[0001] The present invention relates to an alveolar sheet of polycarbonate comprising a
first outer wall and a second outer wall, with both of said walls being horizontal
and parallel, and joined with each other by perpendicular, equidistant baffles. At
least one of said outer walls comprises a polycarbonate layer, to which a substance
capable of neutralizing the action of U.V. light -- which in the following is simply
denominated "U.V.-protective substance" -- is added.
[0002] The alveolar sheets of polycarbonate are used above all in the industrial buildings
for replacing glass when large luminous surfaces endowed with optimum characteristics
of thermal insulation, impact strength, light-weight, easy assemblage and transportation,
have to be accomplished.
[0003] However, polycarbonate is known to the particularly sensitive to U.V. light, the
sun light is composed by.
[0004] Such U.V. light has the property of neutralizing the molecular bonds which endow
the polycarbonate with the excellent mechanical characteristics it is provided with,
causing it to rapidly decay. In the presence of such a phenomenon, those skilled in
the art are used to speak in terms of "polycarbonate ageing".
[0005] In order to obviate such a drawback, it is known to blend a U.V.-protective substance
to polycarbonate during the extrusion step. Said U.V.-protective substance performs
its function by performing a filtering action, of random character, of U.V. light.
[0006] In other terms, the higher the concentration of particles of U.V.-protective substances
per each unit of surface area to be protected, the higher the probability that a U.V.
beam impinging on the same surface meets one of said particles, rather than a molecule
of polycarbonate. The U.V. beam impinging against an U.V.-protective particle is
obviously neutralized by the said particle.
[0007] A sheet as above described is already known from European patent No. 110,238.
[0008] According to such patent, in said sheet at least one of the two outer walls, kept
bonded to the other outer wall by vertical baffles, is constituted by two overlapping
polycarbonate layers.
[0009] The first, outermost, layer, is constituted by simple polycarbonate, and the second
layer, underlying the first layer, and adherent to it, is constituted by polycarbonate
to which an U.V.-protective substance is added.
[0010] Such a structure, although fulfils in a satisfactory way the tasks it was designed
for, suffers from some drawbacks. Those skilled in the art know that the addition
of the U.V.-protective substance impairs the extrusion ability characteristics of
a polycarbonate containing such an additive, and that, therefore, the higher the percentage
of U.V.-protective substance, the more difficult the sheets to be obtained with no
extrusion drawbacks.
[0011] Furthermore, from a probabilistic standpoint, the increase, beyond certain limits,
of the concentration of U.V.-protective substances along one surface only of the sheet,
does not result in a proportional increase in protection, but in an actual protection
increase, which is proportionally lower and lower, until a saturation limit is reached.
[0012] One should furthermore bear in his mind that the U.V.-protective substance is particularly
expensive, and that the manufacturers of the sheets are interested in keeping the
used percentages thereof as low as possible.
[0013] The purpose of the present invention is to provide a sheet which makes it possible
the above drawbacks to be obviated, and which is hence endowed with a good level of
resistance to ageing, even if low percentages of U.V.-protective substance are used,
and which, thanks to the use of limited percentages of U.V.-protective substance is
also cheap and easily extrudable.
[0014] The alveolar sheet of polycarbonate of the present invention comprises a first outer
wall and a second outer wall, both of which are horizontal and parallel, and are joined
with each other by equidistant perpendicular baffles, with at least one of said two
outer walls comprising a layer of polycarbonate to which an U.V. light neutralizing
substance is added, and is characterized in that it comprises, associated with said
layer of polycarbonate to which an U.V. light neutralizing substance is added, a set
of layers perpendicular to said layer, which perpendicular layers also are made from
polycarbonate to which an U.V.-protective substance is added.
[0015] The advantages obtained by means of the present invention are substantially those
of producing a sheet which, with its resistance to ageing being the same, results
cheaper, and more easily extrudable. The better extrusion ability of the sheet results
in a reduction in the pieces affected by imperfections.
[0016] The invention is disclosed in greater detail in the following, with the aid of the
hereto attached drawing table, wherein Figure 1 shows a perspective view of a piece
of sheet manufactured according to the invention.
[0017] The sheet of the invention, generally indicated by the reference numeral 1, is a
polycarbonate sheet of alveolar type.
[0018] It is constituted by a first outer wall 2 and a second outer wall 3, which are joined
with each other by a plurality of baffles 4 positioned perpendicularly to the same
walls 2 and 3.
[0019] The first wall 2 is constituted by an outer layer 5 of pure carbonate adhering to
an inner layer 6 of polycrbonate to which an U.V.-protective substance is added.
[0020] For indicative purposes, the inner layer 6 is constituted by 96% of polycarbonate
and 4% of U.V.-protective substance.
[0021] The perpendicular baffles 4 have a thickness which is substantially equal to the
thickness of the walls 2 and 3 and in the nearby of their middle axis, baffles 7 are
provided, which are parallel to the walls 2 and 3, and have a thickness lower than
the thickness of the perpendicular baffles 4.
[0022] The portions 10 of the perpendicular baffles 4 between the baffles 7 and the inner
layer 6 are constituted by a structure having, for purely indicative purposes, a composition
of 98% of polycarbonate, to which a 2% of U.V.-protective substance is added.
[0023] The sheet 1 is assembled in the building in such a way that the wall 2 is directed
towards the light source generating the U.V. light. Nearly all of the U.V. light impinging
of the wall 2 is neutralized by the inner layer 6, and the outer layer 5 performs
a simple action of protection of the inner layer 6 from possible attacks of chemical,
or mechanical nature, which may take place above all during the sheet extrusion process.
[0024] The U.V. light which succeeds in overcoming the inner layer 6 is neutralized by the
baffle portions 10, with a particularly high effectiveness, precisely thanks to the
perpendicular position of said baffle portions 10 relatively to the layer 6.
[0025] The overall effectiveness of the inner layer 6 associated with the pluralty of portions
of baffles 10 perpendicular to it, is generally higher than it would be obtained by
means of a single layer, or of a plurality of parallel layers containing, in the overall,
identical percentages of U.V.-protective substance.
[0026] The layer(s) of polycarbonate containing the U.V.-protective substance, and associated
with the perpendicular baffles 4 can be also extended, of course, along the portions
6.
1. Alveolar sheet of polycarbonate comprising a first outer wall and a second outer
wall, both of which are horizontal and parallel, and joined with each other by equidistant
perpendicular baffles, with at least one of said two outer walls comprising a layer
of polycarbonate to which an U.V. light neutralizing substance is added, and is characterized
in that it comprises, associated with said layer of polycarbonate to which an U.V.
light neutralizing substance is added, perpendicular layers also made from polycarbonate
to which an U.V.-protecting substance is added.
2. Sheet according to claim 1, characterized in that one only of the outer walls (2)
comprises a layer of polycarbonate (6) to which an U.V.-light neutralizing substance
is added, with the perpendicular layers of polycarbonate to which an U.V. light neutralizing
substance is added being associated with the perpendicular baffles (4).
3. Sheet according to claim 2, characterized in that with each perpendicular baffle
(4) one, and only one, layer of polycarbonate to which an U.V.-light neutralizing
substance is added, is associated.
4. Sheet according to claim 3, characterized in that the layer of polycarbonate to
which an U.V.-light neutralizing substance is added, is dispersed inside each perpendicular
baffle (4).
5. Sheet according to claim 4, characterized in that the dispersion of polycarbonate
to which an U.V.-light neutralizing substance is added, is carried out in one portion
(10) only of the perpendicular baffles (4), which is comprised between the outer plane
(2), comprising the layer (6) of polycarbonate to which a neutralizing substance is
added, and the baffles (7) incident to the perpendicular baffles (4).
6. Sheet according to claim 5, characterized in that the incident baffles (7) have
a thickness substantially lower than the thickness of the outer walls (2), (3) and
than the thickness of the perpendicular baffles (4).