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EP 0 379 764 B1 |
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EUROPEAN PATENT SPECIFICATION |
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Mention of the grant of the patent: |
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19.10.1994 Bulletin 1994/42 |
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Date of filing: 27.01.1989 |
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Method and apparatus for making cross-laminated non-woven fabrics
Verfahren und Gerät zur Herstellung von kreuzgelegten Vliesstoffen
Procédé et dispositif de fabrication de tissus non tissés stratifiés croisés
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Designated Contracting States: |
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DE FR GB IT |
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Date of publication of application: |
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01.08.1990 Bulletin 1990/31 |
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Proprietors: |
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- POLYMER PROCESSING RESEARCH INSTITUTE LIMITED
Tokyo (JP)
- NIPPON PETROCHEMICALS CO., LTD.
Tokyo 100 (JP)
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Inventors: |
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- Tani, Haruhisa
Tokorozawa-shi
Saitama-ken (JP)
- Kurihara, Kazuhiko
Itabashi-ku
Tokyo (JP)
- Yazawa, Hiroshi
Kunitachi-shi
Tokyo (JP)
- Ohishi, Toshikazu
Kawaguchi-shi
Saitama-ken (JP)
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Representative: Carmichael, David Andrew Halliday et al |
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G.F. REDFERN & CO.,
Redfern House
149/151 Tarring Road Worthing
West Sussex BN11 4HE Worthing
West Sussex BN11 4HE (GB) |
| (56) |
References cited: :
FR-A- 1 505 969 US-A- 4 609 423
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US-A- 4 052 243
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
|
[0001] The present invention relates generally to the manufacture of cross-laminated non-woven
fabrics, and more particularly to a method and apparatus for heat setting a cross-laminated
non-woven fabric composed of warp and weft webs as they are bonded on and around a
hot cylinder.
[0002] Throughout the specification and claims, the term "warp web" is used to refer to
a web formed of fibers arranged to extend substantially in the lengthwise direction
of the web and hence having a larger strength in the lengthwise direction than in
the transverse direction thereof, the term "weft web" is used to refer to a web formed
of fibers arranged to extend substantially in the transverse direction of the web
and hence having a larger strength in the transverse direction than in the lengthwise
direction, and the term "cross-laminated non-woven fabric" is used to refer to a non-woven
fabric composed of the warp and weft webs laminated together, with the fibers in the
warp web extending crosswise the fibers in the weft web.
[0003] Cross-laminated non-woven fabrics, cross-laminated films or the like cross-laminated
sheet materials have recently been developed and placed on the market. In the manufacture
of such cross-laminated sheet materials, warp and weft webs are bonded together into
layers. In this instance, it is necessary to heat-set the warp and weft webs as they
are bonded together. To meet this requirement, a hot cylinder is utilized in general.
The hot cylinder has the advantage of its small installation space and high heat efficiency.
The hot cylinder has a drawback however that the warp and weft webs while being heat-set
on the hot cylinder are caused to shrink widthwise. This widthwise shrinkage lowers
the productivity of the cross-laminated sheet material and also adversely affects
the strength, Young's modulus and other physical properties of the cross-laminated
sheet material.
[0004] The foregoing widthwise shrinkage of the webs while being heat-set can be prevented
by using a conventional tentering process in which the webs are held firmly at the
opposite sides or selvages by pins or clips. The tentering process, however, requires
an expensive apparatus which is large in size and hence occupies a large space for
installation thereof. Another problem is that a hot air heating system employed in
the tenter frame is low in thermal efficiency. Furthermore, the tentering process
is totally unsatisfactory when used in the manufacture of a cross-laminated sheet
material in which bonding of warp and weft webs is a major requirement.
[0005] US 4,609,423 discloses the use of an endless belt to urge a laminated non-woven fabric
into contact with a heating cylinder, wherein the web of non-woven material passes
between an endless band and a roller, and is retained in such a manner as to control
stretching or shrinkage of the material. The web is described as comprising two layers
of non-woven fabrics of different fibres.
[0006] French Patent 1,505,969 shows a method of making a non-woven criss-crossed fabric
of a net structure from two groups of strands. In this known method, a first group
of adhesive warp strands is laminated with a second group of criss-cross strands free
of adhesive treatment with the latter strands gripped at their opposite selvages between
an endless belt and a hot rotating cylinder. The criss-cross strands are thus prevented
from widthwise shrinkage.
[0007] Both these prior techniques require apparatus more cost intensive and complex than
that of the present invention, and do not achieve the desired result.
[0008] With the foregoing difficulties in view, the present invention seeks to provide a
method of making a cross-laminated sheet material composed of warp and weft webs bonded
together into layers and heat set on a hot cylinder without causing widthwise shrinkage
which would otherwise lower the productivity and physical properties of the cross-laminated
sheet material.
[0009] The present invention further seeks to provide an apparatus for reducing the foregoing
method into practice, which apparatus is simple in construction and can be manufactured
less costly, and is small in size and occupies only a small space for installation
thereof.
[0010] According to a first aspect of the present invention, there is provided a method
of making a cross-laminated non-woven fabric of the type having a warp web and a weft
web bonded together, said warp web being stronger in the longitudinal direction than
in the transverse direction, said weft web being stronger in the transverse direction
than in the longitudinal direction and being shrinkable widthwise upon exposure to
heat, said method comprising continuously feeding said warp and weft webs in cross-laminated
relation to each other and onto a hot rotating cylinder via a pair of parallel spaced
endless belts, characterised in that said weft web is a transversely stretched web
of transversely parallel-laid weft fibres having selvage portions along its opposite
marginal edges and gripping said warp web at its opposite side edges and said weft
web at the selvage portions by and between an outer peripheral surface of said hot
cylinder and said pair of endless belts, said endless belts being normally tensioned
against the outer peripheral surface of said hot cylinder, whereby said warp and weft
webs held in laminated relation are bonded together into a non-woven fabric structure
free from widthwise shrinkage as they are passed around said hot cylinder.
[0011] According to a second aspect of the present invention, there is provided an apparatus
for making a cross-laminated non-woven fabric of the type having a rotating hot cylinder
for bonding and heat-setting a warp web having a larger strength in the lengthwise
direction than in the transverse direction and a weft web having a larger strength
in the transverse direction than in the lengthwise direction as they are continuously
fed around the rotating hot cylinder in a superposed relating to one another, characterised
in that said apparatus comprises a pair of endless belts held under tension against
an outer peripheral surface of the rotating hot cylinder for gripping at least opposite
selvages of the warp and weft webs therebetween as the warp and weft are fed around
the hot cylinder, thereby preventing the warp and weft webs from shrinking widthwise
as they are heat-set on the hot cylinder.
[0012] Many other advantages and features of the present invention will become manifest
to those versed in the art upon making reference to the detailed description and the
accompanying sheets of drawings in which preferred structural embodiments incorporating
the principles of the present invention are shown by way of example.
Figure 1 is a diagrammatical view showing the general construction of an apparatus
according to the present invention;
Figure 2 is a schematic plan view of a rotating hot cylinder and associated endless
belts of the apparatus shown in Figure 1;
Figure 3 is an enlarged side view of a portion of the endless belt which is indicated
by a circle A in Figure 1;
Figure 4 is a view similar to Figure 2, but showing another embodiment of the present
invention.
[0013] Figure 1 diagrammatically shows the general construction of an apparatus for making
a cross-laminated non-woven fabric or the like sheet material by bonding and heat-setting
a warp web 1 and a weft web 2 as they are continuously fed on and along an outer peripheral
surface of a hot cylinder 3 rotatably driven by a motor (not shown). At least one
of the warp and weft webs 1, 2 has a certain degree adhesiveness or is treated with
an adhesive. The apparatus further includes first and second pinch or nip rolls 4,
5 held in contact with the hot cylinder 3 and having their central axes spaced from
one another at an angle of about 60 degrees relative to the central axis of the hot
cylinder 3 so as to guide the warp and weft webs 1, 2 along about five-sixths of the
full circumference of the hot cylinder 3. Disposed downstream of the second nip roll
5 is a cooling cylinder 6 for cooling a cross-laminated sheet material composed of
the warp and weft webs 1, 2 which have been bonded together and heat-set on the hot
cylinder 3. The cooling cylinder 6 is provided with a third pinch or nip roll 7 for
holding the cross-laminated sheet material in intimate contact with the cooling cylinder
6 as the cross-laminated sheet material is withdrawn from the cooling cylinder 6.
[0014] According to an important feature of the present invention, the warp and weft webs
1, 2 are gripped at least at opposite sides or selvages while they are fed around
the hot cylinder 3 in superposed relation, so that the warp and weft webs 1, 2 are
prevented from shrinking widthwise. To this end, the apparatus includes a pair of
parallel spaced endless belts 8, 8 guided around the first nip roll 4 and first, second
and third guide rolls 9a, 9b, 9c so as to be held under tension against the outer
peripheral surface of the hot cylinder 3. In the illustrated embodiment, the third
guide roll 9c is disposed upstream of the second nip roll 5 and circumferentially
spaced at an angle of about 60 degrees from the second nip roll 5 so that the endless
belts 8 travel about four-fifths of a longitudinal portion of the superposed warp
and weft webs 1, 2 which is retained on the hot cylinder 3. The endless belts 8 may
be arranged to further extend around the second nip roll 5 in which instance the endless
belts 8 coextend with the respective selvages of the warp and weft webs 1, 2 retained
on the hot cylinder 3.
[0015] The endless belts 8 are made of a heat-resistant material so as to withstand a temperature
of the hot cylinder 3. As shown in Figure 3, each of the endless belts 8 has a release
coating layer 8a on one surface thereof which is engageable with the outermost web
1. The release coating layer 8a preferably comprises a fluorine plastic film or a
silicone plastic film.
[0016] Materials eligible for the warp web 1 includes a web of stretched or oriented tapes
arranged in parallel juxtaposition in the lengthwise direction of the web, a reticular
split fiber web spread widthwise 1.1 - 5.0 times its original width, and a non-woven
fabric formed of fibers arranged to extend in the lengthwise directions. The weft
web includes a laminated web which is composed of a continuous warp web of parallel-laid
non-woven fabric, and a succession of discrete weft webs of parallel laid non woven
fabric arrange lengthwise of and bonded with the continuous warp web, with their adjacent
edges slightly overlapping one another. The laminated web may be made by a cross-laminating
machine such as disclosed in U. S. Patent No. 4,052,243 proposed by the present inventors.
In making the laminated web, a weft web is conveyed laterally over the warp web in
the machine direction and overlaid onto the warp web in the manner of side by side
arrangement without leaving any gaps between each other, after being cut by the length
corresponding to the width of the warp web. Stated otherwise, one of two identical
continuous warp webs of parallel laid non-woven fabric is fed transversely over the
other warp web in timed relation to the movement of the other warp web. The one warp
web is severed successively into individual lengths which are substantially equal
to the width of the other warp webs. The thus severed individual lengths of warp web
are united by bonding to the other warp web with their adjacent edges slightly overlapping
one another, as stated above. The weft web may be a continuous transversely stretched
web such as disclosed in U. S. Patnt No. 4,349,500, or a non-woven fabric formed of
fibers arranged to extend in the widthwise or transverse directions.
[0017] In operation, the warp and weft webs 1, 2 are longitudinally fed successively around
the first nip roll 4, the hot cylinder 3 and the second nip roll 5. During that time,
the warp and weft webs 1, 2 are firmly gripped at their opposite selvages by and between
the outer peripheral surface of the hot cylinder 3 and the respective endless belts
8, 8 with the result the warp and weft webs 1, 2 are heat-bonded together into a cross-laminated
sheet material and heat-set on the hot cylinder 3 without causing heat-shrinkage in
the widthwise direction. The cross-laminated sheet material is withdrawn from the
hot cylinder 3 and then fed around the cooling cylinder 6 during which time the cross-laminated
sheet material is cooled to set. The thus cooled cross-laminated sheet material is
finally withdrown from the apparatus through the third nip roll 7.
[0018] A modified apparatus shown in Figure 4 is substantially identical to the apparatus
shown in Figures 1 and 2 with the exception that the superposed warp and weft webs
1, 2 are gripped substantially throughout the width thereof by and between the outer
peripheral surface of the hot cylinder 3 and a single endless belt 10. The endless
belt 10 has substantially the same width as the webs 1, 2 and includes a multiplicity
of small pores or perforations 11 uniformly distributed over the entire surface thereof.
The perforated endless belt 10 is permeable to vapor and hence allows smooth vaporization
of the moisture content from the webs 1, 2 as the webs 1, 2 are heat-set on the hot
cylinder 3.
[0019] As described above, at least the selvages of warp and weft webs are gripped by and
between the outer peripheral surface of a hot cylinder and two endless belts, so that
the warp and weft webs are bonded together into a cross-laminated sheet material and
heat-set without causing widthwise heat-shrinkage. The thus produced cross-laminated
sheet material is sightly in appearance, is uniform in structure and posesses improved
physical properties such as tensile strength and Young's modulus. The apparatus of
the present invention which is composed of a hot cylinder and endless belts is simple
in construction and hence can be manufactured easily at a low cost. Furthermore, the
apparatus is small in size and hence occupies only a small space for installation
thereof.
1. A method of making a cross-laminated non-woven fabric of the type having a warp web
(1) and a weft web (2) bonded together, said warp web (1) being stronger in the longitudinal
direction than in the transverse direction, said weft web (2) being stronger in the
transverse direction than in the longitudinal direction and being shrinkable widthwise
upon exposure to heat, said method comprising continuously feeding said warp and weft
webs (1, 2) in cross-laminated relation to each other and onto a hot rotating cylinder
(3) via a pair of parallel spaced endless belts (8), characterised in that said weft
web (2) is a transversely stretched web of transversely parallel-laid weft fibres
having selvage portions along its opposite marginal edges and gripping said warp web
(1) at its opposite side edges and said weft web (2) at the selvage portions by and
between an outer peripheral surface of said hot cylinder (3) and said pair of endless
belts (8), said endless belts (8) being normally tensioned against the outer peripheral
surface of said hot cylinder (3), whereby said warp and weft webs (1, 2) held in laminated
relation are bonded together into a non-woven fabric structure free from widthwise
shrinkage as they are passed around said hot cylinder (3).
2. A method of Claim 1, wherein said warp web (1) is a split web stretched widthwise
by 1.1 to 5.0 times its original width.
3. A method of Claim 1, wherein said warp web (1) is a stretch type, a reticulate web
formed of trunk and branch filaments, a slit reticulate web formed of trunk and branch
filaments, a slit reticulate web formed of wide stretched film or a longitudinally
stretched non-woven fabric, either alone or in combination.
4. A method of Claim 1, wherein said warp web (1) or said weft web (2) or both comprise
an upper layer, a lower layer and a core interposed therebetween, said core having
a higher melting or softening point than said upper and lower layers.
5. An apparatus for making a cross-laminated non-woven fabric of the type having a rotating
hot cylinder (3) for bonding and heat-setting a warp web (1) having a larger strength
in the lengthwise direction than in the transverse direction and a weft web (2) having
a larger strength in the transverse direction than in the lengthwise direction as
they are continuously fed around the rotating hot cylinder (3) in a superposed relating
to one another, characterised in that said apparatus comprises a pair of endless belts
(8) held under tension against an outer peripheral surface of the rotating hot cylinder
(3) for gripping at least opposite selvages of the warp and weft webs (1, 2) therebetween
as the warp and weft (1, 2) are fed around the hot cylinder (3), thereby preventing
the warp and weft webs (1, 2) from shrinking widthwise as they are heat-set on the
hot cylinder (3).
6. An apparatus according to Claim 5, wherein said endless belts (8) have a multiplicity
of perforations uniformly distributed over the entire surface thereof.
7. An apparatus according to Claim 5, wherein said endless belts have a release coating
layer (8a) on one surface thereof engageable with an outermost one of the webs (1,
2).
8. An apparatus according to Claim 7, wherein said release coating layer (8a) comprises
a fluorine plastic layer.
9. An apparatus according to Claim 7, wherein said release coating layer (8a) comprises
a silicone plastic film.
1. Verfahren zur Herstellung eines kreuzweise geschichteten ungewirkten Gewebes von dem
Typus, daß Längs- (1) und Querfadengewebe (2) miteinander verbunden werden, wobei
das Längsfadengewebe (1) in Längsrichtung fester ist als in Querrichtung und das Querfadengewebe
(2) in Querrichtung fester ist als in Längsrichtung und in der Breite schrumpfen kann,
wenn es Hitze ausgesetzt wird, wobei das Verfahren das kontinuierliche Zuführen der
Längs- und Querfadengewebe (1,2) in kreuzweise geschichteter Beziehung zueinander
und auf einen heißen Rotationszylinder (3) über ein Paar parallel angeordneter Endlosbänder
(8) umfaßt,
dadurch gekennzeichnet,
daß das Querfadengewebe (2) ein in Querrichtung gestrecktes Gewebe aus in Querrichtung
parallel liegenden Querfadenfasern ist, die Kantenbereiche entlang ihrer gegenüberliegenden
marginalen Kanten haben und daß das Längsfadengewebe (1) an seinen gegenüberliegenden
Seitenkanten und das Querfadengewebe (2) an den Kantenbereichen über und zwischen
einer äußeren peripheren Oberfläche des heißen Zylinders (3) und dem Paar Endlosbänder
(8) gegriffen wird, daß die Endlosbänder (8) im allgemeinen gegen die äußere periphere
Oberfläche des heißen Zylinders (3) gespannt sind, wobei die Längs- und Querfadengewebe
(1,2) in geschichteter Beziehung zueinander und miteinander zu einer ungewirkten Gewebestruktur
verbunden werden, die frei von Breitenschrumpfungen ist, wenn die Gewebe um den Zylinder
(3) herumgeführt werden.
2. Verfahren nach Anspruch 1, worin das Längsfadengewebe (1) ein geteiltes Gewebe ist,
das in der Breite um das 1.1 bis 5.0 fache seiner ursprünglichen Breite gestreckt
ist.
3. Verfahren nach Anspruch 1, worin daß Längsfadengewebe (1) vom gestreckten Typ ist,
ein netzförmiges Gewebe ist, das aus Rumpf- und Zweigfasern besteht, ein geschlitztes
netzförmiges Gewebe ist, das aus Rumpf- und Zweigfasern besteht, ein geschlitztes
netzförmiges Gewebe ist, das aus einem breit gestreckten Film oder einer in Längsrichtung
getreckten ungewirkten Faser besteht, und zwar entweder allein oder in Kombination.
4. Verfahren nach Anspruch 1, worin das Längsfadengewebe (1) oder das Querfadengewebe
(2) oder beide eine obere Schicht, eine untere Schicht und einen dazwischen befindlichen
Kern umfassen, wobei der Kern einen höheren Schmelz- oder Erweichungspunkt als die
obere und die untere Schicht hat.
5. Vorrichtung zur Herstellung von kreuzweise geschichteten ungewirkten Geweben mit einem
heißen Rotationszylinder (3) zum Verbinden und Heiß-Fixieren eines Längsfadengewebes
(1), das eine größere Festigkeit in Längs- als in Querrichtung aufweist, und eines
Querfadengewebes (2), das eine größere Festigkeit in Quer- als in Längsrichtung aufweist,
wenn diese in überlagerter Beziehung zueinander kontinuierlich um den heißen Rotationszylinder
(3) herumgeführt werden,
dadurch gekennzeichnet,
daß die Vorrichtung ein Paar Endlosbänder (8) umfaßt, die unter Spannung an der äußeren
peripheren Oberfläche des heißen Rotationszylinders (3) gehalten werden, um mindestens
die gegenüberliegenden Kanten der dazwischen befindlichen Längs- und Querfadengewebe
(1,2) zu greifen, wenn die Längs- und Querfadengewebe (1,2) um den heißen Zylinder
(3) herumgeführt werden, wodurch bei den Längs- und Querfadengeweben (1,2) ein Schrumpfen
in der Breite verhindert wird, wenn diese auf dem heißen Zylinder (3) heiß-fixiert
werden.
6. Vorrichtung nach Anspruch 5, worin die Endlosbänder (8) eine Vielzahl von Perforationen
aufweisen die gleichmäßig über deren gesamte Oberfläche verteilt sind.
7. Vorrichtung nach Anspruch 5, worin die Endlosbänder eine Auslöse-Deckschicht (8a)
auf einer ihrer Oberflächen aufweisen, die mit dem äußersten Gewebe (1,2) in Eingriff
bringbar ist.
8. Vorrichtung nach Anspruch 7, worin die Auslöse-Deckschicht (8a) eine Fluor-Kunststoffschicht
umfaßt.
9. Vorrichtung nach Anspruch 7, worin die Auslöse-Deckschicht (8a) einen Silizium-Kunststoffilm
umfaßt.
1. Procédé de fabrication d'une étoffe non tissée stratifiée croisée du type comprenant
une nappe de chaîne (1) et une nappe de trame (2) reliées l'une à l'autre, ladite
nappe de chaîne (1) étant plus résistante dans la direction longitudinale que dans
la direction transversale, ladite nappe de trame (2) étant plus résistante dans la
direction transversale que dans la direction longitudinale et pouvant se rétracter
en largeur après exposition à la chaleur, ledit procédé comprenant l'alimentation
continue desdites nappes de chaîne et de trame (1, 2) selon une relation de stratification
croisée l'une par rapport à l'autre et sur un cylindre rotatif chaud (3) par l'intermédiaire
d'une paire de courroies sans fin (8) parallèles et espacées, caractérisé en ce que
ladite nappe de trame (2) est une nappe étirée transversalement de fibres de trame
disposées parallèlement en direction transversale, et comprenant des portions de lisière
le long de ses bords marginaux opposés et maintenant ladite nappe de chaîne (1) sur
ses bords latéraux opposés et ladite nappe de trame (2) dans les portions de lisière
par et entre une surface périphérique externe dudit cylindre chaud (3) et ladite paire
de courroies sans fin (8), lesdites courroies sans fin (8) étant normalement tendues
contre la surface périphérique externe dudit cylindre chaud (3), lesdites nappes de
chaîne et de trame (1, 2) étant ainsi maintenues selon une relation de stratification
et reliées l'une à l'autre en une structure d'étoffe non tissée sans retrait en largeur
quand elles passent autour dudit cylindre chaud (3).
2. Procédé selon la revendication 1, dans lequel ladite nappe de chaîne (1) est une nappe
subdivisée étirée en largeur de 1,1 à 5,0 fois sa largeur d'origine.
3. Procédé selon la revendication 1, dans lequel ladite nappe de chaîne (1) est du type
étiré, une nappe réticulée formée de filaments principaux et secondaires, une nappe
réticulée subdivisée formée de filaments principaux et secondaires, une nappe réticulée
subdivisée formée par une pellicule étirée ou une étoffe non tissée étirée longitudinalement,
soit seules soit en combinaison.
4. Procédé selon la revendication 1, dans lequel ladite nappe de chaîne (1) ou ladite
nappe de trame (2), ou les deux, comprennent une couche supérieure, une couche inférieure
et une couche de coeur interposée entre elles, ladite couche de coeur présentant un
point de fusion ou de ramollissement plus élevé que lesdites couches supérieure et
inférieure.
5. Dispositif pour réaliser une étoffe non tissée stratifiée croisée du type comprenant
un cylindre rotatif chaud (3) pour relier et polymériser à chaud une nappe de chaîne
(1) présentant une résistance plus élevée dans la direction longitudinale que dans
la direction transversale, une nappe de trame (2) présentant une résistance plus élevée
dans la direction transversale que dans la direction longitudinale lorsqu'elles sont
alimentées de façon continu autour du cylindre rotatif chaud (3) selon une relation
de superposition l'une par rapport à l'autre, caractérisé en ce que ledit dispositif
comprend une paire de courroies sans fin (8) maintenues sous tension contre la surface
périphérique externe du cylindre rotatif chaud (3) pour maintenir au moins les lisières
opposées des nappes de chaîne et de trame (1, 2) entre elles lorsque la chaîne et
la trame (1, 2) sont alimentées autour du cylindre chaud (3), empêchant ainsi les
nappes de chaîne et de trame (1, 2) de se rétracter en largeur lorsqu'elles sont polymérisées
à la chaleur sur le cylindre chaud (3).
6. Dispositif selon la revendication 5, dans lequel lesdites courroies sans fin (8) comprennent
une multiplicité de perforations réparties uniformément sur la totalité de leur surface.
7. Dispositif selon la revendication 5, dans lequel lesdites courroies sans fin comprennent
une couche de revêtement anti-adhésive (8a) sur l'une de leurs surfaces, pour venir
en engagement celle des nappes (1, 2) qui est la plus à l'extérieur.
8. Dispositif selon la revendication 7, dans lequel ladite couche de revêtement anti-adhésive
(8a) comprend une couche de matière plastique fluorée.
9. Dispositif selon la revendication 8, dans lequel ladite couche de revêtement anti-adhésive
(8a) comprend une pellicule de matière plastique silicone.

