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EP 0 374 050 B1 |
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EUROPEAN PATENT SPECIFICATION |
| (45) |
Mention of the grant of the patent: |
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01.02.1995 Bulletin 1995/05 |
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Date of filing: 14.12.1989 |
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International Patent Classification (IPC)6: H05B 33/04 |
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Improved desiccant for el lamps
Trockenmittel für Leuchtstofflampen
Dessicateur pour lampes électro-luminescentes
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Designated Contracting States: |
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DE FR GB IT NL SE |
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Priority: |
16.12.1988 US 285796
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Date of publication of application: |
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20.06.1990 Bulletin 1990/25 |
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Proprietor: LOCTITE LUMINESCENT SYSTEMS, INC. |
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Lebanon
New Hampshire 03766 (US) |
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Inventors: |
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- Nativi, Larry A.
Rocky Hill
Connecticut 06067 (US)
- Marion, Robert H.
Lebanon
New Hampshire 03766 (US)
- Ashour, Tahsin A.
Amherst
New Hampshire 03031 (US)
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| (74) |
Representative: Dubois-Chabert, Guy et al |
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Société de Protection des Inventions
25, rue de Ponthieu 75008 Paris 75008 Paris (FR) |
| (56) |
References cited: :
DE-B- 2 035 454 JP-A-60 185 394 US-A- 4 066 925 US-A- 4 687 968
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GB-A- 2 049 274 JP-A-63 213 289 US-A- 4 104 555
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
|
BACKGROUND OF THE INVENTION
[0001] This invention relates to a method of manufacturing visible display devices from
electroluminescent phosphors and more particularly to a method of making an electroluminescent
light source in the form of a thin, flexible, multi-layered assembly, and to a lamp
as produced.
[0002] An electroluminescent lamp is basically composed of a layer of electroluminescent
phosphor material typically of a metal activated zinc sulfide fixed in place by a
polymer binder between two conductive layers, one of which is transparent. When an
alternating electric field is applied across the conductors, the phosphors are excited
and emit photons with almost all of the radiated energy lying within the visible light
spectrum. The emission spectrum and wavelength generated by the phosphors is controlled
by the activator element such as copper or manganese.
[0003] Electroluminescent phosphors and the polymer binders used are inherently hygroscopic
and sensitive to moisture. When exposed to high humidity, the luminescent capability
of the phosphor particles is diminished, and performance deteriorates. The sensitivity
of the phosphor particles to moisture is so strong that exposure even to conditions
of low humidity may adversely affect performance and decrease the light output capacity
and useful life of the lamp in which the phosphors are incorporated. To effectively
reduce the exposure of the electroluminescent phosphors to moisture, an internal desiccant
layer may be incorporated in the lamp.
[0004] One method of fabricating an electroluminescent lamp is currently employed starting
with a conductive non-transparent substrate of, for example, a sheet of aluminum foil
upon which is coated an insulating layer of high dielectric constant material such
as barium titanate. Then, an electroluminescent phosphor in a polymer binder is deposited
over the dielectric layer and oven dried. A transparent conductive coating formed
from, for example, indium oxide and/or indium tin oxide is then deposited over the
phosphor layer to form the front electrode. Alternatively, the front electrode may
be formed from indium-tin-oxide sputtered Mylar film. A busbar having a conductivity
greater than the conductivity of the transparent conductive coating is formed adjacent
the periphery of the transparent conductive coating, and a thin nylon preformed film
is then applied over the busbar and front electrode. The nylon film or other suitable
desiccant film acts as an internal desiccant whose purpose is to collect and hold
any small traces of moisture left over from the manufacturing process and to scavenge
and retain any moisture which may infiltrate the lamp area. Thereafter, the nylon
desiccant film is pulled up to position and attach the front lead, and a second lead
is attached to the aluminum foil conductive substrate. Alternatively, the front lead
may be positioned before applying the desiccant film, but this may present staining
problems since the desiccant film also protects the lamp during processing and handling
to prevent staining due, for example, to skin oils from the person handling the lamp.
Therefore, the preferable method is to apply the desiccant film and peel it back to
position the lead on the busbar.
[0005] The entire assembly excluding a portion of the connecting leads is then sandwiched
between two moisture barrier films such as a polychlorotrifluoroethylene (PCTFE) film
which is commercially available from Allied Chemical Co. under the trade name ACLAR
R, or a polyester film, both of which are heat laminated to the assembly and to each
other around the perimeter of the lamp. As will be appreciated, the current manufacturing
procedure is labor intensive and time consuming, and has inherent quality control
problems resulting in a considerable number of unusable lamps. Moreover, in current
manufacture lifting the nylon desiccator film in order to position and attach the
front lead may break the busbar, and/or permit ingress of moisture and/or contaminants
which may result in premature lamp failure in the filed.
[0006] Moreover, the use of nylon desiccant films adds other manufacturing difficulties.
These include the necessary precutting which is usually done off-line, and static
charge build-up which inherently occurs in the handling of nylon film. This static
charge attracts dust, often causing unacceptable lamps. Other problems involve hand
tacking and lead attachment when using nylon film.
[0007] The reference US-A-4 687 968 concerns an encapsulated electroluminescent lamp using
multilayer barrier film to protect the active components of the lamp.
BRIEF SUMMARY OF THE INVENTION
[0008] The present invention overcomes the aforesaid and other prior art problems by using
a patternable formed-in-place desiccant polymer film in place of a preformed desiccant
film of nylon or other suitable dessicator materials. Then, the invention relates
to an electroluminescent lamp assembly as defined in claim 1 and a method for manufacturing
this assembly as defined in claim 9. According to the invention, the patternable formed-in-place
desiccant polymer material is applied directly to the assembly following attachment
of the busbars, leaving the lead traces exposes, an is cured-in-place by a method
appropriate to the particular material selected, for example, thermal curing, air
drying, or exposure to ultra-violet or other radiation. The resulting cured-in-place
polymeric film material completely protects the underlying layers. Besides applying
a layer of the desiccant polymer material to the light-emitting side of the lamp,
a similar layer may be applied to the back of the lamp. Thereafter, the resulting
assembly can be, and is preferably sealed between two moisture barrier members such
as ACLAR
R PCTFE film.
DETAILED DESCRIPTION OF THE INVENTION
[0009] For a fuller understanding of the invention reference should be made to the following
specification taken in connection with the drawings in which:
Figure 1 shows an exploded diagrammatic schematic view of an electroluminescent lamp
made in accordance with the present invention. This drawing also included a flow sheet
of processing steps involved in a preferred form of the invention; and
Figure 2 shows a membrane switch incorporating an electroluminescent lamp made in
accordance with the present invention.
[0010] Referring now to Figure 1 of the drawings, the construction and process of the present
invention involves the following steps: An aluminum 24 oz. foil sheet 10 is first
coated with a barium titanate paint layer 12, which is then oven dried. Thereafter,
a phosphor paint layer 14 is applied over layer 12 and this is oven dried. An indium
tin oxide electrode 16 is then silkscreened on, and this is oven dried. Next silver
busbars 18 are silkscreened onto electrode 16 and oven dried. The resulting assembly
is then coated with a patternable curable desiccant polymer coating 20 which is silkscreened
over the busbars 18 (leaving an area for lead attachment exposed) and over the indium
tin oxide electrode 16, and the coating is cured-in-place to form a desiccant film
coating. The patternable curable desiccant polymer coating may comprise one or a mixture
of screenable materials which form on curing a film. The term curing as used herein
includes, but is not limited to, air drying, oven drying, heat curing, solvent evaporation,
photocuring, and radiation curing. The term patternable as used herein refers to materials
which are capable of being applied using any one of a number of techniques, including
but not limited to printing, coating, spraying, depositing, painting, silkscreening,
or otherwise forming in place. While there are a large number of materials which can
be used as the patternable curable desiccant polymer coating material in accordance
with the present invention, the preferred materials comprise those which (1) are sufficiently
flowable in the uncured state so as to be capable of being patternable, printable,
formed-in-place, or applied using selective deposition techniques such as silkscreening,
in order to cure to films; (2) have good bonding characteristics to the underlying
surfaces; (3) are thermally stable at the expected processing and operating temperatures
of the lamp; and (4) have a relatively low but sufficient solubility in water to scavenge
and retain any moisture left over from the manufacturing process or which may infiltrate
the lamp during its design life. Among suitable materials are mentioned soluble nylon
such as Elvamide
R (available from E.I. DuPont de Nemours Co.), cellulose acetate, polyvinyl alcohol
(PVA), and polyethyloxazoline (PEOX
R, available from Dow Chemical Co.) resins. Additionally, certain thermal setting polymers
and resins can be used to achieve the advantages of the present invention. Yet another
and preferred class of materials useful in the present invention comprise UV or other
radiation curable materials. Amongst suitable and preferred UV curable materials are
mentioned Lite-Tak™ 375 UV curing adhesive and Lite-Tak™ 376 UV curing adhesive, both
available from Loctite Corporation. The manufacturer describes these materials as
comprising a mixture of polyurethane acrylate resins, a cyclic amide, acrylate or
ethoxyethocyethyl acrylate, and a photoinitiator.
[0011] The coated assembly then is subjected to appropriate conditions to cure the polymer
material. Thereafter, the leads 19 are attached and the resulting assembly is sealed
between two layers (22 and 24) of moisture barrier sheet materials such as ACLAR
R film available from Allied Chemical Co., which may be laminated to the opposite faces
of the assembly using an adhesive or hot laminating technique whereby to form an electroluminescent
lamp.
[0012] The features and advantages of the present invention are more fully shown with respect
to the following working example which describes a preferred embodiment of the invention.
WORKING EXAMPLE
[0013] In a preferred embodiment of the invention the basic lamp structure is fabricated
in known manner by applying a suspension of barium titanate in a heat curable resin
and drying onto an aluminum foil substrate. A phosphor paint is deposited over the
barium titanate layer, indium tin oxide electrode is formed over the phosphor paint,
and silver busbars are formed all in known manner.
[0014] Thereafter, a screenable UV curable desiccant layer comprising a mixture of polyurethane
acrylate resins, a cyclic amide, an acrylate ester and a photoinitiator of the type
sold by Loctite Corporation under the Trademark "Lite-Tak" type 375 UV Curing Adhesive
is applied to the resulting assembly. The manufacturer describes the "Lite-Tak" 375
formulation as follows: The polyurethane acrylate resin mixture in the UV curable
adhesive is a mixture of resins sold by Celanese Chemical Co. under the designation
Interez CMD-8800. The cyclic amide is N-vinyl pyrrolidone sold by GAF Corp. Chemical
Products under the designation V-Pyrol. The acrylate ester is ethoxy ethylethoxy ethyl
acrylate sold by Thiokol Chemical Corp. under the designation RC-20 and the photoinitiator
is Irgacure 651 sold by Ciba Geigy. This photoinitiator is a substituted acetophenone.
The UV curable desiccant layer should be applied to form a cured film of 0.2 to 20
mil; preferably 1 to 2 mil. Curing time is directly proportional to film thickness.
For example, for a one mil dried thickness of "Lite-Tak" 375, 5 seconds exposure at
365 nanometers, 150,000 microwatts per square centimeter is adequate. For three mils
thickness, 10 seconds exposure is desired.
[0015] Electrical characteristics of an electroluminescent lamp made in accordance with
the foregoing working example were recorded before and after life tests and compared
with a conventional, prior art electroluminescent lamp made using a 4 mil thick modified
Nylon-6 desiccant film. The results are summarized as follows:
1. Brightness degradation measured over time in a 98% relative humidity environment
at 40°C is similar for 4 mil thick modified Nylon-6 and 3 mil thick "Lite-Tak" films.
2. Power and power factor were similar for "Lite-Tak" and modified Nylon-6.
3. Initial brightness was about 10% lower with "Lite-Tak".
[0016] As can be seen from the foregoing, the present invention offers a number of significant
advantages over the prior art. These include:
1. Dirt and contamination are less of a problem than with a preformed film, since
dirt can be filtered out prior to silkscreening; also, there is no problem with static
dust;
2. When the lamp assembly process involves lifting the desiccant to place the leads,
busbar liftoff can be eliminated, since the desiccant can be patterned leaving exposed
areas for the lead contact;
3. Lead attachment can be automated since the prior art step of partially hand-lifting
the nylon desiccant film to attach the front lead is eliminated; and
4. The lamp assembly process can be automated much easier because the desiccant layer
can be accurately aligned to the lamp, preventing intrusion into the sealed area;
also, the placement of the leads is simplified;
5. Dyes can be incorporated into the desiccant layer to create varying colors, eliminating
the extra layer, filter, or processing step which is sometimes needed for colorization;
6. The lamp assembly can become an in-line automated process.
[0017] While the above embodiments are shown to provide a preferred embodiment of the invention,
modifications thereof may be made within the spirit and scope of the invention. For
example, as shown in Figure 2, the invention also may be advantageously used in the
manufacture of thin, highly-flexible lights for use in membrane switch products where
it becomes necessary to use other flexible substrates as opposed to the traditionally
used rigid aluminum foil. Prior art membrane switch lamps made of soft foil or aluminized
polyester typically comprise holes and cut-out areas for the membrane switch. When
used with a sheet desiccant, the phosphor and barium titanate coatings have a tendency
to delaminate from the soft foil or aluminized polyester when cut. The use of a patternable
formed-in-place desiccant polymeric film in place of the traditionally used Nylon
desiccant film prevents this from occuring since the cured film coating strengthens
the layers. More particularly, as seen in Figure 2, an electroluminescent lamp is
produced following the general procedure detailed for Figure 1, however, substituting
for the 24 oz. aluminum foil sheet 10 10 oz. soft aluminum foil 10A or aluminized
polyester. Barium titanate 12 is deposited as before, and a phosphor paint layer 14
deposited over the barium titanate coating 12. An indium tin oxide electrode 16 is
screened on as before, and the resulting assembly is coated with a patternable curable
desiccant polymer coating 20 in accordance with the teachings of the present invention.
The resulting assembly is laminated between ACLAR films 22, 24 and affixed between
the switch and graphics layers of the membrane switch. (Further details of the membrane
switch panel 26 have been omitted since the switch panel per se forms no part of the
present invention.) It should be noted that typical membrane switch lamps inherently
have a low life since they use thin materials and no desiccant layer to increase the
tactility (in order to minimize actuation force). The membrane switch lamp in this
invention uses a desiccant layer which increases the life of the lamp.
1. An electroluminescent lamp assembly comprising an electroluminescent lamp (a) having,
in order, a base electrode layer (10), an electroluminescent phosphor layer (14),
a transparent or translucent electrode layer (16) and a busbar (18) in contact with
said transparent or translucent electrode layer, and (b) a moisture barrier (22,24)
encasing said electroluminescent lamp (a), the assembly comprising the presence of
at least one desiccant layer (20) in said electroluminescent lamp (a), the assembly
being characterized in that said desiccant layer (20) comprises a cured, patterned,
hygroscopic film which has been prepared by applying a liquid film of a curable film-forming
hygroscopic coating material, in a pattern, to at least one of the other layers in
said electroluminescent lamp (a) and thereafter curing the same in-situ.
2. The electroluminescent lamp assembly of claim 1, characterized in that at the least
one desiccant layer (20) is adjacent said base electrode layer (10), opposite said
electroluminescent phosphor layer.
3. The electroluminescent lamp assembly of claim 1, characterized in that the desiccant
layer (20) is transparent or translucent in its cured state.
4. The electroluminescent lamp assembly of claim 1, further characterized in that the
lamp comprises an insulating layer (12) between said base electrode layer (10) and
said electroluminescent phosphor layer (14).
5. The electroluminescent lamp assembly of claim 1, characterized in that the electroluminescent
phosphor layer (14) comprises an insulating material having the phosphor dispersed
therein.
6. The electroluminescent lamp assembly of claim 1, characterized in that said liquid,
curable, hygroscopic coating material comprises any one of the following :
(a) - a film forming polymer solution,
(b) - a film forming polymer emulsion, or
(c) - a film forming curable composition.
7. The electroluminescent lamp assembly of claim 1, characterized in that the desiccant
layer (20) comprises a photo cured polyurethane acrylate resin.
8. The electroluminescent lamp assembly of claim 1, characterized in that said desiccant
layer (20) further comprises a dye.
9. A method for manufacturing an electroluminescent lamp assembly, said method comprising
manufacturing an electroluminescent lamp (a) and thereafter encasing said electroluminescent
lamp in a moisture barrier (22, 24) wherein the electroluminescent lamp itself is
manufactured by the method comprising the steps of preparing, in order, a base electrode
layer (10), an electroluminescent phosphor layer (14), a transparent or translucent
electrode layer (16) and a busbar (18) in contact with said transparent or translucent
electrode layer, said method being characterized by the additional steps of applying
a coating of a liquid, curable, patternable film-forming hygroscopic coating material
to at least one of said other layers of said electroluminescent lamp and thereafter
curing said coating material, in-situ, so as to create a desiccant film layer in said
electroluminescent lamp.
10. The method of claim 9, further characterized by the step during the manufacture of
said electroluminescent lamp wherein said base electrode layer (10) is first formed
on a first layer of a moisture-proof film (24) which is adjoined to a second layer
of a moisture-proof film (22) applied atop the completed electroluminescent lamp opposite
said first moisture-proof film layer so as to encase said electroluminescent lamp
in the final step of its manufacture.
11. The method of claim 9, further characterized by the step wherein the coating material
is applied to the surface of the base electrode layer opposite said electroluminescent
phosphor layer.
12. The method according to claim 9, further characterized by the feature that the hygroscopic
coating material is transparent or translucent in its cured state and is applied to
the transparent or translucent electrode layer (16) opposite the electroluminescent
phosphor layer.
13. The method of claim 9, further characterized by the feature that said film-forming
hygroscopic material is cured by any one of solvent evaporation, photocuring, heat
curing, air drying, oven drying, and radiation curing as appropriate for the selected
film-forming material.
1. Eine Elektrolumineszenzlampen-Vorrichtung, umfassend eine Elektrolumineszenzlampe
(a), die sich der Reihe nach zusammensetzt aus einer Grundelektrodenschicht (10),
einer elektrolumineszierenden Phosphorschicht (14), einer transparenten oder durchlässigen
Elektrodenschicht (16) und einem Sammelschienenleiter (18), der sich in Kontakt zu
besagter transparenter oder durchlässiger Elektrodenschicht befindet, und (b) eine
Feuchtskeitssperre (22, 24), die besagte Elektrolumineszenzlampe (a) umschließt, wobei
die Vorrichtung das Vorhandensein mindestens einer Trocknungsschicht (20) in besagter
Elektrolumineszenzlampe (a) beinhaltet; hierbei ist die Vorrichtung dadurch charakterisiert,
daß die besagte Trocknungsschicht (20) einen ausgehärteten, profilierten, hygroskopischen
Film umfaßt, der durch Auftragen eines Flüssigfilms aus einem aushärtungsfähigen,
filmbildenden hygroskopischen Beschichtungsmaterial in profilierter Form auf mindestens
eine der anderen Schichten in besagter Elektrolumineszenzlampe (a) und dessen nachfolgende
Aushärtung an Ort und Stelle hergestellt wurde.
2. Die Elektrolumineszenzlampen-Vorrichtung aus Anspruch 1, dadurch charakterisiert,
daß mindestens eine Trocknungsschicht (20) an besagte Elektrodenschicht (10) gegenüber
besagter elektrolumineszierender Phosphorschicht (14) angrenzt.
3. Die Elektrolumineszenzlampen-Vorrichtung aus Anspruch 1, dadurch charakterisiert,
daß die Trocknungsschicht (20) in ihrem ausgehärteten Zustand transparent oder durchlässig
ist.
4. Die Elektrolumineszenzlampen-Vorrichtung aus Anspruch 1, des weiteren dadurch charakterisiert,
daß die Lampe eine isolierende Schicht (12) zwischen besagter Grundelektrodenschicht
(10) und besagter elektrolumineszierender Phosphorschicht (14) umfaßt.
5. Die Elektrolumineszenzlampen-Vorrichtung aus Anspruch 1, dadurch charakterisiert,
daß die elektrolumineszierende Phosphorschicht (14) ein isolierendes Material umfaßt,
worin der Phosphor dispers verteilt ist.
6. Die Elektrolumineszenzlampen-Vorrichtung aus Anspruch 1, dadurch charakterisiert,
daß besagtes flüssiges, aushärtungsfähiges, hygroskopisches Beschichtungsmaterial
eine der folgenden Komponenten enthält:
(a) - eine filmbildende Polymerlösung
(b) - eine filmbildende Polymeremulsion oder
(c) - eine filmbildende aushärtungsfähige Zusammensetzung.
7. Die Elektrolumineszenzlampen-Vorrichtung aus Anspruch 1, dadurch charakterisiert,
daß die Trocknungsschicht (20) ein lichtgehärtetes Polyurethanakrylatharz umfaßt.
8. Die Elektrolumineszenzlampen-Vorrichtung aus Anspruch 1, dadurch charakterisiert,
daß besagte Trocknungsschicht (20) des weiteren einen Farbstoff enthält.
9. Ein Verfahren zur Herstellung einer Elektrolumineszenzlampen-Vorrichtung, wobei besagtes
Verfahren die Herstellung einer Elektrolumineszenzlampe (a) und die anschließende
Einfassung besagter Elektrolumineszenzlampe in eine Feuchtigkeitssperre (22, 24) umfaßt,
indem die Elektrolumineszenzlampe selbst in dem Verfahren hergestellt wird, das der
Reihenfolge nach die Schritte der Herstellung einer Grundelektrodenschicht (10), einer
elektrolumineszierenden Phosphorschicht (14) einer transparenten oder durchlässigen
Elektrodenschicht (16) und eines Sammelschienenleiters (18), der sich in Kontakt zu
besagter transparenter oder durchlässiger Elektrodenschicht befindet, umfaßt und das
besagte Verfahren durch die zusätzlichen Schritte der Auftragung einer Beschichtung
aus einem flüssigen, aushärtungsfähigen, profilierungsfähigen filmbildenden hygroskopischen
Beschichtungsmaterial auf mindestens eine der besagten anderen Schichten besagter
Elektrolumineszenzlampe und die anschließende Aushärtung des besagten Beschichtungsmaterials
an Ort und Stelle zur Schaffung einer Trocknungsfilmschicht in besagter Elektrolumineszenzlampe
charakterisiert ist.
10. Das Verfahren aus Anspruch 9, des weiteren durch den Schritt im Laufe der Herstellung
besagter Elektrolumineszenzlampe charakterisiert, bei dem besagte Grundelektrodenschicht
(10) zuerst auf einer ersten Schicht eines feuchtigkeitsfesten Films (24) ausgebildet
wird, der an eine zweite Schicht eines feuchtigkeitsfesten Films (22) zuoberst der
vollständigen Elektrolumineszenzlampe gegenüber besagter erster feuchtigkeitsfesten
Filmschicht zur Umschließung besagter Elektrolumineszenzlampe im letzten Schritt ihrer
Herstellung angrenzt.
11. Das Verfahren aus Anspruch 9, des weiteren durch den Schritt charakterisiert, bei
dem das Beschichtungsmaterial auf die Oberfläche der Grundelektrodenschicht gegenüber
besagter elektrolumineszierender Phosphorschicht aufgetragen wird.
12. Das Verfahren aus Anspruch 9, des weiteren durch die Eigenschaft charakterisiert,
daß das hygroskopische Beschichtungsmaterial in seinem ausgehärteten Zustand transparent
oder durchlässig ist und auf die transparente oder durchlässige Elektrodenschicht
(16) gegenüber der elektrolumineszierenden Phosphorschicht aufgetragen wird.
13. Das Verfahren aus Anspruch 9, des weiteren durch die Eigenschaft charakterisiert,
daß besagtes filmbildendes hygroskopisches Material durch jeden beliebigen der für
das gewählte filmbildende Material geeigneten Prozesse der Solvent-Verdampfung, Lichthärtung,
Wärmehärtung, Lufttrocknung, Ofentrocknung und Bestrahlungshärtung gehärtet wird.
1. Ensemble de lampe électroluminescente comprenant une lampe électroluminescente (a)
ayant, dans l'ordre, une couche d'électrode de base (10), une couche de substance
phosphorescente électroluminescente (14), une couche d'électrode transparente ou translucide
(16) et une barre bus (18) en contact avec ladite couche d'électrode transparente
ou translucide, et (b) une barrière d'humidité (22, 24) enveloppant ladite lampe électroluminescente
(a), l'ensemble comprenant la présence d'au moins une couche de déshydratant (20)
dans ladite lampe électroluminescente (a), l'ensemble étant caractérisé en ce que
ladite couche de déshydratant (20) comprend une pellicule traitée, hygroscopique à
motifs qui a été préparée en appliquant une pellicule liquide d'une matière de revêtement
hygroscopique formant une pellicule, pouvant être traitée, suivant un motif, sur au
moins une des autres couches dans ladite lampe électroluminescente (a) et en traitant
celle-ci in situ.
2. Ensemble de lampe électroluminescente selon la revendication 1, caractérisé en ce
que l'au moins une couche de déshydratant (20) est adjacente à ladite couche d'électrode
de base (10), en face de ladite couche de substance phosphorescente électroluminescente.
3. Ensemble de lampe électroluminescente selon la revendication 1, caractérisé en ce
que la couche de déshydratant (20) est transparente ou translucide dans son état traité.
4. Ensemble de lampe électroluminescente selon la revendication 1, caractérisé, en outre,
en ce que la lampe comprend une couche isolante (12) entre ladite couche d'électrode
de base (10) et ladite couche de substance phosphorescente électroluminescente (14).
5. Ensemble de lampe électroluminescente selon la revendication 1, caractérisé en ce
que cette couche de substance phosphorescente électroluminescente (14) comprend une
matière isolante ayant la substance phosphorescente qui y est dispersée.
6. Ensemble de lampe électroluminescente selon la revendication 1, caractérisé en ce
que ladite matière liquide de revêtement hygroscopique, pouvant être traitée, comprend
une quelconque des suivantes :
(a) - une solution de polymère formant une pellicule,
(b) - une émulsion de polymère formant une pellicule, ou
(c) - une composition formant une pellicule pouvant être traitée.
7. Ensemble de lampe électroluminescente selon la revendication 1, caractérisé en ce
que la couche de déshydratant (20) comprend une résine d'acrylate de polyuréthane,
traitée par moyen photo.
8. Ensemble de lampe électroluminescente, selon la revendication 1, caractérisé en ce
que ladite couche de déshydratant (20) comprend en outre un colorant.
9. Procédé pour la fabrication d'un ensemble de lampe électroluminescente, ledit procédé
comprenant la fabrication d'une lampe électroluminescente (a) et par la suite, l'enrobage
de ladite lampe électroluminescente par une barrière d'humidité (22, 24), dans lequel
la lampe électroluminescente elle-même est fabriquée par un procédé comprenant les
étapes de préparation, dans l'ordre, d'une couche d'électrode de base (10), d'une
couche de substance phosphorescente électroluminescente (14), d'une couche d'électrode
transparente ou translucide (16) et d'une barre bus (18), en contact avec ladite couche
d'électrode transparente ou translucide, ledit procédé étant caractérisé par les étapes
additionnelles d'application d'un revêtement d'une matière liquide de revêtement hygroscopique,
formant une pellicule, pouvant être traitée, sur au moins une desdites autres couches
de ladite lampe électroluminescente, et par la suite, de traitement de ladite matière
de revêtement, in situ, afin de créer une couche de pellicule de déshydratant dans
ladite lampe électroluminescente.
10. Procédé selon la revendication 9, caractérisé en outre par l'étape, pendant la fabrication
de ladite lampe électroluminescente, dans laquelle la couche d'électrode de base (10)
est d'abord formée sur une première couche à l'épreuve de l'humidité (24) qui est
adjointe à une seconde couche à l'épreuve de l'humidité (22) appliquée au-dessus de
la lampe électroluminescente terminée, en face de ladite première couche à l'épreuve
de l'humidité, afin d'envelopper ladite lampe électroluminescente au cours de la dernière
étape de sa fabrication.
11. Procédé selon la revendication 9, caractérisé en outre par l'étape dans laquelle la
matière de revêtement est appliquée sur la surface de la couche d'électrode de base
en face de ladite couche de substance phosphorescente électroluminescente.
12. Procédé selon la revendication 9, caractérisé en outre par la particularité que la
matière de revêtement hygroscopique est transparente ou translucide, dans son état
traité et est appliquée sur la couche d'électrode transparente ou translucide (16),
en face de la couche de substance phosphorescente électroluminescente.
13. Procédé selon la revendication 9, caractérisé en outre par la particularité que ladite
matière hygroscopique, formant une pellicule, est traitée par l'un quelconque des
traitements par évaporation de solvant, par la lumière, par la chaleur, par le séchage
à l'air, par le séchage dans un four ou par rayonnement, comme cela est approprié
pour la matière choisie, formant une pellicule.

