| (19) |
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(11) |
EP 0 291 859 A1 |
| (12) |
EUROPEAN PATENT APPLICATION |
| (43) |
Date of publication: |
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23.11.1988 Bulletin 1988/47 |
| (22) |
Date of filing: 12.05.1988 |
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| (84) |
Designated Contracting States: |
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AT BE CH DE ES FR GB GR IT LI NL |
| (30) |
Priority: |
18.05.1987 IT 2056887 13.11.1987 IT 2263487
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| (71) |
Applicant: T.A.T. S.a.s. di COMBI MARIA LUISA & C. |
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I-20022 Castano Primo (Milano) (IT) |
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| (72) |
Inventor: |
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- Alessi, Augusto
I-20022 Castano Primo (Milano) (IT)
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| (74) |
Representative: Dr. Ing. A. Racheli & C. S.r.l. |
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Viale San Michele del Carso, 4 20144 Milano 20144 Milano (IT) |
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| |
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| (54) |
Anti-ballistic material and related manufacturing process |
(57) The present invention concerns an anti-ballistic material consisting of loose fibres,
one or two layers of woven or non-woven fabric impregnated with a cellulose acetate
butyrate or cellulose acetate propionate resin or ethyl vinyl acetate, as such or
plasticated or in a mixture with other resins the content of which is less than 50%.
Said material lends itself to various uses and in particular to further processing,
in that, being produced with a thermoplastic resin, it can be made plastic again by
heating.
[0001] The present invention concerns a bullet- and splinter- proof material.
[0002] Known processes use bonded layers for this purpose each layer consisting of a fabric-type
structure (woven or non-woven fabric, loose fibres, for example nylon, carbon or Kevlar,
a Dupont registered trademark, or other aromatic polyammides or aramides) which is
impregnated or in any event coated with plastic material. With the materials thus
far in use there are difficulties in achieving a homogeneous material, as far as ballistic
proofing characteristics are concerned, especially when manufacturing large items.
Moreover the material used up to now has a relatively high unit weight, rendering
the items produced too heavy or too bulky. Normally anti-ballistic material is also
difficult to form.
[0003] The aim of the present invention is to provide a material having high ballistic proofing
over its entire surface, that also has a low unit weight and is preferably easy to
process.
[0004] The above aims have been achieved with a material consisting of loose fibres, spun
products, woven and non-woven fabrics, impregnated or coated with cellulose acetate
butyrate or cellulose acetate propionate or ethyl vinyl acetate as such or plasticated
or mixed with other resins the content of which is lower than 50%.
[0005] The above described material is preferably produced by immersing the base layer in
a tank containing a solution or a dispersion of the above-mentioned resin and then
subjecting it to heat treatment to allow the solvents or the water to evaporate.
[0006] The amount of product deposited on each layer is adjusted simply by changing the
viscosity of the solution or the dispersion or by constantly squeezing the base. In
this manner a high degree of evenness is easily achieved in the production of each
layer. Heating is preferably carried out in a heated vertical tunnel through which
the material is passed, an impregnated product being obtained that feels soft and
is therefore easily shaped.
[0007] If the material is heated to a higher temperature, 120-130°C, the result is a semi-rigid
impregnated product suitable for flat shapes.
[0008] The material according to the invention offers a series of advantages. As far as
its characteristics are concerned, it has a lower unit weight than other known materials
having the same strength, its ballistic proofing is even and remains unchanged by
time. As far as its formability is concerned, being produced with a thermoplastic
resin the material lends itself to re-shaping and re-forming: all that is required
is heating to make the hardened product become plastic again. As regards cost, the
production cycle is economical because the process does not involve any critical step,
thus it requires only limited supervision.
1. An anti-ballistic material characterized in that it consists of fibres, spun products
impregnated with cellulose acetate butyrate or cellulose acetate propionate or ethyl
vinyl acetate as such or plasticated or mixed with less than 50% of other resins.
2. A material according to claim 1, characterized in that loose fibres are impregnated.
3. A material according to claim 1, characterized in that a layer of woven or non-woven
fabric is impregnated.
4. A material according to the preceding claims, characterized in that a plurality
of impregnated base layers are made fast with each other by hot-pressing.
5. A material according to any one of the preceding claims, characterized in that
the impregnated fibres, spun products or fabrics consist of aramides, aromatic polyammides,
glass, carbon or other synthetic or artificial materials.
6. Anti-ballistic products characterized in that they have been manufactured from
the material according to any one of claims 1 to 5.
7. A manufacturing process for the material coated with cellulose acetate butyrate
or cellulose acetate propionate or ethyl vinyl acetate, characterized in that the
base layer is covered, spread, soaked, impregnated with cellulose acetate butyrate
or cellulose acetate propionate or ethyl vinyl acetate.
8. A process according to claim 7, characterized in that each layer is immersed in
a tank containing a solution or a dispersion of the resin, then subjected to heat
treatment to allow the solvents or the water to evaporate.
9. A process according to claim 7 or 8, characterized in that each layer, after impregnation
or coating with cellulose acetate butyrate or cellulose acetate propionate or ethyl
vinyl acetate passes through a heated vertical tunnel.
