(19)
(11) EP 0 423 742 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
12.06.1991 Bulletin 1991/24

(43) Date of publication A2:
24.04.1991 Bulletin 1991/17

(21) Application number: 90119862.2

(22) Date of filing: 16.10.1990
(51) International Patent Classification (IPC)5G03C 7/30, G03C 1/83, G03C 7/305
(84) Designated Contracting States:
DE FR GB NL

(30) Priority: 16.10.1989 JP 268580/89

(71) Applicant: FUJI PHOTO FILM CO., LTD.
Kanagawa (JP)

(72) Inventor:
  • Usui, Hideo, c/o Fuji Photo Film Co., Ltd.
    Minami Ashigara-shi, Kanagawa (JP)

(74) Representative: Grünecker, Kinkeldey, Stockmair & Schwanhäusser Anwaltssozietät 
Maximilianstrasse 58
80538 München
80538 München (DE)


(56) References cited: : 
   
       


    (54) Silver halide color reversal photographic photosensitive material


    (57) A silver halide color reversal photographic photosensitive material is disclosed comprising a support having thereon at least one red sensitive emulsion layer, at least one green sensitive emulsion layer and at least one blue sensitive emulsion layer, at least one hydrophilic colloid layer of said photographic photosensitive material containing a microcrystalline dispersion of at least one compound selected from the compounds represented by formulae (I), (II), (III), (IV), (V) and (VI), and at least one hydrophilic colloid layer of said photographic photosensitive material containing at least one compound represented by formula (VII):



    wherein A and A′, which may be the same or different, each represents an acidic nucleus; B represents a basic nucleus; and X and Y, which may be the same or different, each represents an electron attractive group; R represents a hydrogen atom or an alkyl group; R₁ and R₂ each represent an alkyl group, an aryl group, an acyl group or a sulfonyl group, or R₁ and R₂ are joined together to form a five or six membered ring; R₃ and R₆ each represent a hydrogen atom, a hydroxy group, a carboxyl group, an alkyl group, an alkoxy group or a halogen atom; R₄ and R₅ each represent a hydrogen atom or a group of non-metal atoms joined together with R₁ and R₂, respectively, to form a five or six membered ring; L₁, L₂ and L₃ each represent a methine group; m represents 0 or l, n and q each represent 0, 1 or 2, and p represents 0 or 1, and when p is 0, R₃ represents a hydroxy group or a carboxyl group and R₄ and R₅ each represent a hydrogen atom; B′ represents a heterocyclic group containing a carboxyl group, a sulfamoyl group or a sulfonamido group;
    said compound represented by formulae (I) to (VI) containing at least one dissociable group such taht the pKa value of the compound in a 1 : 1 by volume mixed solvent comprising water and ethanol is within the range of from 4 to 11:
    A-(Time)t-Z      (VII)
    wherein A represents a redox parent nucleus which eliminate -(Time)t-Z by oxidation during photographic development processing; Time represents a timing group which is bonded to A with a sulfur atom, a nitrogen atom, an oxygen atom or a selenium atom; t represents an integer of value 0 or 1; and Z represents a development inhibitor group.





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