[0001] This invention relates to built liquid detergent compositions for laundry and general
purpose applications which exhibit stability against phase separation.
[0002] Built liquid detergent compositions are popular with consumers because they are easy
to store, dispense and measure and do not cake as some granular detergent products
are apt to do when stored for lengthy periods of time or become damp. A major disadvantage
of built liquid detergent compositions has been their cost in comparison to the granular
products. The cost of built liquid detergents is exacerbated because of the difficulties
encountered in preparing homogeneous built liquid detergent compositions.
[0003] The current commercially available built liquid detergent compositions typically
contain one or more synthetic detergents and an inorganic builder, such as potassium
polyphosphate, in an aqueous medium. One major problem encountered in formulating
built liquid detergent compositions is the difficulty of including in a concentrated
solution sufficient detergent and builder to provide the performance expected of a
product intended for washing soiled clothing and other household chores. Attempts
to combine the detergents and builders at effective levels in a homogeneous liquid
system have resulted in the development of complicated formulae with large numbers
of ingredients, including inactive cleaning ingredients such as hydrotropes, polymeric
stabilizers and thickeners in these formulations. These inactive cleaning ingredients
contribute little, if any, to the performance of the liquid detergent and, in fact,
are sometimes deleterious to cleaning performance. They do increase the cost of the
formulation and their use is justified only if it results in higher concentrations
of detergent and builder in the solution.
[0004] In accordance with the present invention, there is provided a liquid built laundry
detergent composition in which a high percentage of a nonionic surfactant can be incorporated
with a high percentage of detergent builder without phase separation. Further, this
is unexpectedly accomplished with a material which is an active cleaning agent. According
to the present invention, a liquid detergent composition comprises from 5 to 22 percent
by weight of at least one ethoxylated nonionic surfactant, from 3 to 11 percent by
weight of at least one alkyl polyglycoside and from 20 to 50 weight percent of at
least one detergent builder, and soft water.
[0005] The principal ingredients of the built liquid laundry detergents of the invention
include at least one builder, at least one ethoxylated nonionic surfactant and at
least one polyalkyl glycoside. These principal ingredients are included in the liquid
detergent compositions in the following ranges:
Ingredient |
Range |
Preferred Range |
Best Mode |
Ethoxylated nonionic |
5-22% |
5-12% |
7% |
Alkyl polyglycoside |
3-11% |
4-9% |
7% |
Builder |
20-50% |
30-45% |
35-45% |
The Alkyl Polyglycosides
[0006] The alkyl polyglycosides which are employed as a cosurfactant in this invention are
preferably those having a hydrophobic group containing from about 6 to 30 carbon atoms,
preferably from about 10 to 16 carbon atoms and a polysaccharide, for example, a polyglycoside,
hydrophylic group containing from about 1-1/2 to about 10, preferably from about 1-1/2
to about 3, and most preferably from about 1.6 to about 2.7 saccharide units. These
materials are known as surfactants, but are not known as compatabilizers for ethoxylated
nonionic surfactants and detergent builders as they also function in the present invention.
[0007] Reducing saccharide containing 5 or 6 carbon atoms can be used, for example, glucose,
lactose and galactosyl moieties can substitute for the glucosyl moieties. Optionally,
the hydrophobic group can be attached at the 2, 3, 4, etc. positions, thus giving
a glucose or galactose as compared to a glucoside or galactoside. The intersaccharide
bonds can be, for example, between the 1 position of the additional saccharide units
and the 2-, 3-, 4- and/or 6 positions on the preceding saccharide units. Optionally,
there can be a polyalkylene oxide chain joining the hydro-phobic moiety and the polysaccharide
moiety. The preferred alkoxide is ethylene oxide. Typical hydrophobic groups include
alkyl groups, either saturated or unsaturated, branched or unbranched containing from
about 6 to about 18, preferably from 10 to 16 carbon atoms. Preferably, the alkyl
group is a straight chain saturated alkyl group. The alkyl group can contain up to
3 hydroxy groups and/or the polyalkoxide chain can contain up to about 10, preferably
less than 5, most preferably 0, alkoxide moieties. Suitable alkyl polysaccharides
are octyl, nonyl decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl,
heptadecyl and octadecyl, di-, tri-, tetra-, penta- and hexaglucosides, galactosides,
lactoses, lactosides, glucoses, fructosides, fructoses and/or galactoses. Suitable
mixtures include coconut alkyl, di-, tri-, tetra- and pentaglucosides and tallowalkyl
tetra-, penta- and hexaglucosides.
[0008] The preferred alkyl polyglycosides have the formula
RO(C
nH
2nO)
t(glycosyl)
x
wherein R is selected from the group consisting of alkyl, alkyl phenyl, hydroxy alkyl,
hydroxy alkyl phenyl and mixtures thereof in which said alkyl groups contain from
about 10 to 18, preferably from 12 to 14 carbon atoms; and is 2 or 3, preferably 2,
t is from 0 to 10, preferably 0; and x is from 1-1/2 to 10, preferably from 1/2 to
3, most preferably from about 1.6 to about 2.7. The glycosyl is preferably derived
from glucose. To prepare the compounds, the alcohol or alkylpolyethoxy alcohol may
be formed first and then reacted with glucose, or a source of glucose to form the
glycoside (attachment at the 1- position). The additional glycosyl units may be attached
between their 1- position and the preceding glycosyl units 2-, 3-, 4 and/or 6 position,
preferably predominantly the 2-position.
Nonionic Surfactants
[0009] The ethoxylated nonionic surfactants which are suitable for use in the present invention
include surface active or detergent compounds which contain an organic hydrophobic
group and a hydrophylic group which is a reaction product of a solubilizing group
such as carboxyl, hydroxyl, thiol, amide or amine with an alkylene oxide, such as
ethylene oxide or propylene oxide or the polyhydration product thereof, such as polyethylene
glycol and polypropylene glycol. Representative of such nonionic surfactants are:
1. The polyethylene oxide condensates of alkyl phenols. These compounds include the
condensation product of alkyl phenols having from 1 to 15, preferably 6 to 12 carbon
atoms in a straight chain or branch chain configuration with from 4 to 25, preferably
4 to 16, moles of ethylene oxide per mole of alkyl phenol. The alkyl substituents
in such compounds can be derived, for example, from polymerized polypropylene, diisobutylene
and the like. Examples of compounds of this type include nonyl phenol condensed with
about 9.5 moles of ethylene oxide per mole of nonyl phenol; dodecyl phenol condensed
with about 12 moles of ethylene oxide per mole of phenol; dinonyl phenol condensed
with about 15 moles of ethylene oxide per mole of phenol. Commercially available nonionic
surfactants of this type include Igepal CO-630, marketed by the GAF Corporation, and
Triton X-45, X-114, X-100 and X-102, all marketed by the Rohm & Haas Company.
2. The condensation products of aliphatic alcohols and thiols with from 1 to 25, preferably
5 to 16, moles of ethylene oxide. The alkyl chain with the aliphatic alcohol or thiol
can either be straight or branched, primary or secondary and generally contain from
about 8 to 22 carbon atoms. Examples of such ethoxylated alcohols include the condensation
products of myristyl alcohol condensed with about 10 moles of ethylene oxide per mole
of alcohol; and the condensation product of about 9 moles of ethylene oxide with coconut
alcohol (a mixture of fatty alcohols with alkyl chains varying in length from 10 to
14 carbon atoms). A representative ethoxylated thiol is the condensation product of
a C₁₂ tertiary thiol with about 7 moles of ethylene oxide per mole of thiol. Examples
of commercially available nonionic surfactants of this type include Tergitol 15-S-9,
marketed by Union Carbide Corporation; Neodol - 45-9, Neodol 23-6.5, Neodol 45-7 and
Neodol 25-7, marketed by Shell Chemical Company, Kyro EOB, marketed by The Proctor
& Gamble Company and Alcodet ethoxylated thiols marketed by Alcolac Corporation. The
ethoxylated alcohols and thiols are currently preferred nonionic surfactants.
3. The condensation products of ethylene oxide with a hydrophobic base formed by the
condensation of propylene oxide with propylene glycol. The hydrophobic portion of
these compounds has a molecular weight from about 1500 to 1800 and exhibits water
insolubility. The addition of polyoxyethylene moieties to this hydrophobic portion
tends to increase the water solubility of the molecule as a whole, and the liquid
character of the product is retained up to the point where the polyoxyethylene content
is about 50% of the total weight of the condensation product, which corresponds to
condensation of up to about 40 moles of ethylene oxide. Examples of compounds of this
type include certain of the commercially available Pluronic surfactants, marketed
by Wyandott Chemical Corporation.
4. The condensation products of ethylene oxide with a product resulting from the reaction
of propylene oxide and ethylene diamine. The hydrophobic moiety of these products
consists of the reaction product of ethylene diamine and excess propylene oxide, the
moiety having a molecular weight from about 2500 to 3000. This hydrophobic moiety
is condensed with ethylene oxide to the extent that the condensation product contains
from about 40 to 80% by weight of polyoxyethylene and has a molecular weight from
about 5000 to 11000. Examples of this type of nonionic surfactant include certain
of the commercially available Tectronic compounds marketed by Wyandott Chemical Corporation.
Builders
[0010] The built detergent compositions of the invention also contain from 20 to 50%, preferably
from 30 to 45%, and more preferably 35 to 45% by weight of a detergency builder, especially
a water-soluble inorganic or organic electrolyte. Preferred electrolytes include the
common alkaline polyvalent calcium ion sequestering agents. The builder can also include
water-insoluble calcium ionic exchange materials.
[0011] Nonlimiting examples of suitable water-soluble inorganic detergent builders include
alkaline metal carbonates, borates, phosphates, polyphosphates, bicarbonates, silicates,
sulphates and chlorides. Specific examples of such salts include sodium and potassium
tetraborates, perborates, bicarbonates, carbonates, tripolyphosphates, orthophosphates,
pyrophosphates, hexametaphosphates and sulphates.
[0012] Examples of suitable organic alkaline detergency builders include water-soluble amino
carboxylates and amino polyacetates, such as sodium and potassium glycinates, ethylene
diamine tetraacetates, nitrilo triacetates and N-(2-hydroxy ethyl)nitrilo diacetates
and diethylene triamine pentaacetates; water-soluble salts of phytic acid, such as
sodium and potassium phytates; water-soluble polyphosphates including sodium, potassium
and lithium salts of ethane-1-hydroxy-1, 1-diphosphonic acid, the sodium potassium
and lithium salts of ethylene diphosphonic acid and the like; water-soluble polycarboxylates
such as in salts of lactic acid, succinic acid, malonic acid, maleic acid, citric
acid, carboxymethyloxy succinic acid, 1,1,2,2-ethane tetracarboxylic acid, cyclopentane-cis,cis,cis-tetracarboxylic
acid, mellitic acid and pyromellitic acid; water-soluble organic amines and amine
salts such as monoethanol amine, diethanol amine and triethanol amine and salts thereof.
[0013] Another type of detergency builder useful in the present composition comprises water-soluble
material capable of forming a water-insoluble reaction product with water hardness
cations preferably in combination with a crystallization seed which is capable of
providing growth sites for said reaction product.
[0014] A further class of detergency builder materials useful in the present invention are
insoluble sodium aluminosilicates, especially those having a calcium ion exchange
capacity of at least 200 milligrams equivalent per gram and a calcium ion exchange
rate of at least .53 grams per litre per minute per gram.
Additional Ingredients
[0015] The built detergent compositions of the present invention can be supplemented by
the usual additives conventionally employed in detergent compositions. Optional ingredients
include soil suspending agents at about 0.1 to 10% by weight, including water-soluble
salts of carboxy methyl cellulose, carboxy hydroxy methyl cellulose and polyethylene
glycols having a molecular weight of about 400 to 10000. Dyes, pigments, optical brighteners
and perfumes, enzymes, preservatives such as sodium benzoate, alkaline metal or alkaline
earth metal silicates, suds regulating or suppressing agents, natural and synthetic
microcrystalline and oxidized microcrystalline waxes, inorganic and organic peroxy
bleaching agents, polyphosphonic acids and acid salts. These materials may be employed
in the practice of this invention at conventional levels normally employed in detergent
formulations.
[0016] Substantially any of the known anionic fluorescent brightening and/or wetting agents
can be employed in the practice of this invention. The currently most preferred whiteners
are 4,4′-bis[(4-anilino-6-[bis(2-hydroxy ethyl)-amino]-s-triazine-2-yl)amino]-2,2′
stilbene disulphonic acid; 4,4-bis[(4-anilino-t[N-2-hydroxy ethyl-N-methyl amino]-
s-triazine-2-yl)amino]-2,2′ stilbene disulphonic acid disodium salt; and 4-[2H-naphthol(1,2-d)triazol-2-yl]-2-stilbene
sulphonic acid sodium salt. Also suitable for use are nonionic brighteners such as
p-[3-(p-fluorophenol)-2-pyrozolin-1-yl] benzene sulfonamide.
[0017] The compositions of the present invention can also optionally include both cationic
and anionic surfactants. Substantially any of the known cationic surfactants can be
advantageously included in the detergent compositions of the invention. Preferred
cationic surfactants are the alkyl quaternary ammonium halides and sulphates, especially
the mono long chain alkyl (C₈₋₂₂) and alkylene oxylated mono long chain alkyl surfactants.
The most preferred quaternary ammonium surfactants are the chloride, bromide and methyl
sulphate C₈₋₂₂ alkyltrimethylammonium salts, C₈₋₂₂ alkyl (dihydroxyethyl)methylammonium
salts, C₈₋₂₂ alkylhydroxyethyldimethylammonium salts, C₈₋₂₂ alkyloxypropyltrimethylammonium
salts, C₈₋₂₂ alkyloxypropyl (dihydroxyethyl)methylammonium salts and C₈₋₂₂ alkyloxy
propylhydroxyethyldimethylammonium salts, with C₈₋₂₂ alkyloxypropylbis (hydroxyethyl)methylammonium
salts being especially preferred. The current cationic surfactant of choice is isotridecyloxypropylbis(hydroxyethyl)methyl
ammonium chloride. The cationic surfactants, when used, will be present in amounts
up to 12 percent by weight, preferably from 1 to 5 percent by weight, and most preferably
in the range from 2 to 4 percent by weight.
[0018] Although substantially any of the known anionic surfactants which are typically employed
in detergent compositions can be advantageously included in the detergent compositions
of the invention, water-soluble salts, preferably the alkaline metal ammonium and
alkylol ammonium salts, of organic sulphuric reaction products having in their molecular
structure an alkyl group containing from about 10 to 20 carbon atoms and a sulphonic
or sulphuric acid group are especially preferred. Examples of this group of anionic
surfactants are the sodium and potassium alkyl sulphates, especially those obtained
by sulphating the higher alcohols (C8-C18 carbon atoms) such as those produced by
reducing the glycerides of tallow or coconut oil; and the sodium and potassium alkyl
benzene sulphonates in which the alkyl group contains from about 9 to about 15 carbon
atoms, in straight chain or bent chain configuration. Especially valuable are linear
straight chain alkyl benzene sulphonates in which the average number of carbon atoms
in the alkyl group is from about 11 to 13, abbreviated as C₁₁-C₁₃ LAS.
[0019] Other suitable anionic surfactants are the alkyl polyethoxylate sulphates, particularly
those in which the alkyl group contains from 10 to about 22, preferably from 12 to
18 carbon atoms, and wherein the polyethoxylate chain contains from 1 to 15 ethoxylate
moieties, preferably from 1 to 3 ethoxylate moieties. Also suitable for use in the
invention are anionic surfactants such as the sodium alkyl glycerol ether sulphonates,
especially those ethers of higher alcohols derived from tallow and coconut oil, sodium
coconut oil, fatty acid monoglyceride sulphonates and sulphates; sodium and potassium
salts of alkyl phenol, ethylene oxide ether sulphates containing from 1 to 10 units
of ethylene oxide per molecule and wherein the alkyl groups contain from 8 to 12 carbon
atoms; and sodium or potassium salts of alkyl ethylene oxide ether sulphates containing
from 1 to 10 units of ethylene oxide per molecule and wherein the alkyl group contains
from 10 to 20 carbon atoms.
[0020] Other anionic surfactants include water-soluble salts of esters with alpha-sulphonated
fatty acids containing from 6 to 20 carbon atoms in the fatty acid group and from
1 to 10 carbon atoms in the ester group; water-soluble salts of 2-acyloxy-alkane-1-sulphonic
acids containing from 2 to 9 carbon atoms in the acyl group and from 9 to 23 carbon
atoms in the alkane moiety; alkyl ether sulphates containing from 10 to 20 carbon
atoms in the alkyl group and from 1 to 30 moles of ethylene oxide; water-soluble salts
of olefin sulphonates containing from 12 to 24 carbon atoms; and beta-alkyloxy alkane
sulphonates containing from 1 to 3 carbon atoms in the alkyl group and from 8 to 20
carbon atoms in the alkane moiety. When used, the anionic surfactants will be employed
in amounts up to 12 percent by weight, preferably in the range from 1 to 7 percent
by weight, and most preferably, from 2 to 5 percent by weight. The anionic surfactants
are preferably employed in combination with cationic surfactants. Alkyl sarcosinates
are currently preferred anionic surfactants.
[0021] Other optional ingredients which can be included in the detergent compositions of
the present invention, in their conventional art established levels for use include
solvents, bleaching agents, bleach activators, soil-suspending agents, corrosion inhibitors,
dyes, fillers, optical brighteners, germicides, pH adjusting agents (monoethanolamine,
sodium carbonate, sodium hydroxide and the like), enzymes, enzyme-stabilizing agents,
perfumes, fabric softening components, static control agents, and the like.
[0022] The liquid detergent compositions of the present invention can be conveniently prepared
in accordance with the known formulation procedures or techniques which are usually
employed in the preparation of conventional anionic surfactant-based liquid detergent
products. Preferably, the desired surfactant components (i.e., the glycoside surfactant,
the ethoxylated nonionic surfactant, and, if employed, the anionic and/or cationic
surfactant components) are first dissolved in water and any auxiliary additives which
may be desired for use herein such as, for example, stabilizers, perfumes, preservatives,
colourants, etc. are subsequently added to the resulting aqueous surfactant solution.
Preferably, any such auxiliary ingredients either will be water soluble in character
or will be presolubilized or pre-dispersed in a portion of the surfactant system prior
to being added to the mixture. The application of heat to the aqueous mixture is often
beneficial during the formulation process in facilitating the obtaining of a homogeneous
mixture and it is generally preferred to stir, or to otherwise provide good agitation
to the mixture during said process. Further, in those formulations employing a viscosifying
agent such as ammonium or alkali metal salts, it is generally preferred to dissolve
the desired amount of same in the water at the beginning of the formulation process.
[0023] The pH of the present formulations is not particularly critical and can be varied
or adjusted as desired in a given instance. As a general rule, however, the pH of
such formulations will typically be within the range of from about 8 to 12.
Experimental Procedures and Results
[0024] The detergent compositions were evaluated in the examples as follows:
[0025] Soiled cloths were washed in a laboratory-scale washing machine (Terg-O-Tometer,
U.S. Testing Company) which simulates the action of an agitator-type home washer.
Appropriate amounts of detergent formulations are added to one litre of water at a
controlled hardness. Wash temperature, agitator speed and wash, as well as rinse,
time can be controlled via the Terg-O-Tometer. After washing, rinsing (machine or
by hand) and drying, detergency is taken as a change in the reflectance of the cloths.
Assignments of formulas to the test spots are randomized using a simple random number
table.
[0026] The effectiveness of the detergent compositions is determined by reflectance readings
using a Gardner Color Difference Meter, with all cloths being read before and after
laundering. Each cloth is individually placed on the reflectometer and covered by
a white ceramic plate standard. For the Bandy black clay soil cloths, only Rd readings
are taken. For all cloths, a and b values, in addition to Rd readings, may be observed.
[0027] The soil types which were evaluated are as follows:
Bandy Black Clay (BBC): an artificially prepared soil cloth prepared by a dry soiling
method where the clay is ball milled into the fabric.
TFI: a printed soil cloth (mineral oil-carbon black base) purchased from Test Fabrics
Incorporated.
HCO: a soiled cloth prepared by immersion in a lard, margarine and peanut oil-carbon
black mixture.
Spangler (SPNG): a soiled cloth prepared by immersion in a soil bath (synthetic sebum,
air conditioner dust) and then padded and dried.
EMPA: a soiled cloth prepared by immersion in an olive oil-carbon black mixture.
DMO: a soiled cloth prepared by immersion in dirty motor oil.
[0028] Cotton, cotton/Dacron, cotton with permanent press finish, cotton, Dacron with permanent
press finish were used for the Bandy Black Clay, TFI, DMO, HCO and Spangler soils.
Cotton and cotton: Dacron with permanent press finish were used for EMPA and grass
soils.
[0029] The following examples illustrate, but are not limiting of, detergent compositions
of the present invention. All formulations were evaluated at 37.7°C. (100° F.) in
water having 3, 6 or 12 grains of hardness.
[0030] Stability evaluations were made by storing containers of the detergent compositions
and evaluating the appearance of the compositions over time. Compositions which had
phase separated, that is, formed distinct layers, over the indicated test periods,
were considered to be failures and thus unacceptable. The failures are reported as
"F". The formulations which over the test period had not phase separated but exhibited
some loss in homogeneity of the emulsion, e.g., creaming, were reported by the symbol
"S". These formulations while not optimal, are still satisfactory for use. Formulations
which exhibited little, if any, change over the test period were reported by the symbol
"P".
EXAMPLE 1 |
|
Invention |
Control |
Tetrapotassium pyrophosphate |
40.0 |
40.0 |
|
C₁₂₋₁₃ Alkylmonoglyceride |
7.0 |
7.0 |
|
C₁₂ t-thiol ethoxylate, 7 moles ethylene oxide |
7.0 |
7.0 |
|
Isotridecyl oxypropyl-bis(2-hydroxy ethyl)-methyl ammonium chloride |
2.0 |
2.0 |
|
Sodium lauryl sarcosinate |
0.0 |
2.4 |
|
Sodium lauryl sulfate |
1.8 |
0.0 |
|
Water |
Q.S. |
Q.S. |
|
Test Results - Reflectance Difference (before and after washing readings) |
|
|
|
TFI-3¹ |
25.20 |
24.80 |
22.0 |
SPNG-3¹ |
16.50 |
15.40 |
24.8 |
BBC-3¹ |
86.60 |
87.80 |
87.90 |
HCO-3¹ |
7.40 |
7.00 |
7.20 |
DMO-3¹ |
13.60 |
10.40 |
7.20 |
TFI-12² |
14.70 |
19.90 |
21.00 |
SPNG-12² |
10.70 |
9.80 |
17.50 |
BBC-12² |
84.70 |
85.00 |
86.70 |
HCO-12² |
6.10 |
5.20 |
7.10 |
DMO-12² |
11.70 |
10.30 |
8.20 |
1: Cloths were washed in water having a hardness of .051 grams.l (3 grains/U.S. gallon). |
2: Cloths were washed in water having a hardness of .205 grams.l (12 grains/U.S. gallon). |
[0031] As can be seen from the reflectance data, detergent compositions embodying the invention,
on balance, provide equivalent to better detergency results on oil-based soils when
compared to a leading commercial liquid detergent, in both "soft" and "hard" water,
with performance of both the invention detergents and the commercial detergents being
less effective in the harder water. The concentrated detergents of the invention were
used at 1/4-cup dosage equivalent and the commercial detergent was used at 1/2-cup
dosage equivalent, i.e., 0.11% and 0 . 1 8 % , respectively, as the actual concentrations
in the wash water.
EXAMPLE 2
[0032] Formulations embodying the inventive concept were made up as set forth in the Table
identified as Example 2. As can be seen from the reflectance data of Examples 1 and
2, detergent compositions embodying the concept of the invention can be expected to
provide equivalent to better performance to that provided by the commercial liquid
detergent control of Example 1 on most oil-based stains, and to provide an acceptable
level of performance on sebum (SPNG) stains.
EXAMPLE 3
[0033] Formulations embodying the inventive concept were made up as set forth in the Table
identified as Example 3. The reflectance data reported in the Example 3 Table demonstrate
that the detergent compositions of the invention can be formulated, e.g., increase
alkalinity, to increase the level of performance on sebum stains and it is not expected
that the increase in sebum stain removal would be accompanied by any loss in oil-based
stain removal.
EXAMPLE 4
[0034] Formulations embodying the inventive concept were made up as set forth in the Table
identified as Example 4. The data is generally self-explanatory. The data reported
in the Example 4 Table demonstrate that excellent to acceptable emulsions are provided
by the invention formulations. The data also show that emulsion stability may be a
factor of the alkylglycoside:nonionic ratio, which preferably is 1:1.
EXAMPLE 5
[0035] Formulations embodying the inventive concept of the invention were made up as set
forth in the Table identified as Example 5. The data is generally self-explanatory.
The stability data reported in the Example 5 Table demonstrate that excellent to acceptable
emulsions are provided by the invention formulations. The stability results reported
as an "S" are indicative of emulsions which remained acceptable over the test period
but showed slight separation or creaming over the period.
EXAMPLE 6
[0036] Formulations embodying the inventive concept were made up as set forth in the Table
identified as Example 6. The stability data reported in the Example 6 Table demonstrate
that the inclusion of additives, such as antiredeposition agents, can offset the stability
of the invention detergents and that some additives may have a detrimental effect.
Polyethylene glycol is a preferred antiredeposition agent in the formulations of this
invention. Thus, some experimental work of a non-inventive nature may be required
in developing fully formulated detergent compositions.
EXAMPLE 7
[0037] Formulations embodying the inventive concept were made up as set forth in the Table
identified as Example 7. The stability data reported in the Example 7 Table demonstrate
the effect of changing the nonionic sufactants in the invention formulations. The
data indicates that a broad range of ethoxylated nonionic sufactants may be used to
prepare detergent compositions in accordance with the invention, and that some experimental
work of a non-inventive nature may be required in optimizing the stability of fully
formulated compositions.
EXAMPLE 2 |
|
91 |
93 |
98 |
96 |
94 |
97 |
95 |
92 |
Potassium tripolyphosphate |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
C₁₂₋₁₃ Alkyl triglycoside |
7.0 |
7.0 |
|
|
|
|
|
|
C₁₂₋₁₃ Alkyl monoglycocide |
|
|
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
C₁₂ t-thiol ethoxylate, 7 moles ethylene oxide nonionic |
7.0 |
7.0 |
|
|
|
|
|
|
C₁₂₋₁₅-O-(CH₂CH₂O)₇H nonionic |
|
|
|
7.0 |
|
|
|
|
C₁₂₋₁₃-O-(CH₂CH₂O)₅H nonionic |
|
|
|
|
7.0 |
|
|
|
C₁₁-O-(CH₂CH₂O)₅H topped nonionic |
|
|
|
|
|
|
7.0 |
|
C₁₂ sec-thiol ethoxylate, 9 moles ethylene oxide nonionic |
|
7.0 |
|
|
|
|
|
7.0 |
C₁₂₋₁₄-O-(CH₂CH₂O)₅H narrow, nonionic |
|
|
|
|
|
7.0 |
|
|
Isotridecyloxypropyl-bis(2-hydroxyethyl)methyl ammonium, chloride |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
Sodium lauryl sarcosinate |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
Water |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Test Results: Reflectance Difference |
|
|
|
|
|
|
|
|
TFI-6¹ |
20.5 |
19.6 |
18.0 |
18.4 |
19.1 |
19.8 |
20.2 |
20.0 |
SPNG-6¹ |
12.7 |
13.2 |
13.8 |
14.4 |
12.8 |
11.8 |
14.8 |
13.9 |
EMPA-6¹ |
10.1 |
13.0 |
12.2 |
12.2 |
10.6 |
9.7 |
10.4 |
13.1 |
1: Cloths were washed in water having a hardness of 102 grams.l (6 grains/gallon). |
EXAMPLE 3 |
|
01 |
02 |
03 |
04 |
05 |
06 |
07 |
08 |
Potassium tripolyphosphate |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
Sodium carbonate |
6.5 |
6.5 |
6.5 |
6.5 |
6.5 |
6.5 |
6.5 |
6.5 |
Alkyl monoglycoside |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
C₁₁-O-(CH₂CH₂O)₇H nonionic |
7.0 |
|
|
|
|
|
|
|
AOS anionic¹ |
|
7.0 |
|
|
|
|
|
|
AES anionic² |
|
|
7.0 |
|
|
|
|
|
C₁₁-O-(CH₂CH₂O)₅H topped nonionic |
|
|
|
13.0 |
|
|
|
|
C₁₁-O-(CH₂CH₂O)₉H nonionic |
|
|
|
|
13.0 |
|
|
|
C₁₂ t-thiol ethoxylate, 7 moles ethylene oxide nonionic |
|
|
|
|
|
13.0 |
|
|
C₁₂ sec-thiol ethoxylate, 9 moles ethylene oxide nonionic |
|
|
|
|
|
|
13.0 |
|
C₁₂₋₁₄-O-(CH₂CH₂O)₇H narrow, nonionic |
|
|
|
|
|
|
|
13.0 |
Isotridecyloxypropyl-bis(2-hydroxyethyl)methyl ammonium chloride |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
Sodium lauryl sarcosinate |
2.4 |
|
|
|
|
|
|
|
Water |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Test Results: Reflectance Difference |
|
|
|
|
|
|
|
|
SPNG-6³ |
19.0 |
16.3 |
16.4 |
20.1 |
21.9 |
18.9 |
21.4 |
19.7 |
1: a - olefin sulfonate anionic |
2: alkyl ether sulfonate anionic |
3: Cloths were washed in water having a hardness of .051 grams.l (6 grains/gallon). |
EXAMPLE 4 |
|
51 |
52 |
53 |
54 |
55 |
56 |
57 |
58 |
59 |
61 |
62 |
63 |
64 |
65 |
66 |
TKPPa |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
24.0 |
APG-1b |
5.0 |
7.5 |
3.75 |
5.0 |
5.0 |
5.0 |
5.0 |
5.0 |
5.0 |
7.5 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
TTE-7c |
7.5 |
2.5 |
7.5 |
5.0 |
10.0 |
10.0 |
5.0 |
|
5.0 |
2.5 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
TTE-9d |
|
|
|
|
|
|
|
5.0 |
|
|
|
|
|
|
|
Quate |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
4.0 |
3.0 |
4.0 |
2.0 |
2.0 |
Sarcf |
2.4 |
2.4 |
2.4 |
1.8 |
1.5 |
2.4 |
2.4 |
2.4 |
0.6 |
0.0 |
0.0 |
2.4 |
2.4 |
2.4 |
0.0 |
LESg |
|
|
|
|
|
|
|
|
|
1.2 |
1.2 |
|
|
|
1.2 |
H₂O |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Stability Test Results |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
1 mo. stability |
F |
F |
F |
P |
F |
F |
P |
P |
P |
F |
P |
P |
P |
P |
P |
3 mo. stability |
F |
F |
F |
P |
F |
F |
P |
P |
F |
F |
P |
P |
P |
P |
? |
a: Tetrapotassium pyrophosphate |
b: C₁₂₋₁₃ Alkyl polyglycoside having 1 mole of glycoside |
c: C₁₂ Tertiary thiol ethoxylate having 7 moles of ethylene oxide |
d: C₁₂ Tertiary thiol ethoxylate having 9 moles of ethylene oxide |
e: Isotridecyloxypropylbis(2-hydroxyethyl)methyl ammonium chloride nonionic |
f: Lauryl sarcosinate sodium salt anionic |
g: Lauryl ether sulfate sodium salt anionic |
EXAMPLE 5 |
|
67 |
68 |
71 |
72 |
73 |
74 |
75 |
76 |
78 |
TKPP |
40.0 |
40.0 |
40.0 |
40.0 |
40.0 |
40.0 |
40.0 |
40.0 |
40.0 |
APG-1 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
TTE-7 |
7.0 |
7.0 |
|
|
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
25-7¹ |
|
|
|
7.0 |
|
|
|
|
|
1-5T² |
|
|
7.0 |
|
|
|
|
|
|
Quat |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
|
|
2.0 |
2.0 |
Sarc |
|
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
0.0 |
3.0 |
2.4 |
LES |
1.8 |
|
|
|
|
|
|
|
|
Water |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Stability Test Results |
|
|
|
|
|
|
|
|
|
1 mo. stability |
P |
P |
P |
P |
P |
? |
P |
P |
P |
3 mo. stability |
? |
? |
? |
? |
? |
? |
? |
? |
? |
1: C₁₂₋₁₅ ethoxylated alcohol having 7 moles of ethylene oxide |
2: Topped ethoxylated C₁₁ alcohol having 5 moles ethylene oxide |
EXAMPLE 6 |
|
81 |
82 |
83 |
84 |
85 |
86 |
87 |
88 |
KIP |
30.0 |
30.0 |
30.0 |
30.0 |
30.0 |
30.0 |
36.5 |
|
K Citrate |
|
|
|
|
|
|
|
38.6 |
APG-1 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
TTE-7 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
Quat |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
Sarc |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
PA-1000² |
|
1.0 |
|
|
|
|
|
|
PA4500³ |
1.0 |
|
|
|
|
|
|
|
SSMA-1000⁴ |
|
|
1.0 |
|
|
|
1.0 |
1.0 |
PEG-5000⁵ |
|
|
|
1.0 |
|
|
1.0 |
1.0 |
PVP⁶ |
|
|
|
|
1.0 |
|
|
|
CHC/MC⁷ |
|
|
|
|
|
1.0 |
|
|
H₂O |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Stability Test Results |
|
|
|
|
|
|
|
|
1 mo. stability |
F |
? |
P |
P |
F |
F |
P |
P |
3 mo. stability |
F |
F |
F |
P |
F |
F |
F |
F |
1: Potassium citrate |
2: Polyacrylate homopolymers, 1000 mw |
3: Polyacrylate homopolymers, 4500 mw |
4: Sulphonated styrene maleic anhydride polymer, 1000 mw |
5: Polyethylene glycol, 5000 mw |
6: Polyvinyl pyrollidone |
7: Mixture of carboxymethyl cellulose and methyl cellulose |
EXAMPLE 7 |
|
91 |
92 |
93 |
94 |
95 |
96 |
97 |
98 |
KTP |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
APG-3 |
7.0 |
|
7.0 |
|
|
|
|
|
APG-1 |
|
7.0 |
|
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
TTE-7 |
7.0 |
|
|
|
|
|
|
7.0 |
STE-9¹ |
|
7.0 |
7.0 |
|
|
|
|
|
23-5² |
|
|
|
7.0 |
|
|
|
|
1-5T |
|
|
|
|
7.0 |
|
|
|
25-7 |
|
|
|
|
|
7.0 |
|
|
24-25N³ |
|
|
|
|
|
|
7.0 |
|
Quat |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
Sarc |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
2.4 |
H₂O |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Stability Test Results |
|
|
|
|
|
|
|
|
1 mo. stability |
P |
P |
P |
? |
? |
P |
P |
P |
3 mo. stability |
? |
P |
? |
F |
F |
P? |
F |
? |
1: C₁₂ Secondary thiol ethoxylate having 9 moles of ethylene oxide |
2: C₁₂₋₁₃ alcohol having 5 moles ethylene oxide |
3: Narrow C₁₂₋₁₄ alcohol having 5 moles ethylene oxide |
EXAMPLE 8 |
|
01 |
02 |
03 |
04 |
05 |
06 |
07 |
08 |
09 |
KTP |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
36.5 |
APG-1 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
7.0 |
1-7¹ |
7.0 |
|
|
|
|
|
|
|
|
AOS |
|
7.0 |
|
|
|
|
|
|
|
AES |
|
|
7.3 |
|
|
|
|
|
|
1-5T |
|
|
|
13.0 |
|
|
|
|
|
1-9 |
|
|
|
|
13.0 |
|
|
|
|
TTE-7 |
|
|
|
|
|
13.0 |
|
|
|
STE-9 |
|
|
|
|
|
|
13.0 |
|
|
24-60N³ |
|
|
|
|
|
|
|
13.0 |
|
24-85N⁴ |
|
|
|
|
|
|
|
|
13.0 |
Quat |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
2.0 |
Sarc |
2.4 |
|
|
|
|
|
|
|
|
H₂O |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Q.S. |
Stability Test Results |
|
|
|
|
|
|
|
|
|
1 mo. stability |
P |
P |
P |
P |
P |
P |
P |
F |
F |
3 mo. stability |
? |
P |
F |
F |
F |
? |
? |
F |
F |
1: C11 alcohol having 7 moles ethylene oxide |
2: C11 alcohol having 9 moles ethylene oxide |
3: Narrow c₁₂₋₁₄ alcohol having 7 moles ethylene oxide |
4: Narrow C₁₂₋₁₄ alcohol having 9 moles ethylene oxide |
[0038] The data demonstrate the effect of changing the nonionic surfactants in the invention
formulations, and indicates that experimental work of a non-inventive nature may be
required in developing fully formulated compositions.