| (19) |
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(11) |
EP 0 263 508 A3 |
| (12) |
EUROPEAN PATENT APPLICATION |
| (88) |
Date of publication A3: |
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03.08.1988 Bulletin 1988/31 |
| (43) |
Date of publication A2: |
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13.04.1988 Bulletin 1988/15 |
| (22) |
Date of filing: 07.10.1987 |
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| (84) |
Designated Contracting States: |
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BE CH DE FR GB IT LI LU NL SE |
| (30) |
Priority: |
10.10.1986 US 917505
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| (71) |
Applicant: E.I. DU PONT DE NEMOURS AND COMPANY |
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| (54) |
Process for preparing a photographic emulsion containing tabular grains exhibiting
high speed |
(57) Process for preparing a photographic emulsion containing tabular silver halide grains,
which exhibit high speed upon sensitization, having a thickness of about 0.05 to 0.5
µm, average grain volume of about 0.05 to 1.0 µm³ and mean aspect ratio of greater
than 2:1 comprising
A. adding silver nitrate to a vessel containing dispersing medium/bromide mixture,
initial bromide ion concentration 0.08 to 0.25 N, to form tabular seed grains;
B. adding an ammoniacal base solution, to achieve 0.002 to 0.2 normal of the base
(e.g., after at least 2% of total silver nitrate has been added); and
C. adding additional silver nitrate and halide, i.e., Br⁻ or BrI⁻, by balanced double
jet procedure. The emulsions are used in photographic elements for x-ray, graphic
arts, etc.