Composition for processing silver halide color photographic light-sensitive material

Abstract

 A bleaching solution composition for processing a silver halide color photographic light-sensitive material comprising a substance capable of bleaching is disclosed, said composition comprising a ferric complex of a compound represented by the following Formula A, which has bleaching capability, in an amount of not less than 40 wt% of the total amount of said substance contained in said composition and pH of said composition is in the range of from 2.0 to 6.0:

Description

FIELD OF THE INVENTION

[0001] This invention relates to a composition for processing a silver halide color photographic light-sensitive material and, more particularly, to a composition for processing a silver halide color photographic light-sensitive material which can be rapidly processed and excellent in long term stable preservability.

BACKGROUND OF THE INVENTION

[0002] To obtain a color photographic image, it is essential to carry out the so-called desilvering treatment in which a metal silver produced together with a dye image obtained in a color developing step is removed from a silver halide color photographic light-sensitive material.

[0003] Generally, such desilvering treatment is carried out in the following steps, namely, a step of converting metal silver once into silver halide through a treatment with a bleaching solution containing halogen ions and an oxidizer, and another successive step of removing silver halide produced by the bleaching treatment and silver halide remaining undeveloped through a treatment with a fixing solution containing a silver halide solvent.

[0004] Heretofore, following a color developing step, a silver halide color photographic light-sensitive material has been bleached with a bleaching agent such as a compound of hexancyanoferrate, ferric chloride, ferric complex salts of organic acids or the like.

[0005] Hexacyanoferrate and ferric chloride each are excellent bleaching agents, because they have a strong bleaching capability, a high bleaching speed, i.e., a high oxidizing speed, and a sufficient capability of making a leuco compound that is an intermediate of a dye color-recurred. However, hexacyanoferrate itself is a cyan-type compound, and there may be some instances where free cyan ions may be produced from the aqueous solution thereof by photo-dissociation. In the case of the disposal of waste, it is, therefore, necessary to make the waste completely pollution-free.

[0006] Bleaching solutions using ferric chloride have the disadvantages that metals constituting a processor containing such bleaching solution are seriously corroded away by the strong corrosive action thereof and that iron hydroxide is produced in a washing step following a bleaching step so that the so-called stains are produced on a light-sensitive material.

[0007] Ferric complex salts of organic acids are known as a bleaching agent having less environmental problems and more ready to carry out a recovering process as compared to ferric chloride. Inter alia, ferric complex salt of ethylenediamine-­tetraacetic acid is popularly put to practical use, because of its excellent bleaching capability and stability.

[0008] In recent years, a rapid processing system is demanded more than ever along with the popularization of color photography and, in parallel with the demands for the rapid processing system, the simplification of processing control system is also demanded as most photofinishers are getting decentralized to the so-called 'mini-labs', including in-store photofinishers, who are being on the rise now. An answer to the above-mentioned demands is to simplify the labor of dissolving processing chemicals. For example, there is the so-clled processing chemical kit usually preparedy by mixing in advance its processing chemical components together each in a prescribed amount. Such kit may be ready to use when simply adding water to the mixture of the chemicals to make a uniform solution before using. The above-mentioned kits are available in both of the solid powder type and the so-called liquid type in which the solution is concentrated in advance. The latter type is preferable from the viewpoint of a simplified dossolving labor. The already known liquid type kits include, for example, those for developers, bleacher, fixers, bleach-fixers, stabilizers and so forth. However, these kits still have a problem remaining unsolved on how to concentrate their solutions without decomposition

[0009] For example, the above-mentioned bleacher or bleach-­fixer has a problem that the crystallization and deposition or deposition in the course of storage. of popular ammonium halides such as ammonium bromide are produced in low temperature storage.

SUMMARY OF THE INVENTION

[0010] It is an object of the invention to provide a light-­sensitive material bleacher which is excellent both in rapid processability and in storage stability.

[0011] Another object of the invention is to provide a light-sensitive material bleacher having neither precipitate produced in storage nor color recurring deterioration.

[0012] A further object of the invention is to provide a composition of a light-sensitive material bleacher excellent in storage stability.

[0013] Still further object of the invention is to provide a composition of a light-sensitive material bleacher having neither precipitate produced in storage nor color recurring deterioration.

DETAILED DESCRIPTION OF THE INVENTION

[0014] The objects of the invention can be accomplished with a bleaching solution composition comprising a substance capable of bleaching, wherein said composition comprises a ferric complex of a compound represented by the following Formula A, which has bleaching capability, in an amount of not less than 40 wt% of the total amount of said substance contained in said composition and pH of said composition is in the range of from 2.0 to 6.0:

wherein A₁, A₂, A₃ and A₄ each may be the same with or the different from each other and they represent each CH₂OH-, -COOM or -PO₃M₁M₂ in which M, M₁ and M₂ each represent a hydrogen atom, a sodium atom, a potassium atom or an ammonium group; X represents a substituted or unsubstituted alkylene group having 3 to 6 carbon atoms.

[0015] Further, the above-mentioned objects of the invention can be accomplished in the case that the above-mentioned composition should contain ferric complex salt represented by Formula A in an amount of not less than 0.3 mol per one liter and not less than 50 mol% of the cation of the salts contained therein should comprise ammonium and, further, the pH value of the composition should be within the range of from 2.0 to 5.5; and

[0016] Next, the compounds each represented by Formula A will be detailed.

[0017] The substituted or unsubstituted alkylene groups each having 3 to 6 carbon atoms, represented by X, include, for example, a group of propylene, butylene, trimethylene, tetramethylene, pentamethylene or the like. The substituents thereof include, for example, a hydroxyl group. Preferable compounds represented by the foregoing Formula A will typically be given below.

[0018] Besides the above-given examples of the compounds (A-1) through (A-8), those of sodium salt, potassium salt or ammonium salt may also be used arbitrarily.

[0019] Among those, ammonium salts of ferric complex thereof may preferably be used from the viewpoint of the effects of the objects of the invention.

[0020] Especially among the examples of the above-given compounds, (A-1), (A-2), (A-4) and (A-7) may more preferably be used in the invention and, inter alia, (A-1).

[0021] The invention will be more effective when a ferric complex of a compound represented by the foregoing Formula A contains in an amount of not less than 0.3 mol per liter of a bleaching solution, more preferably within the range of from 0.3 to 2 mol per liter and, further preferably, from 0.35 to 1 mol per liter.

[0022] As for a substance having bleaching capability which is other than those represented by Formula A, any compound known as a bleaching agent may generally be used. From the viewpoints of economy and less bleach-fog, it is preferable to use ferric aminopolycarboxylate complexes such as ferric ethylenediaminetetraacetate complex, ferric diethylene­triaminepentaacetate complex, ferric 1,2-cyclohexanediamine­tetraacetate complex, ferric glycoletherdiaminetetraacetate complex.

[0023] The compound represented by the foregoing Formula [A] should be contained in an amount of not less than 40 wt%, preferably, not less than 45 wt% and, more preferably, not less than 50 wt%, to the total amount of a substance having bleaching capability. If it is contained in an amount of not less than 50 wt%, the effects of the invention can suffi­ciently be displayed.

[0024] Cations of both ferric aminopolycarboxylate complex of the foregoing bleaching agent and the salts of additives such as those given below are usually comprised of alkali metal ion, ammonium ion and hydrogen ion. In the case that the composition of the invention contains not less than 50 mol% of ammonium ion, it means that a proportion of ammonium ion to alkali metal ion is not less than 50 mol%. The compo­sition of the invention contains, preferably, not less than 70 mol%, more preferably, not less than 90 mol% and, preferably in particular, 100 mol%, of ammonium ion.

[0025] The above-mentioned ferric aminopolycarboxylic acid complex salt is preferred to contain free aminopolycarboxylic acid not having an iron ligand in a proportion of not more than 20 mol% and, more preferably, not more than 10 mol% to the ferric aminopolycarboxylic acid complex salt.

[0026] It is another preferable method that two or more kinds of different aminopolycarboxylic acids are used in the above-mentioned free aminopolycarboxylic acid and ferric aminopolycarboxylic acid complex salt.

[0027] Compounds preferably added to the composition of a bleaching solution of the invention include, for example, a haliode and a pH buffer. Such halides include, for example, halogen ion releasing compounds such as ammonium bromide, sodium bromide, potassium bromide, ammonium chloride, ammonium iodide and so forth.

[0028] Such pH buffers preferably applicable to the invention include, for example, the compounds represented by the following Formulas I through III and inorganic compounds each containing at least one nitrogen atom, phosphorus atom or boron atom.

Formula I

[0029] B-COOH
wherein B represents an organic compound group or a hydrogen atom.

Formula II

[0030] B₁-PO₃H₂
wherein B₁ is synonymous with the above-given B.

Formula III

[0031] 

wherein B₂, B₃ and B₄ each represent a hydrogen atom or an organic compound group, provided that at least one of B₂, B₃ and B₄ is an organic compound group.

[0032] Typical compounds represented by Formula I include, for example, fatty acid compounds and cyclic structured acid compounds.

[0033] Such fatty acid compounds include, preferably, formic acid, acetic acid, acrylic acid, adipic acid, acetylene­dicarboxylic acid, acetoacetic acid, isopropylmalonic acid, azelaic acid, isocrotonic acid, isobutylic acid, itaconic acid, isovaleric acid, ethylmalonic acid, caproic acid, valeric acid, citric acid, glycolic acid, aconitic acid, glutaric acid, 3,3-dimethylglutaric acid, crotonic acid, chlorofumaric acid. α-chloropropionic acid, gluconic acid, glyceric acid, β-chloropropionic acid, succinic acid, cyanoacetic acid, diethylacetic acid, diethylmalonic acid, dichloracetic acid, citraconic acid, dimethylmalonic acid, oxalic acid, d-tartaric acid, meso-tartaric acid, trichloro- lactic acid, tricarballylic acid, trimethylacetic acid, lactic acid, vinylacetic acid, pimelic acid, pyrotartaric acid, racemic acid, fumaric acid, propionic acid, propyl­malonic acid, maleic acid, malonic acid, mesaconic acid, methylmalonic acid, monochloroacetic acid, n-lactic acid, malic acid, aspartic acid, Dl-alanine, glutamic acid, 3,3-dimethylglutaric acid and so forth.

[0034] The examples of the foregoing cyclic-structured acids include, preferably, ascorbic acid, atropic acid, allocinn­amic acid, benzoic acid, isophthalic acid, oxybenzoic acid (m-, p-), chlorobenzoic acid (o-, m-, p-), chlorophenylacetic acid (0-, m-, p-), cinnamic acid, salicylic acid, dioxy­benzoic acid (2,3, 2,4, 2,5, 2,6, 3,4, 3,5), cyclobutane-­1,1-dicarboxylic acid, cyclobutane-1,2-dicarboxylic acid (trans-, cis-), cyclopropane-1,1-dicarboxylic acid, cyclopropane-1,2-dicarboxylic acid (trans, cis), cyclo­ hexane-1,1-dicarboxylic acid, cyclohexane-1,2-dicarboxylic acid (trans, cis-), cyclohexylacetic acid, cyclopentane-­1,1-dicarboxylic acid, 3,5-dinitrobenzoic acid, 2,4-dinitro­phenoldiphenylic acid, sulfanilic acid, terephthalic acid, toluic acid (o-, m-, p-), naphthoic acid (α-, β-), nicotinic acid, nitroanisole (o-, m-, p-), nitrobenzoic acid, nitrophenylacetic acid (o-, m-, p-), p-nitrophenetole, p-nitrophenetole, uric acid, hippuric acid, barbituric acid, violuric acid, phenylacetic acid, phthalic acid, fluoro­benzoic acid (o-, m-, p-), picorinic acid, bromobenzoic acid (o-, m-, p-), hexahydrobenzoic acid, benzilic acid, dl-mandelic acid, mesitylenic acid, methoxybenzoic acid (o-, m-, p-), methoxycinnamic acid (o-, m-, p-), p-methoxyphenyl­acetic acid, gallic acid, aminobenzoic acid (o-, m-, p-), and so forth.

[0035] Besides the above, additional examples of the preferable compounds represented by Formula I include, typically, glycine, N-(2-acetamido)iminodiacetic acid, N-(2-acetamido)­aminoethanesulfonic acid, bis(2-hydroxyethyl)iminotris(hydroxy­methyl)methane, 2-(N-morpholino)ethanesulfonic acid, 3-(N-morpholino)-2-hydroxypropanesulfonic acid, piperazine-­N,N′-bis(2-ethanesulfonic acid), ethylenediaminediacetic acid, ethylenediamine-2-propionic acid, N-hydroxyethylene­diamine-N,N′,N′-triacetic acid, and so forth.

[0036] Typical examples of the compounds represented by Formula II include, preferably, amine compounds such as isoamylamine, isobutylamine, isopropylamine, ethylamine, ethylenediamine, diisoamylamine, diisobutylamine, diethylamine, dipropylamine, dimethylamine, tetramethylenediamine, triethylamine, trimethylamine, trimethylenediamine, butylamine, sec-­butylamine, tert-butylamine, propylamine, pentamethylene­diamine, hexamethylenetetramine, quinoline, o-toluidine, aminobenzenesulfonic acid (o-, m-, p-), N-methylbenzylamine, o-methylbenzylamine, m-methylbenzylamine, p-methylbenzyl­amine, 2-methylpiperidine, N-methoxybenzylamine, o-methoxy­benzylamine, m-methoxybenzylamine, p-methoxybenzylmine, benzylamine, coniine, diethylbenzylamine, cyclohexylamine, piperazine, and so forth.

[0037] The examples of preferable inorganic acid compounds include, typically, nitrous acid, phosphorous acid, hypophosphorous acid, boric acid, triphosphoric acid, metatriphosphoric acid, phosphoric acid, pyrophosphoric acid, polyphosphoric acid, polymetaphosphoric acid, and so forth.

[0038] The typical compounds represented by Formula III include, for example, nitrilotris(methylenephosphonic acid), ethylenediaminetetrakis(methylenephosphonic acid), amino­methylphosphonic acid-N,N-diacetic acid, 2-phosphonoethyl­iminodiacetic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, 1-hydroxyethylidene-1,1-diphosphonic acid, 1-amino­ethylidene-1,1-diphosphonic acid, and so forth.

[0039] Besides the above compounds, the other additives which may be added to the constituents of the bleaching solution of the invention include, for example, defoaming agents, rust preventives such as nitrate and so forth, activators, antimolds, bleaching accelerators, and so forth.

[0040] The bleaching solutions of the invention may be used in the form of a concentrated composition which is defined to be more condensed than a bleaching solution in such a state that it is stored in a bleaching solution preparation kit.

[0041] The concentrated composition of bleaching solution consist of a single solution or a set of separate parts such as a set of two or three separate liquid parts, a set of one liquid part and one powder part, or the like.

[0042] The concentrated composition of the invention means one of the separate parts described above, that is a concentrated one containing ferric aminopolycarboxylic acid complex salt. In the case of a set of two liquid parts in particular, it is preferred to adjust the pH of the other concentrated part than that of the invention to be within the range of 4 to 7 so as to prevent the precipitation when mixing the parts together.

[0043] A bleaching solution is prepared by mixing the concentrated compositions of a bleaching solution of the invention together and/or diluting the compositions with water. Thus prepared bleaching solution can be used for processing ordinary type light-sensitive materials.

[0044] Next, some series of preferable processing steps will be given below.

(1) Color developing - bleaching - fixing - washing,

(2) Color developing - bleaching - fixing - washing - stabilizing,

(3) Color developing - bleaching - fixing - stabilizing,

(4) Color developing - bleaching - fixing - first stabilizing - second stabilizing,

(5) Color developing - bleaching - bleach-fixing - washing,

(6) Color developing - bleaching - bleach-fixing - washing - stabilizing,

(7) Color developing - bleaching - bleach-fixing - stabilizing,

(8) Color developing - bleaching - bleach-fixing - first stabilizing - second stabilizing

[0045] The pH of the bleaching solution of the invention is in the range of 2.0 to 6.0, preferably 2.5 to 5.5 and, more preferably, 2.5 to 5.0.

[0046] Further, it is usual to add a halide such as ammonium bromide. It is also allowed to add various types of fluorescent whitening agents and defoaming agents or surface active agents and antimolds.

EXAMPLES

[0047] Now, some examples of the invention will be detailed below. It is, however, to be understood that the invention shall not be limited thereto.

Example-1

[0048] The combinations of the following ferric organic acid complex salts each and ammonium bromide were dissolved in water in the following proportions and the pH values of the resulted solutions each were adjusted to be within the range of 1.8 to 7.5 as shown in Table-1, respectively. Each of the resulted solutions was put separately into a polyethylene container and allowed to stand at 5°C for one month. After then, the crystal deposition of each composite, i.e., each processing kit, was examined.

[0049] The results thereof are shown in Table-1.

[0050] In the compositions (2) through (8), the proportions of ferric 1,3-propanediaminetetraacetic acid complex salts to the whole bleaching component were equivalent to 30 wt%, 35 wt%, 40 wt%, 45 wt%, 50 wt%, 55 wt% and 60 wt%, respectively.

[0051] Table-2 shows the results obtained by using Fe(III) ammonium 2-hydroxy-1,3-propanediaminetetraacetate, mono­hydrate, in place of Fe(III) ammonium 1,3-propanediamine­tetraacetate, monohydrate and Table-3 shows the results obtained by using Fe(III) ammonium 1,4-butanediaminetetra­acetate, monohydrate, instead.

Table-1

Composite No.	pH of Composites
	1.8	2.0	2.5	3.0	4.0	5.0	5.5	6.0	6.5	7.5
(1)	xx	xx	xx	xx	xx	xx	xx	xx	xx	xx
(2)	xx	xx	xx	xx	xx	xx	xx	xx	xx	xx
(3)	x	x	x	x	x	x	x	x	xx	xx
(4)	x	Δ	Δ	Δ	Δ	Δ	Δ	Δ	x	xx
(5)	x	Δ	Δ	o	o	o	Δ	Δ	x	x
(6)	x	Δ	o	o	o	o	Δ	Δ	x	x
(7)	x	Δ	o	o	o	o	o	Δ	x	x
(8)	x	Δ	o	o	o	o	o	Δ	x	x

Table-2

Composite No.	pH of Composites
	1.8	2.0	2.5	3.0	4.0	5.0	5.5	6.0	6.5	7.5
(1)	xx	xx	xx	xx	xx	xx	xx	xx	xx	xx
(2)	xx	xx	xx	xx	xx	xx	xx	xx	xx	xxx
(3)	xx	xx	xx	x	x	x	xx	x	xx	xx
(4)	xx	x	x	Δ	Δ	Δ	Δ	Δ	x	x
(5)	x	Δ	Δ	Δ	Δ	o	o	Δ	x	x
(6)	x	Δ	Δ	o	o	o	o	Δ	x	x
(7)	x	Δ	o	o	o	o	Δ	Δ	x	x
(8)	x	Δ	o	o	o	o	Δ	Δ	x	x

Table-3

Composite No.	pH of Composites
	1.8	2.0	2.5	3.0	4.0	5.0	5.5	6.0	6.5	7.5
(1)	xx	xx	xx	xx	xx	xx	xx	xx	xx	xx
(2)	xx	xx	xx	xx	xx	xx	xx	xx	xx	xx
(3)	xx	xx	x	x	x	x	x	xx	x	xx
(4)	x	x	Δ	Δ	Δ	Δ	Δ	x	x	x
(5)	x	Δ	Δ	Δ	o	o	Δ	Δ	x	x
(6)	x	Δ	Δ	o	o	o	Δ	Δ	x	x
(7)	x	Δ	o	o	o	o	o	Δ	x	x
(8)	x	Δ	o	o	o	o	o	Δ	x	x

[0052] In the above-given tables, o mark indicates that no crystal deposition was found at all; Δ mark indicates that some crystal-like matters were found; and x mark indicates that crystal depositions were apparently found. The more x marks are, the more the depositions are serious.

Example-2

[0053] The same composites as used in Example-1 were put into a polyethylene container and allowed to stand at 50°C for two weeks. After then, the concentration of the ferrous complex salt of the composite was quantitatively measured with o-phenanthroline method. The results thereof are shown in Table-4

[0054] The numerical values shown in the table each express the production ratios of ferrous complex salts. pH was adjusted to be within the range of 2.0 to 10.0 as shown in Table-4. Table-5 shows the results obtained by using Fe(III) ammonium 2-hydroxy-1,3-propanediaminetetraacetate, monohydrate in place of Fe(III) ammonium 1,3-propanediaminetetraacetate, monohydrate, and Table-6 shows the results obtained by using Fe(III) ammonium 1,4-butanediaminetetraacetate, monohydrate.

Table-4

Composite No.	pH of Composites
	2.0	4.0	6.0	8.0	10.0
(1)	5.2	5.5	5.3	7.1	23.0
(2)	5.4	5.3	5.8	12.1	32.4
(3)	6.0	5.9	6.7	12.3	39.6
(4)	5.9	5.8	6.4	15.6	53.3
(5)	6.1	6.3	7.0	18.2	60.9
(6)	6.1	6.4	6.9	21.0	65.1
(7)	5.8	6.0	7.1	20.4	72.5
(8)	6.6	6.5	7.0	23.6	75.5

Table-5

Composite No.	pH of Composites
	2.0	4.0	6.0	8.0	10.0
(1)	5.2	5.5	5.3	7.1	23.0
(2)	6.0	5.9	6.3	15.0	39.2
(3)	6.3	6.5	7.0	21.4	48.7
(4)	6.1	6.6	6.8	22.9	50.6
(5)	6.5	6.8	7.1	21.8	63.3
(6)	6.7	6.7	7.1	25.0	75.7
(7)	6.8	6.9	7.2	25.3	80.3
(8)	7.0	7.2	8.0	24.9	81.4

Table-6

Composite No.	pH of Composites
	2.0	4.0	6.0	8.0	10.0
(1)	5.2	5.5	5.3	7.1	23.0
(2)	5.2	5.8	5.7	10.0	36.6
(3)	6.4	6.2	7.0	18.3	38.4
(4)	6.2	6.0	6.5	20.9	40.3
(5)	6.5	6.7	6.9	23.1	53.6
(6)	6.5	6.6	6.8	33.4	62.1
(7)	6.9	6.8	7.0	38.8	73.2
(8)	7.3	7.4	7.4	50.2	73.0

[0055] It can be found from the results shown in the above tables that the bleaching solutions of the invention do not produce many ferrous complex salts but displays excellent storage stability.

Example-3

[0056] Each of the same composites as in Example-1 was added by 50 g of sodium acetate as a buffer and the pH values thereof each were adjusted to be within the range of 1.8 to 7.5 as shown in Table-7. The resulted composites were named (1′) to (8′), respectively. The composites (1′) to (8′) and (1) to (8) were put into polyethylene conctainers and allowed to stand at 25°C for one month, respectively. After then, the pH variation of each composite was examined.

[0057] The results thereof are shown in Table-7.

Table-7

Composite No.	pH of Composites
	1.8	2.0	2.5	3.0	4.0	5.0	5.5	6.0	6.5	7.5
(1)	xx	xx	x	x	Δ	Δ	Δ	o	o	o
(1′)	xx	x	Δ	Δ	o	o	o	o	o	o
(2)	xx	xx	x	x	x	x	Δ	Δ	o	Δ
(2′)	xx	x	Δ	Δ	o	o	o	o	o	o
(3)	xx	xx	xx	x	x	x	Δ	Δ	Δ	Δ
(3′)	xx	x	Δ	Δ	Δ	o	o	o	o	o
(4)	xx	xx	x	x	x	x	Δ	Δ	Δ	Δ
(4′)	xx	x	Δ	Δ	Δ	o	o	o	o	o
(5)	xx	xx	x	x	x	x	Δ	Δ	Δ	Δ
(5′)	xx	x	Δ	Δ	Δ	o	o	o	o	o
(6)	xx	xx	x	x	x	x	x	Δ	Δ	Δ
(6′)	xx	x	Δ	Δ	Δ	Δ	o	o	o	o
(7)	xx	xx	x	x	x	x	x	Δ	Δ	Δ
(7′)	xx	x	Δ	Δ	Δ	Δ	o	o	o	o
(8)	xx	xx	x	x	x	x	x	x	Δ	Δ
(8′)	xx	x	Δ	Δ	Δ	Δ	Δ	o	o	o
In the above table, mark o indicates a pH variation of not more than ±0.2; mark Δ indicates that within the range of ±0.2 to ±0.4; mark x indicates that within the range of ±0.4 to ±0.6; and mark xx indicates that of not less than 0.6.

[0058] It can be found from the above table that the bleaching solutions of the invention has a few pH variations even after they are stored and an excellent storage stability.

[0059] The same results were obtained even when sodium phosphate was used in place of sodium acetate

Example-4

[0060] Each of the same composites as in Example-1 of which pH had been adjusted to be within the range of 1.8 to 7.5 was allowed to stand at 50°C for two weeks. After then, 500 ml of each of the resulted composites was diluted to make one liter and the pH thereof was adjusted to be 6.0, so that the bleaching solutions were prepared, respectively.

[0061] Using these bleaching solutions and light-sensitive material samples shown below already exposed to light through a wedge, the following processing steps were carried out. After each sample was processed, silver residues in the maximum density area of the sample were measured by fluorescent X-ray method.

[0062] The results thereof are shown in Table-8.

[Processing steps]
	Time	Temperature
Color developing	3min15sec.	38°C
Bleaching	45sec.	38°C
Fixing	3min15sec.	35°C
Washing	3min.	30 to 34°C
Stabilizing	1min20sec.	30 to34°C
Drying

[0063] The following color developer, fixer and stabilizer were used.

[Color developer]
Potassium carbonate	30.0 g
Sodium sulfite	2.0 g
Hydroxylamine sulfate	2.0 g
Potassium bromide	1.2 g
Sodium hydroxide	3.4 g
3-methyl-4-amino-N-ethyl-N-β-hydroxyethylaniline sulfate	4.6 g
Add water to make	1 liter
Adjust pH with sodium hydroxide and a 50% sulfuric acid solution to be	pH10.1

Light-sensitive material

[0064] On a triacetate film base, an antihalation layer and a gelatin layer were coated. Further theron, a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, a filter layer containing yellow colloidal silver, and a blue-sensitive silver halide emulsion layer were coated so as to make the total amount of silver contents thereof to be 62 mg per 100cm². The above-mentioned emulsion layers each were comprised of silver iodobromide containing silver iodide in a proportion of about 4.8 mol%. In this preparation, the blue-sensitive silver halide emulsion layer was added by α-(4-nitrophenoxy)-α-pivalyl-5-[γ-­(2,4-di-t-aminophenoxy)butylamido]-2-chloroacetoanilide as a yellow coupler; the green-sensitive silver halide emulsion layer was added by 1-(2,4,6-trichlorophenyl)-3-{[α-(2,4-di-t-­amylphenoxy)-acetoamido]benzamido)-3-pyrazolone and 1-(2,4,6-trichlorophenyl)-3-{ [α-(2, 4-di-t-amylphenoxy)-aceto­amido]benzamido}-4-(4-methoxyphenylazo)-5-pyrazolone each as magenta couplers; the red-sensitive silver halide emulsion layer was added by the following (C-1) as a cyan coupler; and each emulsion layer was further added by ordinary type additives such as a sensitizing dye, a hardener and so forth in an ordinary method.

Table-8

Composite No.	pH of Composites
	1.8	2.0	2.5	3.0	4.0	5.0	5.5	6.0	6.5	7.5
(1)	19.0	18.4	17.9	17.3	17.5	17.3	17.5	17.4	17.4	17.6
(2)	11.5	10.8	10.6	10.7	10.7	10.9	10.7	10.7	10.8	15.0
(3)	9.9	9.4	9.5	9.4	9.4	9.5	9.5	9.5	9.6	10.1
(4)	3.6	2.4	2.4	2.5	2.3	2.3	2.4	2.4	3.4	8.3
(5)	3.4	1.6	1.7	1.5	1.5	1.6	1.6	1.6	2.5	7.6
(6)	2.7	1.0	1.0	0.8	0.9	0.8	0.8	0.8	2.3	7.4
(7)	2.7	1.0	0.9	0.8	0.8	0.8	0.9	0.9	1.9	6.2
(8)	2.6	0.9	0.9	0.8	0.8	0.9	0.8	0.9	1.7	6.3
Numerical values in the above table represent mg of silver per 100 cm².

[0065] It can be found from the table that the bleaching solu­tions of the invention have a high bleaching capability and an excellent storage stability.

Example-5

[0066] In the concentrated compositions I and II of the follow­ing, aminopolycarboxylic acids were replaced by those shown in Table-9 and the pH values were changed to those within the range of 1.0 to 7.5. The proportion of ammonium ion was changed as shown in Table-9 by mixing concentrated composi­tion I, i.e., sodium ion, and concentrated composition II, i.e., ammonium ion, each having different cation, and the mixture thereof was put into a 100 ml capacity sample bottle. The bottle was stoppered tightly and stored in a 50°C- thermostat chamber for three days. The appearance of the resulted matter was observed by three inspectors. Table-9 shows the observation results.

Concentrated composition I of bleachin solution
Ferric sodium salt of aminopolycarboxylate (Refer to Table-9)	0.8 mol
Aminopolycarboxylic acid (Refer to Table-9)	0.01 mol
Sodium nitrate	20 g
Sodium bromide	50 g
Add water to make	1 liter
Adjust pH with glacial acetic acid and NaCO₃ to be that shown in Table-9

Concentrated composition II of bleaching solution
Ferric ammonium aminopolycarboxylate (Refer to Table-9)	0.8 mol
Aminopolycarboxylic acid (Refer to Table-9)	0.01 mol
Ammonium nitrate	20 g
Ammonium bromide	50 g
Add water to make	1 liter
Adjust pH with glacial acetic acid and aqueous ammonia to be that shown in Table-9

[0067] Next, using the concentrated solution after it was stored in the 100ml-capacity sample bottle, a color film was prepared personally and was then processed with the process­ing solutions in the processing steps as described below. On the other hand, as the comparisons to the above-mentioned concentrated compositions of the stored bleaching solution, the other non-stored bleaching solutions each were processed after adding a concentrated composition in an amount calcu­lated out from the contents of the foregoing concentrated compositions.

[0068] In this example, every amount of components which are to be added to a silver halide photographic light-sensitive material will be indicated in terms of gram per square meter, and every amount of silver or colloidal silver will be indicated in terms of silver contents, unless otherwise expressly stated.

[0069] Onto a triacetyl cellulose film support, the layers having the following compositions were provided in order from the support, so that Sample-1 of a multilayered color photo­graphic light-sensitive material was prepared.

Sample-1

[0070] 

Layer-1 : An antihalation layer, HC-1
Black colloidal silver	...	0.20
UV absorbent, UV-1	...	0.20
Colored coupler, CC-1	...	0.05
Colored coupler, CM-2	...	0.05
High boiling solvent, Oil-1	...	0.20
Gelatin	...	1.4

Layer-2 : An interlayer, IL-1
UV absorbent, UV-1	...	0.01
High boiling solvent, Oil-1	...	0.01
Gelatin	...	1.4

Layer-3 : A low-speed red-sensitive emulsion layer, RL
Silver iodobromide emulsion, EM-1	...	1.2
Silver iodobromide emulsion, Em-2	...	0.6
Sensitizing dye, S-1	...	3.0x10⁻⁴ mol/mol of silver
Sensitizing dye, S-2	...	2.5x10⁻⁴ mol/mol of silver
Sensitizing dye, S-3	...	0.6x10⁻⁴ mol/mol of silver
Cyan coupler, C-4	...	1.2
Cyan coupler, C-2	...	0.06
Colored cyan coupler, CC-1	...	0.05
DIR compound, D-1	...	0.002
High boiling solvent, Oil-1	...	0.5
Gelatin	...	1.4

Layer-4 : A high-speed red-sensitive emulsion layer, RH
Silver iodobromide emulsion, Em-3	...	2.0
Sensitizing dye, S-1	...	2.0x10⁻⁴ mol/mol of silver
Sensitizing dye, S-2	...	2.0x10⁻⁴ mol/mol of silver
Sensitizing dye, S-3	...	0.1x10⁻⁴ mol/mol of silver
Cyan coupler, C-1	...	0.15
Cyan coupler, C-2	...	0.018
Cyan coupler, C-3	...	1.15
Colored cyan coupler, CC-1	...	0.015
DIR compound, D-2	...	0.05
High boiling solvent, Oil-1	...	0.5
Gelatin	...	1.4

Layer 5 : An interlayer, IL-2
Gelatin	...	0.5

Layer-6 : A low-speed green-sensitive emulsion layer, GL
Silver iodobromide emulsion, Em-1	...	1.0
Sensitizing dye, S-4	...	5.0x10⁻⁴ mol/mol of silver
Sensitizing dye, S-5	...	1.0x10⁻⁴ mol/mol of silver
Magenta coupler, M-1	...	0.5
Colored magenta coupler, CM-1	...	0.05
DIR compound, D-2	...	0.015
DIR compound, D-4	...	0.020
High boiling solvent, Oil-2	...	0.5
Gelatin	...	1.0

Layer-7 : An interlayer, IL-3
Gelatin	...	0.8
High boiling solvent, Oil-1	...	0.2

Layer-8 : A high-speed green-sensitive emulsion layer, GH
Silver iodobromide emulsion Em-3	...	1.3
Sensitizing dye, S-6	...	1.5x10⁻⁴ mol/mol of silver
Sensitizing dye, S-7	...	2.5x10⁻⁴ mol/mol of silver
Sensitizing dye, S-8	...	0.5x10⁻⁴ mol/mol of silver
Magenta coupler, M-2	...	0.06
Magenta coupler, M-3	...	0.18
Colored magenta coupler, CM-2	...	0.05
DIR compound, D-3	...	0.01
High boiling solvent, Oil-3	...	0.5
Gelatin	...	1.0

Layer-9 : A yellow filter layer, YC
Yellow colloidal silver	...	0.1
Color contamination preventive, SC-1	...	0.1
High boiling solvent, Oil-3	...	0.1
Gelatin	...	0.8

Layer-10: A low-speed blue-sensitive emulsion layer, BL
Silver iodobromide emulsion, Em-1	...	0.25
Silver iodobromide emulsion, Em-2	...	0.25
Sensitizing dye, S-10	...	7.0x10⁻⁴ mol/mol of silver
Yellow coupler, Y-1	...	0.6
Yellow coupler, Y-2	...	0.12
DIR compound, D-2	...	0.01
High boiling solvent, Oil-3	...	0.15
Gelatin	...	1.0

Layer-11: A high-speed blue-sensitive emulsion layer, BH
Silver iodobromide emulsion, Em-4	...	0.50
Silver iodobromide emulsion, Em-1	...	0.20
Sensitizing dye, S-9	...	1.0x10⁻⁴ mol/mol of silver
Sensitizing dye, S-10	...	3.0x10⁻⁴ mol/mol of silver
Yellow coupler, Y-1	...	0.36
Yellow coupler, Y-2	...	0.06
High boiling solvent, Oil-3	...	0.07
Gelatin	...	1.1

Layer-12: The first protective layer, Pro-1
Finely grained silver iodobromide emulsion, having an average grain size of 0.08µm and an AgI content of 2mol%	...	0.4
UV absorbent, UV-1	...	0.10
UV absorbent, UV-2	...	0.05
High boiling solvent, Oil-1	...	0.1
High boiling solvent, Oil-4	...	0.1
Formalin scavenger, HS-1	...	0.5
Formalin scavenger, HS-2	...	0.2
Gelatin	...	1.0

Layer13: The second protective layer, Pro-2
Surfactant, Su-1	...	0.005
Alkali-soluble matting agent, having an average particle size of 2µm	...	0.10
Cyan dye, AIC-1	...	0.005
Magenta dye, AIM-1	...	0.01
Lubricant, WAX-1	...	0.04
Gelatin	...	0.8

[0071] Besides the above, the following additives were added to each of the layers. Coating assistant Su-2, dispersing assistant Su-3, layer hardening agents H-1 and H-2, antiseptic agent DI-1, stabilizing agent Stab-1 and antifogging agents AF-1 and AF-2.

Em-1: A monodisperse type silver iodobromide emulsion containing low silver iodide on the surface thereof having an average grain size of 0.46µm and an average silver iodide content of 7.5 mol%,

Em-2: A monodisperse type silver iodobromide emulsion having a uniform compositions having an average grain size of 0.32 µm and an average silver iodide content of 2.0 mol%,

Em-3: A monodisperse type silver iodobromide emulsion containing low silver iodide on the surface thereof having an average grain size of 0.78µm and an average silver iodide content of 6.0 mol%, and

Em-4: A monidisperse type silver iodobromide emulsion containing low silver iodide on the surface thereof having an average grain size of 0.95µm and an average silver iodide content of 8.0 mol%

[0072] Em-1, Em-3 and Em-4 are octahedral silver iodobromide emulsions each having a multilayered structure, which may be prepared by referring to Japanese Patent O.P.I Publication Nos. 60-138538/1985 and 61-245151/1986.

[0073] In every emulsion of Em-1 through Em-4, the average ration of grain sizes to grain thickness thereof is 1.0 and the broardness of grain distribution thereof are 14%, 10%, 12% and 12%, respectively.

[0074] Thus prepared light-sensitive materials were exposed to white light through a wedge and then processed in the follow­ing processing steps.

<Development process>
Processing step	Processing time	Processing temperature	Number of tanks
Color developing	3min.15sec.	38°C	1
Bleaching	See Note-1	38°C	1
Fixing	1min.15sec.	38°C	1
Stabilizing	1min.	38°C	3
			(Cascade)
Drying	60sec.	40 to 80°C	-
Note-1: Bleaching time was determined by the results of the preliminary experiments of the foregoing light-sensitive materials, because a period of time necessary for completiing a bleaching step depends on the kinds and adding amounts of aminopolycarboxylic acids.

[0075] The compositions of the processing solutions each used in this example were as follows.

[Color developing solution]
Potassium carbonate	30 g
Sodium hydrogencarbonate	2.5 g
Potassium sulfite	4 g
Sodium bromide	1.3 g
Potassium iodide	1.2 g
Hydroxylamine sulfate	2.5 g
Sodium chloride	0.6 g
4-amino-3-methyl-N-ethyl-N-(β-hydroxylethyl)aniline sulfate	4.8 g
Potassium hydroxide	1.2 g
Add water to make	1 liter
Adjust pH with potassium hydroxide or a 50% sulfuric acid solution to be	pH10.06

[Bleaching solution]
Concentrated composition after stored (See Table-9)	300 ml
Ammonium bromide	140 g
Ammonium acetate	80 g
Imidazole	5 g
Add water to make	1 liter
Adjust pH with aqueous ammonia or glacial acetic acid to be	pH5.0

[Fixing solution]
Ammonium thiosulfate	250 g
Ammonium sulfite	30 g
Disodium ethylenediaminetetraacetate	0.5 g
Sodium carbonate	10 g
The foregoing bleaching solution	100 ml
Add water to make	1 liter
Adjust pH with acetic acid or aqueous ammonia to be	pH7.0

[Stabilizing solution]
Aqueous 37% formaldehyde solution	2 ml
5-chloro-2-methyl-4-isothiazoline-3-one	0.05 g
Emulgen 810	1 ml
Formaldehyde-sodium bisulfite adduct	2 g
Add water to make	1 liter
Adjust pH with aqueous ammonia and a 50% sulfuric acid solution to be	pH7.0

[0076] The bleaching step was carried out for 4 minutes in the case of using a bleaching solution containing a ferric complex salt of ethylenediaminetetraacetic acid and for 40 seconds in the case of using a bleaching solution containing a ferric complex salt of (A-1).

[0077] After the light-sensitive materials were processed, the red transmission densities of their maximum density areas were measured with a photoelectrodensitometer, PDA-65A manufactured by Konica Corporation. Then, after the materials were dipped into an aqueous 5% potassium ferri­cyanide solution for three minutes and dried, the same measurement was made again. The first measured density was regarded as a relative value of 100 and the density increase, i.e., color recurring, obtained in the second measurement was expressed by a percentage relatively. The results thereof are shown in Table-10.

[0078] Table-10 shows the degree of change of a cyan dye to a leuco dye wherein, the less the values are, the more the results are preferable.

Table-10

(Color recurring percentage, %)
(Bleaching agent)	pH	Ratio of ammonium ion (mol%)
Aminopolycarboxylic acid		0	30	50	70	90	100
Ethylenediaminetetraacetic acid	1.0	2	2	2	2	2	2
	1.5	2	2	2	2	2	2
	2.0	2	2	2	2	2	2
	2.5	2	2	2	2	2	2
	3.0	2	2	2	2	2	2
	4.0	2	2	2	2	2	2
	5.0	2	2	2	2	2	2
	5.5	2	2	2	2	2	2
	6.0	2	2	2	2	2	2
	6.5	2	2	2	2	2	2
	7.5	2	2	2	2	2	2
	Not stored	2	2	2	2	2	2
(A-1)	1.0	2	2	2	2	2	2
	1.5	2	2	2	2	2	2
	2.0	2	2	2	2	2	2
	2.5	2	2	2	2	2	2
	3.0	8	6	3	3	2	2
	4.0	10	6	4	3	2	2
	5.0	11	7	4	4	3	2
	5.5	12	9	5	4	4	3
	6.0	15	14	14	13	13	12
	6.5	22	21	22	21	21	21
	7.5	25	26	26	27	27	28
	Not stored	2	2	2	2	2	2

[0079] As are obvious from Table-9 and Table-10, it is found that, in the case of using ethylenediamine tetraacetic acid, the pH value of its concentrated composite should preferably be not lower than 6.5, while, in the case of using the ferric complex of (A-1) of the invention, of which the pH value is 2.0 to 5.5 which is within the range specified in the inven­tion and the ratio of ammonium ions to cations is not lower than 50%, such ferric complex of (A-1) of the invention can be excellently preferable to use, because it does not produce any precipitate and displays a good color recurring property.

Example-6

[0080] In the concentrated composites I and II of the bleaching solution of Example-5, the amounts of ethylenediaminetetra­acetic acid and (A-1) and the pH of the concentrated compos­ites were changed as shown in Table-11. The same storage was carried out as in Example-5 and then the appearance of the solution was observed and the experiment of the color recur­ring property was carried out. The results thereof are shown in Table-11 and Table -12, respectively. Those not stored were also tested for the comparison purpose, similar to those of Example-5.

Table-11

(Appearance of solution)
Concentrated composite	A-1 mol/liter	EDTA* mol/liter	pH of Concentrated composite
			1.5	2.5	4.0	5.5	6.5
I (Sodium ion)	0.2	-	+	-	-	-	-
	0.3	-	++	-	-	-	-
	0.35	-	+++	+	-	-	-
	1.0	-	+++	++	++	++	-
	2.0	-	+++	+++	+++	+++	-
	0.4	0.6	+++	+	+	+	-
	0.5	0.5	+++	+	+	+	-
	0.6	0.3	+++	+	+	+	-
II (Ammonium ion)	0.2	-	+	-	-	-	-
	0.3	-	+++	-	-	-	-
	0.35	-	+++	-	-	-	-
	1.0	-	+++	-	-	-	-
	2.0	-	+++	++	++	++	-
	0.4	0.6	+++	-	-	-	-
	0.5	0.5	+++	-	-	-	-
	0.6	0.3	+++	-	-	-	-
	0.8	-	+++	-	-	-	-
	0.8	0.2	+++	-	-	-	-
	0.8	0.4	+++	-	-	-	-

* EDTA: Ethylenediaminetetraacetic acid

Table-12

(Color recurring property, %)
Concentrated composite	A-1 mol/liter	EDTA* mol/liter	pH of Concentrated composite					Non-stored (For comparison)	Bleaching time
			1.5	2.5	4.0	5.5	6.5
I (Sodium ion)	0.2	-	2	2	2	3	16	2	3min.
	0.3	-	2	4	5	6	17	2	2min.
	0.35	-	2	6	8	10	19	2	1min.30sec.
	1.0	-	2	7	10	12	22	2	45sec.
	2.0	-	2	7	9	11	18	2	30sec.
	0.4	0.6	2	4	4	5	13	2	1min.50sec.
	0.5	0.5	2	6	7	9	17	2	60sec.
	0.6	0.3	2	7	8	10	17	2	50sec.
II (Ammonium ion)	0.2	-	2	2	2	3	16	2	3min.
	0.3	-	2	2	2	3	17	2	2min.
	0.35	-	2	2	2	3	19	2	1min.30sec.
	1.0	-	2	2	2	3	21	2	45sec.
	2.0	-	2	2	2	3	18	2	30sec.
	0.4	0.6	2	2	2	3	12	2	1min.50sec.
	0.5	0.5	2	2	2	3	14	2	60sec.
	0.6	0.3	2	2	2	3	16	2	50sec.
	0.8	-	2	2	2	3	21	2	45sec.
	0.8	0.2	2	2	2	3	18	2	45sec.
	0.8	0.4	2	2	2	3	16	2	45sec.

* EDTA = Ethylenediaminetetraacetic acid

[0081] As are obvious from Table-11 and Table-12. it is found that the bleaching solution of the invention containing ammonium ion as the cation of concentrated composite II should be excellently preferable, when the solution contains ferric complex salt of a compound represented by Formula A in an amount of 0.3 mol per liter and the pH thereof is within the range of 2.0 to 5.5.

Example-7

[0082] The concentrated composites of each bleaching solution were prepared in the same manner as in the concentrated composite II of the bleaching solution of Example-5, except that aminopolycarboxylic acid and the ferric ammonium salt thereof were changed to those shown in Table-13 and the pH value of the solutions were changed to 1.5, 3.0 and 6.5, respectively. The resulted solutions were subjected to the experiments and evaluated.

[0083] The bleaching step thereof was carried out for 6 minutes so as to satisfactorily bleach the samples. The results thereof are shown in Table-13.

Table-13

Chelating agent of ferric complex of organic acid	Appearance of solution			Color recurring (%)
	pH of concentrated composite			pH of concentrated composite
	1.5	3.0	6.5	1.5	3.0	6.5
EDTA*	+++	+++	-	2	2	2
(A - 1)	+++	-	-	2	2	21
(A - 2)	+++	-	-	2	3	20
(A - 3)	+++	-	-	2	4	19
(A - 4)	+++	-	-	2	3	15
(A - 5)	+++	-	-	2	4	27
(A - 7)	+++	-	-	2	3	18

* EDTA = Ethylenediaminetetraacetic acid

[0084] As is obvious from Table-13, it is found that the invention can be effective when using not only a ferric complex of the compound (A-1) but also those of the compounds (A-2), (A-3), (A-4), (A-5) and (A-7) each represented by Formula A.

Example-8

[0085] Concentrated solution of ammonium bromide, ammonium acetate and imidazole, which are components other than ones in the bleaching solution used in Example-5 was prepared as the extra parts in concentration ratios and pH values shown in Table-14. The resulted solution was stored in 50°C thermostat tanks for three days. On the other hand, another bleaching solution was prepared by using the non-stored concentrated composite II having a pH of 3.0 which is the same as in Example-5. Each of the bleaching solution were subjected to the same experiment as in Example-5 so as to evaluate their color recurring properties. The results thereof are shown in Table-14.

Table-14

Concentration ratio	pH of concentrated composite
	2.0	3.0	4.0	5.5	7.0	8.0
700 ml/liter	38	25	3	2	1	13
300 ml/liter	40	26	3	2	1	14

[0086] From the results shown in Table-14 above, it is found that, in the case of a bleaching solution in two liquid parts of concentrated composites, the pH of the part not containing ferric complex salt of organic acid should preferably be within the range of 4 to 7.

Example-9

[0087] The following bleaching solutions each having a single liquid part of concentrated composites were subjected to the same experiment and evaluation as in Example-5.

[0088] The single liquid part of each bleaching solution was diluted double. The results thereof are shown in Table-15.

Bleaching solution having a single liquid concentrated composite III
Ferric sodium salt of Exemplified compound (A-1)	0.8mol
Compound shown in Table-15	See Table-15
Sodium bromide	150 g
Add water to make	900 ml
Adjust pH with acetic acid and NaCO₃ to	pH4.8
Further add water to make	1 liter

Bleaching solution having a single liquid concentrated composite IV
Ferric ammonium salt of Exemplified compound (A-1)	0.8mol
Compound shown in Table-15	See Table-15
Sodium bromide	150 g
Add water to make	900 ml
Adjust pH with acetic acid and NaCO₃ to	pH4.8
Further add water to make	1 liter

Table-15

No.	Compound added	Amount added mol/l	Apparance of solution		Color recurring
			Concentrated composite		Concentrated composite
			III	IV	III	IV
1	None	-	+	-	4	2
2	Citric acid	0.5	++	-	11	2
3	Succinic acid	0.5	++	-	10	2
4	Salicylic acid	0.5	++	-	12	2
5	Phthalic acid	0.5	++	-	10	2
6	Triethylamine	0.5	++	-	9	2
7	Hexamethylene tetramine	0.5	++	-	8	2
8	Nitrous acid	0.5	++	-	10	2
9	Triphosphoric acid	0.5	++	-	10	2
10	Acetic acid	0.5	+	-	5	2
11	ditto	1.0	++	-	7	2
12	ditto	1.5	++	-	10	2
13	ditto	2.0	++	-	12	2
14	Sulfuric acid	0.5	++	+	4	2
15	Ethyl alcohol	0.5	+	-	4	2
16	Ethylene glycol	0.5	+	-	4	2
17	Tetramethyl ammonium chloride	0.5	++	++	31	20
In Table-15 above, Compounds No. 2 through No. 15 should be preferable for preventing bleach-fog.

[0089] As is obvious from the results shown in Table-15, it is found that, in the case that a concentrated composite contains one of the compounds No. 2 through No. 13, precipi­tates are liable to be produced, however, the invention has effectively worked against such precipitation production. It is also found that the invention was extremely effective in color recurring when any of the compounds No. 2 through No. 13 was contained.

Claims

1. A bleaching solution composition for processing a silver halide color photographic light-sensitive material, comprising a substance capable of bleaching, wherein said composition comprises a ferric complex of a compound represented by the following Formula A, which has bleaching capability, in an amount of not less than 40 wt% of the total amount of said substance contained in said composition and pH of said composition is in the range of from 2.0 to 6.0:

wherein A₁, A₂, A₃ and A₄ each may be the same or different from each other and represent CH₂OH-, -COOM or -PO₃M₁M₂ in which M, M₁ and M₂ each represent a hydrogen atom, a sodium atom, potassium atom or an ammonium group; X represents a substituted or an unsubstituted alkylene group having 3 to 6 carbon atoms.

2. The composition of claim 1, wherein said composition comprises said ferric complex in an amount of not less than 45 wt% of the total amount of said substance in said composition.

3. The composition of claim 1, wherein said composition comprises said ferric complex in an amount of not less than 50 wt% of the total amount of said substance in said composition.

4. The composition of claim 1, wherein pH of said composition is in the range of from 2.0 to 5.5.

5. The composition of claim 1, wherein pH of said composition is in the range of from 2.5 to 5.5.

6. The composition of claim 1, wherein pH of said composition is in the range of from 2.5 to 5.0.

7. The composition of claim 1, wherein said composition is comprised of not less than 50 mol% of an ammonium cation to the total cation.

8. A bleaching solution composition for processing a silver halide color photographic light-sensitive material, comprising a substance capable of bleaching, wherein said composition comprises not less than 0.3 mol per liter of a ferric complex of a compound represented by the following Formula A and not less than 50 mol% of an ammonium cation to the total cation contained in said composition and pH of said composition is in the range of from 2.0 to 6.0:

wherein A₁, A₂, A₃ and A₄ each may be the same or different from each other and represent CH₂OH-, -COOM or -PO₃M₁M₂ in which M, M₁ and M₂ each represent a hydrogen atom, a sodium atom, potassium atom or an ammonium group; X represents a substituted or an unsubstituted alkylene group having 3 to 6 carbon atoms.

9. The composition of claim 8, wherein pH of said composition is in the range of from 2.0 to 5.5.