(19)
(11) EP 0 208 357 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
11.10.1989 Bulletin 1989/41

(43) Date of publication A2:
14.01.1987 Bulletin 1987/03

(21) Application number: 86201020.4

(22) Date of filing: 11.06.1986
(51) International Patent Classification (IPC)4C01F 7/02, B01J 32/00
(84) Designated Contracting States:
BE DE FR GB IT NL

(30) Priority: 05.07.1985 US 751778

(71) Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
NL-2596 HR Den Haag (NL)

(72) Inventors:
  • Schoenthal, Galeon Wayne
    Houston Texas 77077 (US)
  • Slaugh, Lynn Henry
    Cypress Texas 77429 (US)


(56) References cited: : 
   
       


    (54) Wide pore alumina supports


    (57) A process for preparing a high surface area, wide-pore-containing, porous alumina material which comprises:

    a) preparing a first alumina hydrogel by precipitating an aqueous solution of aluminium nitrate with an aqueous solution of an alkali metal or ammonium carbonate or bicarbonate, then washing said first hydrogel,

    b) separately preparing a second alumina hydrogel by precipitating an aqueous solution of sodium aluminate with an aqueous solution of a strong inorganic acid, then washing said second hydrogel,

    c) co-mulling the washed first and second hydrogels in the presence of a peptizing agent, wherein the weight percentage of the alumina provided by the first hydrogel ranges from 10 to 30 percent by weight, basis alumina (Al₂O₃), of the total and, adjusting, as needed the water content of the mulled material to provide an extrudable mixture,

    d) extruding the product of c),

    e) drying the product of d), and

    f) calcining the product of e) at a temperature ranging from 500 to 700 °C.







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