[0001] The present invention relates to a continuous method for providing electroluminescent
lamps, and to lamps produced by said methods. The electroluminescent lamps are comprised
of a plurality of separate films having two major surfaces, each film including one
or more layers, beginning with a flexible plastic substrate. Laminating the aforesaid
films under heat and/or pressure yields effective electroluminescent lamps through
the employment of greatly simplified and less critical production techniques.
[0002] Flexible electroluminescent (EL) devices are well known in the art. For example,
U.S. Patent No. 4,684,353 discloses a flexible electroluminescent device including
a flexible plastic dielectric substrate which is successively provided on one major
surface thereof with an electroluminescent layer, a light-transmissive conductive
layer, and a layer comprised of a bus electrode; in addition thereto, the opposite
major surface of the plastic substrate is provided with a back electrode.
[0003] Each of these four layers is formed by successively passing the plastic substrate
through appropriate coating equipment. In the production of a lamp having multiple
coatings or layers, it is not uncommon to encounter registration problems which, if
not resolved, lead to a considerable waste of time, money, material, and effort. This
is especially so in the case of the electroluminescent and light-transmissive materials,
which are the two most expensive materials employed in the laminated product.
[0004] In addition, the plastic substrate of the example given above undergoes a minimum
of four coating operations which greatly increase the handling of the substrate as
well as increasing the possibility of introducing production problems which will result
in a defective and useless product.
[0005] Furthermore, the product produced according to the teachings of U.S. Patent No. 4,684,353
lacks good dimensional stability and, prior to being encapsulated, does not afford
protection for the electroluminescent phosphor which is sensitive to moisture; nor
does it afford protection of the electrodes from contamination or oxidation.
[0006] Thus, it is an object of this invention to provide solutions to the aforesaid production
problems, while also providing a new and improved electroluminescent lamp.
[0007] According to the present invention, a continuous method for simultaneously producing
a plurality of flexible electroluminescent lamp assemblies is characterised by:
(a) providing an elongated flexible back electrode sheet having a layer comprising
a plurality of elongated spaced substantially parallel back electrodes disposed thereon;
(b) providing an elongated flexible busbar sheet having a layer comprising a plurality
of elongated spaced substantially parallel busbars thereon, each of said busbars being
substantially parallel with a corresponding one of said back electrodes in the complete
assembly;
(c) disposing an electroluminescent phosphor layer having an overlying light-transmissive
conductive layer thereon between said elongated flexible back electrode sheet and
said busbar sheet;
(d) registering at least said elongated flexible back electrode and busbar sheets
with the phosphor layer therebetween; and
(e) laminating at least said elongated flexible back electrode and busbar sheets together
with the phosphor layer so as to provide electrical contact between said phosphor
layer and said busbar and to join said back electrode layer to said phosphor layer
thereby providing a plurality of flexible electroluminescent lamp assemblies.
[0008] In this method for producing flexible EL devices, the number of handling and/or coating
steps performed on any given plastic substrate is significantly reduced, and registration
problems are confined to those layers which are least expensive to produce.
[0009] Electroluminescent lamps produced by the method of the invention have excellent dimensional
stability, afford excellent protection of the busbar and back electrode from oxidation,
and provide a highly flexible structure from which lamps can be cut, stamped, perforated,
and printed upon without any additional surface treatment, while at the same time
providing lamps having an extremely long operating life and a high illumination level.
[0010] In a preferred embodiment, one major surface of a first thin plastic dielectric substrate
is coated with an electroluminescent phosphor. Although the aforementioned U.S. Patent
No. 4,684,353 discloses a preferred coating technique, any other suitable technique
may be employed. A thin transparent, semi-transparent, or translucent (herein "light-transmissive")
layer of electrically conductive material, which serves as a front electrode, is then
applied over the exposed surface of the electroluminescent phosphor layer.
[0011] A second flexible, light-transmissive, thin gauge plastic substrate is then, optionally,
coated in an independent operation on at least a part of one major surface thereof
with a suitable light-transmissive adhesive layer, preferably of the heat sealable
type. An electrically conductive busbar is coated over at least a portion of the exposed
surface of the substrate or adhesive layer.
[0012] A third flexible, thin gauge plastic substrate is at least partially coated or covered
on one major surface thereof in an independent operation with a back electrode layer.
An adhesive layer is then optionally applied upon any exposed, uncoated surface of
the substrate as well as the back electrode.
[0013] The busbar and back electrode, formed, respectively, on the second and third plastic
substrates, are carefully controlled as to size and orientation on their respective
substrates and are preferably aligned in registry with at least one edge of the associated
plastic substrate. The edges may be held in alignment mechanically, but optical sensors
reading the film or electrode edges will assure registration.
[0014] The above-mentioned films are then laminated together, e.g., employing heat and/or
pressure, with the films being aligned so that the busbar is in electrical contact
with the front electrode, i,e the light-transmissive conductive layer, and so that
the back electrode is joined with the remaining major exposed surface of the plastic
substrate supporting the electroluminescent phosphor layer.
[0015] The second and third, i.e. outer, films having the busbar and back electrode, respectively,
are preferably brought into registry by edge alignment or optical alignment of the
longitudinal edges of the conductive strips on the plastic substrates. Another method
of alignment is accomplished by optically sensing the back electrode and positioning
the busbar, in which case there need be no actual edge alignment of the films. Alternatively,
the second and third films are provided with mechanical alignment means, e.g., holes
along the edges through which alignment pins fit when the holes in the films are in
register. There are no registry problems whatsoever with respect to the first, middle
film, since the electroluminescent phosphor and light-transmissive conductive coatings
are substantially completely coincident with each other and with the plastic substrate
and thus have no unique orientation of one layer relative to the other, whereby the
problem of misregistration of the first film within the resulting laminated product
is eliminated.
[0016] The optional adhesive layer and busbar applied to the second plastic substrate are
preferably applied by a gravure technique. The conductive material for the busbar
may, for example, be a conductive ink such as a silver ink. The thickness of the adhesive
layer is a function of the cost and desired transparency of the adhesive, as well
as the bond strength required.
[0017] The back electrode and optional adhesive are applied to the third plastic substrate
in a substantially similar manner to that used to produce the second film incorporating
the busbar. Alternatively, the back electrode may be applied via a knife over roll
method, transfer roll, or conventional coating and in-line printing methods. As a
further alternative, the back electrode and adhesive and/or the busbar and associated
adhesive may be applied in reverse order from that previously described.
[0018] In a preferred technique for producing the aforesaid embodiment, the second, top
substrate is adhesive coated, dried and wound up into a roll. A silver ink busbar
is then applied and dried, and the second, top film is wound into a roll. The third,
bottom plastic substrate is silver ink-coated, dried and rewound. The adhesive is
then coated, and the third film is rewound. Both second and third film rolls are then
ready for the lamination process.
[0019] Since certain conductive inks, e.g., silver inks, contain sufficient resin to adhere
the third film containing the back electrode to the plastic substrate of the first,
middle film, the adhesive coating otherwise applied to the film containing the back
electrode may be omitted if desired when such inks are used. It is also possible to
omit the adhesive layer otherwise provided in the second film incorporating the busbar,
especially in applications where two or more spaced parallel busbars are provided
in the final product, the resin in the silver ink again can function as an adhesive.
[0020] As still another alternative embodiment, the process for producing the first, middle
layer incorporating the electroluminescent coating may be totally eliminated. The
adhesive coating in the third film incorporating the back electrode may be eliminated,
and the electroluminescent coating may be deposited directly upon the back electrode.
Thereafter, the conductive light-transmissive layer may be coated directly upon the
electroluminescent coating, thus increasing the number of coating steps on the third
substrate to a total of three, while totally eliminating the need for a first film
of the type employed in the preferred embodiment described above and, more importantly,
eliminating one adhesive coating step and one plastic substrate. It should be borne
in mind, however, that the aforesaid alternative requires that the dielectric strength
of the electroluminescent layer is high enough to support the electric field applied
across it.
[0021] In important variants of the aforesaid embodiments, a dielectric layer, other than
the plastic substrate mentioned above, can be interposed between the back electrode
and the electroluminescent phosphor layer. For example, the dielectric layer can be
introduced as a coating, rather than as the free-standing plastic substrate. As another
variant, the back electrode can be a free-standing, flexible, conductive foil, such
as aluminum foil, rather than a coating.
[0022] When all of the films to be utilized in the finished product have been completed,
lamination is performed by aligning the two outer films, i.e. the films containing
the busbar and back electrode, respectively, which alignment can be accomplished by
an edge guide or by alignment through the use of optical sensors. The films to be
laminated can be passed through the nip of a pair of heatable pressure rollers, and
the layers subjected to a temperature in a range from about 38 to about 175°C (about
100 to about 350°F) when hot melt adhesives are employed. The rollers preferably comprise
a heated roller and a cooperating pressure roller. The elevated temperature activates
the heat sealable adhesive. After lamination, the completed product is rolled on a
take-up roll.
[0023] The completed product, i.e., any of the lamp embodiments described hereinabove, preferably
utilizes films which are in the form of elongated sheets that can be rolled and processed
on conventional web-handling equipment. The product preferably incorporates a plurality
of spaced, parallel, elongated lamp structures. Each of the spaced, parallel lamp
structures may be cut away from the others. Lamps of any desired length may be provided
by cutting each of the individual elongated lamp strips to the desired length. Individual
lamps may be adapted for connection to a power source by coupling connector terminals
to the lamp structure. Completed lamp structures may be encased in a suitable vapor
barrier, resistant envelope which may, for example, be formed from a suitable vapor
resistant material, such as a halocarbon resin
[0024] As described in detail hereinafter, the production method of this invention eliminates
the need for the use of integral electrical connection tails, which must be separately
produced, and which further require providing adhesive coatings thereon to properly
adhere the metal-to-metal contacts of the lamp and the associated tails.
[0025] Individual lamps may be produced through a laminating process similar to that described
above. The electrodes utilized to produce small lamp structures can be printed upon
plastic sheets in a pattern incorporating a plurality of such electrodes, which electrodes
can either be cut out and then used in the assembly process or, alternatively, can
first be assembled with the other layers, whereupon the individual lamps may then
be cut away from the large sheet and provided with clincher-type terminals, for example,
and vapor resistant layers, if desired.
[0026] Although the back electrode is advantageously formed of a conductive ink as described
above for many applications, it may alternatively be formed of a metal per se, e.g.,
flexible metallic foils, such as aluminum, or vapor-deposited thin films which may
be produced thermally or by cathode sputtering, for example. In this regard, vapor-deposited
aluminum (VDAL) is inexpensive and conveniently employed. The VDAL or other back electrode
may be provided as a coating on the third plastic substrate or on the rear surface
of the first substrate supporting the light emitting layer. The VDAL may be deposited
as a continuous layer entirely coating its associated substrate or, alternatively,
may be formed into strips or other patterns. The VDAL provides a conductive back electrode
which is significantly lower in cost than a silver electrode.
[0027] Any flexible, electrically conductive, chemically stable, and light-transmissive
material may be employed as the conductive layer contacting the electroluminescent
phosphor layer. The conductive layer can be applied by solvent coating or from the
vapor phase, for example.
[0028] VDAL, and the other materials mentioned above in connection with back electrode materials,
may be used to produce the busbar. In this role, conductors such as metal, including
VDAL, or metal oxides may be directly deposited onto the transparent conductive layer
or separately coated onto a thin film, slit to a strip, and then laminated to the
light-transmissive conductive layer.
BRIEF DESCRIPTION OF THE DRAWINGS
[0029] Figure 1 is an enlarged, diagrammatic, partial end view of a plurality of films formed
and arranged in accordance with the principles of the present invention.
[0030] Figure 2 is a plan view taken along line 2-2 in Fig. 1 and which includes the laminated
structure of Figure 1.
[0031] Figure 3 is a simplified exploded view of the layers making up the laminated lamp
of Figs. 1 and 2.
[0032] Figure 4 is an exploded view of the combination registration and lamination means
utilized to produce individual lamp structures.
[0033] Figure 4a is a plan view of the arrangement shown in Figure 4.
[0034] Figures 5 and 6 are simplified diagrammatic views useful in explaining some of the
techniques which may be used to practice the present invention.
[0035] Figure 7 is an enlarged, diagrammatic, partial end view of an alternative lamp embodiment
made with the method of the present invention.
[0036] Figure 8 is an exploded isometric view of still another embodiment made with the
method of the present invention.
[0037] Figures 9 through 13 show enlarged, diagrammatic, partial end views of still other
embodiments made with the method of the present invention.
[0038] Figure 14 is an enlarged, diagrammatic, partial end view of yet another embodiment
made with the method of this invention.
DETAILED DESCRIPTION OF THE INVENTION
[0039] Figures 1-3 show a embodiment of the lamp assembly made with the method of this invention.
Fig. 1 is a greatly enlarged view of one of the preferred embodiments of the present
invention which comprises a structure formed of films 20, 30 and 40 which contain
various layers and are laminated together, preferably by heat and pressure, in a manner
to be more fully described hereinafter. Each of the individual layers and the manner
of its formation will now be described.
[0040] First film 20, which is the center or middle film of the laminated structure, may
be a commercially available product, such as set forth in U.S. Patent No. 4,684,353.
The film 20 is preferably formed of a suitable flexible substrate 22b, such as polyethylene
terephthalate (PET), for example, and carries a layer of light-emitting, electroluminescent
phosphor-containing material 22a. A light-transmissive conductive layer 24, e.g.,
metal oxide, is deposited upon layer 22a. Layer 24 serves as a light-transmissive
top electrode for the lamp. In an important variation, substrate 22b can be a suitable
coated dielectric material, rather than a free-standing plastic film, as described
hereinafter.
[0041] The transparent conductive layer referred to throughout the description of the invention
is preferably formed of indium tin oxide (ITO) ink or indium oxide (IO) ink, which
is typically ITO or IO in a resin and can be solvent-coated, but other well known
equivalents can be employed. At the thickness desired, these inks are not completely
transparent. Functionally equivalent materials include metals, such as silver, gold,
and aluminum, and metal oxides, such as tin and indium oxides, for example. Such materials
can be applied from the vapor phase by well known evaporation or cathode sputtering
techniques. For example, vapor-deposited aluminum (VDAL) may be employed as the conductive,
light-transmissive electrode.
[0042] A detailed description of the structure, composition and techniques employed for
producing film 20 are set forth in U.S. Patent No. 4,684,353. It is sufficient for
purposes of the present invention to understand that the film 20 is formed by passing
the plastic substrate 22b, which is preferably 6-35»m (0.25 mils) thick in one preferred
embodiment, through suitable coating means for application of the light emitting layer
22a, after which the substrate with the light emitting layer is air dried, generally
in a heated oven, and rolled up. Thereafter, a second coating operation is performed,
whereupon the conductive layer 24 is applied thereto. The light-transmissive conductive
coating may be evaporated or sputtered directly onto layer 22a or may be coated in
a resin. In the latter case, the layer is then air dried and the completed film is
then wound up in preparation for the lamination process.
[0043] Second film 30 is comprised of a flexible plastic substrate 32, which may preferably
be PET two mils thick. The PET layer may, if desired, be in a range from about 6.35
to to 127»m (about 0.25 to 5 mils) thick. If desired, commercially available polyesters
in a range from 50.8 to 635»m (2 to 25 mils) may alternatively be employed for substrate
32.
[0044] Although other flexible plastic substrates can be utilized, polyesters, e.g., PET,
are a preferred choice for substrate 32 in many instances due to their excellent transparency
characteristics and dimensional stability. Plastic substrate 32 can also be translucent
if desired, and it may be substantially colorless or deliberately dyed to be colored.
If substrate 32 is colored, the light emitted from the electroluminescent lamp will
be correspondingly affected. Other types of plastic substrates which can be employed
in any of the films include various thermoplastic films, such as polyolefins, e.g.,
polyethylene, poly(haloethylene), or polypropylene; cellulose derivatives, e.g., cellulose
acetate; vinyl polymers, such as poly(vinyl chloride); acrylic polymers, e.g., acrylate
or methacrylate esters; as well as copolymers including monomers similar to those
cited. Among these various alternatives, poly(haloethylenes), such as poly(trichlorofluoroethylene)
are especially attractive, because of their low vapor transmission rates. Such plastic
film substrates are available in commerce; e.g., ACLAR is a trademark of Allied Chemical
Co., and KEL-F is a trademark of 3M Co. for such materials.
[0045] An adhesive layer 34 is optionally formed on one major surface of plastic substrate
32. The adhesive can be either hot melt or solvent coated. The preferred class of
adhesives is heat sealable adhesives having an activation range of the order of about
38 to 175°C (about 100 to about 350°F).
[0046] The adhesives employed are preferably polyester adhesives such as, for example, the
National Starch Duro Lam 30-9103 adhesive. However, any other adhesive may be employed
which is suitable for joining film 30 to film 20. The above objectives and materials
are also appropriate for the adhesive employed in film 40, as will be more fully described
hereinbelow.
[0047] For certain lamp applications it may be advantageous to include a dye in the adhesive
in order to control the color of the light emitted from the lamp. Adhesive thickness
is preferably in a range from about 0.0254 to about 254»m (about 0.001 to about 10
mils), with the thickness selected being a function of bonding strength and opacity,
it being understood that since the light from the lamp will pass through film 30 it
is desirable to minimize the opacity of the adhesive layer.
[0048] A variety of coating techniques may be employed to apply the adhesive 34 to plastic
substrate 32, including the gravure technique, the Mayer rod technique, and the reverse
roll-offset technique. The gravure technique is the preferred technique and employs
a gravure roller which, together with a second roller forms a nip through which plastic
substrate 32 passes.
[0049] As a further alternative, the adhesive employed may be of the pressure sensitive
type. Pressure sensitive adhesives have the disadvantage, as compared with heat sealable
adhesives, of requiring a protective cover sheet in the event that the web is wound
up prior to performance of the next step in the lamp producing process. The protective
strip may be eliminated if the layer is directly fed to the laminating station.
[0050] The adhesive is applied to the plastic substrate 32 which is preferably in the form
of an elongated web passing through the coating nip. The coated substrate is passed
through an oven to be dried, and the web is rewound in preparation for application
of the busbar 36. The busbar 36 is preferably formed of silver and may be applied
directly to the adhesive using a smooth gravure roller having circular cuts or channels
arranged at spaced longitudinal intervals about the surface of the gravure roller
with the width and spacing of the aforesaid channels being selected according to the
desired width and spacing between the busbars 36 as shown in Figure 2. Figure 5 shows
a gravure roller 52 forming a nip N with a smooth roller 54. Gravure roller 52 is
provided with the plurality of grooves or channels 52a having a width and interval
spacing selected to obtain a desired width and spacing of the busbars 36 in applications
where it is desirable to form a plurality of individual laminated lamps across the
width of the film 30.
[0051] The busbar layer 36 is preferably formed of a conductive ink such as a silver ink.
One suitable commercially available silver ink is produced by the Olin Hunt Corporation
and identified by the designation ADVANCE 725A. The silver ink is preferably modified
by dilution with 10 to 15 percent cyclohexanone. The silver ink and cyclohexanone
are thoroughly mixed and the resulting homogenous composition is delivered to the
channels 52a of gravure roller 52 for forming spaced strips of the type shown as layers
36 in Figure 1 along the film 30, as also shown in Figure 2. The gravure process does
not require any special temperature conditions and may be employed at room temperature.
[0052] Although the ADVANCE 725A silver ink has been found to provide a flexible busbar
having good conductivity, other silver inks may be employed. Such silver inks are
available from Olin Hunt Corporation, DuPont Corporation and Acheson Colloids Incorporated
as well as numerous -other producers of silver ink. Alternatively, other conductive
inks or conductive liquids may be employed, such as graphite-containing inks, as well
as blends of silver and graphite. In addition, vapor-deposited metals or metals deposited
by chemi-deposition can be utilized. Selection of the conductive material is tempered
by a requirement for good adhesion.
[0053] No surface treatment is usually required preparatory to coating the busbar 36 upon
the adhesive layer 34. In addition, since the busbar 36, in one preferred embodiment,
contains resin which will adhere to the surface of layers 24 and 32 using a lamination
process employing heat and pressure, the adhesive layer 34 may be omitted, especially
in those instances where a plurality of spaced parallel busbars 36 are provided in
film 30. This lamination process is then similar to the above-mentioned process but
frequently employs higher temperatures and longer dwell times which are dependent
upon the resins used by the manufacturers in the production of their conductive materials.
However, the films 20 and 30 may come apart in the regions containing no busbar when
the individual lamp strips are cut away from the laminated webs.
[0054] As the busbar(s) is(are) formed on the substrate 32 or upon the adhesive 34, the
film 30 is passed through an oven to be air dried and then rolled up in readiness
for the final lamination process.
[0055] Third film 40 is preferably comprised of a 50.8»m (2 mil) thick, flexible PET plastic
substrate 42 chosen due to its excellent stability and flexibility characteristics.
However, any other suitable plastic material may be employed, such as those mentioned
hereinabove. The substrate 42 need not be transparent or even translucent and may
be opaque, since light is emitted through the film 30.
[0056] A back electrode layer 44, which may be silver ink, is formed on one major surface
of substrate 42. Back electrode 44 may be formed utilizing the same composition used
to form the busbar 36 of film 30. A slotted knife reverse roll technique is preferably
utilized to apply the back electrode layer directly to substrate 42. No surface treatment
of substrate 42 is required ordinarily preparatory to application of the back electrode
44.
[0057] The slotted knife reverse roll technique employs a knife provided with slots having
a width and spacing relative to the adjacent slots to form back electrodes 44 of a
width and spacing as shown, for example, in Figure 2.
[0058] After the coating forming the back electrode(s) is applied, the web is passed through
an oven and air dried. Substrate 42 with layer 44 is then either rolled up preparatory
to the next coating operation or, alternatively, the web may pass directly through
an adhesive application station. The size and shape of the back electrode determines
the size and shape of the light emitting area, so it will be evident that various
lighted patterns can be created thereby.
[0059] The application of adhesive layer 46 to back electrode 44 is preferably similar to
the techniques employed for coating substrate 32 with adhesive layer 34. In addition,
the class of adhesives and thicknesses utilized are preferably chosen in the same
manner as outlined hereinabove for adhesive layer 34. Electrode 44 requires no surface
treatment preparatory to receiving the adhesive layer. The opacity of the adhesive
layer is not of great concern, since light is not normally emitted through electrode
44, but the layer should be as thin as possible.
[0060] As an alternative, the adhesive layer 46 may be totally eliminated if desired, provided
there is sufficient resin in back electrode 44, e.g., silver ink, to adhere film 40
directly to film 20. the adhesive layer can be eliminated in the production of film
40 since the back electrode 44 typically has sufficient surface area to provide good
adhesion between back electrode 44 and the adjacent plastic substrate of film 20.
On the other hand, only where film 30 is formed with a plurality of silver busbars
36 (note Figure 2) should the adhesive layer 34 be eliminated. If film 30 includes
a single busbar, the laminated films 20 and 30 would pull apart due to the large unbound
surface area between layers 24 and 34.
[0061] As another alternative, either or both of back electrode layer 44 and adhesive layer
46 can be applied to first plastic substrate 22b, rather than to third plastic substrate
42. Also, the order of forming the adhesive and silver busbar layers 34 and 36 upon
plastic substrate 32 may be reversed, if desired, the adhesive layer generally being
of a thickness which does not have a significant effect on the electrical conductivity
path between conductive layer 24 and busbar 36.
[0062] The final lamination process preferably is performed by placing each of the completed
films 20, 30 and 40 upon rotatable supply rollers R₁-R₃ for delivering the webs to
a pair of nip rollers 56 and 58 as shown in Figure 6. One of said rollers typically
is a hot roller and is preferably formed of a resilient compressible material or of
a metallic core material having an outer layer of a resilient compressible material
or other suitable roller composition. The nip N is maintained under pressure by urging
the rollers toward one another. The hot roller generally is heated to a level sufficient
to maintain a temperature in the range between about 38 to about 175°C (about 100
to about 350°F) to activate the heat sealable adhesive(s).
[0063] Preparatory to lamination, the films 30, 20 and 40, arranged on feed rollers R1,
R2 and R3, respectively, are brought into proper registry by aligning the film edges,
or the conductive strips of films 30 and 40. There is no criticality in the alignment
of the intermediate film 20 relative to films 30 and 40, since the phosphor and light-transmissive
conductive layers 22a and 24, respectively, generally are coextensive with the width
of their associated substrate. Alternatively, the films 30 and 40 may be aligned by
employing an edge guide arranged along one edge, such as, for example, a left hand
edge, of the laminating equipment. Other means of controlling film alignment have
been described earlier. The resulting laminated structure is then wound up upon a
take-up roll.
[0064] The resulting product, which includes layers of three plastic substrates, exhibits
excellent dimensional stability. The substrates 32 and 42 serve to protect the busbar
and back electrodes 36 and 44, respectively, and prevent these electrodes from oxidizing,
which is extremely important.
[0065] The finished product is flexible and can be cut, stamped and perforated with ease.
Either of the exposed surfaces of layers 32 and 42 can be printed upon without any
additional surface treatment. Printing on either exposed surface may be performed
using a gravure or offset technique, and the exposed surfaces may even be painted
using paint applied directly to the exposed surface by spraying or even by an artist's
brush. The layers 32 and 42 serve as excellent substrates for use with light-transmissive
inks.
[0066] In addition to the use of clear transparent film to form layers 32 and 42, as mentioned
hereinabove, the film can be dyed or mixed with a dye to produce light of different
colors. If desired, the dye may also be added to and mixed with the adhesive, e.g.,
adhesive 34. The film may be either transparent or translucent, if desired. Since
the back electrode 42 generally renders back layer 40 substantially opaque, the dye
need only be admixed with either layer 32 or adhesive 34 or both, if desired.
[0067] Figure 2 shows the completed laminated structure of which Figure 1 is a part. The
busbars 36 and the back electrodes 44 are arranged in spaced parallel fashion and
are substantially parallel to the longitudinal direction of the web. Electrodes 36
and 44 are non-overlapping. The spacing S between adjacent front and back electrodes
is preferably of the order of 1.27mm (0.050 inches). However, any other suitable spacing
may be employed if desired. The spacing S₁ between the left-hand edge of each busbar
36 and the right-hand edge of the back electrode associated with the next lamp may
be significantly greater than spacing S and is utilized to sever adjacent lamp strips
from one another. For example, the two right-hand-most lamp strips may be severed
from the composite web by cutting along dotted lines D₁ and D₂. The right-hand portion
of the right-hand-most strip may be trimmed by cutting along line D₃, for example,
so as to provide elongated lamp strips of substantially uniform width.
[0068] After the lamination and cutting operations have been performed, each of the individual
elongated strips may be cut to any desired length and electrically coupled to a suitable
power source, for example, through the employment of a puncture connector such as,
for example, a Berg clincher-type connector produced by DuPont. Other connectors such
as pressure type insertion type connectors can be used for establishing an electrical
connection between the lamp and a power source. The lamp is advantageously designed
to be powered by a conventional 115 volt 60 cycle AC source but may be powered at
a wide variety of voltages and frequencies, if desired. The strips may be of any desired
length and may be placed upon flat or curved surfaces without effecting their ruggedness,
light intensity and useful operating life.
[0069] Figure 7 shows an alterative embodiment of the lamp assembly in which the fabrication
of film 20 of Figures 1-3 is substantially eliminated as will be described and wherein
the layers 22a and 24 are formed as part of a film layer 40′, totally eliminating
plastic substrate 22b and adhesive 46. Noting, Figure 7, film 40′ is modified from
film 40 of Figure 1 by application of the phosphor coating 22a directly upon the back
electrode 44, in turn carried on substrate 42. The adhesive layer 46 employed in layer
40 of Figure 1 is eliminated, and conductive layer 24 is applied directly upon phosphor
layer 22a.
[0070] The modified structure of Figure 7 eliminates the need for a separate film 20 and
hence eliminates the preparation of film 20 per se and also reduces the total number
of process steps. Layer 30 of Figure 7 is formed using the same materials and process
steps as layer 30 of Figure 1. Layer 40′ requires the performance of the additional
steps of forming a phosphor layer 22a upon the back electrode 44 and forming the conductive
layer 24 upon phosphor layer 22a. However, the step of applying adhesive layer 46
in the formation of film 40 (see Figure 1) is eliminated. In addition, the plastic
substrate 22b employed as part of film 20 (see Figure 1) is totally eliminated, thereby
reducing the overall cost of the laminated structure shown in Figure 7 as compared
with the laminated structure shown in Figure 1. The finished product will be substantially
the same in appearance, looking down upon the top surface as shown in Figure 2, as
the finished product of Figs. 1-3. The major disadvantage of the embodiment shown
in Figure 7 resides in the fact that the most expensive layer of the laminated structure
shown in Figure 7 is film 40′. In the event that there is any misregistration of the
busbar 36 or back electrode 44 in the embodiment of Figure 1, film 20 is nevertheless
protected and will not result in an expensive waste of material. On the other hand,
any misregistration problems in the formation of film 40′ will result in waste of
the most expensive portions of the structure. Exertion of careful quality control
in the formation of the films 30 and 40′ will significantly reduce such waste, making
the embodiment of Figure 7 a practical alternative to that shown in Figure 1.
[0071] Fig. 14 represents an important variation of the aforesaid lamp structures in which
a back electrode 44, which is preferably a metal foil, e.g., an aluminum or copper
foil, about 0.0254-0.762mm (about 0.001-0.030 in.) thick, is contacted with a dielectric
layer 22c. The dielectric layer may be a free-standing flexible film, but preferably,
dielectric layer 22c is coated onto back electrode 44 from solution. The dielectric
material may itself be or may contain an organic resin, but inorganic dielectric materials
are advantageously incorporated into dielectric layer 22c. Suitable inorganic dielectric
materials include metal oxides, such as zinc and titanium oxides, for example; or
various metallic titanates, such as barium or strontium titanates, for example. A
preferred inorganic dielectric material is barium titanate, which, for coating purposes,
is advantageously mixed with the same resins employed in the electroluminescent phosphor
layer as disclosed in U.S. 4,684,353, incorporated herein by reference. However, other
resins, such as cyanoethylated resins, may be employed and are preferred in some applications.
It is preferred that dielectric layer 22c be as thin as reasonably possible, e.g.,
about 20-100 microns thick when dried.
[0072] After application of dielectric layer 22c to back electrode 44, electroluminescent
phosphor layer 22a and transparent conductor 24 are added, substantially as described
hereinabove. Although busbar layer 36 can be added to the construction in other ways,
it is convenient to coat busbar 36 directly upon transparent conductor 24. The lamp
assembly is completed by securing flexible plastic substrates 32 and 42 to the assembly
as shown in Fig. 14, either by including one or both of adhesive layers 34 and 46,
or, preferably, by omitting layers 34 and 46. In the latter event, plastic substrates
32 and 42 are fused together by heat-laminating the entire assembly. For these purposes
it is preferred that plastic substrates 32 and 42 be poly(haloethylene) films, such
as ACLAR.
[0073] The laminated product shown in Figure 7 or in Figure 14 may be cut in a manner similar
to that shown in Figure 2 to produce individual lamp strips of any desired length
and coupled to electrical power through the use of any of the aforementioned terminal
connectors.
[0074] If desired, the completed laminated structure may be enclosed within suitable vapor
barrier layers secured to opposite sides of the laminated lamp structure. One suitable
vapor barrier material is known by the registered trademark ACLAR as described hereinabove;
see U.S. Patent No. 4,684,353. However, any other suitable vapor barrier layers may
be employed.
[0075] Figures 9 through 13 show still other preferred embodiments of the present invention
in which vapor deposited aluminum (VDAL) is employed for the material of the back
electrode. Noting, for example, Figure 9, film 30 is substantially identical to film
30 of Figure 1. Film 40‴ is comprised of a plastic substrate 42 and an adhesive layer
46. The light-emitting film 20˝ is substantially the same as film 20 of Figure 1 in
that is includes conductive layer 24, phosphor layer 22a, and plastic substrate 22b.
In addition thereto, a vapor deposited aluminum layer (VDAL) 70 is formed on the underside
of substrate 22b. When VDAL is formed on the underside of layer 22b the protective
film 40‴ may be used.
[0076] Alternatively, film 40‴ may be omitted, if desired. These layers are laminated together
in the same manner as the layers of Figure 1, adhesive layers 34 and 46 preferably
being the heat sealable type.
[0077] The structure of Figure 10 more clearly resembles the embodiment of Figure 1 in that
films 30 and 20 are substantially the same as those shown in Figure 1 and wherein
the film 40‴′ is formed by initially producing a VDAL layer 70 directly upon one surface
of substrate 42 and then depositing an adhesive layer 46 upon the VDAL layer 70. The
films of Figure 10 are then laminated together in a manner similar to that described
for Figure 1.
[0078] Film 30 of Figure 11 is substantially identical to film 30 shown in Figure 9. The
intermediate and bottom films 20˝ and 40‴ of Figure 9, for example, are substantially
eliminated and replaced by a composite layer 20‴ comprised of a VDAL layer 70 deposited
upon plastic substrate 22b. In the embodiment of Figure 11 the plastic substrate 22b
is preferably 2 mils thick. A phosphor layer 22a is formed upon VDAL layer 70 and
a conductive layer 24, e.g., either ITO (indium tin oxide) or IO (indium oxide), is
deposited upon phosphor layer 22a. The films 20‴ and 30 are laminated together using
the preferred technique described hereinabove.
[0079] The structure of Figure 12 comprises a layer 40‴′ substantially identical to layer
40‴′ of Figure 10 in that it is comprised of plastic substrate 42, VDAL layer 70,
and adhesive layer 46. A layer 30˝ comprised of plastic substrate 32, busbars 36,
ITO layer 24, which is formed by either a coating operation such as a gravure coating
or sputter coating operation, and a phosphor layer 22a, is laminated to layer 40‴′
using the preferred technique described above.
[0080] The VDAL layer may be a continuous, uniform layer as shown in Figures 9 through 12,
or alternatively may be formed in elongated strips as shown by Strips 70a, 70b, and
70c making up VDAL layer 70 of film 40‴˝ in Figure 13, which layer 70 is arranged
between plastic substrate 42 and adhesive layer 46. The VDAL layer of any of the embodiments
in Figures 9 through 13 provides a back electrode of excellent conductivity while
significantly reducing the material and processing costs as compared with those encountered
in the production of the conductive ink back electrodes described above and especially
the back electrodes formed using silver ink.
[0081] The transparent conductive coating 24 of any of the embodiments described also may
be formed of VDAL of a thickness selected so as to allow at least a portion of the
light emitted by the phosphor layer 22a to pass through the VDAL.
[0082] The VDAL may also be used as a busbar by forming VDAL upon a plastic substrate. The
substrate is then cut into strips and laminated to a conductive transparent layer.
[0083] Figure 4 shows still another embodiment of the present invention which is utilized
for producing individual lamp structures, as opposed to a plurality of lamp strips
described and shown, for example, in Figures 1-3, 7 and 14.
[0084] The film 30′ of Figure 4 differs from the film 30 shown in Figure 1 in that a substantially
J-shaped busbar 36′ is formed on the underside of the plastic substrate 32a. Film
30′ further may also include an adhesive layer, not shown for purposes of simplicity,
but which is substantially the same as adhesive layer 34 shown in Figure 1.
[0085] Film 40˝ of Figure 4 differs from films 40 and 40′ of Figures 1 and 7, respectively,
in that the back electrode 44′ is provided with an integral trace or tail T2 electrically
connected with the back electrode and extending toward the right-hand edge 42a of
plastic substrate 42. A tail T1 is arranged in spaced parallel fashion with tail T2.
Film 40˝ may be further provided with an adhesive layer, not shown in Figure 4 for
purposes of simplicity, but which is substantially the same as the adhesive layer
46 employed, for example, in the embodiment of Figure 1.
[0086] The substrates 32 and 42 of films 30′ and 40˝ are further provided with alignment
holes 32b and 42b, respectively, pairs of said alignment holes preferably being arranged
on opposite sides of the electrodes 36′ and 44′ in the manner shown. The films 20,
30′ and 40˝ are positioned upon an assembly jig 60 comprising a surface 62 having
a plurality of registration pins 64 adapted to extend through the registration openings
32b and 42b in order to place layers 30′ and 40˝, and specifically the busbar and
back electrode, in proper registration. Film 40˝ is placed upon surface 62 with openings
42b each receiving one of the associated pins 64.
[0087] Film 20 (see Figure 1) is then placed upon the top surface of layer 40˝ so that its
left-hand edge 20a rests against stop 66 provided upon surface 62. The width W of
layer 20 is preferably just slightly less then the distance D3 between the pins 64
arranged along opposite longitudinal sides of surface 62. Positioning of film 20 relative
to layer 40˝ (as well as layer 30′) is not critical for the reasons set forth hereinabove
so long as film 20 is substantially coextensive with the front and back electrodes
36′ and 44′.
[0088] Finally, film 30′ is placed upon film 20 so that each of its openings 32b receives
one of the associated pins 64. The films are now in proper alignment.
[0089] Figure 4a shows a top plan view of the films 30′, 20 and 40˝ mounted upon the alignment
pins and in proper registry. Tail T1 electrically engages the right hand portion 36a′
of busbar 36′. If desired, the films may be placed upon the alignment pins in the
reverse order, i.e. film 30′ first; then film 20, then film 40˝. The films are laminated
together utilizing, for example, a platen provided with alignment holes, each receiving
one of the associated alignment pins 64. The platen may be pressed downwardly upon
the assembly. Either the platen or surface 62 may be heated by suitable heating means
to a temperature, preferably in a range between about 38 and about 175°C (about 100°
and about 350°F) to activate the heat sealable adhesive or resin. The above procedure
may be semi- or fully automated for a continuous web operation.
[0090] Noting Figure 8, films 30′ and 40˝ of Fig. 4, may be elongated webs provided with
alignment openings 32b, 42b arranged in the longitudinal sides of the elongated webs
at regularly spaced intervals. One of the rollers 56, 58 (see Figure 6) may be provided
with alignment pins 58a, for example, which enter into cooperating openings (not shown)
in roller 56 and which enter the alignment openings in films 30′, 40˝ to maintain
the busbars and back electrodes in registry. The light emitting film 20 (Figure 8)
has a width slightly less than the spacing between the alignment pins. The nip may
be heated to activate heat sealing resin(s). The finished lamp assemblies may then
undergo a die cutting operation, which may also be an assembly of cooperating rollers
located downstream relative to the laminating nip and the drying station.
[0091] Alternatively, the films may be advanced by pinch rollers engaging the opposite longitudinal
sides of the films to be laminated. Optical means (not shown) can detect registration
marks and halt feeding of the films through the laminating nip if a misregistration
condition is detected.
[0092] The films may be sealed in the above manner and then die cut. The die cutting may
be either a separate process step or may be incorporated in the heat sealing operation,
for example, by providing a suitable groove in surface 62 (Figure 4) for receiving
a cutting edge, said cutting edge being of a rectangular shape for cutting away the
unused outer marginal portion of the laminated structure. The traces or tails, aligned
on the same side of the back electrode 44˝, provide optimum connector contact.
[0093] The laminant of Figs. 4, 4a and 8 totally seals the phosphor, busbars, and back electrodes
between plastic substrates 32 and 42 to protect these layers from contamination and
oxidation. Traces T1 and T2 are preferably terminated at a point slightly inward from
the edge El of the laminated structure shown in Figure 4a in order to likewise be
totally sealed. A puncture connector can then be aligned and pressed into position.
The connector may, for example, be a Berg Clincher (TM) connector produced by DuPont.
Alternatively, pressure-type or insertion-type connectors may be employed as suitable
alternatives.
[0094] The technique just described eliminates the need for separate conductive tails employed
in prior techniques, which are prepared in a separate operation, and which further
require the application of an adhesive to be applied to and properly adhere the metal-to-metal
contacts between the laminated structure of Figure 4a and the aforementioned conductive
tails.
[0095] The individual electroded films 30′ and 40˝ may be produced one-at-a-time as in Fig.
4, or, alternatively, a plurality of the electrodes may be produced using a large
plastic substrate having a plurality of electrode patterns arranged upon the sheet
in a regular fashion as shown in Figure 8. These patterns can then be individually
cut out and assembled in the manner shown in Figures 4 and 4a. Alternatively, the
sheets containing a plurality of the busbars and electrodes, respectively, may first
be assembled together using a registration and alignment technique as shown in Figures
4 and 4a, whereupon all of the individual lamp structures are laminated in one operation
and thereafter are separated into individual lamps by a cutting operation. The films
30′ and 40˝ may be aligned using the alignment pins and cooperating alignment holes
of Figures 4 and 4a, or an optical alignment technique if desired.
[0096] The advantages of the system employing films 30′ and 40˝ in the embodiment shown
in Figures 4 and 4a, as well as the embodiment shown in Figures 1-3 reside in the
fact that any misregistration or any other errors encountered in the production of
films 30 and 40 do not result in the expensive layer 20 being discarded due to the
formation of a defective or misaligned busbar and/or electrode layer.
[0097] A latitude of modification, change and substitution is intended in the foregoing
disclosure, and in some instances, some features of the invention will be employed
without a corresponding use of other features. For example, the technique of Figures
4 and 4a may be used to laminate the films shown in Figures 7 and 14. Accordingly,
it is appropriate that the invention herein described be construed in a manner consistent
with the scope of the appended claims.