(19)
(11) EP 0 372 918 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
24.07.1991 Bulletin 1991/30

(43) Date of publication A2:
13.06.1990 Bulletin 1990/24

(21) Application number: 89312694.6

(22) Date of filing: 06.12.1989
(51) International Patent Classification (IPC)5C01B 33/025
(84) Designated Contracting States:
AT DE ES FR GB IT NL SE

(30) Priority: 08.12.1988 NO 885453

(71) Applicant: ELKEM A/S
N-0483 Oslo 4 (NO)

(72) Inventors:
  • Forwald, Karl
    N-4622 Kristiansand (NO)
  • Sorli, Oyvind
    Sewickley PA 15143 (US)
  • Schüssler, Gunnar
    N-3000 Drammen (NO)

(74) Representative: Rees, David Christopher et al
Kilburn & Strode 30 John Street
London WC1N 2DD
London WC1N 2DD (GB)


(56) References cited: : 
   
       


    (54) Silicon powder and method for its production


    (57) The present invention relates to a silicon powder, which is characterised in that it is produced by gas atomizing of molten silicon and having a particle size between 0.1 and 1000 µm, a specific area between 0.001 and 1 m²/g, and the following chemical composition in percent by weight:
    0.1 - 1% iron, 0.01 - 1% aluminium, 0 - 8% copper, 0 - 1% calcium, 0 - 1% zinc, 0 - 1% tin, 0 - 5% boron, 0 - 0.5% phosphorus, 0 - 0.5% sodium, 0 - 0.5% lithium, 0 - 0.5% potassium, 0 - 0.5% magnesium, 0 - 0.5% strontium, 0 - 0.5% barium, 0 - 0.5% beryllium, the rest being silicon and less than 0.3% impurities as Ti, V, Cr, Mo, W and Zr.
    The silicon powder is produced continuously by a method comprising the following steps:

    a) continuous production of silicon in an electric smelting furnace,

    b) refining and alloying of the molten silicon in a metal treatment vessel,

    c) continuous supply of molten silicon from the metal treatment vessel to a holding furnace,

    d) continuous supply of molten silicon to a closed atomising apparatus wherein the molten silicon is atomised by means of an inert gas supplied from a pressure vessel or a compressor unit,

    e) continuous removal of atomised silicon powder from the atomising apparatus,

    f) separation of atomised silicon powder and inert gas in a solid/gas separator,

    g) screening of the silicon powder into preset particle size fractions,

    h) supply of the different particle size fractions of silicon powder to closed product silos,

    i) filtration of the inert gas from step f) for removing any remaining solid particles from the inert gas,

    j) cooling and compressing the inert gas from step i) and recycling of the compressed inert gas to the pressure vessel or directly to the atomising apparatus.









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