Ferrite particles and ferrite resin composite for bonded magnetic core and process for their production

Abstract

 Ferrite particles suitable for a bonded magnetic core which particles comprise crystal grains of from 5 to 15µm in average diameter and have an average particle diameter of from 20 to 150µm and a magnetic permeability of not less than 25; a ferrite resin composition thereof; and a process for producing the same.

Description

[0001] The present invention relates to ferrite particles suitable for a bonded magnetic core, a process for producing the particles and a ferrite resin composite containing the particles.

[0002] Ferrite particles and a ferrite resin composite are mainly used as a magnetic core material of an induction coil for various electronic machines such as a computer, communications apparatus and home appliances, and a magnetic core material of a transformer, etc.

[0003] A bonded magnetic core which is superior to a sintered magnetic core in dimensional stability, processability and resistance to brittleness, is advantageous in that a small or thin core is realizable and mass production of even cores having a complicated shape is easy. With the recent development of electronics, the demands for providing lighter-weight, miniaturization and higher-accuracy cores which are to be produced by making good use of these advantages has been increasing.

[0004] A bonded magnetic core is generally produced by kneading a magnetic material with a resin such as nylon and phenol, and molding the resultant mixture by compression molding or injection molding.

[0005] As the magnetic material, an oxide material such as Mn-Zn ferrite and Ni-Zn ferrite is used. Such an oxide magnetic material is generally obtained by mixing a main raw material such as Fe₂O₃, MnO, ZnO and NiO in advance by wet or dry blending so as to have a desired composition, granulating the resultant mixture into particles having a diameter of about several mm to several ten mm, calcining the obtained particles and pulverizing the calcined particles into particles having an average particle diameter of several µm to several hundred µm.

[0006] A bonded magnetic core is required to have a magnetic permeability as large as possible. This demand has been increasing with the recent demand for a bonded magnetic core having a higher capacity.

[0007] It is known that a bonded magnetic core is composed of a magnetic material combined with a resin such as nylon and phenol, as described above, and that various properties, in particular, the magnetic permeability of the bonded core has a closer relation to and is more influenced by the properties of the magnetic material used in comparison with a sintered core. Therefore, in order to obtain a bonded magnetic core having a large magnetic permeability, it is advantageous to use ferrite particles having a large magnetic permeability as a magnetic material.

[0008] With the recent tendency toward bonded magnetic cores having a higher capacity, demands for smaller, thinner and complicated-molded products has been increasing. To satisfy such demands, it is important that a ferrite resin composite can sufficiently fill in all parts of the mold. For this purpose; the ferrite resin composite is required to have an excellent fluidity.

[0009] However, in the ferrite particles produced by mixing raw materials such as Fe₂O₃, MnO, ZnO and NiO, granulating the resultant mixture into particles having a diameter of about several mm to several ten mm, calcining the obtained particles at a high temperature and pulverizing the calcined particles in accordance with the above-described conventional method, the crystal grains grow as large as several hundred µm and become non-uniform. In addition, the crystal grain contains many pores. Due to the non-uiniform crystal grains and the presence of many pores, the magnetic permeability is lowered. As a result the obtained ferrite particles show a small magnetic permeability as magnetic powder. Furthermore, since the magnetic powder itself is angular particles by pulverization, the fluidity thereof is too poor for a suitable magnetic material for a bonded magnetic core.

[0010] A magnetic material suitable for obtaining a bonded magnetic core having a large magnetic permeability was conventionally proposed.

[0011] For example, in the method described in Japanese Patent Application Laid-Open (KOKAI) No. 55-103705(1980), mixed ferrite particles consisting of particle groups having different particle sizes of from 100 µm to 5 mm in diameter, for example, a large-particle group having a diameter of 400 µm to 5 mm and a small-particle group having a diameter of 100 to 350 µm are used as a magnetic material for obtaining a molded product (bonded core) having a large initial magnetic permeability. However, since the mixed ferrite particles contain particles having a large diameter such as 5 mm, they are not suitable as a magnetic material for a bonded magnetic core.

[0012] The magnetic permeability and the fluidity of the ferrite resin composite for producing a bonded magnetic core are mainly dependent on the properties of the ferrite particles which are mixed with base materials of a resin composite. The magnetic permeability of the ferrite resin composite has a tendency to be enlarged with the increase in the magnetic permeability of the ferrite particles mixed. The fluidity of the ferrite resin composite has a tendency to become more excellent as the average particle diameter of the ferrite particles mixed becomes smaller and the surfaces of the particles become smoother. The magnetic permeability of the ferrite particles has a close relation to the average particle diameter and, hence, the magnetic permeability of the ferrite resin composite is enlarged with the increase in the average particle diameter. On the other hand, when the average particle of the ferrite particles increases, the fluidity of the ferrite resin composite is deteriorated.

[0013] As to the relationship between the magnetic permeability and the average particle diameter of the ferrite particles obtained by the conventional method, when the average particle diameter is about 100 µm, the magnetic permeability is about 18, and when the average particle diameter is about 200 µm, the magnetic permeability is about 23.

[0014] Therefore, in order to obtain a ferrite resin composite having a large magnetic permeability and an excellent fluidity, the ferrite particles mixed are required to have an appropriate average particle diameter which produces a large magnetic permeability and does not obstruct the fluidity, in particular, an average particle diameter of not more than 200 µm, and to have as smooth a surface as possible.

[0015] In the researches undertaken so as to provide ferrite particles which have a large magnetic permeability, an appropriate particle diameter and an excellent smoothness, the present inventors have noticed that in order to produce ferrite particles having a large magnetic permeability, it is necessary to obtain ferrite particle having uniform crystal grains and an appropriate grain size and containing no pore, and that in order to obtain such ferrite particles, it is important to use spherical granules for calcination which satisfy all the following conditions: (1) pores are easy to difluse in the ferrite particles, (2) the ferrite particles are easy to balance with the calcination atmosphere, and (3) the ferrite particles easily receive heat uniformly. The present inventors have also paid attention to spray drying which is capable of granulation substantially in the form of a sphere. As a result, it has been found that by dispersing and mixing a mixed powder for producing ferrite particles consisting essentially of 47 to 55 mol%, calculated as Fe₂O₃, of iron oxide or iron oxide hydroxide powder, 10 to 23 mol%, calculated as NiO, of nickel oxide powder and 25 to 40 mol%, calculated as ZnO, of zinc oxide powder into and with water containing 0.2 to 1.0 wt% of a surfactant based on the weight of the mixed powder for producing ferrite particles so as to prepare a water-dispersed slurry having a slurry concentration of 40 to 60 wt%, spray-drying the resultant slurry so as to obtain the granules having an average particle diameter of 25 to 180 µm, and calcining the obtained granules at a temperature of 1100 to 1350°C, the obtained nickel zinc ferrite spherical particles comprises crystal grains of 5 to 15 µm in average diameter, and have an average particle diameter of 20 to 150µm and a magnetic permeability of not less than 25. The present invention has been achieved on the basis of this finding.

[0016] In a first aspect of the present invention, there are provided ferrite particles for a bonded magnetic core, comprising crystal grains of 5 to 15µm in average diameter, and having an average particle diameter of 20 to 150µm and a magnetic permeability of not less than 25.

[0017] In a second aspect of the present invention, there is provided a ferrite resin composite which comprises nickel zinc ferrite spherical particles comprising crystal grains of 5 to 15µm in average diameter and having an average particle diameter of 20 to 150µm, and base materials of a resin composite and which has a magnetic permeability of not less than 25 and an excellent fluidity.

[0018] In a third aspect of the present invention, there is provided a process for producing ferrite particles for a bonded magnetic core, comprising crystal grains of 5 to 15µm in average diameter, and having an average particle diameter of 20 to 150µm and a magnetic permeability of not less than 25, the process comprising the steps of dispersing and mixing a powder for producing ferrite particles consisting essentially of 47 to 55 mol%, calculated as Fe₂O₃, of an iron oxide or iron oxide hydroxide powder, 10 to 23 mol%, calculated as NiO, of a nickel oxide powder and 25 to 40 mol%, calculated as ZnO, of an zinc oxide powder as a starting material into and with water containing 0.2 to 1.0 wt% of a surfactant based on the weight of the powder for producing ferrite particles so as to prepare a water-dispersed slurry having a slurry concentration of 40 to 60 wt%, spray-drying the resultant slurry so as to obtain granules having an average particle diameter of 25 to 180µm, and calcining the obtained granules at a temperature of 1100 to 1350°C.

[0019] In the accompanying drawings:

Figs. 1 to 6 are scanning-type electron micrographs (x 6500), in which

Figs. 1, 2 and 3 show the structures of the ferrite particles for a bonded magnetic core obtained in Examples 1, 2 and 4, respectively; and

Figs. 4, 5 and 6 show the structures of the ferrite particles obtained in Comparative Examples 3,4, and 7, respectively.

[0020] The nickel zinc ferrite spherical particles as ferrite particles, comprising crystal grains of 5 to 15µm in average diameter and having an average particle diameter of 20 to 150µm of the present invention are produced by using an iron oxide or iron oxide hydroxide powder, a nickel oxide powder and a zinc oxide powder as starting materials. More specifically, the nickel zinc ferrite spherical particles are produced by dispersing and mixing a mixed powder for producing ferrite particles of 47 to 55 mol%, preferably 48 to 53 mol%, calculated as Fe₂O₃, of iron oxide or iron oxide hydroxide, 10 to 23 mol%, preferably 13 to 20 mol%, calculated as NiO, of nickel oxide and 25 to 40 mol%, preferably 27 to 39, calculated as ZnO, of zinc oxide into and with water containing 0.2 to 1.0 wt% of a surfactant based on the weight of the mixed powder for producing ferrite particles so as to prepare a water-dispersed slurry having a slurry concentration of 40 to 60 wt%, spray-drying the resultant slurry so as to obtain the granules having an average particle diameter of 25 to 180µm, and calcining the obtained granules at a temperature of 1100 to 1350°C.

[0021] The reason why the nickel zinc ferrite spherical particles having a magnetic permeability of not less than 25 are obtained according to the present invention is considered to be that the nickel zinc ferrite spherical particles obtained by the process according to the present invention comprises uniform crystal grains of an appropriate size containing few pores.

[0022] Since the ferrite particles for a bonded magnetic core according to the present invention are spherical particles having appropriate sizes unlike the irregular, the particles of the present invention have an excellent fluidity which facilitates the production of a molded product having a complicated shape when the ferrite particles are kneaded with a resin and molded, especially, by injection molding.

[0023] The ferrite particles for a bonded magnetic core according to the present invention comprises ferrite particles having a composition represented by 47 to 55 mol%, preferably 48 to 53 mol% of Fe₂O₃, 10 to 23 mol%, preferably 13 to 20 mol% of NiO and 25 to 40 mol%, preferably 27 to 39 of ZnO. The particles having a composition other than this ranges are unfavorable for practical use because the magnetic permeability is apt to be lowered.

[0024] The ferrite particles for a bonded magnetic core according to the present invention comprise nickel zinc ferrite spherical particles having an average diameter of 20 to 150µm, preferably 30 to 140 µm and comprising crystal grains of 5 to 15µm, preferably 5 to 13 µm in average diameter. If the average particle diameter of the ferrite particles is less than 20µm, the growth of the particles is unfavorably insufficient. The average particle diameter of more than 150µm is also unfavorable because the crystal grains abnormally grow and many pores tend to remain therein, thereby lowering the magnetic permeability.

[0025] In order to obtain the ferrite particles for a bonded magnetic core according to the present invention, it is necessary to control the average particle diameter of the granules before calcination in the range of 20 to 180µm.

[0026] For this purpose, it is necessary to disperse and mix the mixed powder for producing ferrite particles into and with water containing 0.2 to 1.0 wt%, preferably 0.2 to 0.8 wt% of a surfactant based on the weight of the mixed powder for producing ferrite particles, thereby obtaining a water-dispersed slurry having a slurry concentration of 40 to 60 wt%, preferably 40 to 55 wt%, and thereafter to spray-dry the resultant slurry. If the slurry concentration is less than 40 wt%, the spray-drying efficiency is lowered, which often leads to the reduction in the productivity. If the slurry concentration is more than 60 wt%, it is difficult to supply and spray-dry the slurry and, hence, it is difficult to produce the ferrite particles for a bonded core of the present invention.

[0027] As the iron oxide, which is one of the starting materials of the present invention, α-Fe₂O₃, γ-Fe₂O₃ and Fe₃O₄ are usable. As the ion oxide hydroxide, α-­FeOOH, β-FeOOH and γ-FeOOH are usable.

[0028] As the surfactant, surfactants generally used as a dispersant for a water-dispersed slurry, for example, alkali salts, amine salts and ammonium salts of anionic surfactants, lower fatty acid salts and hydrochlorides of cationic surfactants are usable. The amount of surfactant used is preferably 0.2 to 1.0 wt% based on the weight of the mixed powder for producing ferrite particles in consideration of sphericity of the ferrite particles obtained.

[0029] The calcining temperature is in the range of 1100 to 1350°C. If the temperature is lower than 1100°C, it is difficult to obtain large crystal grains. If it exceeds 1350°C, the abnormal growth of the crystal grains is accelerated, so that the crystal grains become unfavorably non-uniform and contain many pores.

[0030] The ferrite resin composite according to the present invention is a mixture of the above-described nickel zinc ferrite spherical particles comprising crystal grains of 5 to 15µm in average diameter and having an average particle diameter of 20 to 150µm and a resin, and has a magnetic permeability of not less than 25 and an excellent fluidity.

[0031] The nickel zinc ferrite spherical particles of the present invention may be coated in advance with a coupling agent which is generally used as a surface treating agent, for example, a silane coupling agent, titanium coupling agent, aluminum coupling agent and zircoaluminate coupling agent, or a cationic, anionic or nonionic surfactant in order to enhance various properties such as the dispersibility.

[0032] The mixing ratio (wt%) of the nickel zinc ferrite spherical particles to the base materials of a resin composite according to the present invention is 90 to 95/5 to 10, preferably 92 to 9416 to 8 in consideration of the magnetic permeability and the fluidity of the ferrite resin composite.

[0033] The base materials of a resin composite in the present invention is a resin with a plasticizer, lubricant, antioxidant, etc., added thereto, if necessary.

[0034] As the resin, those generally used for a resin component are usable. Concrete examples thereof are a thermoplastic resin such as a polystyrene resin, polyethylene resin, AS resin (acrylonitrile-styrene copolymer), ABS resin (acrylonitrile-butadiene-styrene copolymer), vinyl chloride resin, EVA resin (ethylene-vinylacetate copolymer), PMMA resin (polymethylmethacrylate), polyamide resin, polypropylene resin, EEA resin (ethylene-ethylacrylate copolymer) and PPS resin (polyphenylene sulfide), and a thermosetting resin such as a phenol resin, urea resin, melamine resin, alkyd resin, epoxy resin and polyurethane resin.

[0035] Although the ferrite resin composite of the present invention is usable both for compression molding and for injection molding, since the fluidity thereof is excellent, it is preferably used for injection molding.

[0036] The nickel zinc ferrite spherical particles of the present invention, which have an average particle diameter of 20 to 150µm and a magnetic permeability of not less than 25, are suitable as ferrite particles for a bonded magnetic core.

[0037] A ferrite resin composite of the present invention has a large magnetic permeability such as not less than 25 due to the large magnetic permeability of the ferrite particles which are mixed with the base materials of a resin composite, and an excellent fluidity due to the ferrite particles having appropriate size and smooth spherical surfaces. The ferrite resin composite of the present invention is thereof suitable as a ferrite resin composite which is now demanded.

[0038] In addition, the application of the ferrite resin composite of the present invention, which has a large magnetic permeability, to an electromagnetic wave absorber and an electromagnetic wave insulator is expected.

[Examples]

[0039] The present invention will be more precisely explained while referring to Examples as follows.

[0040] However, the present invention is not restricted to Examples under mentioned. From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of the present invention, and without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.

[0041] In the following examples and comparative examples, a cylindrical molded product having an outer diameter of 36 mm, an inner diameter of 24 mm and a height of 10 mm was produced by the press-molding of the granules of a mixture of ferrite particles and polyvinyl alcohol (MABOZORUT-30 produced by Matsumoto Yushi Seiyaku Co., Ltd.) under a pressure of 1 ton/cm² as a sample being measured. The magnetic permeability of the ferrite particles are expressed by the values obtained by measuring the magnetic permeability of the thus-­obtained molded product which has been wound with a winding at 40 turns, by an impedance analyzer 4194A (produced by Yokokawa Hewlet Packard, Ltd.) at a frequency of 1 MHz.

[0042] The magnetic permeability of the ferrite resin composite of the present invention was measured by the same method described above except for using a molded product having an outer diameter of 36mm, an inner diameter of 24mm and a height of 10mm, and produced by the press-molding of the granules of the ferrite resin composite.

Example 1

[0043] 

[0044] 33.85 kg of iron oxide (α-Fe₂O₃), 6.10 kg of nickel oxide and 10.95 kg of zinc oxide were mixed to produce a mixed powder for producing ferrite particles which contained 50.1 mol% of Fe₂O₃, 18.7 mol% of NiO and 31.2 mol% of ZnO. The mixed powder was then charged into 60.5ℓ of an aqueous solution of 0.3 wt% of polycarboxylic acid ammonium salt (SN dispersant 5468: produced by Sannopco Co., Ltd.) based on the weight of the mixed powder for producing ferrite particles. The slurry concentration in the aqueous solution was 45.7 wt%. The slurry was spray-dried to obtain granules having an average particle diameter of 105µm.

[0045] The granules obtained were calcined at a temperature of 1320°C for 3 hours to obtain ferrite particles for a bonded magnetic core which was composed of nickel zinc ferrite spherical particles.

[0046] The magnetic permeability of the ferrite particles for a bonded magnetic core obtained was 32.7. It was confirmed from the observation of the scanning-type electron micrograph shown in Fig. 1 that the ferrite particles were nickel zinc ferrite spherical particles which were composed of crystal grains 12.2µm in average diameter and which had an average particle diameter of 80µm and few pores.

Examples 2 to 6, Comparative Examples 1 to 7

[0047] Ferrite particles for a bonded magnetic core were produced in the same way as in Example 1 except for varying the composition of the mixed powder for producing ferrite particles, the kind and the amount of surfactant, the concentration of the mixed slurry for producing ferrite particles, the particle size of the granules and the calcining temperatures.

[0048] The main producing conditions and the properties of the ferrite particles for a bonded magnetic core are shown in Table 1.

[0049] In Example 3, Fe₃O₄ was used as the iron oxide material and in Example 5, polycarboxylic acid sodium salt (Nobcosant K: produced by Sannopco Co., Ltd.) was used as the surfactant.

[0050] In Comparative Example 7, the mixed powder for producing ferrite particles was granulated into granules about 6 mm in diameter by the conventional method without spray-drying, the granules were calcined at a temperature of 1250°C, and the calcined granules were then pulverized to obtain ferrite particles for a bonded magnetic core having a particle diameter of 39µm and containing many pores.

Example 7

[0051] 190 g (equivalent to 94.9 wt% based on the composite) of the ferrite particles obtained in Exmaple 1, 10 g (equivalent to 5.0 wt% based on the composite) of ethylene-vinyl acetate copolymer resin (Evaflex 250, density 0.95 g/cc, produced by Mitsui Polychemical Co., Ltd.) and 0.2 g (equivalent to 0.1 wt% based on the composite) of zinc stearate were kneaded at 110°C for 15 minutes by a blast mill 30C-150 (produced by Toyo Seiki Co., Ltd.) to obtain a kneaded mixture.

[0052] The thus-obtained kneaded mixture was granulated into granules having an average particle diameter of about 3 mm, and press-molded at a temperature of 75°C and a pressure of 1.5 ton/cm² to obtain a cylindrical molded product having an outer diameter of 36 mm, an inner diameter of 24 mm and a height of 10 mm. Since the ferrite resin composite filled in all parts of the mold including every corner, the surface of the molded product was smooth and the circumferential portions of the upper surface and the lower surface of the cylinder are formed into complete circles without any chipping and deformation.

[0053] The magnetic permeability of the molded product was 31.0

Examples 8 to 11 and Comparative Examples 8 to 11

[0054] 

[0055] Ferrite resin composites were produced in the same way as in Example 7 except for varying the kind and the amount of ferrite particles, the kind and amount of additive and the kneading temperature and time.

[0056] The main producing conditions and the properties of the composites obtained are shown in Table 2.

[0057] Since the ferrite resin composite filled in all parts of the mold including every corner, the molded product produced from the ferrite resin composite obtained in any of Examples 8 to 11 had a smooth surface and complete circular circumferential portions of the upper surface and the lower surface of the cylinder without any chipping and deformation like the molded product obtained in Example 7.

[0058] In contrast, in the molded products produced from the ferrite resin composites obtained in Comparative Examples 8 and 10, the surfaces were uneven and chipping or deformation was observed at a part of the circumferential portions of the upper surface and the lower surface of the cylinder.

Table 1

Examples & Comparative Examples	Mixing ratio of raw materials			Amount of Surfactant (wt%)	Slurry concentration (wt%)	Average particle diameter of granules (µm)	Calcining temperature (°C)	Ferrite particles for bonded magnetic core
	FezO₃ (mol %)	NiO (mol %)	ZnO (mol %)					Magnetic permeability	Average particle diameter of crystal grains (µm)	Average particle diameter (µm)
Example 1	50.1	18.7	31.2	0.3	45.7	105	1320	32.7	12.2	80
Example 2	50.1	18.7	31.2	0.3	45.7	120	1280	30.2	9.5	100
Example 3	50.1	18.7	31.2	0.3	45.7	99	1150	28.0	8.2	79
Example 4	50.1	18.7	31.2	0.7	52.0	170	1100	25.3	5.1	139
Example 5	52.0	17.5	30.5	0.3	50.2	115	1300	31.5	8.3	85
Example 6	48.3	14.5	37.2	0.3	41.3	46	1320	26.2	9.2	34
Comparative Example 1	50.1	18.7	31.2	0.75	58.3	250	1250	20.2	10.0	200
Comparative Example 2	50.1	18.7	31.2	0.3	30.6	18	1150	18.3	2.2	15
Comparative Example 3	49.8	18.6	31.6	0.5	43.2	53	1000	12.0	1.5	45
Comparative Example 4	49.8	18.6	31.6	0.5	43.2	89	1380	18.6	20.0	67
Comparative Example 5	43.2	23.0	33.8	0.5	43.2	97	1250	7.0	8.5	75
Comparative Example 6	60.2	27.5	12.3	0.5	43.2	102	1180	5.0	5.3	80
Comparative Example 7	49.5	18.4	32.1	―	―	―	1250	17.5	27.1	39

Table 2

Examples & Comparative Examples	Manufacture of ferrite resin composite								Ferrite resin composite
	Ferrite particles		Resin		Additive		Kneading		Magnetic permeability
	Kind	Amount (wt%)	Kind	Amount (wt%)	Kind	Amount (wt%)	Temperature (°C)	Time (min.)
Example 7	Example 1	95.0	Evaflex 250 (produced by Mitsui Polychemical Co.,Ltd.)	4.9	Zn stearate	0.1	110	15	31.0
Example 8	Example 1	93.0	ditto	7.9	Zn stearate	0.1	100	15	28.4
Example 9	Example 2	95.0	ditto	4.9	Zn stearate	0.1	110	15	28.7
Example 10	Example 1	92.0	12-Nylon 3014U (produced by Ube Industries,Ltd.)	7.9	Ca stearate	0.1	250	15	28.5
Example 11	Example 5	91.0	ditto	8.9	Ca stearate	0.1	250	15	27.2
Comparative Examples 8	Comparative Examples 1	95.0	Evaflex 250 (produced by Mitsui Polychemical Co.,Ltd.)	4.9	Zn stearate	0.1	110	15	18.6
Comparative Examples 9	Comparative Examples 2	95.0	ditto	4.9	Zn stearate	0.1	120	15	16.8
Comparative Examples 10	Comparative Examples 3	92.0	12-Nylon 3014U (produced by Ube Industries,Ltd.)	7.9	Ca stearate	0.1	250	15	10.6
Comparative Examples 11	Comparative Examples 7	95.0	Evaflex 250 (produced by Mitsui Polychemical Co.,Ltd.)	4.9	Zn stearate	0.1	120	15	16.5

Claims

1. Ferrite particles suitable for a bonded magnetic core, which particles comprise crystal grains of from 5 to 15µm in average diameter and have an average particle diameter of from 20 to 150µm and a magnetic permeability of not less than 25.

2. Ferrite particles according to claim 1, which comprise from 48 to 53 mol% of Fe₂O₃, from 13 to 20 mol% of NiO and from 27 to 39 mol% of ZnO.

3. A ferrite resin composite comprising ferrite particles according to claim 1 or 2 and a base resin, said ferrite resin composite having a magnetic permeability of not less than 25.

4. A composite according to claim 3, which comprises from 92 to 94 wt% of the particles and from 8 to 6 wt% of the base resin.

5. A composite according to claim 3 or 4 which comprises spherical nickel zinc ferrite particles.

6. A composite according to any one of claims 3 to 5 in the form of a magnetic core.

7. A process for producing ferrite particles as defined in claim 1 or 2 which comprises:

(i) mixing a) from 47 to 55 mol%, calculated as Fe₂O₃, of an iron oxide or iron oxide hydroxide powder, b) from 10 to 23 mol%, calculated as NiO, of a nickel oxide powder and c) from 25 to 40 mol%, calculated as ZnO, of a zinc oxide powder and d) water containing from 0.2 to 1.0 wt% of a surfactant based on the total weight of the powders a), b) and c) so as to prepare a slurry having a slurry concentration of from 40 to 60 wt%,

(ii) spray-drying the resultant slurry so as to obtain granules having an average particle diameter of from 25 to 180µm, and

(iii) calcining the obtained granules at a temperature of from 1100 to 1350°C.

8. A process according to claim 7 in which stage (i) comprises mixing:

a) from 48 to 53 mol% of Fe₂O₃

b) from 13 to 20 mol% of NiO

c) from 27 to 39 mol% of ZnO

d) water containing from 0.2 to 0.8 wt% of a surfactant.

9. A process according to claim 7 or 8 in which the surfactant in stage (i) is an alkali metal salt, an amine salt, an ammonium salt of an anionic surfactant, a fatty acid salt or a hydrochloride of a cationic surfactant.

10. A process according to any one of claims 7 to 9 which comprises the additional step of kneading the ferrite particles with the base resin and press molding the mixture to produce a moulded product.

Drawing