(19)
(11) EP 0 384 912 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
11.09.1991 Bulletin 1991/37

(43) Date of publication A2:
29.08.1990 Bulletin 1990/35

(21) Application number: 90870028.9

(22) Date of filing: 20.02.1990
(51) International Patent Classification (IPC)5C11D 3/39, D06L 3/02, C11D 3/26, C11D 3/32
(84) Designated Contracting States:
AT BE CH DE DK ES FR GB GR IT LI LU NL SE

(30) Priority: 21.02.1989 US 312995

(71) Applicant: MONSANTO COMPANY
St. Louis Missouri 63167 (US)

(72) Inventors:
  • May, Bronislav Henri
    B-1900 Overijse (BE)
  • Zutterman, Freddy Gustaaf
    B-5140 Naninne (BE)
  • Nijs, Hubert Hendrik
    St. Louis, Missouri 63005 (US)
  • Coleman, James Patrick
    Maryland Heights, Missouri 63043 (US)
  • Monzyk, Bruce Francis
    Maryland Heights, Missouri 63043 (US)

(74) Representative: Ernst, Hubert et al
Monsanto Services International S.A. Avenue de Tervuren 270/272
1150 Bruxelles
1150 Bruxelles (BE)


(56) References cited: : 
   
       


    (54) Hydroxamate bleach stabilizer


    (57) There are disclosed compositions comprising peroxygen containing bleach systems containing a bleach stabilizing amount of compound represented by the formula

    wherein R is selected from the group consisting of optionally substituted straight and branched chained alkyl C₁-₂₁, alkenyl C₁-₂₁, hydrogen, and optionally substituted phenyl groups, and

    wherein each R˝ is independently selected from groups consisting of hydrogen, alkyl C₁-₂₁ and alkenyl C₁-₂₁, provided that the total number of carbons in both R˝ groups is not greater than 21, each X is independently selected from hydrogen and SO₃ and Z is selected from the group consisting of hydroxy, alkoxy C₁-5 and alkenoxy C₁-₅, -O⁻M⁺, -NR₂‴ wherein each R‴ is independently selected from the group consisting of hydrogen, alkyl C₁-₅ or alkenyl C₁-₅, and R′ is selected from the group consisting of hydrogen, optionally substituted straight and branched chained alkyl C₁-₂₁, alkenyl C₁-₂₁ and an optionally substituted phenyl group, provided only one of R and R′ is hydrogen said stabilizer having a hydrophile-lipophile (HLB) balance within the same range as the HLB of said compounds wherein R is an unsubstituted C₁-₂₁ alkyl group and R′ is hydrogen or an unsubstituted C₁-₆ alkyl group, M is selected from hydrogen and a non-­interfering cation, and further provided that when M⁺ represents hydrogen and the composition contains a detergent active agent, the bleaching agent is selected from an inorganic peroxy compounds and bleach activator combination or an organic peroxy acid.





    Search report