(19) |
 |
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(11) |
EP 0 186 995 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
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29.07.1987 Bulletin 1987/31 |
(43) |
Date of publication A2: |
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09.07.1986 Bulletin 1986/28 |
(22) |
Date of filing: 12.12.1985 |
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(84) |
Designated Contracting States: |
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DE FR GB NL |
(30) |
Priority: |
21.12.1984 JP 27018184
|
(71) |
Applicant: NIPPON OIL CO. LTD. |
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() |
|
(72) |
Inventors: |
|
- Sano, Akira
()
- Yokoyama, Shigeki
()
- Miyazaki, Yasunosuke
()
- Kuroishi, Tetsujiro
()
- Matsuura, Kazuo
()
|
|
|
|
(54) |
Process for producing polyethylene of ultrahigh molecular weight |
(57) A process for producing ultrahigh molecular weight polyethylene having an intrinsic
viscosity of 10 - 30 dℓ/g at 135°C in decalin comprises at least the following two
polymerization reaction stages: (a) a first reaction stage in which ethylene is polymerized
using a catalyst comprising a solid component containing at least Mg, Ti and/or Va
and an organometallic compound and in the absence of hydrogen or its presence at a
lower concentration to produce 70 - 99.5 weight parts of polyethylene having an intrinsic
viscosity of 12 - 32 df/g at 135°C in decalin; and (b) a second reaction stage in
which a fresh feed of ethylene is polymerized in the presence of hydrogen at higher
concentration to produce 30 - 0.5 weight parts of polyethylene having an intrinsic
viscosity of 0.1 - 5 df/g at 135°C in decalin. Such UHMW polyethylene has improved
moldability characteristics.