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(11) |
EP 0 399 478 B1 |
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EUROPEAN PATENT SPECIFICATION |
| (45) |
Mention of the grant of the patent: |
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13.04.1994 Bulletin 1994/15 |
| (22) |
Date of filing: 22.05.1990 |
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| (54) |
Method and apparatus for improving a multi-color electrophotographic image by buffing
Verfahren und Gerät zum Verbessern eines elektrophotographischen mehrfarbigen Bildes
durch Polieren
Procédé et appareil permettant de modifier une image électrophotographique en couleur
à l'aide d'un brossage
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| (84) |
Designated Contracting States: |
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GB |
| (30) |
Priority: |
26.05.1989 US 358101 26.05.1989 US 358916 26.05.1989 US 358918
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Date of publication of application: |
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28.11.1990 Bulletin 1990/48 |
| (73) |
Proprietor: EASTMAN KODAK COMPANY |
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Rochester,
New York 14650-2201 (US) |
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| (72) |
Inventors: |
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- Steele, Lawrence Charles,
c/o Eastman Kodak Co.
Rochester,
New York 14650 (US)
- Rook, Kenneth Edward,
c/o Eastman Kodak Co.
Rochester,
New York 14650 (US)
- Santilli, Domenic,
c/o Eastman Kodak Co.
Rochester,
New York 14650 (US)
- Kamp, Dennis Reed,
c/o Eastman Kodak Co.
Rochester,
New York 14650 (US)
|
| (74) |
Representative: Blickle, K. Werner, Dipl.-Ing. et al |
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KODAK AKTIENGESELLSCHAFT
Patentabteilung 70323 Stuttgart 70323 Stuttgart (DE) |
| (56) |
References cited: :
US-A- 3 467 468 US-A- 4 660 503
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US-A- 4 659 640
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
|
BACKGROUND OF THE INVENTION
Field of the Invention
[0001] This invention relates to electrophoretic liquid development and more particularly
to an improved process of plural stage development.
Description Relative to the Prior Art
[0002] In the liquid development of electrostatic charge latent images, as in electrophotography
and in other processes that form and develop electrostatic charge patterns, a substrate
having a charge pattern on its surface is contacted with a liquid developer which
is essentially a suspension of colloidal toner particles in an insulating liquid.
Liquid developers normally contain also a stabilizer or charge control agent. The
latter is an ionic compound which controls the magnitude of the charge on the toner
particles and aids in maintaining a stable charge on the toner particles within the
insulating carrier liquid.
[0003] Liquid developers can be used in single stage or plural stage development processes.
Examples of the latter may include the sequential development on a photoconductor
of two or more color-separation images, the annotation of a previously developed image,
or the repeated re-exposure and development of images on a reusable photoconductor,
with transfer of images upon completion of a number of imaging cycles.
[0004] In certain plural stage development processes which use liquid developers a problem
has been found which is especially significant in processes for the electrophotographic
reproduction of multi-color images of graphic arts quality. In these processes electrostatic
latent images are formed sequentially on a chargeable substrate such as an electrophotographic
medium, with liquid development or toning of each latent image before the next is
formed. A leading example of this kind of system involves processing an electrophotographic
medium sequentially through a series of four imaging cycles including four sequential
development or toning stages.
[0005] While the present invention is useful in any electrostatic imaging process wherein
a charge pattern is formed and developed with a liquid developer on a surface which
has previously been developed with a liquid developer, it is particularly useful in
combination with a recently developed electrophotographic process of making lithographic
color proofs, such as described in U. S. Patent No. 4,600,669. In that process a photoconductor,
which has a uniformly charged thin transparent dielectric overlayer, is subjected
to a series of exposures through registered color separation transparencies. After
each exposure the dielectric layer is developed with a liquid developer, and the surface
is again uniformly charged and exposed. The sequence is repeated for each of the color
transparencies, usually four. It has been found that image defects occur in areas
of the image which are toned areas of a previous imaging cycle. The defect appears
as a color contamination of the previously toned areas which imparts a non-uniform
density thereby altering color rendition, a defect which, though perhaps acceptable
in some kinds of add-on, plural stage imaging, is not acceptable for producing high
quality images as required, for example, in the graphic arts field.
[0006] It has been discovered that the described image defects in plural-stage liquid development
appear to be caused by the presence of forces, substances, or charge acceptance in
the previously toned areas that interfere with the correct subsequent development
in those areas. Although the nature of those forces or substances is not clear, the
present invention provides a method of reducing or eliminating the problem.
[0007] U. S. Patent No. 4,660,503 describes the improvement in the process of the '669 patent
of cleaning the image by brushing the surface of the toned image with a soft, smooth,
and supple fibrous brush member between the development of an image and the exposure
of the next image to remove counterion material from the untoned areas which interferes
with subsequent toning cycles in the above-mentioned process. The improvement of the
'503 patent affects only the untoned areas of the developed substrate or photoconductor
and has been found to have no effect on the toned areas where the present problem
has been discovered.
[0008] Thus the problem addressed by the present invention is that of preventing color contamination
of previously toned areas rather than preventing contamination of the untoned areas.
The solution must not adversely affect the desired electrophoretic deposition of toner
particles in both previously toned and untoned areas to develop the latent electrostatic
image areas of subsequent imaging cycles.
[0009] Further, it has been found that in some instances involving the treatment of the
cyan image in particular, the buffing step either removes (flakes off) a portion of
the cyan image or smears it, neither of which are acceptable for producing high quality
images as required, for example, in the graphic arts field.
[0010] Accordingly, the provision of a simple and relatively easily implemented solution
to these problems, particularly if it can be done at a nominal cost and does not have
any significant negative effects on the resulting image, would be very advantageous.
SUMMARY OF THE INVENTION
[0011] The present invention thus provides a method and apparatus as defined in claim 1
and claim 9 respectively for producing a multi-color electrophotographic image that
enhances the image quality by preventing the small toner particles of liquid developers
from adhering to previously toned areas unless electrostatic latent image fields are
present to support such deposition.
[0012] Various means for practicing the invention and other features and advantages thereof
will be apparent from the following detailed description of an illustrative preferred
embodiment of the invention, reference being made to the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0013]
FIG. 1 is a schematic illustration of apparatus for carrying out the method of producing
a multi-color electrophotographic image in accordance with the present invention.
FIG. 2 is a cross-sectional view through the brushing mechanism taken along line 2
- 3 of FIG. 3; and
FIG. 3 is a perspective view, partially in section, of the brushing apparatus.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
[0014] Although the present invention is applicable to various electrophotographic elements,
methods and apparatus, the embodiment to be described is directed to a multi-color
electrophotographic image producing apparatus employing an electrophotographic medium
of the type disclosed in the above-identified '669 patent.
[0015] A schematic illustration of a multi-color electrophotographic image processor is
illustrated in FIG. 1 and consists of a carrier or platen 12 which is movable along
the processing path, represented by dotted line 14, past the respective processing
stations of the apparatus, to be described hereinafter. The path 14 may be determined
by guide rails or other structure of the apparatus in a manner well-known in the art
whereby the platen may move from a starting position, illustrated, to the right-most
position and then returned to the left to the starting position. The platen 12 is
preferably transparent and is provided with means, not shown, for retaining an electrophotographic
medium 16 on the lower surface thereof with an image-bearing transparency 18 disposed
therebetween which is used to generate the image in the electrophotographic medium
16, in a manner more thoroughly described hereinbelow.
[0016] As noted in the above-cited '669 patent, the electrophotographic medium comprises
a photoconductive layer on an electrically conducting substrate which is capable of
transmitting actinic radiation to which the photoconductive layer is responsive. A
dielectric support is releasably adhered to the substrate and comprises the photoconductive
layer or an overcoat thereof which forms an outer surface of the element capable of
holding an electrostatic charge. To use the element the surface of the dielectric
support is charged and the photoconductive layer is image-wise exposed to the actinic
radiation, thereby forming a developable electrostatic image on the dielectric surface.
The electrostatic image in turn is developed with a toner to form a first color image.
A composite color image can be formed on the element by repeating the sequence one
or more times with image-wise exposure of the photoconductive layer to actinic radiation
transmitted through the transparent support, and developing over each preceding image
with a different color toner. The composite toned image is then transferred with the
dielectric support to a receiving element to form a color copy which may be a color
proof closely simulating the color print expected from a color print press.
[0017] Accordingly, the electrophotographic medium 16 is mounted onto the platen 12 with
the transparency original 18, which may be a color separation representing a color
to be printed, sandwiched therebetween. The electrophotographic medium 16 and the
transparency original 18 may be held to the platen 12 by any suitable means known
in the art such as a vacuum clamp whereby they are maintained in close proximity to
assure satisfactory exposure, processing and register. Further, the electrophotographic
medium must also be suitably grounded to the apparatus to enable the charging process
to be satisfactorily carried out. A number of grounding means are known in the art
and will not be described herein. As the platen 12, with the original and the electrophotographic
medium 16, is translated to the right (in FIG. 1), the dielectric support of the electrophotographic
medium is given an overall charge via a charging means 20, such as a corona charger,
to form a uniform potential on the surface of the dielectric support. Upon being so
charged the electrophotographic medium is image-wise exposed by passing beneath an
exposure lamp apparatus 22 which projects light through the transparent platen 12,
the transparency original 18, and through the transparent conductive substrate of
the electrophotographic medium. When the photoconductive layer is thus image-wise
exposed, mobile charge carriers, in this case positively charged holes, are formed
in the photoconductive layer and migrate towards the interface of the photoconductive
layer and the conducting layer as described in the '669 patent. Accordingly, the electric
field strength in exposed regions is diminished while the field strength in unexposed
regions remains approximately the same. As a result, an electrostatic differential
pattern is formed on the dielectric support corresponding to the pattern on the transparency
original.
[0018] The platen continues its movement, to the right in FIG. 1, passing over a pre-rinse
head 24 which is fixed in position whereby the fluid head provided thereat when activated
contacts the lower surface of the electrophotographic medium as it passes in the processing
direction, i.e., to the right, but does not contact the medium when the fluid head
is inactivated as when the platen is moved to the left in FIG. 1, to the original
position. The pre-rinse head prewets the medium with a dispersant dielectric liquid
prior to the liquid toning step. Thereafter, the platen moves past a raised first
liquid toning station 26 which is raised into operating position whereby the lower
surface of the electrophotographic medium is contacted and a toner image is imparted
thereto, in a manner well-known in the art. In this system, the liquid toner is deposited
in the unexposed, still charged area of the electrophotographic medium thereby forming
a positive image which is a duplicate of the image carried by the transparency 18.
It is also well-known in the art to produce negative images with similar electrophotographic
processes wherein the charges imparted to the electrophotgraphic medium and the toners
are appropriately adjusted to give a negative image. The platen continues movement
to the right in the illustration, past appropriate rinse heads and dryers, not shown.
The last station 28 at the right end of the apparatus is an erase lamp that exposes
the electrophotographic medium after the toning operation to expose those parts of
the photoconductive layer that were not exposed by the original image exposure so
that the entire electrophtographic medium has substantially the same exposure history.
[0019] The platen 12 is then reversed and is returned to the starting position illustrated
in FIG. 1. At this point the first original transparency or color separation 18 is
removed and replaced by a second transparency or color separation and registered with
the electrophotographic medium 16 preparatory for the next pass through the apparatus
to generate the second color image. When the electrophotographic medium 16 and the
next original sheet 18 are re-registered on the platen 12, the platen is moved to
the right again for charging, exposure, and subsequent toning. However, the platen
first passes over a cleaning station 30 which includes a rotating brush member 40.
This cleaning station and its operation are described in the above-referenced '503
patent. When the cleaning station is raised into operative position with respect to
the electrophotographic medium surface, the brush bristles engage the toned image
and lightly clean it. The platen then moves to a buffing station 31 which forms the
improvement of the present invention. The construction and operation of the buffing
station are more thoroughly described hereinbelow.
[0020] The platen then moves to the charging station 20 where the electrophotographic medium
is again charged and then moves to the exposure position 22 where light again is projected
through the platen and the second color separation 18 to selectively charge the photoconductive
layer in accordance with the transparancy or color separation then in contact with
the electrophotographic medium. Thereafter, the platen moves the electrophotographic
medium to the pre-rinse station 24 and then to a second toning station 32 which is
then in operative position to tone the surface of the electrophotographic medium with
a second color toner to produce a second color visible image overlying the first image.
The platen subsequently moves past the aforementioned rinse and drying stations and
again past the erase exposure station 28 before being returned to the starting position
at the left-hand end of the apparatus. Should it be desired to create a four color
image (or a three color plus black image), the charging, exposing, and toning steps
will be repeated for two more color separation originals with the platen and electrophotographic
medium being moved into operative contact with an additional two toning stations 34
and 36, one for each of the additional colors. Prior to each of these additonal exposing
and toning steps the cleaning and buffing stations 30 and 31 are raised into brushing
contact with the surface of the electrophotographic medium as the platen begins its
travel to the right to again clean and buff the toned medium to both remove toning
materials from the untoned portions thereof without significantly altering the toned
image and then to smooth the toned image, as will be further described hereinbelow.
It will be appreciated that, as known in the art, the toning order may not necessarily
be represented by the physical order of the toning stations in the apparatus, and
the order given above is by way of example only.
[0021] After the final toning, rinsing, and drying steps, the platen 12 is returned to the
first position where the electrophotographic medium is removed. On the final return
of the platen the cleaning brush 40 is again raised into the operative position to
clean the final image. In keeping with the desire to rotate the cleaning brush in
a direction counter to the direction of travel of the electrophotographic medium,
the brush is rotated in a clockwise direction (as viewed in FIG. 1) for this operation.
While there are no additional toning operations to be conducted on the medium at this
point, it has been found that the final brushing step aids in the lamination of the
image-bearing release layer of the film to the paper stock, minimizing artifacts that
have been found to occur without this final brushing operation.
[0022] While the other components of the electrophotographic apparatus described herein
are known in the art, the buffing station assembly 31 is described in further detail
with respect to FIGS. 2 and 3. As illustrated, the buffing station assembly takes
up little additional space along the travel length of the apparatus, being only wide
enough to mount the brush itself and the ancillary components. In the embodiment illustrated,
the buffing station assembly is a self-contained assembly carrying the necessary structural
members to support the brush assembly and its drive, and can be readily dropped into
the allocated position in the electrophotographic apparatus. Thus the brush 41 is
journaled in the upper edge of the brush assembly at 43 and 45 for rotation about
its axis, driven by a reversible motor 46 mounted below the brush and connected thereto
via a belt 48. One end of the brush may be provided with a spring loaded hub 50 which
facilitates the removal and replacement of the brush itself. A bar 51 is disposed
below and in contact with the brush bristles to provide for cleaning of excess toner
material from the bristles to extend the life of the brush material.
[0023] Although the brush is arranged for rotation in either a clockwise or counter-clockwise
direction while the platen is moving from left to right, it has been found that a
slight improvement in the final image is obtained when the bristles are moving in
the same direction as the medium when they are in contact. Thus, the preferred direction
of brush rotation is clockwise in the present embodiment. When the buffing station
is in operative position the brush contacts the surface of the medium whereby the
brush bristles engage the toned image and lightly buff it before the platen reaches
the charging station 20.
[0024] It has been found that the brush material and texture are important factors in achieving
the improvement of the present invention and the bristles should be formed of a relatively
coarse, stiff and rough material. While Orlon fibers have been found to provide satisfactory
brush bristles for the present invention, a preferred buffing brush is formed of bristles
made of Nomex fiber which provide for optimum buffing action. (Orlon and Nomex are
DuPont brand names for acrylic and aramid fibers, respectively.) In the preferred
embodiment the brush has a length which is equal to or slightly greater than the width
of the electrophotographic medium and the core of the brush has a diameter of approximately
76.2 mm (three inches). The length of the bristle is approximately 15.2 mm (0.6 inches)
and the buffing brush station is arranged to engage the plane of the electrophotographic
medium with a fiber penetration of approximately 1.65 mm (0.065 inch) so that a nip
of between 19 and 25.4 mm (0.75 and 1.0 inch) is effected when the brush contacts
the medium. The brush is rotated at a speed of 1700 to 1800 rpm. The weft of the brush
is made of 37/2 Nomex and the pile is made of 2/20 Nomex. The pile has 7.75 picks/cm²
(50 picks/sq.in.) and is further tigered to create more fibrous structure to the brush.
[0025] By buffing the developed image with a buffing brush in accordance with the present
invention, it has been found that the toned image areas are prevented from becoming
contaminated as subsequent images are produced, such as by having their color rendition
altered, apparently by preventing the small toner particles of the liquid developer
from adhering to the portions of the previously toned areas which are not imaged in
the current imaging step. Although we do not wish to be bound by any theoretical explanation
of the mechanism of the present invention, a possible explanation for the results
observed is that the buffing of the developed photoconductor smoothes any previously
toned areas thereby minimizing unwanted toner particle adherence. It may be that such
buffing locally heats the toned image areas thus fusing it and smoothing the microstructure
of the toned image so that there is less surface roughness to which stray toner particles
can adhere.
[0026] While the brush bristles used in the '503 patent are smooth, soft, and supple, it
has been found that the most satisfactory bristles for the brush of the present invention
are relatively coarse, stiff and rough. This appears to support the above theory that
the brush physically smooths the surface of the toned areas. On the other hand, it
must be recognized that fibers that are too stiff, such as metal fibers, can remove
the entire toned image or worse.
[0027] The two brushing steps together provide for the removal of counter-ions and backround
density in the untoned areas by the first brush and for the prevention of color contamination
in the toned image areas by smoothing the toner surface with the second brush. Further,
it has been found that the use of the same bristle material for the buffing brush
as is used in the first brush does not yield the intended image quality improvement.
The bristle material that solves the present problem (Nomex) does not remove the counter-ion
material or backround density that is removed by the cleaning brush. Rather, its use
fuses the particles which create the background density in the untoned areas producing
unacceptable image quality upon subsequent toning cycles. Moreover, the material used
in the cleaning brush does not solve the present problem.
[0028] While the foregoing has significantly improved the problem of color contamination,
it has been found that in some instances that the cyan image may be adversely affected
by the buffing step. With cyan toner as disclosed generally in U. S. Patent No. 4,659,640
it has been found that the buffing of the cyan image either causes portions of the
image to flake off or to smear, neither of which is acceptable.
[0029] It has been found that the flake-off of the cyan toner can be reduced by increasing
the amount of wax in the toner composition. However, when the wax is incoporated into
the toner particles as taught as the preferred embobiment in the '640 patent, image
smear resulted from the buffing action.
[0030] Surprisingly, it has been found that when the additional wax necessary to prevent
flake-off is a separately dispersed component from the toner particles in the liquid
carrier, image smear does not occur. This alternate form of the toner preparation
is disclosed as a less preferred embodiment in the '640 patent. However there is no
suggestion that that toner would provide the unexpected advantage of permitting image
clarification by buffing without the attendant problem of flake-off or smear.
[0031] Thus the cyan developer is a self-fixing, liquid electrographic developer comprising
a volatile, electrically insulating liquid carrier. Dispersed in the carrier are (i)
toner particles comprising a polymeric binder, a cyan pigment and a dispersing agent,
and (ii) wax particles, substantially as disclosed in the '640 patent, and wherein
the additional wax is a separately dispersed component from the toner particles in
the liquid carrier.
ALTERNATIVE EMBODIMENT
[0032] While the buffing station has been disclosed as being preferably located between
the cleaning station and the charging station, it will be appreciated that it can
also be located along with the cleaning station to the right of the erase lamp 28.
The only necessity is that the buffing step be accomplished after the cleaning step,
if the cleaning step is used. The location of the cleaning and buffing stations between
the loading position and the charging station provides the advantage that the toned
electrophotographic medium has had the maximum opportunity to dry prior to cleaning
and buffing without necessitating an unduly long waiting time. However, if time is
not of the essence then the platen can be arranged to stop prior to the brushing assemblies
to the right of the erase exposure lamp, so that the toned image is sufficiently dry
to permit brushing at that location.
[0033] It will be appreciated that the present invention thus provides an improved method
and apparatus for producing a multi-color electrophotographic image that enhances
the image quality by preventing small toner particles of the liquid developers from
adhering to previously toned areas unless that area has been imaged during the current
imaging cycle. Moreover, the present invention provides a simple and relatively easily
implemented solution to this problem at a nominal cost and without any significant
negative effects on the resulting image. Still further, it has been found that the
present invention does not adversely affect the ability to transfer the final multi-color
image to a paper substrate.
1. Apparatus (10) for producing a multi-color electrophotographic image using a multi-stage
process, said apparatus (10) comprising means for providing an electrographic medium
(16) on a carrier therefor, translating the carrier and medium over a predetermined
path (14), means (20) for charging said medium (16), means (22) for exposing said
medium (16) to a first light-borne image, means for toning (26) the image bearing
charged region of said medium (16) to produce a first color visible image, means for
returning the carrier to the starting position to repeat the foregoing steps of charging
said medium (16), exposing it to a second light-borne image and toning said second
image with a second toning element (32) to produce a second visible image, and means
(30) for cleaning the untoned portions of the medium between the toning of the first
image and the second charging step, said apparatus (10) is characterized by:
means (31) for buffing the surface of the first toned image with a coarse, stiff
and rough fibrous brush member (41) after said medium (16) has been cleaned and prior
to the second charging step thereby smoothing any previously toned areas and minimizing
unwanted toner particle adherence.
2. The apparatus according to claim 1 including means (46 and 48) for rotating said buffing
means (31) in a direction concurrent to the direction of movement of said medium (16)
during the buffing step.
3. The apparatus according to claim 1 wherein means is provided for supplying toning
means with a liquid toner.
4. The apparatus according to claim 1 wherein means is provided for drying said image
before said medium (16) is passed into contact with said buffing brush (41).
5. The apparatus according to claim 1 including means (50) for selectively moving said
buffing means (31) into and out of contact with said medium (16).
6. The apparatus according to claim 1 wherein means is provided for exposing (22, 28)
and toning (26, 32, 34, 36) said medium (16) with four different images to produce
a four color image.
7. The apparatus according to claims 1 and 6 including means (51) for removing toner
components from said brush during the buffing step.
8. Apparatus according to claims 1, 6 and 7 wherein said bristles are selected from a
group consisting of Nomex and Orlon fibers.
9. A method for producing multi-color electrophotographic image using a multi-stage process
comprising the steps of providing an electrophotographic medium (18) on a carrier
therefor, translating the carrier and medium together over a predetermined path (14),
charging the medium, exposing the medium to a first light-borne image, toning the
image bearing charged region of said medium (16) to produce a first visible image,
and returning said carrier to the first position to repeat the foregoing steps of
charging said medium (16), exposing it to a second light-borne image and toning said
second visible image, said method is characterized by:
a step of buffing the surface of the developed image with a coarse, stiff and rough
fibrous brush member (41) after a development step and prior to the next charging
step thereby smoothing any previously toned areas and minimizing unwanted toner particle
adherence.
10. A method according to claim 9 for producing multi-color electrophotographic image
using a multi-stage process including a step of rotating said brush in a direction
concurrent to the direction of movement of said carrier during the buffing step.
11. A method according to claim 9 for producing multi-color electrophotographic image
using a multi-stage process comprising the steps providing the toning (26, 32, 34,
36) element with a liquid toner and drying the image before said buffing step is performed.
12. A method according to claim 9 for producing multi-color electrophotographic image
using a multi-stage process wherein said buffing step is performed after each toning
step and each cleaning step.
13. A method according to claim 9 for producing multi-color electrophotographic image
using a multi-stage process wherein at least one of said color visible images is a
cyan image, the step of producing said cyan image is characterized by:
developing said cyan image with a self fixing, liquid electrographic developer
comprising a volatile, electrically insulating liquid carrier and, dispersed in said
carrier,
(i) toner particles comprising a polymeric binder, cyan pigment and a dispersing agent
and
(ii) wax particles and
buffing the surface of said cyan image with a coarse, stiff and rough fibrous
brush member (41) whereby said cyan image does not flake off or smear during said
buffing step.
1. Gerät (10) zur Herstellung eines mehrfarbigen elektrofotografischen Bildes unter Verwendung
eines mehrstufigen Verfahrens mit Mitteln, die ein elektrografisches Mediums (16)
auf einem dafür vorgesehenen Träger bereitstellen, indem sie den Träger und das Medium
über eine vorbestimmte Bahn (14) bewegen, einer Einrichtung (20) zum Aufladen des
Mediums (16), einer Einrichtung (22) zum Aufbelichten eines ersten Vorlagenbildes
auf das Mediums (16), einer Einrichtung (26) zum Tonern des das Bild tragenden aufgeladenen
Bereichs des Mediums (16) und Erzeugen eines ersten sichtbaren farbigen Bildes, einer
Einrichtung, die den Träger in seine Ausgangsposition zurückführt, so daß das Medium
(16) erneut aufladbar, ein zweites Vorlagenbild aufbelichtbar und das zweite Bild
zum Erzeugen eines zweiten sichtbaren Bildes mit einem zweiten Tonerelement (32) tonerbar
ist, und einer Einrichtung (30) zum Reinigen der nicht getonerten Bereiche des Mediums
zwischen dem Tonern des ersten Bildes und dem zweiten Aufladevorgang, dadurch gekennzeichnet, daß
eine Einrichtung (31) vorgesehen ist, die die Oberfläche des ersten getonerten Bildes
mittels einer groben, steifen und rauhen aus Fasern bestehenden Bürste (41) poliert,
nachdem das Medium (16) gereinigt worden ist und bevor der zweite Aufladevorgang stattgefunden
hat, und die dabei zuvor getonerten Bereiche glättet und das Anhaften unerwünschter
Tonerteilchen auf ein Minimum reduziert.
2. Gerät nach Anspruch 1, dadurch gekennzeichnet, daß Mittel (46 und 48) vorgesehen sind,
die die Poliereinrichtung (31) während des Poliervorgangs in einer der Bewegungsrichtung
des Mediums (16) entsprechenden Richtung drehen.
3. Gerät nach Anspruch 1, dadurch gekennzeichnet, daß eine die Tonereinrichtung mit einem
Flüssigtoner versorgende Einrichtung vorgesehen ist.
4. Gerät nach Anspruch 1, dadurch gekennzeichnet, daß eine Einrichtung vorgesehen ist,
die das Bild trocknet, bevor das Medium (16) mit der Polierbürste (41) in Berührung
gelangt.
5. Gerät nach Anspruch 1, dadurch gekennzeichnet, daß eine Einrichtung (50) vorgesehen
ist, die die Poliereinrichtung (31) selektiv mit dem Medium (16) in und außer Berührung
bringt.
6. Gerät nach Anspruch 1, dadurch gekennzeichnet, daß eine Einrichtung vorgesehen ist,
die das Medium (16) mit vier verschiedenen Bildern belichtet (22, 28) und tonert (26,
32, 34, 36), um ein vierfarbiges Bild zu erzeugen.
7. Gerät nach Anspruch 1 und 6, dadurch gekennzeichnet, daß eine Einrichtung (51) vorgesehen
ist, die während des Poliervorgangs Tonerkomponenten von der Bürste entfernt.
8. Gerät nach Anspruch 1, 6 und 7, dadurch gekennzeichnet, daß die Borsten der Bürste
aus einer aus Nomex- und Orlonfasern bestehenden Gruppe auswählbar sind.
9. Verfahren zur Herstellung eines mehrfarbigen elektrofotografischen Bildes in mehreren
Verfahrensschritten, bei dem auf einem dafür vorgesehenen Träger ein elektrofotografisches
Medium (16) bereitgestellt wird und Träger und Medium zusammen über eine vorbestimmte
Bahn (14) bewegt werden, das Medium aufgeladen und und ein erstes Vorlagenbild auf
das Medium aufbelichtet wird, der das Bild tragende aufgeladene Bereich des Mediums
(16) getonert wird, um ein erstes sichtbares Bild zu erzeugen, und der Träger zum
erneuten Aufladen des Mediums (16), zum Aufbelichten eines zweiten Vorlagenbildes
und zum Tonern des zweiten sichtbaren Bildes in seine Ausgangsposition zurückgeführt
wird, dadurch gekennzeichnet,
daß die Oberfläche des entwickelten Bildes nach einem Entwicklungsvorgang und vor
der jeweils nächsten Aufladung mit einer groben, steifen und rauhen Bürste (41) poliert
wird, wobei zuvor getonerte Bereiche geglättet werden und das unerwünschtes Anhaften
von Tonerteilchen auf ein Minimum reduziert wird.
10. Verfahren nach Anspruch 9 zur Herstellung eines mehrfarbigen elektrofotografischen
Bildes in mehreren Verfahrensschritten, dadurch gekennzeichnet, daß die Bürste während
des Polierens in einer der Bewegungsrichtung des Trägers entsprechenden Richtung gedreht
wird.
11. Verfahren nach Anspruch 9 zur Herstellung eines mehrfarbigen elektrofotografischen
Bildes in mehreren Verfahrensschritten, dadurch gekennzeichnet, daß dem zum Tonern
(26, 32, 34, 36) dienenden Element ein Flüssigtoner zugeführt und das Bild vor Durchführung
des Poliervorgangs getrocknet wird.
12. Verfahren nach Anspruch 9 zur Herstellung eines mehrfarbigen elektrofotografischen
Bildes in mehreren Verfahrensschritten, dadurch gekennzeichnet, daß der Poliervorgang
jeweils nach dem Tonern und dem Reinigen erfolgt.
13. Verfahren nach Anspruch 9 zur Herstellung eines mehrfarbigen elektrofotografischen
Bildes in mehreren Verfahrensschritten, bei dem mindestens eines der sichtbaren Farbbilder
ein Cyanbild ist, dadurch gekennzeichnet, daß
das Cyanbild mit einem selbstfixierenden, flüssigen elektrografischen Entwickler entwickelt
wird, der einen flüchtigen, elektrisch isolierenden flüssigen Träger enthält, in dem
(i) ein polymeres Bindemittel, Cyanpigment und ein Dispersionsmittel enthaltende Tonerteilchen
und
(ii) Wachsteilchen dispergiert sind, und daß
die Oberfläche des Cyanbildes mit einer groben, steifen und rauhen Bürste (41) derart
poliert wird, daß das Cyanbild nicht abblättert oder während des Polierens verschmiert.
1. Appareil (10) de formation d'une image électrophotographique en couleurs à l'aide
d'une opération en plusieurs étapes, l'appareil (10) comprenant un dispositif destiné
à former un milieu électrophotographique (16) sur un support, par déplacement en translation
du support et du milieu suivant un trajet prédéterminé (14), un dispositif (20) de
charge du milieu (16), un dispositif (22) d'exposition du milieu (16) à une première
image formée de lumière, un dispositif (26) d'application d'un développateur à la
région chargée du milieu (16) qui porte l'image pour la formation d'une image visible
en une première couleur, un dispositif destiné à ramener le support à la position
initiale pour la répétition des étapes précédentes de charge du milieu (16), d'exposition
de celui-ci à une seconde image formée de lumière et d'application de développateur
à la seconde image avec un second élément (32) d'application de développateur pour
la formation d'une seconde image visible, et un dispositif (30) de nettoyage des parties
du milieu sans développateur entre l'application de développateur à la première image
et la seconde étape de charge, l'appareil (10) étant caractérisé par :
un dispositif (31) de frottement de la surface de la première image de développateur
à l'aide d'une brosse fibreuse grossière, rigide et rugueuse (41) après que le milieu
(16) a été nettoyé et avant la seconde étape de charge, si bien que les régions sur
lesquelles le développateur a été appliqué antérieurement sont régularisées et l'adhérence
indésirable des particules de développateur est réduite au minimum.
2. Appareil selon la revendication 1, comprenant un dispositif (46 et 48) destiné à faire
tourner le dispositif (31) de frottement dans le sens de déplacement du milieu (16)
au cours de l'étape de frottement.
3. Appareil selon la revendication 1, dans lequel un dispositif est destiné à transmettre
un développateur liquide au dispositif d'application de développateur.
4. Appareil selon la revendication 1, dans lequel un dispositif est destiné à sécher
l'image avant que le milieu (16) ne soit transmis au contact de la brosse de frottement
(41).
5. Appareil selon la revendication 1, comprenant un dispositif (50) de déplacement sélectif
du dispositif de frottement (31) afin qu'il vienne au contact du milieu (16) et s'en
écarte.
6. Appareil selon la revendication 1, dans lequel un dispositif est destiné à assurer
l'exposition (22, 28) du milieu (16) et l'application de développateur (26, 32, 34,
36) à ce milieu (16) avec quatre images différentes pour la formation d'une image
à quatre couleurs.
7. Appareil selon les revendications 1 et 6, comprenant un dispositif (51) destiné à
retirer les éléments constituants de développateur de la brosse au cours de l'étape
de frottement.
8. Appareil selon les revendications 1, 6 et 7, dans lequel les soies sont choisies dans
le groupe formé par les fibres de "Nomex" et les fibres d'"Orlon".
9. Procédé de formation d'une image électrophotographique en couleurs à l'aide d'une
opération en plusieurs étapes, comprenant les étapes suivantes : la disposition d'un
milieu électrophotographique (18) sur un support, le déplacement en translation du
support et du milieu ensemble suivant un trajet prédéterminé (14), la charge du milieu,
l'exposition du milieu par une première image formée de lumière, l'application de
développateur à la région chargée du milieu (16) qui porte l'image afin qu'une première
image visible soit formée, et le retour du support à la première position pour la
répétition des étapes précédentes de charge du milieu (16), d'exposition du milieu
à une seconde image formée de lumière et d'application d'un développateur pour la
formation de la seconde étape visible, le procédé étant caractérisé par :
une étape de frottement de la surface de l'image développée avec une brosse fibreuse
grossière, rigide et rugueuse (41) après l'étape de développement et avant l'étape
suivante de charge, si bien que les zones auxquelles un développateur a été appliqué
antérieurement sont régularisées et l'adhérence indésirable des particules de développateur
est réduite au minimum.
10. Procédé selon la revendication 9, destiné à la formation d'une image électrophotographique
en couleurs à l'aide d'un procédé en plusieurs étapes, comprenant une étape d'entraînement
en rotation de la brosse dans le sens de déplacement du support pendant l'étape de
frottement.
11. Procédé selon la revendication 9, destiné à la formation d'une image électrophotographique
en couleurs à l'aide d'un procédé en plusieurs étapes, comprenant des étapes de transmission
d'un développateur liquide à l'élément d'application de développateur (26, 32, 34)
et de séchage de l'image avant l'exécution de l'étape de frottement.
12. Procédé selon la revendication 9, destiné à la formation d'une image électrophotographique
en couleurs à l'aide d'un procédé en plusieurs étapes, dans lequel l'étape de frottement
est réalisée après chaque étape d'application de développateur et chaque étape de
nettoyage.
13. Procédé selon la revendication 9, destiné à la formation d'une image électrophotographique
en couleurs à l'aide d'un procédé en plusieurs étapes, dans lequel l'une au moins
des images visibles en couleurs est une image cyan, l'étape de formation d'image cyan
étant caractérisée par les étapes suivantes :
le développement de l'image cyan par un révélateur électrophotographique liquide
qui se fixe automatiquement et qui contient un véhicule liquide volatil isolant de
l'électricité et, sous forme dispersée dans ce véhicule,
i) des particules de développateur comprenant un liant polymère, un pigment cyan et
un agent dispersant, et
ii) les particules de cire, et
le frottement de la surface de l'image cyan par une brosse fibreuse grossière,
rigide et rugueuse (41), si bien que l'image cyan ne se sépare pas par écaillage ou
ne se salit pas pendant l'étape de frottement.