11) EP 0 186 995 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
29.07.1987 Bulletin 1987/31

(43) Date of publication A2:
09.07.1986 Bulletin 1986/28

(21) Application number: 85309027

(22) Date of filing: 12.12.1985
(84) Designated Contracting States:
DE FR GB NL

(30) Priority: 21.12.1984 JP 27018184

(71) Applicant: NIPPON OIL CO. LTD.
 ()

(72) Inventors:
  • Sano, Akira
     ()
  • Yokoyama, Shigeki
     ()
  • Miyazaki, Yasunosuke
     ()
  • Kuroishi, Tetsujiro
     ()
  • Matsuura, Kazuo
     ()

   


(54) Process for producing polyethylene of ultrahigh molecular weight


(57) A process for producing ultrahigh molecular weight polyethylene having an intrinsic viscosity of 10 - 30 dℓ/g at 135°C in decalin comprises at least the following two polymerization reaction stages: (a) a first reaction stage in which ethylene is polymerized using a catalyst comprising a solid component containing at least Mg, Ti and/or Va and an organometallic compound and in the absence of hydrogen or its presence at a lower concentration to produce 70 - 99.5 weight parts of polyethylene having an intrinsic viscosity of 12 - 32 df/g at 135°C in decalin; and (b) a second reaction stage in which a fresh feed of ethylene is polymerized in the presence of hydrogen at higher concentration to produce 30 - 0.5 weight parts of polyethylene having an intrinsic viscosity of 0.1 - 5 df/g at 135°C in decalin. Such UHMW polyethylene has improved moldability characteristics.





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