|
(11) | EP 0 321 401 B1 |
| (12) | EUROPEAN PATENT SPECIFICATION |
|
|
| (54) |
Polymeric colour couplers Farbbildende polymerische Kuppler Coupleurs polymères formateurs de couleur |
|
|
|||||||||||||||||||||||||||||||
| Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention). |
[0001] This invention relates to new polymeric colour couplers and to their use in photographic materials.
[0002] There is currently on the market camera speed film material which comprises silver halide and colour couplers in a silver halide emulsion layer which yields on colour development a so-called monochromatic dye image. This material has some advantages over the conventional black and white camera speed film material in that the dye images are virtually grainless compared with the silver image obtained using high-speed film material. Furthermore film material of this type can be processed using conventional colour film processing chemistry. Most processing houses are now set-up to process only colour film and thus it is a great convenience to be able to process the monochromatic camera speed film material in a colour film processing system.
[0003] However in order to obtain a negative which is sufficiently dense to inspect visually and has sufficient light absorbing range to print all classes of black and white paper therefrom including variable contrast paper, it has been found necessary to include in the silver halide emulsion yellow, cyan and magenta colour couplers. As these can only be incorporated in the silver halide emulsion as oil solutions this has required that a lot of oil has to be present in the photographic material in order to dissolve and keep in solution all the colour couplers.
[0004] This has led to grave disadvantages. For example when the film is cut-up oil deposits are left on the cutting equipment. Additionally as the silver halide layer is required to be thick the presence of oil droplets reduces sharpness. Further a soft layer is produced which can lead to mechanical damage.
[0005] We have found a method of incorporating cyan, magenta and yellow colour couplers in a single silver halide emulsion layer which does not require the use of oil as a solvent therefor.
[0006] According to the present invention there is provided a polymeric colour coupler which comprises the residue of three monomeric colour couplers of the formulae :-
where R₁ is hydrogen, alkyl, chlorine or bromine, R₂ is a divalent organic radical and W₁, W₂ and W₃ are each an active colour former moiety capable of forming upon chromogenic development of exposed silver halide material with a primary aromatic amine colour developing agent a dye, W₁ forming a yellow dye, W₂ forming a magenta dye and W₃ forming a cyan dye.
[0007] Preferably the three moieties W₁, W₂ and W₃ are present in the polymer in such a ratio that a black or blackish dye is obtained upon colour development.
[0008] W₁, W₂ and W₃ can be any coupler moiety known in the art such as those described below. Preferably R₁ is hydrogen or methyl. Preferably R₂ the divalent organic radical may be the residue of a urethane, a urea, a carbonate, an ester, an ether, a ketone or an amide. More preferably however it is a simple amido linkage -C(O)-NH-.
[0009] The polymeric colour coupler of the type described may be formed as a polymer latex which is not isolated but is used as such. Or it may be formed as a water-soluble solid. If it is formed as a polymer latex there is preferably present in the polymer unit at least one other simple, non-colour-coupling photograhically inert comonomer. The presence of other monomers in the polymer is particularly desirable if the polymer is to be incorporated in photographic material as a latex. In which case it is desirable that a latex polymer is produced having optimum physical properties, such as glass transition temperature, compatibility with the gelatin used in preparing coating solutions, suitable refractive index, as well as beneficial rates of copolymerisation between the coupler monomers and the photographically inert comonomers and the ability to confer lowered viscosity and reasonable miscibility with the mixture of coupler monomers.
[0010] When the polymeric colour coupler of the type described is formed as a water-soluble solid there is present in the polymer from 40 - 60% by weight of the residue of a monomer which has the formula IV
where R₁ has the meaning assigned to it above, L is an alkylene or interrupted alkylene linking group and R¹ and R¹¹ are alkyl groups having 1 to 4 carbon atoms and X is an anion.
[0011] L is preferably an alkylene chain having from 2 to 6 carbon atoms or is an interupted alkylene chain having from 2 to 6 carbon atoms there being an oxygen from or an -NH- group in the chain.
[0013] Suitable comonomers which may be present when the polymeric colour coupler is formed as a polymer latex or as a water soluble polymer include methyl acrylate, ethyl acrylate, butyl acrylate, ethyl hexyl acrylate, vinyl acetate; hydroxyethyl methacrylate, hydroxypropylmethacrylate; methacrylic acid, acrylic acid, itaconic acid, 2-carboxyethyl acrylate and the salts thereof, acrylamide, methacrylamide, N-hydroxymethyl acrylamide, styrene, N-vinyl pyrrolidone, 1-vinyl imidazole; 4-vinylpyridine, dimethylaminoethyl methacrylate, tetrahydrofurfuryl methacrylate; sulfphoethyl methacrylate, vinyl sulphonic acid and salts thereof, acrylonitrile and vinylidene chloride, although this list is not intended to be comprehensive.
[0014] In addition, crosslinking monomers may be present such as divinyl benzene, ethylene dimethacrylate, trivinyl cyclohexane and trimethylol propane triacylate.
[0015] The surface active agents used in the preparation of the polymer latex may be any of those well known in the art, for example nonionic wetting agents including alcohol ethoxylates, sorbitan esters, aryl phenol alkoxylates, alkyl alkanolamides, anionic wetting agents including alkyl sulphates and sulphonates, sulphosuccinates, aryl sulphonates, polyalkoxy sulphates, alkyl phosphates, aryl phenol phosphates, alkyl taurates, sarcosinates, and copolymerisable surfactants such as allyl sulphosuccinates, again this list is not intended to be exhaustive.
[0016] The initiators and initiator systems used for the preparation of the latices may be persulphates, azo compounds, peroxides or any of the other well known initiators used for emulsion polymerisation, including redox systems. Examples of these initiator systems may be found in the book "Emulsion Polymerisation" by D. Blackely, Applied Science Publishers, 1975 especially pages 155 to 250.
[0017] The methods for the preparation of the latices may make use of techniques such as "seed" polymerisation and core-shell techniques, as well as "power-feed" procedures and other methods well known in the art. Latices may be prepared in bulk, semi-continuously or continuously using any of the known designs of apparatus.
[0018] According to another aspect of the present invention there is provided photographic material having at least one gelatino silver halide emulsion layer which comprises a polymeric colour coupler of the type described. More preferably, the photographic material comprises a polymeric colour coupler which comprises the residues of monomers A, B and C shown below.
[0019] In one embodiment the polymeric colour coupler of the type described is present in the silver halide emulsion layer as a polymer latex.
[0020] In another embodiment the colour coupler of the type described is added to the silver halide emulsion layer as an aqueous solution.
[0021] Any of the monomeric colour couplers described in the prior art may be used in the polymeric colour coupler of the present invention. The colour coupler portion of the monomer may comprise ballasting groups or leaving groups for example so that the colour coupler may act as a two equivalent coupler.
[0022] Examples of the yellow dye forming monomeric colour couplers include couplers of the general formula VI -
wherein each of R₃, R₄, R₅ and R₆ are hydrogen, halogen, alkoxy, sulphoxy or sulphonamido, R₁ and R₂ are as defined above, R₇ is hydrogen or a leaving group and L₁ and L₂ are direct linkages or -NH-.
[0024] Preferably one of L₁ and L₂ is a direct linkage. An example of such a monomer is Monomer B which is used in the Examples which follow. This monomer has the formula VII :
[0026] A further example of a monomer of general formula VI which has a leaving group in the monomer of the formula IX :-
[0028] Another class of yellow dye forming monomeric colour couplers has a pivaloyl end group rather than a benzoyl end group.
[0029] Such colour couplers have the general formula X :-
where R₁, R₂, R₆ and R₇ have the meanings assigned to them above.
[0031] Examples of magenta dye forming monomeric colour couplers include couplers of the general formula XII :-
where R₁ and R₂ are as defined above, R₈ is hydrogen or a leaving group and R₁₀ R₁₁ and R₁₂ are each hydrogen, halogen or alkoxy. Preferably the alkoxy group comprises an alkyl moiety having up to six carbon atoms.
[0032] Preferably R₁ is hydrogen or -CH₃
Preferably R₂ is -CO NH -
However other useful linking groups R₂ include
-CO NH(CH₂)x -O-CO-NH
where x is 2 to 6,
where in the above two formulae the phenylene group is optionally substituted by chlorine alkyl having 1 to 4 carbon atoms.
[0033] Particularly useful monomers of formula XII are those wherein at least two of R₁₀, R₁₁ and R₁₂ are chlorine atoms.
[0034] Examples of leaving groups R₇ or R₈ includes the group -S- R₉ where R₉ is a long chain alkyl group having over 10 carbon atoms or is a substituted phenyl group having at least one alkyl or alkoxy group. Preferably R₉ when an alkyl group has from 12 to 20 carbon atoms or the chain.
[0036] Examples of monomers of formula XII are :-
and Monomer A which is used in the Examples which follow and which has the formula :-
[0038] Another type of magenta dye forming monomeric colour couplers are those of general formula XVI :-
wherein R₁, R₈ and R₁₀ are as defined above and R₁₉ is alkyl, dialkyl amino, optionally substituted phenyl and optionally substituted acylamino. Substituents in the phenyl or ecylamino group include alkyl groups having 2 to 6 carbon atom and chloric.
[0039] These couplers may be prepared by reacting magenta colour couplers of the formula
with acryloyl or methacryloyl chloride
[0040] Examples of cyan dye forming monomeric colour couplers include phenol couplers of the general formula XVIII :-
and of general formula XIX :
and a naphthol coupler of the general formula XX :-
wherein the above three formulae R₁ and R₁₂ are as defined above, R₁₄ is hydrogen or a leaving group such as a halogen atom or a substituted alkoxy group, R₁₃ is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, R₁₅ is an optionally substituted alkyl or acylamino group or is a para - cyano amilino group and R₁₇ is a linking group and y is 0 or 1, and R₁₆ is an alkoxy, amino, amido or sulphonamido group or hydrogen atom.
[0042] Examples of the linking groups R₁₇ include alkylene chains of 2 to 6 carbon atoms including interrupted alkylene chains and an alkyl group for example
[0043] Preferably interupted alkylene chains have from 2 to 6 carbon atoms and - O - or - NH - group in the chain.
[0045] This Monomer C which is used in the Examples which follow, further examples of monomers of formula XVIII are of the formula
[0049] The colour couplers of the type described are of particular use in monochromatic camera speed silver halide film material. The photographic material after imagewise exposure is developed in a colour developing bath by use of a para - phenylene diamine developing agent to yield a developed silver image and black dye image. The material is then subjected to a bleach fix treatment which removes the developed silver image and then unexposed silver halide leaving the black dye negative image which can be used to print all types of black and white paper including variable contrast paper.
[0050] The colour couplers of the type described can also be used to prepare monochromatic paper. That is to say paper which can be processed using colour processing chemistry to yield a black dye image instead of a silver image. Paper of this type is of particular use from which to prepare proof prints.
[0051] The colour coupler of the type described can also be used to reinforce silver halide images at such time that, as occurred some years ago, the price of silver becomes too prohibitive to use in photography when a very dense silver image is required.
[0052] The photographic material of the present invention preferably comprises gelatin as the binder in the silver halide emulsion layer.
[0053] The halide used can be any of the silver halides normally used in photography e.g. silver bromide, silver iodobromide, silver chloride, silver chlorobromide and silver iodochlorobromide. The silver halide grains may be both optically and chemically sensitised. The silver halide emulsion may contain stabiliser, bacteriocides and any of the other additives commonly found in photographic silver halide emulsions. The gelatin may have been hardened and may contain coating aids as usual when preparing coated silver halide emulsions.
[0054] For camera speed film material the base can be any of the usual transparent bases used in photography for example subbed polyester, polycarbonate or polystyrene base, or may be a cellulose triacetate or cellulose acetate - butyrate base. If the material is to be used for proof prints the base may be any opaque base in common use for photographic print material for example baryta coated paper base or polyethylene laminated paper base.
Example 1
[0056] To a solution of sodium oleyl methyl taurate which comprised 0.16 g in 15.8 ml of water maintained at 80°C in a 100 ml reaction vessel there was added under a nitrogen atmosphere and mechanical stirring 70 mg of potassium persulphate and 10 mg of sodium metabisulphite.
[0057] A monomer solution was made by dissolving in 2.00 g hydroxy propyl methacrylate and 3.00 g butyl acrylate 0.34 g Monomer A, (magenta monomer), 0.34g Monomer B (yellow monomer) and 0.34 g Monomer C (cyan monomer). The vessel containing this solution was maintained at about 30 to 40°C. A surfactant solution was prepared by dissolving in 5.80 g water sodium oleylmethyl taurate 0.16 g and potassium persulphate 40 mg.
[0058] The surfactant and monomer solutions were then fed slowly into the 100 ml vessel which comprised the initiator solution first set forth. These additions were made over 2 hours. The resultant latex formed in the 100 ml vessel was maintained at 80°C for 1 ½ hours. The contents were then cooled and filtered.
[0059] After isolation a latex having 22 % solids content was obtained with particle size of 72 nm. A total of only 0.04 g of coagulum was present in the vessel.
[0060] The latex as just prepared was used to prepare colour photographic material. To 2.2 ml of an undyed twinned crystal iodobromide gelatino emulsion there was added 0.4 ml of the latex and 7 ml of water. To this emulsion there was added 0.4 ml. of water. To this emulsion there was added 0.4 ml of a 3% solution of a triazine hardener. The emulsion was then coated on clear cellulose triacetate base to provide a silver coating weight of 12 mg/dm². The coating was dried and inspected in green light to show a clear, glossy coating.
This photographic material was then exposed to a white light source for 10 seconds and processed in a colour developing solution for 3.25 minutes at 38°C.
[0064] The formula of the bleach bath used is as follows :-
- ammonium bromide
- 150 g
- ferric EDTA 1.8 M
- 150 ml
- sodium nitrate
- 20 g
- water to
- 1 litre
[0065] The material was then passed to a fixing bath at 35°C for 6 ½ minutes of the formula :-
- ammonium thiosulphate (80% w/v)
- 190 ml
- sodium sulphite
- 19 g
- sodium EDTA
- 1.5 g
- water to
- 1 litre
[0066] The material was then washed for 3 minutes in water at 30°C and then dried. A neutral grey image was present on the photographic material. This image has the visible absorption spectrum shown in the accompanying Figure 1. This shows that the material has good absorption in the blue, green and red regions of the visible spectrum.
[0067] Two other samples of photographic material as just prepared were prepared except that the silver halide emulsion comprised a green sensitising dye and a red sensitising dye. Thus the material was panchromatically sensitised.
[0069] One of the negatives obtained thereby was placed in a photographic enlarger and was used to print normal non-optically sensitised black and white paper. After processing the exposed paper a bright image having clear highlights and dark shadows was obtained.
The other of the negatives obtained was placed in a photographic enlarger provided with a filter to enable variable contrast photographic paper to be printed. An inspection of the image on the enlarger baseboard indicated that a No. 2 contrast filter should be used. This was placed in position with a sheet of variable contrast material below it and was printed using the negative. After processing the print was examined. As before a bright print having clear highlights and dark shadows was obtained.
[0070] The shows that the photographic material of the present invention can be used to provide negatives which can be used to print ordinary black and white paper material as well as variable contrast black and white photographic papers.
Example II
[0072] p-Toluene sulphonic acid (4g) was dissolved in industrial alcohol (30 ml). Sufficient of the monomer dimethyl-aminoethyl methacrylate was added with stirring to raise the pH to 7. This required 5.2 g. This solution was placed in a 50 ml flask to which were added 1 g of Monomer A (the magenta monomer), 0.5 g of Monomer B (the yellow monomer) and 0.5 g of Monomer C (the cyan monomer). The flask was equipped with a condenser, nitrogen inlet, oil bath and magnetic stirrer. Nitrogen was bubbled through for 10 minutes at room temperature. The flask was then heated to 70°C and maintained at that temperature.
[0073] A free radical initiator solution was prepared which comprised 0.5 g azobis(isobutyronitrile) in 50 ml of industrial alcohol. 4.8 ml of this solution was added to the flask. After 2 hours a further 1.2 ml of the initiator solution was added and this was repeated after a further 2 hours. After 7 hours reaction time the contents of the flask were added to ether (500 ml) and a tacky brown solid precipitated. This solid was dissolved in industrial alcohol and reprecipitated in ether to give a free flowing white powder. Yield 7.13 g (67.3 %). This powder was found to be completely water soluble.
[0074] 0.1g of this solid was then added to an emulsion as prepared in Example 1. A clear glossy coating was used in Example 1. A clear glossy coating was found on inspection in green light. As in Example 1 the coating was exposed to white light for 10 seconds and then was processed as set forth in Example 1.
1. A polymeric colour coupler which comprises the residue of three monomeric colour
couplers of the formulae : -
where R₁ is hydrogen, alkyl, chlorine or bromine, R₂ is a divalent organic radical and W₁, W₂ and W₃ are each an active colour former moiety capable of forming upon chromogenic development of exposed silver halide material with a primary aromatic amine colour developing agent a dye, W₁ forming a yellow dye, W₂ forming a magenta dye and W₃ forming a cyan dye.
where R₁ is hydrogen, alkyl, chlorine or bromine, R₂ is a divalent organic radical and W₁, W₂ and W₃ are each an active colour former moiety capable of forming upon chromogenic development of exposed silver halide material with a primary aromatic amine colour developing agent a dye, W₁ forming a yellow dye, W₂ forming a magenta dye and W₃ forming a cyan dye.
2. A polymer colour coupler according to claim 1 wherein R₁ is hydrogen or methyl.
3. A polymeric colour coupler according to claim 1 wherein R₂ is the residue of a
urethane, a urea, a carbonate, an ester, an ether, a ketone or an amide.
4. A polymeric colour coupler according to claim 3 wherein R₂ is - C (0) - NH -.
5. A polymeric colour coupler according to claim 1 wherein the polymer is formed as
a latex which is not isolated but which is used as such.
6. A polymeric colour coupler according to claim 5 wherein the polymer comprises units
derived from at least one non-colour coupling, photographically inert comonomer.
7. A polymeric colour coupler according to claim 6 wherein the photographically inert
comonomer is methyl acrylate, ethyl acrylate, butyl acrylate, ethyl hexyl acrylate,
vinyl acetate; hydroxyethyl methacrylate, hydroxypropylmethacrylate; methacrylic acid,
acrylic acid, itaconic acid, 2-carboxyethyl acrylate and the salts thereof, acrylamide,
methacrylamide, N-hydroxymethyl acrylamide, styrene, N-vinyl pyrrolidone, 1-vinyl
imidazole; 4-vinylpyridine, dimethylaminoethyl methacrylate, vinyl sulphonic acid
and their salts thereof, acrylonitrile and vinylidene chloride.
8. A polymeric colour coupler according to claim 1 wherein the polymer is formed as
a water-soluble solid.
9. A polymeric colour coupler according to claim 8 wherein there is present in the
polymer from 40 - 60% by weight the residue of a monomer which has the formula.
wherein R₁ has the meaning assigned to it in claim 1, L is an alkylene or interupted alkylene linking group R¹ and R¹¹ are alkyl groups having 1 to 4 carbon atoms and X⁻ is an anion.
wherein R₁ has the meaning assigned to it in claim 1, L is an alkylene or interupted alkylene linking group R¹ and R¹¹ are alkyl groups having 1 to 4 carbon atoms and X⁻ is an anion.
10. A polymeric colour coupler according to claim 1 which comprises the residue of
a yellow dye forming monomeric colour coupler of the general formula :-
wherein each of R₃, R₄, R₅ and R₆ are hydrogen, halogen, alkoxy, sulphoxy or sulphonamido, R₁ and R₂ are as defined in claim 1, R₇ is hydrogen of a leaving group and L₁ and L₂ are direct linkages or -NH-.
wherein each of R₃, R₄, R₅ and R₆ are hydrogen, halogen, alkoxy, sulphoxy or sulphonamido, R₁ and R₂ are as defined in claim 1, R₇ is hydrogen of a leaving group and L₁ and L₂ are direct linkages or -NH-.
11. A polymeric colour coupler according to claim 1 which comprise the residue of
a yellow dye forming monomeric colour coupler of the general formula :-
wherein R₁ and R₂ are as defined in claim 1 and R₆ and R₇ are as defined in claim 10.
wherein R₁ and R₂ are as defined in claim 1 and R₆ and R₇ are as defined in claim 10.
12. A polymeric colour coupler according to claim 1 which comprises the residue of
a magenta dye forming monomeric colour coupler of the general formula :-
where R₁ and R₂ are as defined in claim 1, R₈ is hydrogen or a leaving group and R₁₀, R₁₁ and R₁₂ are each hydrogen halogen or alkoxy.
where R₁ and R₂ are as defined in claim 1, R₈ is hydrogen or a leaving group and R₁₀, R₁₁ and R₁₂ are each hydrogen halogen or alkoxy.
13. A polymeric colour coupler according to claim 1 which comprises the residue of
a magenta dye forming monomeric colour coupler of the general formula
wherein R₁ is as defined in claim 1, R₈ and R₁₀ are as defined in claim 12 and R₉ is alkyl, dialkylamino, operationally substituted aryl and optionally substituted acylamino.
wherein R₁ is as defined in claim 1, R₈ and R₁₀ are as defined in claim 12 and R₉ is alkyl, dialkylamino, operationally substituted aryl and optionally substituted acylamino.
14. A polymeric colour coupler according to claim 1 which comprises the residue of
a cyan dye forming monomeric colour coupler which is a phenol coupler of the general
formula :-
or is a phenol coupler of the general formula :-
or is a naphthol coupler of the general formula
wherein the above three formulae R₁ and R₁₂ are as defined in claim 13, R₁₄ is hydrogen or a leaving group such as a halogen atom or a substituted alkoxy group, R₁₃ is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, R₁₅ is an optionally substituted alkyl or acylamino group or is a para - cyano anilino group and R₁₇ is a linking group and y is 0 or 1, and R₁₆ is an alkoxy, amino amido, sulphonamide group or a hydrogen atom.
or is a phenol coupler of the general formula :-
or is a naphthol coupler of the general formula
wherein the above three formulae R₁ and R₁₂ are as defined in claim 13, R₁₄ is hydrogen or a leaving group such as a halogen atom or a substituted alkoxy group, R₁₃ is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, R₁₅ is an optionally substituted alkyl or acylamino group or is a para - cyano anilino group and R₁₇ is a linking group and y is 0 or 1, and R₁₆ is an alkoxy, amino amido, sulphonamide group or a hydrogen atom.
15. Photographic material having at least one gelatino silver halide emulsion layer
which comprises a polymeric colour coupler as claimed in claim 1.
1. Polymerer Farbkuppler, bestehend aus dem Rest dreier monomerer Farbkuppler der
Formeln:
worin R₁ Wasserstoff, Alkyl, Chlor oder Brom, R₂ einen zweiwertigen organischen Rest und W₁, W₂ und W₃ jeweils einen aktiven Farbbildnerrest bedeuten, der dazu in der Lage ist, bei chromogener Entwicklung von belichtetem Silberhalogenidmaterial mit einem Farbentwicklungsmittel aus primärem aromatischem Amin einen Farbstoff zu bilden, wobei W₁ einen gelben Farbstoff, W₂ einen Magentafarbstoff und W₃ einen Cyanfarbstoff bildet.
worin R₁ Wasserstoff, Alkyl, Chlor oder Brom, R₂ einen zweiwertigen organischen Rest und W₁, W₂ und W₃ jeweils einen aktiven Farbbildnerrest bedeuten, der dazu in der Lage ist, bei chromogener Entwicklung von belichtetem Silberhalogenidmaterial mit einem Farbentwicklungsmittel aus primärem aromatischem Amin einen Farbstoff zu bilden, wobei W₁ einen gelben Farbstoff, W₂ einen Magentafarbstoff und W₃ einen Cyanfarbstoff bildet.
2. Polymerer Farbkuppler nach Anspruch 1, worin R₁ Wasserstoff oder Methyl bedeutet.
3. Polymerer Farbkuppler nach Anspruch 1, worin R₂ den Rest eines Urethans, Harnstoffs,
Carbonats, Esters, Ketons oder Amids darstellt.
4. Polymerer Farbkuppler nach Anspruch 3, worin R₂ -C(O)-NH- bedeutet.
5. Polymerer Farbkuppler nach Anspruch 1, worin das Polymer als Latex entsteht, der
nicht isoliert, sondern als solcher verwendet wird.
6. Polymerer Farbkuppler nach Anspruch 5, worin das Polymer aus Einheiten besteht,
die von mindestens einem nichtfarbkuppelnden, fotografisch inerten Comonomeren abgeleitet
sind.
7. Polymerer Farbkuppler nach Anspruch 6, worin es sich bei dem fotografisch inerten
Comonomeren um Methylacrylat, Ethylacrylat, Butylacrylat, Ethylhexylacrylat, Vinylacetat;
Hydroxyethylmethacrylat, Hydroxypropylmethacrylat; Methacrylsäure, Acrylsäure, Itaconsäure,
2-Carboxyethylacrylat sowie deren Salze, Acrylamid, Methacrylamid, N-Hydroxymethylacrylamid,
Styrol, N-Vinylpyrrolidon, 1-Vinylimidazol; 4-Vinylpyridin, Dimethylaminoethylmethacrylat,
Vinylsulfonsäure sowie deren Salze, Acrylnitril und Vinylidenchlorid handelt.
8. Polymerer Farbkuppler nach Anspruch 1, worin das Polymer als wasserlöslicher Feststoff
entsteht.
9. Polymerer Farbkuppler nach Anspruch 8, worin in dem Polymer 40-60 Gew.% des Restes
eines Monomeren der Formel
worin R₁ die in Anspruch 1 angegebene Bedeutung aufweist, L eine Alkylen- oder unterbrochene Alkylenverknüpfungsgruppe darstellt und R₁ sowie R¹¹ Alkylgruppen mit 1 bis 4 Kohlenstoffatomen und X⁻ ein Anion bedeuten, vorliegen.
worin R₁ die in Anspruch 1 angegebene Bedeutung aufweist, L eine Alkylen- oder unterbrochene Alkylenverknüpfungsgruppe darstellt und R₁ sowie R¹¹ Alkylgruppen mit 1 bis 4 Kohlenstoffatomen und X⁻ ein Anion bedeuten, vorliegen.
10. Polymerer Farbkuppler nach Anspruch 1, bestehend aus dem Rest eines gelbfarbstoffbildenden
monomeren Farbkupplers der allgemeinen Formel:
worin R₃, R₄, R₅ und R₆ jeweils Wasserstoff, Halogen, Alkoxy, Sulfoxy oder Sulfonamido bedeuten, R₁ und R₂ die in Anspruch 1 angegebene Bedeutung aufweisen, R₇ Wasserstoff oder eine Abgangsgruppe und L₁ und L₂ Direktverknüpfungen oder -NH- bedeuten.
worin R₃, R₄, R₅ und R₆ jeweils Wasserstoff, Halogen, Alkoxy, Sulfoxy oder Sulfonamido bedeuten, R₁ und R₂ die in Anspruch 1 angegebene Bedeutung aufweisen, R₇ Wasserstoff oder eine Abgangsgruppe und L₁ und L₂ Direktverknüpfungen oder -NH- bedeuten.
11. Polymerer Farbkuppler nach Anspruch 1, bestehend aus dem Rest eines gelbfarbstoffbildenden
monomeren Farbkupplers der allgemeinen Formel:
worin R₁ und R₂ die in Anspruch 1 angegebene Bedeutung und R₆ und R₇ die in Anspruch 10 angegebene Bedeutung aufweisen.
worin R₁ und R₂ die in Anspruch 1 angegebene Bedeutung und R₆ und R₇ die in Anspruch 10 angegebene Bedeutung aufweisen.
12. Polymerer Farbkuppler nach Anspruch 1, bestehend aus dem Rest eines magentafarbstoffbildenden
monomeren Farbkupplers der allgemeinen Formel:
worin R₁ und R₂ die in Anspruch 1 angegebene Bedeutung aufweisen, R₈ Wasserstoff oder eine Abgangsgruppe bedeutet und R₁₀, R₁₁ und R₁₂ jeweils Wasserstoff, Halogen oder Alkoxy darstellen.
worin R₁ und R₂ die in Anspruch 1 angegebene Bedeutung aufweisen, R₈ Wasserstoff oder eine Abgangsgruppe bedeutet und R₁₀, R₁₁ und R₁₂ jeweils Wasserstoff, Halogen oder Alkoxy darstellen.
13. Polymerer Farbkuppler nach Anspruch 1, bestehend aus dem Rest eines magentafarbstoffbildenden
monomeren Farbkupplers der allgemeinen Formel:
worin R₁ die in Anspruch 1 und R₈ und R₁₀ die in Anspruch 12 angegebene Bedeutung aufweisen und R₉ Alkyl, Dialkylamino, gegebenenfalls substituiertes Aryl und gegebenenfalls substituiertes Acylamino bedeutet.
worin R₁ die in Anspruch 1 und R₈ und R₁₀ die in Anspruch 12 angegebene Bedeutung aufweisen und R₉ Alkyl, Dialkylamino, gegebenenfalls substituiertes Aryl und gegebenenfalls substituiertes Acylamino bedeutet.
14. Polymerer Farbkuppler nach Anspruch 1, bestehend aus dem Rest eines cyanfarbstoffbildenden
monomeren Farbkupplers, bei dem es sich um einen Phenolkuppler der allgemeinen Formel:
oder um einen Phenolkuppler der allgemeinen Formel:
oder um einen Naphtholkuppler der allgemeinen Formel:
worin in den obigen drei Formeln R₁ und R₁₂ die in Anspruch 13 angegebene Bedeutung aufweisen, R₁₄ Wasserstoff oder eine Abgangsgruppe wie ein Halogenatom oder eine substituierte Alkoxygruppe, R₁₃ ein Wasserstoffatom oder eine Alklgruppe mit 1 bis 5 Kohlenstoffatomen, R₁₅ eine gegebenenfalls substituierte- Alkyl- oder Acylaminogruppe oder eine para- Cyananilingruppe und R₁₇ eine Verknüpfungsgruppe und y 0 oder 1 und R₁₆ eine Alkoxy-, Amino-, Amido- oder Sulfonamidgruppe oder ein Wasserstoffatom bedeuten, handelt.
oder um einen Phenolkuppler der allgemeinen Formel:
oder um einen Naphtholkuppler der allgemeinen Formel:
worin in den obigen drei Formeln R₁ und R₁₂ die in Anspruch 13 angegebene Bedeutung aufweisen, R₁₄ Wasserstoff oder eine Abgangsgruppe wie ein Halogenatom oder eine substituierte Alkoxygruppe, R₁₃ ein Wasserstoffatom oder eine Alklgruppe mit 1 bis 5 Kohlenstoffatomen, R₁₅ eine gegebenenfalls substituierte- Alkyl- oder Acylaminogruppe oder eine para- Cyananilingruppe und R₁₇ eine Verknüpfungsgruppe und y 0 oder 1 und R₁₆ eine Alkoxy-, Amino-, Amido- oder Sulfonamidgruppe oder ein Wasserstoffatom bedeuten, handelt.
15. Fotografisches Material mit mindestens einer Gelatine-Silberhalogenidemulsionsschicht,
die einen polymeren Farbkuppler nach Anspruch 1 enthält.
1. Copulant couleur polymère, qui comprend le résidu de trois copulants couleur monomères
de formules :
dans lesquelles R₁ est un hydrogène, un groupe alkyle, un chlore ou un brome, R₂, est un radical organique divalent et W₁, W₂ et W₃ sont chacun un groupement chromogène actif capable de former un colorant, par développement chromogène d'une substance halogénure d'argent exposée, avec un agent développateur de colorant de type amine aromatique primaire, W₁ formant un colorant jaune, W₂ formant un colorant magenta et W₃ formant un colorant cyan.
dans lesquelles R₁ est un hydrogène, un groupe alkyle, un chlore ou un brome, R₂, est un radical organique divalent et W₁, W₂ et W₃ sont chacun un groupement chromogène actif capable de former un colorant, par développement chromogène d'une substance halogénure d'argent exposée, avec un agent développateur de colorant de type amine aromatique primaire, W₁ formant un colorant jaune, W₂ formant un colorant magenta et W₃ formant un colorant cyan.
2. Copulant couleur polymère selon la revendication 1, dans lequel R₁ est un hydrogène
ou un groupe méthyle.
3. Copulant couleur polymère selon la revendication 1, dans lequel R₂ est le résidu
d'un uréthanne, d'une urée, d'un carbonate, d'un ester, d'un éther, d'une cétone ou
d'un amide.
4. Copulant couleur polymère selon la revendication 3, dans lequel R₂ est -C(O)-NH-.
5. Copulant couleur polymère selon la revendication 1, dans lequel le polymère est
formé sous forme d'un latex qui n'est pas isolé, mais qui est utilisé tel quel.
6. Copulant couleur polymère selon la revendication 5, dans lequel le polymère comprend
des motifs dérivés d'au moins un comonomère inerte en photographie, non copulant couleur.
7. Copulant couleur polymère selon la revendication 6, dans lequel le comonomère inerte
en photographie est l'acrylate de méthyle, l'acrylate d'éthyle, l'acrylate de butyle,
l'acrylate d'éthylhexyle, l'acétate de vinyle; le méthacrylate d'hydroxyéthyle, le
méthacrylate d'hydroxypropyle; l'acide méthacrylique, l'acide acrylique, l'acide itaconique,
l'acrylate de 2-carboxyéthyle et ses sels, l'acrylamide, le méthacrylamide, le N-hydroxyméthylacrylamide,
le styrène, la N-vinylpyrrolidone, le 1-vinylimidazole; la 4-vinylpyridine, le méthacrylate
de diméthylaminoéthyle, l'acide vinylsulfonique et ses sels, l'acrylonitrile et le
chlorure de vinylidène.
8. Copulant couleur polymère selon la revendication 1, dans lequel le polymère est
formé sous forme d'un solide soluble dans l'eau.
9. Copulant couleur polymère selon la revendication 8, dans lequel est présent, dans
le polymère, de 40 à 60% en poids du résidu d'un monomère répondant à la formule
dans laquelle R₁ a la signification qui lui est attribuée dans la revendication 1, L est un groupe de liaison alkylène ou alkylène interrompu et R¹ et R¹¹ sont des groupes alkyle comportant 1 à 4 atomes de carbone et X⁻ est un anion.
dans laquelle R₁ a la signification qui lui est attribuée dans la revendication 1, L est un groupe de liaison alkylène ou alkylène interrompu et R¹ et R¹¹ sont des groupes alkyle comportant 1 à 4 atomes de carbone et X⁻ est un anion.
10. Copulant couleur polymère selon la revendication 1, qui comprend le résidu d'un
copulant couleur monomère formant un colorant jaune de formule générale :
dans laquelle chacun des radicaux R₃, R₄, R₅ et R₆ sont un hydrogène, un halogène, un groupe alcoxy, sulfoxy ou sulfonamido, R₁ et R₂ sont tels que définis dans la revendication 1, R₇ est un hydrogène ou un groupe partant et L₁ et L₂ sont des liaisons directes ou -NH-.
dans laquelle chacun des radicaux R₃, R₄, R₅ et R₆ sont un hydrogène, un halogène, un groupe alcoxy, sulfoxy ou sulfonamido, R₁ et R₂ sont tels que définis dans la revendication 1, R₇ est un hydrogène ou un groupe partant et L₁ et L₂ sont des liaisons directes ou -NH-.
11. Copulant couleur polymère selon la revendication 1, qui comprend le résidu d'un
copulant couleur monomère formant un colorant jaune de formule générale :
dans laquelle R₁ et R₂ sont tels que définis dans la revendication 1 et R₆ et R₇ sont tels que définis dans la revendication 10.
dans laquelle R₁ et R₂ sont tels que définis dans la revendication 1 et R₆ et R₇ sont tels que définis dans la revendication 10.
12. Copulant couleur polymère selon la revendication 1, qui comprend le résidu d'un
copulant couleur monomère formant un colorant magenta de formule générale :
dans laquelle R₁ et R₂ sont tels que définis dans la revendication 1, R₈ est un hydrogène ou un groupe partant et R₁₀, R₁₁ et R₁₂ sont chacun un hydrogène, un halogène ou un groupe alcoxy.
dans laquelle R₁ et R₂ sont tels que définis dans la revendication 1, R₈ est un hydrogène ou un groupe partant et R₁₀, R₁₁ et R₁₂ sont chacun un hydrogène, un halogène ou un groupe alcoxy.
13. Copulant couleur polymère selon la revendication 1, qui comprend le résidu d'un
copulant couleur monomère formant un colorant magenta de formule générale :
dans laquelle R₁ est tel que défini dans la revendication 1, R₈ et R₁₀ sont tels que définis dans la revendication 12 et R₉ est un groupe alkyle, dialkylamino, aryle éventuellement substitué et acylamino éventuellement substitué.
dans laquelle R₁ est tel que défini dans la revendication 1, R₈ et R₁₀ sont tels que définis dans la revendication 12 et R₉ est un groupe alkyle, dialkylamino, aryle éventuellement substitué et acylamino éventuellement substitué.
14. Copulant couleur polymère selon la revendication 1, qui comprend le résidu d'un
copulant couleur monomère formant un colorant cyan qui est un copulant phénol de formule
générale :
ou qui est un copulant phénol de formule générale :
ou qui est un copulant naphtol de formule générale :
formules dans lesquelles R₁ et R₁₂ sont tels que définis dans la revendication 13, R₁₄ est un hydrogène ou un groupe partant, comme un atome d'halogène ou un groupe alcoxy substitué, R₁₃ est un atome d'hydrogène ou un groupe alkyle comportant 1 à 5 atomes de carbone, R₁₅ est un groupe alkyle ou acylamino éventuellement substitué, ou un groupe para-cyanoanilino, et R₁₇ est un groupe de liaison et y est nul ou égal à 1, et R₁₆ est un groupe alcoxy, amino, amido, sulfonamide ou un atome d'hydrogène.
ou qui est un copulant phénol de formule générale :
ou qui est un copulant naphtol de formule générale :
formules dans lesquelles R₁ et R₁₂ sont tels que définis dans la revendication 13, R₁₄ est un hydrogène ou un groupe partant, comme un atome d'halogène ou un groupe alcoxy substitué, R₁₃ est un atome d'hydrogène ou un groupe alkyle comportant 1 à 5 atomes de carbone, R₁₅ est un groupe alkyle ou acylamino éventuellement substitué, ou un groupe para-cyanoanilino, et R₁₇ est un groupe de liaison et y est nul ou égal à 1, et R₁₆ est un groupe alcoxy, amino, amido, sulfonamide ou un atome d'hydrogène.
15. Matériau photographique comportant au moins une couche d'émulsion de gélatino-halogénure
d'argent, qui comprend un copulant couleur polymère selon la revendication 1.