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(11) | EP 0 221 559 A2 |
| (12) | EUROPEAN PATENT APPLICATION |
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| (54) | Photocopolymerizable compositions based on epoxy and hydroxyl-containing organic materials |
| (57) Described herein are photocopolymerizable compositions comprising a cycloaliphatic
epoxide, an alkylene oxide derived polyol having an average molecular weight of from
2000 to 4500, and a photoinitiator. These compositions are particularly suited for
coating paper, wood. metal, and plastic substrates. |
[0001] This invention is directed to a photocopolymerizable composition comprising a cycloaliphatic epoxide, an alkylene oxide derived polyol having an average molecular weight of from 2000 to 4500 and a photoinitiator.
[0002] . u.s.-A-4,256,828 describes photocopolymerizable compositions which contain epoxides, organic material with hydroxyl functionality and a photosensitive aromatic sulfonium or iodonium salt of a halogen-containing complex ion. The organic material with hydroxyl functionality is stated in said patent to include polymeric hydroxyl-containing materials such as polyoxypropylene glycols and triols of molecular weight from about 200 to about 10,000 corresponding to an equivalent weight of 100 to 5000 for the diols or 70 to 3300 for the triols. The examples which describe these glycols are Examples 8,15,16,45,46,49 and 50. However, these glycols have molecular weights of 1000 or less. The photocured compositions containing these glycols do not have the flexibility, toughness and impact strength which are acceptable in many end use applications.
[0003] U.S.-A-4,231,951 also describes photocopolymerizable compositions which contain cycloaliphatic epoxides, organic materials having a hydroxyl functionality of 2 and a triarylsulfonium complex salt photoinitiator. Specifically, Examples 25 to 35 describe compositions containing a cycloaliphatic epoxide, polyethyleneglycol 400 and particular photo- initators. However, here again the polyethyleneglycol has a very low molecular weight, i.e., about 400 and thus has the same deficiencies as those compositions described in U.sTA-4,256,828.
THE INVENTION
[0004] It has now been found that the combination of a cycloaliphatic epoxide, an alkylene oxide derived polyol having an average molecular weight of from 2000 to 4500, and a photoinitiator results in photocopolymerizable compositions which when cured provide coatings which have high flexibility, toughness and impact strength. These compositions are particularly suited for coating paper, wood, metal and plastic substrates.
[0005] The compositions preferably include additives, such as oils and surfactants to achieve flow and leveling control, and/or low molecular weight alcohols, cellosolves, carbitols, diethyleneglycol to achieve viscosity reduction, and/or glycidyl-type epoxides, such as those prepared from bisphenol-A, epoxy novolaks and glycidyl ethers.
[0006] Suitable cycloaliphatic epoxides for purposes of this invention are those having an average of more than one vicinal epoxy group per molecule. The epoxy groups can be terminal epoxy groups or internal epoxy groups as exemplified by the cycloaliphatic epoxides which are subsequently described. Particularly desirable cycloaliphatic epoxides are the cyclohexane diepoxides, that is epoxides having at least one cyclohexane ring to which is attached at least one vicinal epoxy group.
FORMULA I
[0008] Diepoxides of cycloaliphatic esters of dicarboxylic acids having the formula:
wherein Ri through R9, which can be the same or different are hydrogen or alkyl radicals generally containing 1 to 9 carbon atoms inclusive and preferably containing 1 to 3 carbon atoms inclusive as for example methyl, ethyl, n-propyl, n-butyl, n-hexyl, 2-ethylhexyl, n-octyl, n-nonyl;
[0009] R is a valence bond or a divalent hydrocarbon radical generally containing 1 to 10 carbon atoms inclusive and preferably containing 4 to 6 carbon atoms , as for example, alkylene radicals, such as trimethylene, tetramethylene, pentamethylene, hexamethylene, 2-ethylhexamethylene, octamethylene, nonamethylene; cycloaliphatic radicals, such as 1,4-cyclohexane, 1,3-cyclohexane and 1,2-cyclohexane.
[0010] Particularly desirable epoxides, falling within the scope of Formula I, are those wherein R1 through Rg are hydrogen and R is alkylene containing 4 to 6 carbon atoms.
[0011] Among specific diepoxides of cycloaliphatic esters of dicarboxylic acids are the following:
bis(3,4-epoxycyclohexylmethyl)oxalate,
bis(3,4-epoxycyclohexylmethyl)adipate,
bis(3,4-epoxy-6-methylcyclohexylmethyl)adipate,
bis(3,4-epoxycyclohexylmethyl)pimelate. Other suitable compounds are described in U.S.-A-2,750,395.
FORMULA II
[0012] A 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate having the formula:
wherein R1 through R9 which can be the same or different are as defined for R1 in formula I. Particularly desirable compounds are those wherein R1 through R9 are hydrogen.
[0013] Among specific compounds falling within the scope of Formula II are the following: 3,4-epoxycyclohexylmethyl, 3,4-epoxycyclohexanecarboxylate, 3,4-epoxy-1-methylcyclohexylmethyl, 3,4-epoxy-1-methylcyclohexanecarboxylate, 6-methyl-3,4-epoxycyclohexylmethyl, 6-methyl-3,4-epoxycyclohexanecarboxylate, 3,4-epoxy-3-methylcyclohexylmethyl, 3,4-epoxy-3-methylcyclohexanecarboxylate, 3,4-epoxy-5-methylcyclohexylmethyl, 3,4-epoxy-5-methylcyclohexanecarboxylate. Other suitable compounds are described in U.S-A-2,890,194.
FORMULA III
[0014] Diepoxides having the formula:
wherein the R single and double primes, which can be the same or different, are monovalent substituents such as hydrogen, halogen, i.e. chlorine, bromine, iodine or fluorine, or monovalent hydrocarbon radicals, or radicals as further defined in U.S.-A--3,318,822.
[0017] The preferred cycloaliphatic epoxides are the following:
3,4-Epoxycyclohexylmethyl-3,4-Epoxycyclohexane caboxylate
Bis-(3,4-Epoxycyclohexylmethyl)Adipate
2-(3,4-Epoxycyclohexyl-5,5-spiro-3.4-epoxy)cyclohexane-meta-dioxane
Vinyl cyclohexene dioxide
or mixtures thereof.
[0018] Epoxides with 6 membered ring structures may also be used, such as diglycidyl esters of phthalic acid, partially hydrogenated phthalic acid or fully hydrogenated phthalic acid. Diglycidyl esters of hexahydrophthalic acids being preferred.
[0019] The alkylene oxide derived polyol suitable for use in this invention has an average molecular weight of from 2000 to 4500, preferably from 2500 to 4200.
[0020] The preferred alkylene oxide derived polyols are of the following formula:
wherein R10 is alkane of 3 to 10 carbon atoms, preferably 3 carbon atoms, and n is an integer of from 10 to 25.
[0021] Said polyols constitute from 10 to 0221559 weight percent of the photopolymerizable formulation.
[0022] The photoinitiator suitable for use herein may be any one of the well known photoinitiators such as described in, for example, u.s.-A-4,231,951; 4,256,828; 4,138,255 and 4,058,401 .
[0023] Preferred photoinitiators include triarylsulfonium complex salts as described in u.s.-A-4,231,951, aromatic sulfonium or iodonium salts of halogen-containing complex ions as described in u.s.-A-4,256,828; aromatic onium salts of Group VIa elements as described in u.s.-A-4,058,401 and 4,138,255. Such salts are commercially available as FC-508 and FC-509 (available from Minnesota Mining and Manufacturing Company), and as UVE-1014 (available from General Electric Company).
[0024] The photoinitiators are used in conventional amounts such as from 0.1 to 30 parts by weight per 100 parts by weight of the combination of cycloaliphatic epoxide and the alkylene oxide derived polyol.
[0025] The compositions may preferably include additives such as oils, particularly silicone oil, surfactants such as silicone- alkylene oxide copolymers, silicone oil containing aliphatic epoxide groups, fluorocarbon surfactants; low molecular weight alcohols; cellosolves, such a butyl cellosolve; carbitols, such as butyl carbitol; diethyleneglycol; glycidyl ether monomers of the formula:
wherein R11 is alkyl or aryl and n is an integer of 1 to 6. Examples are glycidyl ethers of polyhydric phenols obtained by reacting a polyhydric phenol with an excess of chlorohydrin such as epichlorohydrin. Further, examples of this type are described in, for example, U.S.-A-3,018,262; α -olefin epoxides and epoxy novolaka;' -
[0026] If desired, one may include in the photocopolymerizable compositions various conventional non-basic fillers (e.g., silica, talc, glass bubbles, clays, powdered metal such as aluminum, zinc oxide ) up to about 50% by volume or more, viscosity modifiers, rubbers, tackifying agents, pigments, and so forth.
[0027] The photocopolymerizable compositions are particularly suitable in a variety of applications in the fields of protective coatings and graphic arts due to their superior impact resistance and abrasion-resistance and adhesion to rigid, resilient and flexible substrates such as metal, plastic, rubber, glass, paper, wood, and ceramics.
[0028] The photopolymerization of the compositions of the invention occurs on exposure of the compositions to any source of radiation emitting actinic radiation at a wavelength within the ultraviolet and visible spectral regions. Suitable sources of radiation include mercury, xenon, carbon arc and tungsten filament lamps, sunlight, etc. Exposures may be from less than 1 second to 10 minutes or more depending upon the amounts of particular polymerizable materials and photoinitiator being utilized and depending upon the radiation source and distance from the source and the thickness of the coating to be cured. The compositions may also be polymerized by exposure to electron beam irradiation. Generally speaking the dosage necessary is from less than 1 megarad to 100 megarad or more.
[0029] The photocopolymerizable compositions of this invention may be prepared simply by mixing the formulation ingredients together, preferably under "safe light" conditions when the photoinitiator is incorporated.
EXAMPLES
[0030] The following Examples serve to give specific illustration of the practice of this invention.
[0033] Polyol 1: a propylene oxide polyol prepared from propylene oxide and glycerol having a molecular weight of about 6000.
[0040] Photoinitiator 1: FC-508, a solution of a triarylsulfonium hexafluorophosphate with a specific gravity of 1.33 and a Brookfield viscosity of 40,000 to 60,000 (cps ) mPa.s. Photoinitiator 2: UVE-1014, a solution of a triarylsulfonium hexafluoroantimony salt with a specific gravity of 1.39g/cm3 and a Brookfield viscosity of 74 (cps ) mPa·s,
[0042] Acetone resistance - in this test a test specimen was rubbed with a cloth saturated with acetone. A rub back and forth over the test specemen with the cloth was referred to as a "double rub".
[0043] A rating system for evaluating acetone resistance for a given number of double rubs was as follows:
[0045] Crosshatch adhesion - refers to a test usine 10 parallel, single-edge, razor blades to scribe test films with 2 sets of perpendicular lines in a crosshatch pattern. Ratings are based on the amount of film removed after applying and subsequently pulling a contact adhesive tape (Scotch Brand 606) away from the surface of a scribed coating at a 90 degree angle in a fast, rapid movement. It is important to carefully apply and press the tape to the scribed coating to eliminate air bubbles and provide a good bond because adhesion is reported as the percent of film remaining on the substrate with a 100 percent rating indicating complete adhesion of the film in the substrate.
[0046] Reverse or face impact resistance - measures the ability of a given film to resist rupture from a falling weight. A Gardner Impact Tester using an 3.6 kg (8 lbs) dart is used to test the films cast and cured on the steel panel. The dart is raised to a given height in mm (inches) and dropped onto the reverse or face side of a coated metal panel. The m.kg (inches times pounds, designated inch-pounds),absorbed by the film without rupturing is recorded as the reverse impact resistance of the film.
Examples and Controls
[0047] In these Examples and Controls, the type and amount of epoxide (grams), polyol (grams), and photoinitiator (grams) are shown in the Tables. Under "safe light" conditions the ingredients listed in the Tables were placed in brown, glass bottles and mixed by simple stirring to thoroughly blend the - components. Any suitable, convenient means of blending the components can be used.
[0048] The formulated systems were coated onto the substrate, which was Bondenite 37 steel panels, with a wire-wond rod. The coatings varied from 7.62 - 27.93 µm (0.3 to 1.1 mil) in thickness. The coatings were cured with a medium pressure mercury lamp UV light source at 0.9 or 1.8 m (30 or 60 feet) per minute with or without a Post cure of 5 to 10 minutes at 150 to 170 °C.
--EXAMPLE 19
[0049] For comparative purposes, the following mixtures were prepared by placing the indicated ingredients in glass bottles and well mixing them. They were then coated onto Bonderite 37 steel panels with a f20 wire-wound rod and then cured with a Fusion Systems 300 watt/inch ultraviolet light source at 3 m (10 feet) per minute. Formulation 1 is a repetition of Example 14 of U.S. 4,256,828. Formulation 2 is based on the instant invention.
[0050] Epon 828 is an epoxide that is known as the diglycidyl ether of Bisphenol A. This epoxide was used by Smith, U.S. 4,256,828 in Example 14. It is not a cycloaliphatic epoxide.
[0051] ERL-4221 is Epoxy 1 of the instant invention. Chemically it is 3,4-epoxycyclohexyl-methyl-3,4-epoxycyclohexane carboxylate.
[0052] LHT-67 is Polyol 5. It is a propylene oxide polyol prepared from propylene oxide and glycerol having a molecular weight of about 2500.
[0054] Polymeg 2000 is a commercial polytetramethylene oxide polyol marketed by Quaker Chemical. It was used in Smith, U.S. 4,256,828 in Example 14.
[0055] L-5410 is a polyalkyleneoxide modified dimethylpolysiloxane copolymeric surfactant that was used to improve flow and leveling.
[0056] After exposure to the ultraviolet light source, the resulting coating from Formulation 1 was sticky and tacky and could not be stacked, handled, etc. This coating was still tacky 4 days after UV exposure. It should be pointed out that this tack was less four days after exposure than immediately after cure, but there was definite tack or stickiness present in the "cured" coating. It is known to those skilled in the art of UV curing with cationic photoinitiators that cure continues after exposure to ultraviolet light -- thus, one would expect these coatings to cure further as they age under ambient conditions. In contrast, the coating from Formulation 2 cured to give a tack-free coating with good hardness so that it could be easily handled, stacked, etc., when warm immediately after UV exposure.
[0057] Thus, it is readily apparent that there is a marked difference in the performance characteristics of the coating prepared in the manner described by Smith and the manner described in Formulation 2. Further, this demonstrates that the coatings of the instant application are a definite improvement over the state of the art as exemplified by Smith.
--EXAMPLE 20
[0058] For comparative purposes, the following mixtures were prepared by placing the indicated ingredients in glass bottles and mixing them well. They were then coated onto Bonderite 37 steel panels with a 20 wire-wound rod and, then cured with a Fusion Systems 300 watt/inch ultraviolet light source at 10 feet per minute.
[0061] After exposure to the ultraviolet light source, the coating from Formulation 1 was sticky and tacky immediately after exposure to the ultraviolet light source remained tacky for more than ten minutes after exposure. (The experiment was terminated after this period of time had elapsed. Data for longer periods were given in my previous letter.) In contrast, the coating from our application--Formulation 2 --cured to give a tack-free coating with good hardness so that it could be easily handled, stacked, etc., when warm immediately after UV exposure. Thus these data indicate that there is a marked difference in the cure characteristics of the coating prepared in the manner described by Smith and the manner described in the present invention.
1. A photocopolymerizable composition consisting essentially of a cycloaliphatic epoxide,
an alkylene oxide derived polyol having an average molecular weight of from 2000 to
4500 of the formula:
wherein R10 is alkyl having 3 to 10 carbons, R' is H or methyl and n is an integer having values of 10 to 25 and a photoinitiator.
wherein R10 is alkyl having 3 to 10 carbons, R' is H or methyl and n is an integer having values of 10 to 25 and a photoinitiator.
2. The curable composition as in claim 1 wherein the cycloaliphatic epoxide has the
formula:
wherein R1 through R9, which can be the same or different, are hydrogen or alkyl radicals generally containing to carbon atoms inclusive; R is a valence bond or a divalent hydrocarbon radical generally containing 1 to carbon atoms
wherein R1 through R9, which can be the same or different, are hydrogen or alkyl radicals generally containing to carbon atoms inclusive; R is a valence bond or a divalent hydrocarbon radical generally containing 1 to carbon atoms
3. The curable composition as in claim 1 wherein the cycloaliphatic epoxide has the
formula:
wherein R1 through R9, which can be the same or different are hydrogen or alkyl radicals generally containing 1 to 9 carbon atoms .
wherein R1 through R9, which can be the same or different are hydrogen or alkyl radicals generally containing 1 to 9 carbon atoms .
4. The curable composition as in claim 1 wherein the cycloaliphatic epoxide is 3,4-epoxycyclohexylmethyl-3,4-epoxy-cyclohexane
carboxylate., bil(3,4-epoxycyclohexylmethyl)-adipate, 2-(3,4-epoxycyclohexyl-5,5- spiro-3,4-epoxy)cyclohexane-
meta -dioxane, a mixture of bis(3,4-epoxycyclohexylmethyl)adipate and 2-(3,4-epoxycyclohexyl-5,5-spiro-3,4-epoxy)-cyclohexane-meta-dioxane
or a mixture of 3,4-epoxycyclohexylmethyl-3,4-epoxy, cyclohexane carboxylate and bis(3,4-epoxycyclohexylmethyl)adipate.
5. The curable composition as in claims 1 to 4 wherein the alkylene oxide derived polyol
has a molecular weight of from 2500 to 4200.
6. The composition as defined in claims 1 to 5 which contains an oil and/or surfactant.
7. The composition as defined in claims 1 to 6 which contains less than 10% of a low molecular weight alcohol, and/or cellosolve
and/or carbitol and/or diethyleneglycol, and/or glycidyl ether monomer and/or α-olefin
epoxide and/or epoxy novolak.