(57) This invention covers a cold bleaching treatment for any type of corks, by means
of a silicone base solvent-free preparation.
This treatment permits to maintain unaltered chemical-physical characteristics of
the cork, avoid seepage to bottled liquids, simplify operation cycles and eliminate
polluting wastes.
[0001] This invention covers a bleaching treatment for corks. Currently, bleaching treatments
for corks are already being employed and they are all based on chemical oxidation
or reduction processes.
[0002] In the oxidation processes, chlorinated watery solutions or hydrogen peroxide are
used followed by neutralization with diluted organic acids. Whereas, in the reduction
processes, sulfur derivatives, like sulfites, hydrosulfites or sulfuric acid are being
used, followed again by final neutralization.
[0003] These known treatments have several drawbacks. A first drawback is due to the fact
that once the bleaching is completed, the corks must be dried to resume their normal
6-7% humidity rate, before they can be lubricated. A second drawback is due to the
fact that bleaching operations are generally very time-consuming and, as an indication
200,000 corks require a full processing cycle of about 2 works days of eight hours
each.
[0004] Another drawback is due to the fact that, during the oxidation processes with chlorine
derivatives, a whole series of anomalous compounds may develop in spite of final neutralization.
Trichlorophenol is the most remarkable.
[0005] Through its direct contact with alimentary liquids, like wine, it can be methylated
into trichloranisole which is a strongly aromatic substance with a peculiar cork smell
and taste.
[0006] Even with reduction processes based on sulfur compounds, aromatic mercaptans are
likely to develop. With the general formulation AR-SH, they are obtained from hydrogen
sulfide and have a peculiar rotten egg smell.
[0007] If, in addition to what stated here above, health problems in work environment and
ecologic problems of industrial wastes are taken into account, it is clear that these
conventional treatments are by now technologically obsolete. This invention has the
aim to eliminate the above mentioned drawbacks of known bleaching treatments for corks.
This objective is achieved by means of a series of silicone base non-toxic preparations
without any type of solvents which, through one single operation lasting about thirty
minutes, the bleaching of about 10,000 corks is made possible.
[0008] Consequently, up to 160,000 corks can be processed in one single work day.
[0009] According to this invention, the praparation includes the following compounds:
a) Low, medium or high viscosity silicone fluids,
b) Compounds for the reduction of silicon surface tension, without altering its lubricating
properties thus ensuring its regular surface distribution, like metal stearates, kaolins,
talcums, bentonites and similar,
c) Liposoluble dyes or white pigments like zinc oxide, titanium dioxide or similar
to give the cork surface the desired colour,
d) A mixture stabilizer with suspending properties, like atomized silica gel.
[0010] These components are thoroughly mixed together by means of a particular turbo-mixing
plant with alternatively axial movement and provided with recycling equipment micronization
of solid constituents.
[0011] By acting on the viscosity of the silicone fluid and on the percentage of all the
other components, the preparation may either be liquid, creamy or pasty, depending
on the specific need of the user.
[0012] The advantages deriving from the use of the preparation subject matter of this invention
can be summarized as follows:
- Possibility of cold treatment by common bolting, if possible fitted with adequate
spray,
- No variation of the chemical-physical characteristics of cork due to substances
with oxidative or deoxidant properties,
- No possibility of seepage of product components, both under cold and hot conditions,
even after direct protracted contact with bottled liquids,
- Remarkable streamlining of the processing cycle with abolition of expensive, complicated
and dangerous procedures,
- Integral solution to waste problems, connected with the complexity and costs of
managing industrial purification plants as provided by Law,
- Subsequent drastic reduction of production costs thus meeting the aims of this invention.
1) Preparation for the bleaching of corks, characterized by the fact that it is consisting
of a close mixture of the following components:
a) Low, medium or high viscosity silicone fluids,
b) Compounds for the reduction of silicon surface tension, without altering its lubricating
properties thus ensuring its regular surface distribution, like metal stearates, kaolins,
talcums, bentonites and similar,
c) Liposoluble dyes or white pigments like zinc oxide, titanium dioxide or similar
to give the cork surface the desired colour,
d) A mixture stabilizer with suspending properties, like atomized silica gel.
2) Preparation as described in claim n. 1, characterized by the fact that it may either
be liquid, creamy or pasty, depending on the viscosity of the silicone fluid and on
the percentage chosen for the other components.
3) Equipment for preparing the product as described in claim 1, characterized by the
fact that it requires a particular turbo-mixing plant with alternatively axial movement
and provided with recycling equipment for micronization of solid constituents.