[0001] This invention relates to an image forming process in which an image is formed on
a resiliently deformable intermediate support having a hydrophobic surface, by means
of a water-absorbent powder, the intermediate support with the powder image present
thereon is covered with water and the water is squeezed off immediately thereafter
and finally the sticky image is transferred by pressure onto and fixed on a paper
receiving support.
[0002] A process of this kind is known from European Patent Application 0 074 677. In this
known process, the image is formed on the intermediate support in an electrophotographic
process in which a charge image is formed on a drum having a photoconductive surface
layer, the said charge image is developed with water-absorbent toner powder and then
the powder image is transferred onto the intermediate support by pressure. The electrophotographic
image forming process requires a plurality of processing stations to form the powder
image and to regenerate the photoconductive layer after the image transfer.
[0003] The invention provides a new image forming process particularly suitable for forming
images which can be transferred onto a paper receiving support and fixed thereon in
accordance with the process as described in the above-mentioned European Patent Applicaton
0 074 677.
[0004] The process as meant in the preamble is characterised according to the invention
in that the image is formed on the intermedidate support by wetting an image registration
medium with water in accordance with an image pattern, bringing the thus selectively
wetted image registration medium into contact with water-absorbent powder and transferring
the powder image formed onto the intermediate suport by pressure. Thus the invention
provides a simple image forming process requiring considerably fewer processing stations
than the known electrophotographic image forming processes.
[0005] According to a preferred embodiment of the invention, the image is formed by means
of an ink-jet device, the latter being filled, not with ink, but with water. Since
water is used as the image forming liquid, the problems normally occurring with ink-jet
devices due to clogging of the fine spray nozzles by dried ink, are obviated.
[0006] According to another embodiment of the invention, the image forming process makes
use of a printing plate the surface of which has hydrophilic image portions against
an oleophilic background. During the printing process the printing plate is brought
into contact with a water-yielding means, such as a roller wetted with water, only
the image portions of the printing plate accepting water, and then with water-absorbent
powder supplied, for example, to the printing plate by means of a magnetic roller.
The powder image thus formed on the printing plate is then transferred by pressure
to a resiliently deformable intermediate support having a hydrophobic surface.
[0007] The image registration medium on which an image is formed by image-wise wetting with
water, for example in an ink-jet device, followed by a development with water-absorbent
powder, may consist of a support the surface of which is provided with a water-accepting
layer or the surface of which is rendered water-accepting by suitable surface treatment.
Suitable materials for use as an image registration medium in the process according
to the invention are known from planographic printing techniques, more particularly
offset printing. They may, for example, consist of aluminium, the surface of which
is rendered water-accepting by anodization or by treatment with an aqueous solution
of a silicate or an acid such as mellitic acid, phosphomolybdic acid or polyvinylphosphonic
acid. Materials of this kind are described inter alia in German Auslegeschrift 1 134
093, Netherlands Patent 101 230 and US Patents 2 598 043, 2 714 066, 2 764 085, 3
030 210, 3 136 636 and 3 247 791.
[0008] The image registration medium may also consist of a plastics support or a preferably
water- proofed paper support to which a water-accepting layer is applied, with or
without the use of an anchoring layter, the water-accepting layer containing a filler
such as clay, titanium dioxide, zinc oxide or barium sulphate, and a more or less
hydrophilic binder which is insoluble in water or has been made insoluble in water.
Such materials are also knowm from planographic printing technique and are described
inter alia in US Patents 2 542 784, 2 724 665 and 3 161 521, UK Patents 692 387, 728
205 and 739 874, Canadian Patent 673 857 and Netherlands Patent Appliciation 64 03
127. Suitable image registration media are also cellulose ester film superficially
saponified to a depth of 2 -3 micrometer and polyester or other plastics film carrying
a cellulose ester layer wich has been superficially saponified. Materials of this
kind are known as supports for light-sensitive diazotype material.
[0009] In the image forming process according to the invention the image registration medium
is first wetted with water in accordance with an image pattern. The amount of water
applied to the image portions in these conditions is small and is generally 0.5 -5
g/m
2. In the case of weak water-absorbent surfaces, e.g. aluminium whose surface has been
anodized or material having a cellulose ester layer saponified to a depth of only
2 to 3 micrometer, a water yield of 0.5 -2 g/m
2 is usually sufficient, while in the case of materials having a stronger water-absorbent
top layer, e.g. with the composition of a planographic layer as is conventional on
paper planographic printing plates, the water yield must generally be somewhat higher
and be between 2 and 5 g/m
2.
[0010] Image-wise wetting of the image registration medium can be carried out by a water-filled
ink-jet device. Suitable ink-jet devices for this purpose are so-called impulse jet
devices in which the liquid (in this case water) is forced out of the spray nozzles
by pressure pulses generated by a piezoelectric element. Impulse jet devices of this
kind are described inter alia in US Patent 3 832 579 and German Patent Application
2 643 566.
[0011] According to another embodiment of the invention, an image registration medium is
used in the form of a printing plate on which a water-accepting image is present against
a water-repellent background. The printing plate can be obtained by exposing a lightsensitive,
negative working planographic printing plate beneath a positive original and then
developing it in the way specified for the printing plate. The light-sensitive planographic
printing plate consists, for example, of an aluminium support whose surface is pre-treated
with a silicate solution and then sensitized with a dia- zocompound, the light-decomposition
product of which is water-insoluble and water-repellent. The diazo compound is, for
example, a condensation product of p-diazodiphenylamine with an aldehyde, such as
formaldehyde. Light-sensitive, negative working planographic printing plates are generally
known in offset printing and are described inter alia in UK Patent 1 129 407 and US
Patent 2 714 066.
[0012] The image registration medium wetted with water in acordance with an image pattern
is developed by bringing the image registration medium into contact with water-absorbent
powder fed to the image registration medium by a suitable transport means, e.g. a
magnetic roller. A suitable water-absorbent powder consists of a binder which in water
of 30°C is swellable but insoluble, such as a hydrolized polyvinyl acetate having
a degree of hydrolysis between 55 and 65% or higher then 98%, in which non-swellable
filler material, e.g. a mixture of magnetically attractable pigment and carbon black,
is finely distributed. Developing powder of this composition is described in detail
in European Application 0 078 077.
[0013] The powder image thus formed on the image registration medium is then transferred
onto and fixed on a receiving paper in the manner described in the abovementioned
European Patent Application 0 074 677.
[0014] Devices for performing the process according to the invention are illustrated diagrammatically
in the accompanying Figures.
Fig. 1 illustrates a device in which the image is formed by an impulse jet device.
Fig. 2 illustrates a device in which a printing plate is used.
[0015] The device according to Fig. 1 comprises an aluminium drum 1 whose surface is rendered
water-accepting and which is driven in the direction indicated by an arrow. Reference
2 denotes an impuls jet device by means of which water droplets are applied to the
surface of the drum 1 in accordance with an image pattern. The latent wet image formed
on the drum 1 is developed by the magnetic brush developer device 3 filled with water-absorbent
powder. In a pressure zone 4 drum 1 comes into pressure contact with belt 5 consisting
of a flexible support having thereon a resiliently deformable and hydrophobic top
layer, the belt being driven at the same speed as the circumferential speed of drum
1, in the direction indicated by arrows. The powder image is transferred from drum
1 onto belt 5 in the pressure zone 4. The drum 1 then runs past a heating element
6, where the drum is dried, but is not heated to such an extent that powder particles
remaining thereon will soften, and past a cleaning device 7. From pressure zone 4
belt 5 runs to a second pressure zone 8. Immediately before this pressure zone, at
the entry of the water meniscus 13 present there, belt 5 with the powder image adherent
thereto is immersed in water.The excess water is squeezed off in pressure zone 8.
In the third pressure zone 9 the now sticky powder image is transferred onto a sheet
of receiving paper fed from a stock stack 10. The copy is fed by belt 11 to a collection
station 12.
[0016] The device according to Fig. 2 comprises a plate cylinder 20 known from offset printing
machines, on which a printing plate having water-accepting image portions and water-repellent
background areas is secured by clamping means not shown. The plate cylinder is driven
in the direction indicated by an arrow. Water is fed to the printing plate by a damping
roller 21 partially submerged in a water reservoir 22. The wetted image potions of
the printing plate are provided with a layer of water-absorbent powder by the magnetic
brush developer device 23. The powder image is then transferred onto a belt 25 in
the pressure zone 24 and then transferred to and fixed on a sheet of receiving paper
in the manner described in connection with Fig. 1. The image portions of the printing
plate are then re-wetted with water and provided with a layer of water-abosrbent powder.
1. An image forming process in which an image is formed on a resiliently deformable
intermediate support (5) having a hydrophobic surface, by means of a water-absorbent
powder, the intermediate support (5) with the powder image present thereon is covered
with water and the water is squeezed off immediately thereafter and finally the sticky
image is transferred by pressure onto and fixed on a paper receiving support, characterised
in that the image is formed on the intermediate support (5) by wetting an image registration
medium - (1) with water in accordance with an image pattern, bringing the thus wetted
image registration medium (1) into contact with water-absorbent powder and transferring
the powder image formed onto the intermediate support (5) by pressure.
2. A process according to claim 1, characterised in that the image pattern is formed
by spraying the image registration medium (1) with water image-wise.
3. A process according to claim 1, characterised in that image registration medium
(1) is provided with water-accepting image portions and water-repellent background
areas.