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(11) | EP 0 462 504 A3 |
(12) | EUROPEAN PATENT APPLICATION |
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(54) | Process for coating finely divided material with titania and moisture insensitive zinc sulfide luminescent materials made therefrom |
(57) A method for coating finely divided material with titania is disclosed. The method
involves the fluidization of the finely divided material (16) in an inert carrier
gas containing vaporized titanium isopropoxide. The isothermal fluidized bed (15)
is kept at a temperature equal to or below approximately 300°C. The vaporised titanium
isopropoxide reacts to form a coating of titania on the surfaces of the particles
(16) within the fluidized bed (15). The greatest coating efficiency occurs when the
fluidized bed is kept at approximately 300°C for approximately the first 10 minutes
of the reaction and thereafter at approximated 250°C. The titania coating process
is particularly useful for electroluminescent phosphors such as copper doped zinc
sulfide phosphor. The titania coated electroluminescent phosphors are relatively insensitive
to moisture. Lamps made from the coated electroluminescent phosphor are also relatively
insensitive to moisture. |