(19) |
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(11) |
EP 0 262 988 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
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29.06.1988 Bulletin 1988/26 |
(43) |
Date of publication A2: |
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06.04.1988 Bulletin 1988/14 |
(22) |
Date of filing: 02.10.1987 |
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(84) |
Designated Contracting States: |
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AT BE CH DE ES FR GB GR IT LI LU NL SE |
(30) |
Priority: |
02.10.1986 NZ 217786
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(71) |
Applicant: The Director of the Pulp and Paper Research Organisation of New Zealand |
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(57) Processes for producing pulp from lignocellulosic material in which the delignification
agent comprises an alkali metal hydroxide together with a small amount of a sulphite
in the range between 0.1 and 15% expressed as Na₂SO₃ by mass on an oven dry basis
of said lignocellulose. The addition of the small amount of sulphite gives a marked
improvement in both the quality of the paper produced from the pulp and the rate of
delignification. The rate of delignification is improved further by the use of a redox
agent such as anthraquinone, anthrahydroquinone, homologues and derivatives thereof.
Optionally, the process may be carried out in two stages, including a first stage
in which lignocellulose is digested in a liquor containing between 0.1 and 15% of
a sulphite, and another further stage in which said lignocellulose is digested in
a liquor containing an alkali metal hydroxide.
The pulping liquors may also contain other alkaline compounds such as sodium carbonate
which act as buffers.