[0001] The present invention relates to transfer printing, and in particular, to compositions
for use in sublimatic transfer printing.
[0002] Previously proposed sublimatic transfers are used on man-made fabrics, in particular
polyester. They are formed by printing an image in sublimatic dye on to a paper carrier
or substrate. The image may be formed on the substrate by screen printing, for instance.
In order to transfer the image to the fabric, the face of the substrate which bears
the image is placed against the fabric surface. Pressure is then applied at elevated
temperature, for instance by means of a heated press. This causes the dye on the substrate
to undergo sublimation, changing to a gas which impregnates the fabric fibres, where
the dye solidifies on cooling. The resultant image is extremely durable by virtue
of the impregnation of the dye into the fibres, and is vivid.
[0003] The results obtained from sublimatic transfers on natural fibres and man-made fabrics
other than polyester are found to be inferior, and in many cases unsatisfactory. Natural
fibres have a structure which prevents impregnation by sublimatic dyes in a gaseous
state, and in consequence only a faint image is produced and the image is easily removed
by washing.
[0004] It is an object of the present invention to provide an improved sublimatic transfer
which can be used more widely than previously proposed sublimatic transfers.
[0005] A composition according to the present invention is characterised by comprising an
adhesive component and the material or materials of the composition are so chosen
as to be receptive to sublimatic dye transferred thereto by sublimation, and to be
adherable to a surface to be printed, thereby binding the dye to the surface to form
an image thereon.
[0006] The composition may comprise an acrylic resin such as n-butyl methacrylate as an
adhesive component. The coating may also include a solvent for the adhesive component.
The solvent may be a mineral spirit. The mineral spirit may be a dilute benzene based
solvent.
[0007] The composition preferably also includes a plasticizer. The plasticizer may be a
phthalate such as butyl benzyl phthalate.
[0008] Preferably, when the image is to be formed on a fabric, the composition includes
a lubricant for affecting the feel of the transfer after application to the fabric
softener. The lubricant may comprise oleine.
[0009] The composition may include 30 to 50% of adhesive component, 1 to 35% of plasticizer,
10 to 40% of mineral spirit and 1 to 19% of softener.
[0010] The invention also provides a sublimatic transfer comprising a substrate, an image
formed by sublimatic dye, and a coating, the coating and the dye being so selected
that on heating to a predetermined temperature the dye transfers the image to the
coating by sublimation, the resulting transfer being capable of adherence to a surface
to be printed, whereby the coating binds the dye to the surface to form an image thereon.
[0011] The dye image is preferably located between the coating and the substrate. Where
a solvent is included the coating includes sufficient solvent for the adhesive component
to allow removal of the substrate at a temperature in the range 10 to 200°C. The coating
is preferably a composition as set out above.
[0012] In a further aspect, the invention provides a method of transfer printing with sublimatic
dyes, comprising effecting sublimation of a sublimatic dye on to a coating receptive
thereto to transfer an image to the coating, and adhering the coated image to a surface
to be printed, whereby the coating binds the dye to the surface to form said image
thereon.
[0013] Preferably the sublimation is effected before the coating is adhered to the surface
to be printed.
[0014] Preferably the coating is formed over an image which has been applied in sublimatic
dyes to a substrate, the method including removal of the substrate after the coated
image has been applied to said surface.
[0015] Preferably sublimation of the dye is effected by heating, to transfer the image to
the coating before the coating is applied to said surface. The dye may be heated to
a temperature in the range 185 to 215°C to transfer the image to the coating. The
dye is preferably heated for a period of at least ten seconds to transfer the image
to the coating.
[0016] The coating may be applied to said surface at an elevated temperature to cause the
coating to adhere to said surface. The elevated temperature may be in the region of
180 to 220 °C preferably around 190 °C. The coating is preferably applied to said
surface under pressure to cause the coating to adhere to the surface. The application
pressure may be in the region of 7 to 30 psi, preferably around 20 psi.
[0017] Preferably the elevated temperature and pressure are applied for a period of 7 to
25 seconds, preferably around 10 seconds.
[0018] The coating is preferably a composition as set out above.
[0019] A coating according to the invention and a method of using it will now be described
in more detail, by way of example only, and with reference to the accompanying drawing,
which is a diagrammatic section through a transfer incorporating the coating.
[0020] The coating to be described is intended for use in sublimatic transfer printing on
natural fibres such as cotton and cotton mixtures, for example poly/cotton (polyester/cotton).
The coating material consists of four components. An acrylic resin, preferably n-butyl
methacrylate is used as an adhesive component. A mineral spirit is incorporated as
a solvent for the n-butyl methacrylate which is normally a solid. Other suitable solvents
include ethers, fluorocarbons, hydrocarbons, ketones and nitroparaffins. A plasticizer,
preferably a phthalate such as butyl benzyl phthalate is incorporated to improve the
handling properties of the coating. Finally the material also includes a lubricant
such as oleine or another animal fat derivative, or a mineral oil derivative, or a
mixture of such components. This serves to improve the feel ("handle") of the transfer
on the fabric.
[0021] Preferably the composition includes 30 to 50% of n-butyl methacrylate, 1 to 35% of
plasticizer, 10 to 40% of mineral spirit and 1 to 19% of lubricant. A composition
found to produce acceptable results comprises:
n-butyl methacrylate |
- |
48% |
butyl benzyl phthalate |
- |
8% |
mineral spirit |
- |
30% |
lubricant |
- |
14% |
[0022] The formulation of the coating begins by allowing the n-butyl methacrylate to soak
in mineral spirit until it softens and dissolves. Gentle stirring at this stage results
in a viscous liquid. The plasticizer and lubricant are then added and the resulting
mixture is again stirred to an even consistency. The whole formulation process may
take place at room temperature. When the coating has been prepared, it may be applied
to a sublimatic transfer 10 which consists of a paper substrate 12A on which an image
12B has been printed in reverse, using sublimatic dyes and a silk screen or other
printing process. The coating 14 is then applied, for instance by roller, over the
sublimatic dye image 12B which is therefore trapped between the coating 14 and the
paper substrate 12A.
[0023] Once the transfer has been coated, the image may be transferred to the coating by
heating the transfer. Raising the temperature into the range 185 to 215°C for a period
of ten seconds is sufficient to cause the dyes to penetrate the coating by sublimation
so that when the transfer is returned to room temperature, the image is permanently
fixed in the coating.
[0024] To apply the transfer the substrate 12A and dyed coating 14, 12B are placed against
the fabric to be printed with the coating 14 in contact with the fabric. Elevated
temperature and pressure are then applied. The elevated temperature (preferably in
the range 180 to 220°C, for example 190°C) softens the coating enhancing its adhesive
properties and flow characteristics. The applied pressure (preferably in the range
7 to 30 psi, for example 20 psi) forces the dyed coating between the fibres of the
fabric. When room temperature and pressure are restored, the coating adheres to the
fabric fibres, thereby binding the sublimated dyes to the fabric. Thus the durability
and vivid colours of sublimatic transfer images can be achieved on fabrics whose fibres
are not in themselves suitable for impregnation by sublimatic dye.
[0025] The formulation described above has the further advantage that, by varying the quantity
of solvent included in the coating, the adhesive properties can be varied as may be
required to apply the method to different fabrics. The adhesiveness is preferably
reduced sufficiently to allow the backing paper to be readily removed at room temperature,
or at a temperature in the range 10 to 200°C. Room temperature removal is expected
to provide significant advantages when the transfers are used in presses for simultaneously
printing a plurality of articles. Previously proposed sublimatic transfers required
the backing paper to be removed before the transfer had cooled, so that a press operator
may only have a period of a few seconds in which to remove the backing sheets from
all of the transfers which have simultaneously been printed. This may prove to be
impossible, especially if any difficulties are experienced with one or more backing
sheets, and the resultant loss of production caused by failure to remove backing sheets
can be unacceptably high. By contrast, when the backing sheets can be removed at lower
temperatures, it ceases to be necessary to remove all backing sheets within a few
seconds of the press opening.
[0026] The coating formulation described above has also been found to increase the shelf-life
of sublimatic transfers to which it has been applied. Untreated transfers which tend
to degrade as the dyes in the image leach into one another. The presence of the coating
is believed to inhibit leaching.
[0027] The use of the coating to bind the sublimatic dye to the surface to be printed allows
sublimatic transfer printing to be extended to surfaces which are wholly inpenetrable
by sublimatic dyes.
[0028] It will be appreciated that many modifications and variations to the formulation
described above can be made without departing from the spirit and scope of the present
invention. In particular, the choice of adhesive will depend on the surface which
is to be printed, and will be made to ensure that the adhesive can adhere to the surface
but can also take an image by sublimation. Other components such as lubricants, softeners,
solvents, and plasticizers will be included or omitted according to the characteristics
of the coating which are required for particular applications.
[0029] In a modification of the method described above, the coating may be first applied
to the article, following which the dyes are sublimatically transferred to the coating,
to be bound to the article.
1. A composition for use in sublimatic transfer printing, characterised by comprising
an adhesive component and in that the material or materials of the coating composition
are so chosen as to be receptive to sublimatic dye transferred thereto by sublimation,
and to be adherable to a surface to be printed, thereby binding the dye to the surface
to form an image thereon.
2. A composition according to claim 1, characterised by comprising an acrylic resin
as an adhesive component.
3. A composition according to claim 2, characterised in that the acrylic resin is
n-butyl methacrylate.
4. A composition according to any of claims 1 to 3, and including a solvent for the
adhesive component.
5. A composition according to claim 4, characterised in that the solvent is a mineral
spirit.
6. A composition according to claim 5, characterised in that the mineral spirit is
a dilute benzene based solvent.
7. A composition according to any preceding claim and further characterised by including
a plasticizer.
8. A composition according to claim 7, characterised in that the plasticizer is a
phthalate.
9. A composition according to claim 8, characterised in that the phthalate is butyl
benzyl phthalate.
10. A composition according to any preceding claim, characterised by including a lubricant
for affecting the feel of a transfer after application to a fabric.
11. A composition according to claim 10, characterised in that the lubricant comprises
oleine.
12. A composition according to any preceding claim, characterised by including 30
to 50% of adhesive component, 1 to 35% of plasticizer, 10 to 40% of mineral spirit
and 1 to 19% of lubricant.
13. A sublimatic transfer comprising a substrate, and an image formed by sublimatic
dye, and characterised by a coating, the coating and the dye being so selected that
on heating to a predetermined temperature the dye transfers the image to the coating
by sublimation, the resulting transfer being capable of adherence to a surface to
be printed, whereby the coating binds the dye to the surface to form an image thereon.
14. A transfer according to claim 13, characterised in that the dye image is located
between the coating and the substrate.
15. A transfer according to claim 13 or 14, and characterised by including sufficient
solvent for the adhesive component to allow removal of the substrate at a temperature
in the range 10 to 200°C.
16. A transfer according to claims 13, 14 or 15, characterised in that the coating
is a composition according to any of claims 1 to 12.
17. A method of transfer printing with sublimatic dyes, characterised by effecting
sublimation of a sublimatic dye on to a coating receptive thereto to transfer an image
to the coating, and adhering the coating to a surface to be printed, whereby the coating
binds the dye to the surface to form said image thereon.
18. A method according to claim 17, characterised in that the sublimation is effected
before the coating is adhered to the surface to be printed.
19. A method according to claim 17 or 18, characterised in that the coating is formed
over an image which has been applied in sublimatic dyes to a substrate, the method
including removal of the substrate after the coated image has been applied to said
surface.
20. A method according to any of claims 17 to 19, characterised in that the coating
is a composition according to any of claims 1 to 12.