(19) |
 |
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(11) |
EP 0 338 396 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
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02.01.1991 Bulletin 1991/01 |
(43) |
Date of publication A2: |
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25.10.1989 Bulletin 1989/43 |
(22) |
Date of filing: 12.04.1989 |
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(84) |
Designated Contracting States: |
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AT BE CH DE ES FR GB IT LI NL SE |
(30) |
Priority: |
21.04.1988 US 184585
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(71) |
Applicant: BASF Corporation |
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Parsippany, NJ 07054 (US) |
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(72) |
Inventors: |
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- Gagnon, Steven Dallas
Detroit
Michigan 48239 (US)
- Dexheimer, Edward Michael
Grosse Ile
Michigan 48138 (US)
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(74) |
Representative: Michaelis, Wolfgang, Dr. et al |
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BASF Aktiengesellschaft,
Patentabteilung ZDX - C 6 D-67056 Ludwigshafen D-67056 Ludwigshafen (DE) |
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(54) |
Novel surfactants based on poly-(alkylene carbonate)s |
(57) A polyether polycarbonate block copolymer nonionic surface-active agent and method
for making the same. The polyether polycarbonate surface active agent is comprised
of a hydrophilic portion comprised of a polymer selected from the group consisting
of a polyoxyalkylene polyether, a saccharide, a saccharide polyoxyalkylenate, a polycarbonate
having a carbon dioxide content of from about 1 to 15 molar percent and mixtures thereof
and a hydrophobic portion comprising alkylene and carbonate units arranged in alterĀnating
or random order to form a poly(alkylene carbonate) having a total carbon dioxide content
of from about 25 to 50 molar percent and a total molecular weight of from about 300
to 10,000. The hydrophobic portion is bonded to the hydrophilic portion at each side
of a reactive hydrogen. The surface active agent is prepared by polymerizing the hydrophilic
portion with the hydrophobic portion in a weight ratio of about 10:90 to 90:10.