(19) |
 |
|
(11) |
EP 0 230 145 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
|
24.05.1989 Bulletin 1989/21 |
(43) |
Date of publication A2: |
|
29.07.1987 Bulletin 1987/31 |
(22) |
Date of filing: 29.12.1986 |
|
|
(84) |
Designated Contracting States: |
|
BE DE FR GB IT NL |
(30) |
Priority: |
10.01.1986 JP 4035/86
|
(71) |
Applicant: NITTO DENKO CORPORATION |
|
Osaka (JP) |
|
(72) |
Inventors: |
|
- Tajiri, Kazuhiro
Nitto Electric Industrial Co.,Ltd
Ibaraki-shi
Osaka (JP)
- Kohmoto, Michio
Nitto Electric Industrial Co.,Ltd
Ibaraki-shi
Osaka (JP)
- Nakatsuka, Hiroshi
Nitto Electric Industrial Co.,L
Ibaraki-shi
Osaka (JP)
|
(74) |
Representative: Diamond, Bryan Clive (GB) et al |
|
Gee & Co.
Chancery House
Chancery Lane GB-London WC2A 1QU GB-London WC2A 1QU (GB) |
|
|
|
(54) |
Epoxy resin powder coating composition and steel coated therewith |
(57) A powder coating composition comprises by weight (1) 100 parts of an epoxy resin
(e.g. bisphenol A type),
(2) a hardener (e.g. an aromatic diamine),
(3) as filler (i) 30-180 parts of needle-like glass powder of average length at least
40 µm, preferably 50-350 µm, ratio of length: diameter at least 4:1, preferably 5:1
to 100:1, and average diameter 1-30 µm, preferably surface treated with a silane coupling
agent and (ii) 30-150 parts of a granular inorganic filler (e.g. Ti02, BaSO3) of average diameter 1.0 µm or less and preferably surface treated to increase its
weltability; and
(4) 0.1-5.0 parts of an aminosilane, epoxysilane or mercaptosilane as coupling agent.
The composition can be made by melt mixing and powdering.
A steel member, e.g. for a vehicle, is treated with a solution of phosphate, chromate
or chromium/phosphoric acid to form a surface layer on which is deposited the powder
which is heated to form a hardened coating having high impact resistance at ordinary
and low temperature and forming an excellent protection against corrosion of the steel.
