(19)
(11) EP 0 367 227 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
24.07.1991 Bulletin 1991/30

(43) Date of publication A2:
09.05.1990 Bulletin 1990/19

(21) Application number: 89120198.0

(22) Date of filing: 31.10.1989
(51) International Patent Classification (IPC)5G03C 7/30, G03C 7/392, G03C 1/28
(84) Designated Contracting States:
DE FR GB IT NL

(30) Priority: 01.11.1988 JP 276678/88

(71) Applicant: FUJI PHOTO FILM CO., LTD.
Kanagawa-ken (JP)

(72) Inventor:
  • Asami, Masahiro
    Minami Ashigara-shi Kanagawa (JP)

(74) Representative: Grünecker, Kinkeldey, Stockmair & Schwanhäusser Anwaltssozietät 
Maximilianstrasse 58
80538 München
80538 München (DE)


(56) References cited: : 
   
       


    (54) Silver halide color photographic material


    (57) A silver halide color photographic material comprising on a reflective support at least three light-sensitive emulsion layers having different color sensitivities, wherein at least one of said light-sensitive emulsion layers comprises a silver halide emulsion spectrally sensitized with at least one compound represented by the formula (I), that at least one of said light-sensitive emulsion layers or light-insensitive layers comprises on said support at least one compound represented by the formula (II), (III) or (IV) and that the total amount of silver halide emulsion on said support is in the range of 0.65 g/m2 or less as calculated in terms of coated amount of silver:

    wherein Z represents an oxygen atom or sulfur atom; R1 and R2 each represent a substituted or unsubstituted alkyl group; V1, V2, V3, V4, V5, V6, V7, and V8 each represents a hydrogen atom, a halogen atom, an alkyl group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a carboxyl group, a cyano group, a hydroxyl group, an amino group, an acylamino group, an alkoxy group, an alkylthio group, an alkylsulfonyl group, a sulfonic acid group or an aryl group, with the proviso that two of V, to V8 which are bonded to adjacent carbon atoms do not together form a condensed ring and that assuming Hammett's value ap of each of V1 to Vs is σpi (i = 1 to 8) and Y= ap1 + ap2 + ap3 + ap4 +σp5 + σp6 + σp7 + σp8, then Y ≦ -0.08 if Z is an oxygen atom or Y ≦ -0.15 if Z is a sulfur atom; X' represents a charge balance paired ion; and n represents a value required to neutralize the electric charge:

    wherein R represents an alkyl group, an alkenyl group or an aryl group; and X represents a hydrogen atom, an alkali metal atom, an ammonium group or a precursor:

    wherein L represents a divalent connecting group; R4 represents a hydrogen atom. alkyl group, alkenyl group or aryl group; X is as defined for the formula (II); and m represents an integer 0 or 1:

    wherein R and X are as defined for the formula (II); L and m are as defined for the formula (III); R3 has the same meaning as R, with the proviso that these groups may be the same or different; and m represents an integer 0 or 1.







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