[0001] The invention concerns an arrangement in a part of a paper machine in which the surface
properties of a roll and/or rolls are affected by regulating the temperature of the
roll face by means of an external heating device.
[0002] The invention further concerns the use of the arrangement in accordance with the
invention.
[0003] A number of different requirements are imposed on the rolls and roll faces in different
parts of a paper machine, such as, for example, properties of durability, adhesion,
transfer, and detaching.
[0004] For example, in so-called closed press sections, which are used commonly in paper
machines, in connection with the centre roll, one or, as a rule, several press nips
are formed. An example of such a prior-art press section is the press section marketed
by the applicant under the trade mark "Sym-Press II". The smooth-faced centre roll
in the press section, which is a roll of a larger diameter as compared with the other
rolls, is usually made of rock, as a rule of granite. Being an inhomogeneous natural
material of low tensile strength, granite is quite problematic in machine construction.
Should it be desired to heat a granite roll, its deformations dependent on temperature
are non-linear and hard to predict.
[0005] As a press roll material, granite has relatively good properties of adhesion, transfer
and detaching of the web, which is at least one of the reasons for its popularity.
The properties of detaching would, however, require further improvement, in particular
in the case of unbleached paper qualities.
[0006] As is known in prior art, the web is detached by pulling it freely, without support,
off the face of said centre roll in the press. This free draw is quite critical in
view of the operation of the paper machine. In said free draw, a difference in speed
is used which extends the web, resulting in certain drawbacks. Moreover, said free
draw forms a problematic point susceptible to breaks in the paper machine. Earlier,
the detaching was always carried out mechanically by pulling, and the heating took
place in the roll body, whereby the whole roll was hot. Thereby the roll is worn and
the intervals between grindings become short.
[0007] The free draw of the web has become an ever more important problem point because
of ever increasing running speeds of paper machines and because different paper qualities
are often produced by a paper machine, with different adhesion to the face of the
rock roll, which results in variations in the necessary tension required for detaching
of the web.
[0008] In the applicant's FI Patent Application No. 870308 a system of regulation is described
wherein the detaching of the paper web from the smooth face of the centre roll in
a press can be controlled better. It is a particular objective of said invention to
provide such a system of regulation of the detaching of the web wherein the tension
of detaching of the web can be set optimally irrespective of the dry solids content
of the paper web, of the surface energy of the material, and of the running speed
of the paper machine. The method in accordance with the application FI 870308 is characterized
in that in the method the temperature of the face of said smooth-faced press roll
is regulated and that, by means of said regulation, the adhesion between said roll
face and the paper web to be detached is affected and, thereby, the detaching angle
and/or the detaching tension of the paper web is/are set within an optimal range.
[0009] On the other hand, the device in accordance with the invention described in said
application is mainly characterized in that in connection with said smooth-faced press
roll heating devices are provided, by means of which the temperature of the smooth
face of said press roll and thereby the detaching of the web from said roll face are
affected.
[0010] The invention of the FI application 870308 is based on the observation that the temperature
at the interface between the paper web and the smooth roll face from which the web
is to be detached affects the dry solids content of the web, the surface energies
of the materials in contact, and the viscosity of water, which parameters again affect
the adhesion between the paper web and the water contained therein, on one hand, and
the smooth roll face, on the other hand. By establishing the interdependence of said
parameters, by controlling them, and by, on the basis of this information, regulating
the temperature of the roll face by means of the regulating system of said invention,
it is possible to set the detaching tension of the paper web to a suitable level even
within highly varying operating conditions. Thus, in the invention, when running different
paper qualities and with different running speeds of the paper machine, it is possible
to adjust the temperature of the smooth face of the roll to a certain set value, which
provides an optimal detaching of the web and an optimal running quality with the web
quality and machine speed that are used at each particular time.
[0011] In the invention of FI-870308, the central roll of the press or any other corresponding
smooth-faced roll from which the paper web is supposed to be detached is a substantially
metal-mantle roll coated with a metal, with a ceramic material, or with mixtures of
same, a cast-iron roll, or an uncoated metal roll, which are arranged to be heated
by means of adjustable heating devices. The heating may take place from inside and/or
from outside the roll at least partly by means of techniques known in prior art. The
invention of FL 870308 is by no means restricted to be used for the detaching of the
web from the central roll of closed press sections of paper machines alone, but the
invention is suited and intended for controlling the detaching of the web from a smooth-faced
roll in a press in general, i.e. also from a roll other than a central roll.
[0012] As prior art, the solution in accordance with the Finnish Patent Application No.
870309 is also cited, wherein, by means of a heating effect applied, among other things,
to the roll mantle, the water present between the web and the roll face is heated,
preferably vaporized, locally within the area of the detaching point so as to detach
the web from said roll face. Since, in accordance with said invention, the work for
the detaching of the web is carried out by vaporization, to detach the web it is not
necessary to extend the web at all, which again permits a closed draw from the centre
roll in the press to the drying section, e.g. onto the drying wire.
[0013] The object of the present invention is further development of the solutions in accordance
with said FI applications 870308 and 870309 by coming even closer to the objectives
of said applications, which were, among other things, better control of the detaching
of the paper web from the smooth face of the centre roll in the press as well as to
provide such a system for the regulation of the detaching of the web.
[0014] An object of the present invention is further expansion of the field of application
of the invention so that in each application of use the detaching tension of the web
can be set optimally irrespective of the dry solids content of the paper web, of the
surface energy of the material, and of the running speed of the paper machine.
[0015] An object of the present invention is additionally to expand the field of application
of the invention so that the invention can also be used for modification of other
surface properties besides the properties of detaching.
[0016] It is a particular object of the present invention to provide suitable surface materials
for applications of use wherein a heating device outside the roll is used.
[0017] In view of achieving these objectives, the arrangement in accordance with the invention
is mainly characterized in that in the arrangement such a combination of a heating
device and a roll coating is used that the heating radiation penetrates through the
paper or only directly to the roll face but does not heat the roll itself at a greater
depth.
[0018] It is the idea of the combination of coating and heating in accordance with the invention
that the dark surface of the surface material absorbs the light coming from the heating
device efficiently and so that the roll face is heated but the paper not. Moreover,
the coating material is chosen so that it acts as a thermal insulation, whereby the
rest of the roll is not heated and heating power is not wasted.
[0019] Said external heating device is advantageously a short-wave infrared heater or a
laser heater which is capable of heating the coating. It is an advantage of infrared
heating that the face can also be heated through the paper. Only a thin surface layer
of the roll has to be heated, while the rest of the roll remains at the temperature
of the environment. Embodiments of heaters are described in the applicant's earlier
patent applications FI-870308 and FI-870309.
[0020] The function of the coating would be to apply a thermal shock to the paper. The thermal
shock can be utilized, e.g., for drying the paper or for detaching the paper from
the roll. Properties of the coating include dark face, good capacity of thermal insulation,
good resistance to heat, good resistance to thermal shock, low coefficient of thermal
expansion, high heat capacity, good wear resistance, and/or good resistance to corrosion.
One coating of this type is, e.g., chromia-silica composite, which has been prepared
by means of thermal spraying. It is an advantage of this material that it is dark,
corrosion-proof, and wear-resistant, for which reason one objective of the invention
is to apply said material to various objects of use, such as, e.g., to a calender.
[0021] Thus, as said roll coating, a dark readily heatable material is used. The final coating
material in detail is chosen in accordance with the above desired ultimate additional
properties. The coating may be, e.g., a ceramic or a ceramic composite or a mixture
of a ceramic and a metal.
[0022] If hardness and wear-resistance is desired for the material, advantageously materials
based on alumina (Al₂O₃) or chromia (Cr₂O₃) are used. On the other hand, if heat resistance,
impact strength and/or capacity of thermal insulation is/are desired for the material,
advantageously materials based on zirconia (ZrO₂) are chosen. In surface finish applications
of high requirements, advantageously materials based on titania (TiO₂) are used.
[0023] Coating materials can be used alone or in layers depending on the objects of use,
e.g., so as to provide a suitable resistance to thermal shocks or a capacity of thermal
insulation.
[0024] One object of use in accordance with the invention is in a calender roll, wherein
the heating effect of the heating device penetrates through the paper, whereby the
hot roll face modifies the surface properties of the paper. Suitable coating materials
are, e.g., Cr₂O₃, Al₂O₃, TiO₂. If desired, zirconia or equivalent may be used as a
thermal insulation underneath a thin ceramic mantle.
[0025] The invention may also be employed to detach the paper from the web by heating (by
affecting the viscosity of the medium) or by vaporizing the interface, e.g. by vaporizing
the water, in the case of a press roll, or the coating agent, in the case of a guide
roll in a coating device. In other words, the arrangement can be used in a guide roll
in a separate sizing cylinder to facilitate the scraping by means of a doctor, in
which case the hot roll face vaporizes some of the size layer and detaches the paper
from the roll. Coating materials suitable for this purpose include, e.g., Cr₂O₃.
[0026] An object of application may also be a pick-up roll wherein there is a felt between
the paper and the roll.
[0027] The thickness of the coating may be, e.g., 10 µm to 10 mm, most appropriately about
50 µm to 150 µm.
[0028] In the invention, when it is desirable to obtain good adherence of the coating to
the roll, increased toughness, and good wear-resistance of the coating at the same
time, in the coating material it is possible to use a metal as an alloying agent,
the ratio being, for example, 1 to 10...30 (metal to ceramic). One example of a coating
might be a surface layer of WC 86 Co 20 Cr4 isolated from the roll body by a layer
of Zr₂O₃.
[0029] To manufacture a roll coating, it is possible to employ prior-art processes, e.g.
powder-metallurgic processes.
[0030] By means of the invention, a number of advantages are obtained over prior art. By
its means it is possible to provide a wear-resistant face at the same time as the
detaching and other properties of the face can be modified highly precisely in the
desired way by means of the system of heating of the roll and by means of a suitable
choice of materials.
[0031] Thus, the various objects of application of the invention are briefly detaching of
paper from a roll by heating (by acting upon viscosity) or by vaporizing the interface,
heating of the paper, and/or modifying the surface properties of the paper by heating.
[0032] For these applications, a short-wave radiation is suitable, the wavelength being,
e.g., 1 µm when the radiation is supposed to penetrate through the web (infrared heater);
when the roll face is heated directly, a radiation of longer wavelength is suitable
(infrared heater 1...5 µm, CO₂-laser 10.6 µm). The requirement of power depends on
the web length, web thickness, web moisture, and on the filler material. In the following,
examples will be given on materials suitable for use in the invention.
Examples of surface material compositions based on different oxides. |
Constituents |
Ex. 1 (White Alumina) |
Ex. 2 (Gray Alumina) |
Ex. 3 (Alumina Titania) |
Ex. 4 (Zirconia) |
Ex. 5 (Yttriastabilizing Zirconia) |
Ex. 6 (Alumina Zirconia) |
Ex. 7 (Titania) |
Ex. 8 (Chromia) |
Al₂O₃ |
99.64 |
96.06 |
58.29 |
0.45 |
|
73.82 |
0.20 |
1.83 |
SiO₂ |
0.10 |
0.60 |
0.13 |
0.40 |
0.12 |
0.10 |
0.12 |
6.23 |
Na₂O |
0.15 |
|
0.15 |
|
|
0.02 |
|
|
Fe₂O₃ |
0.03 |
0.40 |
0.04 |
0.13 |
0.03 |
0.06 |
0.40 |
0.30 |
CaO |
0.04 |
0.12 |
0.02 |
5.51 |
|
|
0.03 |
0.45 |
MgO |
0.04 |
0.12 |
0.01 |
1.43 |
|
|
|
1.40 |
TiO₂ |
|
2.70 |
41.36 |
0.10 |
0.10 |
2.32 |
99.20 |
|
ZrO₂ |
|
|
|
91.64 |
89.78 |
25.68 |
|
|
Y₂O₃ |
|
|
|
|
9.97 |
|
|
|
Cr₂O₃ |
|
|
|
|
|
|
|
89.50 |
Thermal expans. coeff. x 10⁻¹⁶/oC |
7.4 |
7.6 |
7.8 |
9.5 |
|
|
5.0 |
5.0 |
(20...1500oC) |
|
|
|
|
|
|
|
Thermal conductivity K Cal/m hr oC |
2.36 |
|
|
0.99 |
|
|
2.98 |
|
(550...1100oC) |
|
|
(550...1100oC) |
|
|
(600oC) |
|
1. Arrangement in a part of a paper machine in which the surface properties of a roll
and/or rolls are affected by regulating the temperature of the roll face by means
of an external heating device, characterized in that in the arrangement such a combination of a heating device and a roll coating
is used that the heating radiation penetrates through the paper or only directly to
the roll face but does not heat the roll itself at a greater depth.
2. Arrangement as claimed in claim 1, characterized in that said heating device is an external short-wave infrared heater which is capable
of heating the coating.
3. Arrangement as claimed in claim 2, characterized in that the wavelength of the beam of the infrared heater is 1 µm ± 0.5 µm when heating
takes place through the web, and 1...5 µm when the roll face is heated directly; in
laser heating the wavelength is 10.6 µm when the roll face is heated directly.
4. Arrangement as claimed in any of the claims 1 to 3, characterized in that said roll coating is made of a dark, easily heatable material.
5. Arrangement as claimed in any of the claims 1 to 4, charac terized in that said roll coating insulates heat so that the roll is not heated at a great
depth.
6. Arrangement as claimed in claims 4 and 5, characterized in that the exact composition of the coating material is chosen finally in accordance
with the desired additional properties, said properties being, for example, wear resistance,
detaching properties, resistance to corrosion, capacity of thermal insulation, heat
resistance, resistance to thermal shock, thermal expansion coefficient, and heat capacity.
7. Arrangement as claimed in claim 6, characterized in that the coating consists of a ceramic or of a ceramic composite or of a mixture
of ceramic and metal.
8. Arrangement as claimed in claim 6, characterized in that materials based on alumina (Al₂O₃) or chromia (Cr₂O₃) are used to obtain
hardness and wear resistance.
9. Arrangement as claimed in claim 6, characterized in that materials based on zirconia (ZrO₂) are used to obtain heat resistance, impact
strength, and/or capacity of thermal insulation.
10. Arrangement as claimed in claim 6, characterized in that materials based on titania (TiO₂) are used in applications with high requirements
of surface finish.
11. Arrangement as claimed in claim 6, characterized in that coating materials may be used alone or in layers, depending on the application
of use.
12. Use of an arrangement as claimed in any of the claims 1 to 11 in a calender, characterized in that the heating effect of the heating device is allowed to penetrate through
the paper, whereby the hot roll face modifies the surface properties of the paper.
13. Use as claimed in claim 12, characterized in that coating materials suitable for this purpose are, e.g., Cr₂O₃, Al₂O₃, TiO₂.
14. Use as claimed in claim 12, characterized in that zirconia or equivalent is used as a thermal insulation underneath a thin
ceramic mantle.
15. Use of a system as claimed in any of the claims 1 to 11 for detaching a paper
from a roll by heating (by affecting the viscosity) or by vaporizing the interface,
e.g. of water in the case of a press roll, and of a coating agent in the case of a
guide roll in a coating device, such as a sizing cylinder, so as to facilitate the
scraping by means of a doctor, the hot roll face heating or vaporizing the size layer
and detaching the paper from the roll.
16. Use as claimed in claim 16, characterized in that coating materials suitable for this purpose include, e.g., Cr₂O₃.
17. Use as claimed in claim 14, characterized in that the object of application is the centre roll in a press, a sizing press,
or a release-coating guide roll.