(19)
(11) EP 0 367 278 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
27.11.1991 Bulletin 1991/48

(43) Date of publication A2:
09.05.1990 Bulletin 1990/19

(21) Application number: 89120369.7

(22) Date of filing: 03.11.1989
(51) International Patent Classification (IPC)5C08G 63/60
(84) Designated Contracting States:
DE FR GB

(30) Priority: 04.11.1988 JP 279937/88

(71) Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
Osaka-shi, Osaka (JP)

(72) Inventors:
  • Sugimoto, Hiroaki
    Tsukuba-shi (JP)
  • Ohbe, Yoshitaka
    Tsukuba-shi (JP)
  • Hayatsu, Kazuo
    Ibaraki-shi (JP)

(74) Representative: VOSSIUS & PARTNER 
Postfach 86 07 67
81634 München
81634 München (DE)


(56) References cited: : 
   
       


    (54) A process for producing aromatic polyesters


    (57) An aromatic polyester superior in heat resistance and melt-moldability is obtained by carrying out the polycondensation reaction with
    Component A consisting of at least one compound having the formula,

    wherein R₁ is hydrogen, formyl, acetyl, propionyl or benzoyl, and R₂ is hydrogen, a C₁-C₆ alkyl or a C₆-C₁₈ aryl,
    or a mixture containing not less than 50% by mole of said compound,
    Component B consisting of at least one compound having any one of the formulas,

    wherein R₃ is hydroxyl, a C₁-C₆ alkyloxy, a C₆-C₁₈ aryloxy or halogen,
    or a mixture containing not less than 50% by mole of said compound, and
    Component C consisting of at least one compound having the formula,
    R₄O-A₁-OR₄
    wherein A₁ is a divalent aromatic residue, and R₄ is hydrogen, acetyl, propionyl or benzoyl
    in a reaction vessel at a temperature of 270°C to 380°C until the flow temperature of the produced aromatic polyester reaches a temperature of 240°C or higher.
    The aromatic polyester obtained by the process of the present invention can be used molded into various forms such as fiber, film, etc. In addition, compositions comprising this aromatic polyester and fillers can be used in machine parts, electric and electronic parts and automobile parts because of their excellent mechanical properties, electric properties, chemical resistance and oil resistance.





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