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(11) |
EP 0 282 214 B2 |
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NEW EUROPEAN PATENT SPECIFICATION |
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Date of publication and mentionof the opposition decision: |
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01.09.1999 Bulletin 1999/35 |
| (45) |
Mention of the grant of the patent: |
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09.10.1991 Bulletin 1991/41 |
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Date of filing: 01.03.1988 |
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Machine dishwashing process
Verfahren zum Reinigen von Geschirr
Procédé de lavage de vaiselle
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Designated Contracting States: |
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AT BE CH DE ES FR GB IT LI NL SE |
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Priority: |
07.03.1987 DE 3707366
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Date of publication of application: |
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14.09.1988 Bulletin 1988/37 |
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Proprietor: UNILEVER N.V. |
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3013 AL Rotterdam (NL) |
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Inventors: |
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- Blecher, Jochen
D-5900 Siegen (DE)
- Langenstein, Berthold
D-6751 Mehlingen (DE)
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Representative: de Vries, Johannes Hendrik Fokke et al |
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De Vries & Metman,
Overschiestraat 184 N 1062 XK Amsterdam 1062 XK Amsterdam (NL) |
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References cited: :
EP-A- 0 036 217 DE-A- 1 285 087 DE-A- 2 063 011 DE-A- 2 441 361 DE-A- 3 330 537 FR-A- 1 386 199 FR-A- 2 090 151 FR-A- 2 169 695 FR-A- 2 282 840 FR-A- 2 589 057 GB-A- 1 099 701 GB-A- 1 190 113 US-A- 2 644 473 US-A- 3 043 724 US-A- 3 549 294 US-A- 3 954 500
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EP-A- 0 040 006 DE-A- 1 703 441 DE-A- 2 117 082 DE-A- 2 934 699 DE-U- 7 013 739 FR-A- 2 086 019 FR-A- 2 125 396 FR-A- 2 275 116 FR-A- 2 574 645 GB-A- 1 021 051 GB-A- 1 178 197 US-A- 2 385 264 US-A- 2 910 391 US-A- 3 063 459 US-A- 3 645 421
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- Prospektblatt "Blitz-Grundreiniger für Geschirr", Henkel GV 1976
- Compositionlist and Produktspecification of "Blitz-Grundreiniger für Geschirr"
- Affidavit Mr. Richard Neumann, 10.02.92
- Umrechnungstabelle
- Report by Arnold Krawitowski "Stärkeablagerungen auf dem Spülgut in der Mensa Marburg",
07.03.87
- Composition Spec-Tak EL
- Werksmitteilung Oberwein vom 16.01.89
- Composition Perclin intensiv (GTF40)
- H. Stache/H. Grossmann "Waschmittel"
- H. Mrozek "Die Voraussetzungen erfolgreichen Reinigens"
- W. Wagemann "Wirkung der Einsetzbarkeit von Reinigungsmitteln in Lebensmittelbetrieb"
- P3-topax23
- P3-horolith 617
- P3-topax 21
- Diggelmann "Schmutz wird weggespritzt
- Tenside Detergents 19, 1982, pp 123-126
- GV-Praxis 11/80, "Gewerbliches Geschirrspülen" (Sonderdruck pp. 1-24)
- Etikett NEODISHER GRM, Feb. 87
- Letter of opponent to a client dated 17.01.86
- P. Berth et. al. "Dishwashing formulations in Europe", presented at Second World Conference
on Detergent, October 1986
- Brochure "Hobart Bandvaatwasmachines Serie FT-E", Hobart Benelux, Hobart B.V Rotterdam
(12 pages)
- Pages 42 and 47 of a FogJet nozzles and nozzle assemblies document
- Decision KG 95/334 of 10 April 1995 of the District Court The Hague, The Netherlands
(+ German transation)
- Handboek voor de institutionele reiniging, L.A. Saelman, Kluwer, Deventer 1985, pp.137-149
(+ German translation)
- Affidavit Mr. Hans Otto Hedermann, 20.04.95
- Affidavit Mr. Arnold Krawitowski, 10.06.92
- undated Brochure of MEIKO Maschinenbau GmbH & Co., "MEIKO B-Tronic - die neue Bandautomaten
- Generation"
- Brochure of MEIKO Maschinen- und Apparatenbau Ing. Oskar Meier GmbH & Co., MEIKO Automatik-Geschirrspülanlagen,
January 1989
- Affidavit Mr. Viktor Klement, 05.02.96
- Affidavits Mr. Hans Dittert, 05.02.96 (+ sketch) and 31.10.98
- Affidavit Mr. Dieter Hesse, 02.02.96
- Affidavit Mr. Klaus Liebler, 31.01.96
- Written statement of Jan Nuiver dated 03.12.98
- Letter from Mr. Grillemeier of Georg-August-Universität Gottingen, 20.08.98
- Written statement of Jan Nuiver dated 03.12.98
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[0001] This invention relates to a machine dishwashing process; more particularly, it relates
to an improvement in continuous or non-continuous machine dishwashing, whether conducted
using a single tank, multitank or conveyor type machine.
[0002] In a typical machine dishwashing process, tableware or cookware, such as dishes soiled
with food remains, trays, cutlery and lipstick-smeared glasses, is intensively sprayed
with water in a prewash zone or prewash cycle. The water used for the prewash may
be cold or preheated fresh water or cooling water from a vapour condensation process,
but is generally overflow water of a wash liquor, which is generally sprayed onto
the articles under relatively low pressure and in relatively large amounts using suitably
located spray nozzles. After this prewash zone or prewash cycle, the articles enter
the actual wash zone or wash cycle, where they are again vigorously sprayed this time
with a wash liquor.
[0003] The wash liquor is generally water at a temperature of from 50 to 60°C to which a
liquid or powder-form detergent is added. In order to remove grease, starch, stains
and protein with sufficient reliability, for example powder detergent or liquid detergent
is added to water to provide from 0.1 to 0.3 weight percent of active cleaning agent
in solution. This resulting wash liquor is sprayed onto the articles by pump means
through lower and upper nozzles and, in some cases, through additional lateral nozzles.
The soil present on the articles is removed or at least swollen or softened and partially
dissolved by the wash liquor. In following rinse zones or cycles, the swollen or softened
food remains are removed and, at the same time, the wash liquor is rinsed off by water.
In a final rinse zone or final rinse cycle, any residues of the wash liquor are removed
by water at a temperature of up to about 85°C. The final-rinse water consists of fresh
water with an added rinse aid, which ensures that only an ultrathin film of water
remains on the articles, which can evaporate in a following drying zone.
[0004] Even the use of relatively large amounts of detergent in regular conventional cleaning
will not always avoid the need for periodic heavy-duty cleaning. The object of this
extra cleaning is to remove coatings of, for example water-insoluble stains or starch
which have gradually built up, but which are not immediately discernible. For this
heavy-duty cleaning, the articles are treated occasionally with a wash liquor containing
several times the normal quantity of detergent. Optionally, a manual pre-soak may
be employed to the same end. Both of these methods also mean additional pollution
of the wastewater.
[0005] For example, GB-A-1,099,701, which may be regarded as the most pertinent prior art,
relates to a process for cleaning a surface in which a liquid medium comprising a
detergent in a concentration of at least 0.5% in which are suspended substantially
water-impregnable non-abrasive inert particles is sprayed onto the surface. There
is no suggestion of the use of detergent solutions alone for cleaning surfaces.
[0006] An object of the present invention is to provide surprisingly advantageous dishwashing.
The improved efficiency of cleaning obtainable may reduce labour, water and chemical
consumption, hence lower pollution and rejects, while ensuring satisfactory cleaning
even in adverse conditions.
[0007] The present invention provides a machine dishwashing process which comprises spraying
onto at least partially soiled articles a highly concentrated aqueous cleaning formulation
comprising at least 0.5 weight percent of one or more active cleaning agents and,
after a contact time of at least 2 seconds, removing the cleaning formulation and
soil in one or more subsequent stages.
[0008] A dishwashing machine may be adapted to effect such a process, for example by addition
of extra spray nozzles and associated systems and/or by modifications to the control
systems of the machine.
[0009] The aqueous cleaning formulation may be derived from powder-form or liquid materials.
In accordance with the present invention the sprayed cleaning formulation comprises
at least 0.5 weight percent of one or more active cleaning agents. While, say, 30
weight percent might be regarded as an upper limit, the critical factor is that the
formulation must remain sprayable. Preferably, the sprayed cleaning formulation comprises
from 0.8 to 10 weight percent, more preferably from 0.9 to 3 weight percent, of one
or more active cleaning agents.
[0010] According to the present invention a contact time of at least 2 seconds will be sufficient
for the desired chemical, as opposed to mechanical, action. In preferred embodiments,
this may be from 5 to 100 seconds, in particular from 8 to 25 seconds. So as to provide
the desired prolonged intimate contact or "saturation", the "mechanical effect" of
spraying is at least minimised, if not avoided. During this contact time, the articles
being washed are not deliberately sprayed.
[0011] In order to optimise results, it is important that substantially the whole surface
of a soiled article should be contacted by the sprayed cleaning formulation and the
amount of formulation sprayed and the manner in which it is sprayed may be adapted
bearing this aim in mind. A fine, gentle mist-like spray is used. In a conveyor-type
machine, the belt speed will also be a factor. More particularly, the volume sprayed
and/or the number and/or arrangement of spray nozzles is/are selected so that low
volume and low intensity spraying will ensure the desired type of complete coverage
and even distribution. The nature, volume and concentration of the sprayed formulation
may be varied, as may the spray means, depending, for example, on the load and, where
appropriate, the motion and/or speed of the conveyor. The present low volume/low intensity
mist-like application of concentrated cleaning formulation is in contrast to the vigorous
high volume spraying used in conventional dishwashing.
[0012] The claimed machine dishwashing process optionally comprises one or more prewash
cycles or zones in order, for example to remove heavy soil, one or more wash zones
and one or more rinse zones. In accordance with the present invention, the unusually
high concentration cleaning solution is sprayed somewhere prior to the final rinse,
commonly as at least part of a wash cycle or in a wash zone.
[0013] While all of the cleaning agents required may be included in the sprayed concentrate,
it may be advantageous to introduce additional cleaning formulation in a conventional
manner at some stage of the process. This further material is generally not the same
as the sprayed concentrate, but may merely be the same composition further diluted.
The use of a complementary formulation particularly commends itself. The balance of
the complementary products may also be adjusted. For example, a high alkalinity spray
might be balanced by a lower alkalinity wash to follow. The present system also enables
chemicals which would normally be incompatible when mixed in a single product to be
used in conjunction, for example oxidising agents, such as hypochlorite, may be used
in the spray with, for example, water conditioning agents, such as NTA (nitrilotriacetate)
being introduced later.
[0014] While the concentrated cleaning formulation is generally sprayed more or less throughout
the appropriate part of the dishwashing process, it may be used intermittently or
occasionally, for example during the wash cycle in a non-conveyor type machine.
[0015] The aqueous cleaning formulation sprayed must be flowable, but may be in the form
of a solution, emulsion or slurry, for example. Various materials are known which
will cause or facilitate at least some penetration and/or swelling and/or loosening
and/or dissolution of soil. Typically, a basic cleaning formulation will comprise
a source of alkalinity and a source of sequestering activity. Such formulations may
be adapted to combat particular problems. For example, tea-stain removal might suggest
the inclusion of bleaching agents, while products based on amylase may be useful for
starch removal without alkalinity.
[0016] For purposes of illustration, a machine for carrying out the present process may
be a conveyor transport machine with an optional prewash zone, a wash zone, a rinse
zone, a final rinse zone and a drying zone. Fresh water is only supplied to the final-rinse
zone, subsequently passing cascade-fashion towards the prewash zone in countercurrent
to the direction of transport of the dishes.
[0017] A simple product fairly efficient in removing built-up starch residues and stains
may be formulated from the following:
- Potassium hydroxide
- 20-30 wt%
- Chelating agent(s)
- 15-25 wt%
- Threshold agent(s)
- 2-4 wt%
- Dispersing polymer(s)
- 2-4 wt%
- Wetting agent(s)
- 1-2 wt%
- Balance water
[0018] Optimisation of such a product is possible and desirable. Such a product may be blended
with water in-line before being sprayed at a dilution of about 2.5 % through suitable
spray nozzles situated within the wash zone immediately before or after the conventional
wash zone. Sprayed ware may then pass through part of the wash zone with the pumps
turned off (unless there is already sufficient separation between zones) so as to
allow a contact time of about 15 seconds, before reaching a further wash or rinse
zone. Further detergent may be added by conventional means at other stages to provide
additional destaining and prevention of incrustation of machine parts. Thereafter,
the ware passes to a final rinse stage where rinse aid may be introduced.
[0019] After soiled dishes have been loaded onto the conveyor belt, in the prewash zone
it is deluged in overflow water from the wash zone, which has a temperature of about
40°C. All coarse or relatively large quantities of food remains are thus removed from
the dishes. The dishes then enter the actual wash zone. In the wash zone, the dishes
are sprayed with the highly concentrated detergent solution, each nozzle may be delivering
as little as 6 l/hour and typically there will be from 3 to 10 nozzles. The system
is arranged or adapted to ensure that nothing disturbs the desired prolonged intimate
contact.
[0020] The speed of the conveyor belt is advantageously selected so that the contact time
of the detergent solution, depending on its concentration, is from 2 to 100 seconds,
generally about 10 seconds. Such a contact time and the high concentration of the
detergent solution ensure that all food remains on the dishes, especially grease (fats),
starch, stains and protein, are completely removed and bacteria destroyed.
[0021] After this contact time, the detached food remains, together with the detergent solution
sprayed on, are washed off by the subsequent stages using conventional spray nozzles,
the wash liquor consisting of overflow water from the rinse zone and of rinsed-off,
concentrated detergent solution and any additional dosed complementary cleaning formulation.
With the process according to the present invention, there is no longer any need for
the intermittent heavy-duty cleaning or the manual pre-soak hitherto necessary.
[0022] In the subsequent rinse zone, any loosened food and soil remains still present on
the dishes and residues of the wash liquor are rinsed off with clear water at a temperature
of about 70°C. In the final-rinse zone, fresh water at a temperature of about 85°C
with rinse aid added ensures that only a thin film of water remains on the dishes,
which dries rapidly in the following drying zone either through the heat of the dishes
or by introduction of hot air.
[0023] By virtue of the present process, dishes are reliably maintained to a consistent
high standard of cleanliness.
1. A machine dishwashing process wherein there are one or more optional prewash cycles
or zones, one or more wash cycles or zones and one or more rinse cycles or zones which
comprises spraying inside the machine from a plurality of nozzles onto at least partially
soiled articles in a fine, gentle mist-like spray a highly concentrated aqueous cleaning
formulation comprising at least 0.5 weight percent of one or more active cleaning
agents and, after a contact time of from 2 to 100 seconds during which the articles
are not deliberately sprayed, removing the cleaning formulation and soil in one or
more subsequent stages, the cleaning formulation being sprayed prior to the final
rinse cycle or zone.
2. A process as claimed in claim 1 wherein the sprayed cleaning formulation comprises
from 0.8 to 10 weight percent, preferably from 0.9 to 3 weight percent, of one or
more active cleaning agents.
3. A process as claimed in claim 1 or claim 2 wherein the contact time is from 5 to 100
seconds, preferably from 8 to 25 seconds.
4. A process as claimed in any of claims 1 to 3 wherein the cleaning formulation is sprayed
in such an amount and in such a manner as to contact substantially the whole of the
surfaces of the soiled articles.
5. A process as claimed in claim 4 wherein the volume of cleaning formulation sprayed
and/or the number and/or arrangement of spray nozzles is/are such that low volume
and low intensity spraying will provide substantially complete contact and substantially
even distribution.
6. A process as claimed in any of claims 1 to 5 wherein, in a conveyor-type machine,
the speed and/or motion of the conveyor belt and/or the load is/are such that low
volume and low intensity spraying will provide substantially complete contact and
substantially even distribution.
7. A process as claimed in any of c!aims 1 to 6 wherein, a wash cycle or zone comprises
the spraying of the cleaning formulation.
8. A process as claimed in any of claims 1 to 7 wherein further, preferably non-identical,
cleaning formulation is introduced in a conventional manner.
9. A process as claimed in claim 8 wherein the cleaning formulations are complementary.
1. Verfahren zur maschinellen Reinigung von Geschirr, wobei ein oder mehrere optionale
Vorwaschgänge oder -zonen, ein oder mehrere Waschzyklen oder -zonen und ein oder mehrere
Spülzyklen oder -zonen vorhanden sind, umfassend das Aufsprühen einer hochkonzentrierten
wäßrigen Reinigungsformulierung in einem feinen, sanften, nebelähnlichen Spray aus
einer Vielzahl von Sprühdüsen in der Maschine auf zumindest teilweise verschmutzte
Gegenstände, wobei die Reinigungsformulierung zumindest 0,5 Gew.-% eines oder mehrerer
aktiver Reinigungsmittel umfaßt und, nach einer Kontaktzeit von 2 bis 100 Sekunden,
während der die Gegenstände nicht absichtlich besprüht werden, die Entfernung der
Reinigungsformulierung und des Schmutzes in einem oder mehreren nachfolgenden Schritten,
wobei die Reinigungsformulierung vor dem letzten Spülzyklus oder der letzten Spülzone
aufgesprüht wird.
2. Verfahren nach Anspruch 1, wobei die aufgesprühte Reinigungsformulierung 0,8 bis 10
Gew.-%, bevorzugt 0,9 bis 3 Gew.-%, eines oder mehrerer aktiver Reinigungsmittel aufweist.
3. Verfahren nach Anspruch 1 oder 2, wobei die Kontaktzeit 5 bis 100 Sekunden, bevorzugt
8 bis 25 Sekunden, beträgt.
4. Verfahren nach einem der Ansprüche 1 bis 3, wobei die Reinigungsformulierung in einer
solchen Menge und in einer solchen Weise aufgesprüht wird, um die Oberflächen der
verschmutzten Gegenstände im wesentlichen vollständig damit in Kontakt zu bringen.
5. Verfahren nach Anspruch 4, wobei das Volumen der aufgesprühten Reinigungsformulierung
und/oder die Zahl und/oder die Anordnung der Sprühdüsen derart ist, daß durch das
Aufsprühen eines geringen Volumens und das Aufsprühen mit geringer Intensität ein
im wesentlichen vollständiger Kontakt und eine im wesentlichen gleichmäßige Verteilung
erreicht wird.
6. Verfahren nach einem der Ansprüche 1 bis 5, wobei, in einer Maschine vom Transporttyp,
die Geschwindigkeit und/oder die Bewegung des Transportbandes und/oder die Beladung
derart ist, daß durch das Aufsprühen einer geringen Menge und das Aufsprühen mit geringer
Intensität ein im wesentlichen vollständiger Kontakt und eine im wesentlichen gleichmäßige
Verteilung erreicht wird.
7. Verfahren nach einem der Ansprüche 1 bis 6, wobei ein Waschzyklus oder eine Waschzone
das Aufsprühen der Reinigungsformulierung umfaßt.
8. Verfahren nach einem der Ansprüche 1 bis 7, wobei eine weitere, bevorzugt nicht-identische
Reinigungsformulierung in üblicher Weise eingeführt wird.
9. Verfahren nach Anspruch 8, wobei die Reinigungsformulierungen einander ergänzen.
1. Procédé de lavage de vaisselle à la machine, dans lequel il existe un ou plusieurs
cycles ou zones de prélavage facultatif, un ou plusieurs cycles ou zones de lavage
et un ou plusieurs cycles ou zones de rinçage qui comprend la pulvérisation à l'intérieur
de la machine à partir d'une pluralité d'ajutages sur les articles au moins partiellement
salis en une pulvérisation fine, en douceur, du type brouillard, d'une formulation
de nettoyage aqueuse hautement concentrée comprenant au moins 0,5 % en poids d'un
ou plusieurs agents nettoyants actifs, et, après un temps de contact de 2 à 100 secondes,
pendant lequel les articles ne sont pas délibérément pulvérisés, l'enlèvement de la
formulation de nettoyage et des souillures en un ou plusieurs stades consécutifs,
la formulation de nettoyage étant pulvérisée avant le cycle ou zone de rinçage final.
2. Procédé selon la revendication 1, dans lequel la formulation de nettoyage pulvérisée
comprend de 0,8 à 10 pour cent en poids, de préférence de 0,9 à 3 pour cent en poids
d'un ou plusieurs agents actifs de nettoyage.
3. Procédé selon la revendication 1 ou la revendication 2, dans lequel le temps de contact
est compris entre 5 et 100 secondes, de préférence entre 8 et 25 secondes.
4. Procédé selon l'une quelconque des revendications 1 à 3, dans lequel la formulation
de nettoyage est pulvérisée en une quantité et d'une manière telles qu'elle vient
en contact sensiblement avec la totalité des surfaces des articles souillés.
5. Procédé selon la revendication 4, dans lequel le volume de la formulation de nettoyage
pulvérisée et/ou le nombre et/ou la disposition des ajutages de pulvérisation est/sont
tels qu'une pulvérisation de faible volume et de faible intensité mènera à un contact
sensiblement complet et une répartition sensiblement uniforme.
6. Procédé selon l'une quelconque des revendications 1 à 5, dans lequel, dans une machine
du type à bande transporteuse, la vitesse et/ou le mouvement de la bande transporteuse
et/ou de la charge est/sont tels qu'une pulvérisation de faible volume et de faible
intensité amènera un contact sensiblement complet et une répartition sensiblement
uniforme.
7. Procédé selon l'une quelconque des revendications 1 à 6 dans lequel un cycle ou zone
de lavage comprend la pulvérisation de la formulation de nettoyage.
8. Procédé selon l'une quelconque des revendications 1 à 7, dans lequel une autre formule
de nettoyage, de préférence non identique, est introduite de manière classique.
9. Procédé selon la revendication 8 dans lequel les formules de nettoyage sont complémentaires.