(19) |
 |
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(11) |
EP 0 368 536 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
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03.04.1991 Bulletin 1991/14 |
(43) |
Date of publication A2: |
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16.05.1990 Bulletin 1990/20 |
(22) |
Date of filing: 31.10.1989 |
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(51) |
International Patent Classification (IPC)5: C07F 7/21 |
|
(84) |
Designated Contracting States: |
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BE DE FR GB |
(30) |
Priority: |
09.11.1988 US 269522
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(71) |
Applicant: DOW CORNING CORPORATION |
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Midland
Michigan 48686-0994 (US) |
|
(72) |
Inventors: |
|
- Baile, Gnaneshwar Rao
Midland
Michigan 48640 (US)
- Herman, John Eric
Midland
Michigan 48640 (US)
- Wyshak, Geoffrey Mark
Midland
Michigan 48640 (US)
|
(74) |
Representative: Laredo, Jack Joseph et al |
|
Elkington and Fife
Prospect House
8 Pembroke Road Sevenoaks, Kent TN13 1XR Sevenoaks, Kent TN13 1XR (GB) |
|
|
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(54) |
Preparation of cycloorganotrisilazanes |
(57) What is disclosed is a process for the rearrangement of cylcoorganopolysilazanes
to cycloorganotrisilazanes using quaternary ammonium halides as a catalyst. The quaternary
ammonium halide has the formula R
i₄NX where at least one R
i is a group containing greater than 11 carbon atoms and X is a halogen atom. The rearrangement
process is ran either as a batch or a continuous distillation procedure.