BACKGROUND OF THE INVENTION
Field of the Invention:
[0001] The present invention relates to methods of applying coating compositions. More specifically,
the present invention relates to techniques for enhancing the surface uniformity of
an applied coating.
[0002] While the present invention is described herein with reference to illustrative embodiments
for particular applications, it should be understood that the invention is not limited
thereto. Those having ordinary skill in the art and access to the teachings provided
herein will recognize additional modifications, applications, and embodiments within
the scope thereof and additional fields in which the present invention would be of
significant utility.
Description of the Related Art:
[0003] The external appearance of a finished vehicle depends in large part on the quality
of the coating of paint applied thereto. In particular, certain irregularities in
the painted surface of an automobile reflect light in such a manner as to exhibit
an "orange peel" texture upon close examination.
[0004] Automobile manufacturers have heretofore relied on the surface tension of the applied
paint coating to relax the ripples creating such an orange peel texture. Although
relying exclusively on surface tension to reduce paint surface irregularity is time
consuming, early painting processes were of sufficient duration to allow this technique
to be of some utility. However, advances in automated automobile production have substantially
reduced the time accorded the painting process. As surface tension relaxation of orange
peel ripples typically consumes on the order of twenty hours, use of this technique
has become impractical in automated systems.
[0005] Automobile manufacturers have also attempted to diminish the "orange peel" effect
by adding organic material to the paint prior to application. The organic additives
are utilized to reduce the viscosity of the paint. As a result of this lowered paint
viscosity, ripples in the surface of paint coatings supplemented by organic additives
subside more readily due to surface tension than do ripples subsisting on the surface
of higher viscosity coatings.
[0006] Unfortunately, the organic additives commonly employed to lower paint viscosity are
relatively volatile. This volatility results in the dissemination of the additives
into the atmosphere during application. As the additives contribute to pollution,
the additives have become subject to governmental restriction. Moreover, such low-viscosity
paints tend to "slump" when applied to vertical surfaces due to the force of gravity.
[0007] Hence, a need exists in the art for a time-efficient method for smoothing the surface
of an applied coating composition without resorting to the use of organic additives.
SUMMARY OF THE INVENTION
[0008] The need in the art for a time-efficient method for smoothing the surface of an applied
coating composition is addressed by the technique of the present invention which involves
the generation of electrically charged particles in a volume of space adjacent to
the coating surface. The charged particles cause an electric field to develop across
the viscous coating composition, which induces the charged particles to exert pressure
on the coating surface. Hence, the technique of the present invention, employed subsequent
to the application of a coating composition to an electrically conductive object,
expedites the subsidence of coating surface irregularities.
BRIEF DESCRIPTION OF THE DRAWINGS
[0009] Fig. 1 is a diagram of a simplified, illustrative embodiment of an apparatus utilized
to effect the ripple reduction technique of the present invention.
[0010] Fig. 2 is a magnified cross-sectional view of the coating composition and automobile
surface.
[0011] Fig. 3 is a diagram of an illustrative representation of a preferred embodiment of
the ripple reduction apparatus of the present invention.
DESCRIPTION OF THE INVENTION
[0012] Fig. 1 is a simplified, illustrative embodiment of an apparatus 10 utilized to effect
the coating surface irregularity reduction technique of the present invention. As
will be described more fully below, the apparatus 10 includes a conductive needle
12 which induces an ionic discharge in the atmosphere surrounding the point 13 thereof.
The charged ionic particles created by the discharge subsequently follow electric
field lines 14 to reach a surface 20 of a coating composition 22. The charged particles
expedite the subsidence of irregularities on the surface 20, such as the ripples R1
and R2, by exerting electrostatic pressure thereon.
[0013] Prior to precipitation of the ionic discharge the coating 22 is applied by conventional
means to a grounded, electrically conductive automobile surface 24. In the embodiment
of Fig. 1 the coating 22 is clear (contains no pigment), and covers a previously applied
pigmented base coat (not shown). As shown in Fig. 1, the coating 22 has not yet solidified
following application to the automobile surface 24, and resides thereon in a viscous
liquid state.
[0014] The apparatus 10 includes a negative high voltage source 30. In the preferred embodiment,
the voltage source is capable of providing up to -100 kV. An isolating resistor 34
is electrically coupled to the source 30 and serves to constrain the amount of current
flowing to the needle 12. In the preferred embodiment, the resistor 34 is chosen to
have a value on the order of 10⁶ ohms to achieve the desired current level. The needle
12 may be realized from an electrical conductor, such as tungsten, having a sharpened
point 13. The radius of curvature of the needle point 13 is chosen in conjunction
with the value of the voltage source 30 such that the electric field produced by the
needle 12 is sufficient to ionize the atmosphere.
[0015] The parabolic relation between corona current and voltage is expressed by:
where i is the current, v is the voltage and A and M are experimentally determined
constants.
[0016] An empirical relation developed by J. W. Peck and published in "Dielectric Phenomena
in High Voltage Engineering" McGraw-Hill (1929) is useful for expressing the maximum
surface stress for the onset of corona in air for several geometries of radius r cm.
For spheres
where δ is the density of air relative to that at 25°C and 1 atmosphere. For a point-plane
electrode system, the relation between field strength E and voltage v is E = v/d.
Thus, the field strength which initiated corona (at the negative sphere) given by
Equation [2] can be used to find M in equation [1]:
[0017] To determine the practical limits down to which the radii of points can be taken,
consider that it has been shown that a very small crystal of ten whiskers (10⁻⁴ cm
in diameter) can tolerate extremely large strains in bending without plastic deformation.
Thus, radii of curvature down to 10⁻⁴ cm can be used in equation [3] which then gives,
for atmospheric density in air, M = 0.15 kv. An upper limit is set by the practical
need for a large working voltage range between the onset of corona and the onset of
spark breakdown which cooks and hardens the paint in isolated spots ruining the finish.
The available working voltage range decreases rapidly from well over 100 kv at small
radii to zero at a few cm radius. A large voltage range is needed in order to control
the current which increases rapidly with voltage. A practical choice for the illustrative
embodiment was r ≈ 0.1 cm. at which M = 7.4 kv.
[0018] Fig. 2 is a magnified cross-sectional view of the coating composition 22 and an automobile
surface 24 at ripple R1. As shown in Fig. 2, negative ions 40 are created by ionization
of the atmosphere surrounding the needle 12 (not shown). As a result of the presence
of the negative ions 40, a positive charge (+) accumulates on the conductive surface
of the automobile 24. Hence, an electric field, denoted by the electric field lines
14, is set up between the ions 40 and the automobile surface 24. The ions 40 follow
the field lines 14 to the surface 20 of the coating 22, at which point the ions 40
exert a force F upon the surface 20. The force F acts in conjunction with the inherent
tension of the surface 20 to expedite the subsidence of the ripple R1, thereby enhancing
the uniformity of the surface 20.
[0019] In practice, the coating composition 22 typically has a breakdown field strength
in excess of 10⁵ V/cm, and a dielectric permittivity of three. At this field strength,
the electrostatic pressure exerted on the surface 20 due to the ions 40 is approximately
1.3 x 10⁴ dynes/cm². In contrast, given that ripple R1 has a height of 10µm, width
of 0.5 cm, and surface tension of 30 dyne/cm (typical parameters for an "orange peel"
ripple) the pressure exerted on the surface 20 due to inherent surface tension is
only approximately 1 dyne/cm². The present invention is therefore operative to expedite
the subsidence of coating surface ripples by increasing the pressure exerted thereon.
[0020] The following expression may be utilized to estimate the time (T) required for subsidence
of a coating surface ripple:
where λ is the period of surface ripples, N is the coating viscosity, E is the electric
field strength at the coating surface, ε is the dielectric permittivity and X is the
coating thickness. Using the parameters of λ = 0.5 cm, N = 1 poise, E = 300 volts/cm
and X = 25µm yields a ripple subsidence time T of approximately 44 seconds. As mentioned
in the Background of the Invention, reliance on the pressure exerted by the inherent
surface tension of the coating to effect a substantial reduction in ripple size may
take up to twenty hours. The present invention thus substantially reduces the time
required to induce subsidence of coating surface irregularities.
[0021] Fig. 3 shows an illustrative representation of a preferred embodiment of the ripple
reduction apparatus 100 of the present invention. The apparatus 100 includes a system
controller 110, which is electrically coupled to a high voltage source 120 via a signal
line 125. The controller 110 may be implemented with a digital computer, and the signal
line 125 allows the controller to switch the polarity and magnitude of the voltage
of the source 120. The source 120 is electrically coupled to an ammeter 130 through
a supply line 135. The ammeter 130 gauges the current flowing from the supply line
135 to a supply line 140, and thereby measures the aggregate current consumption of
an array of conductive needles 150. The array of needles 150 is typically two dimensional,
although only a single dimension is depicted in Fig. 3. The needle array 150 is mechanically
coupled to a robot arm 220 by conventional means (not shown). The needles 160 within
the array 150 will typically be spaced 0.5 to 1 inch apart. Each conductive needle
160 taps the supply line 140 through an associated isolating resistor 165.
[0022] As discussed above, in the preferred embodiment, each needle 160 is fabricated from
a conductive material such as tungsten and includes a sharpened needle point 170.
The radii of curvature of the needle points 170 are chosen in conjunction with the
value of the voltage provided by the source 120 such that the electric field existing
in the vicinity of each point 170 is of sufficient magnitude to induce atmospheric
ionization at a desirable current controlling the processing rate. As the polarity
of the source 20 is switchable, either positive or negative ions may be generated
through such an atmospheric discharge.
[0023] As was discussed with reference to Fig. 2, ions produced by the needle array 150
migrate along electric field lines (not shown) to a surface 180 of a coating composition
190. Again, the coating 190 is clear (contains no pigment), and covers a previously
applied pigmented base coat (not shown).
[0024] As shown in Fig. 3 the coating 190 has not yet solidified following application to
an automobile surface 200, and resides thereon in a viscous liquid state.
[0025] As the needle array 150 is moved over the surface 180 a feedback loop formed by the
ammeter 130, the line 230, the controller 110, an electromechanical position control
device 210 and the robot arm 220 coupled thereto keeps the needle array 150 at a relatively
constant distance "d" from the surface 180. Although the source 120 furnishes a DC
voltage to the needle array 150, current propagates through each of the needles 160
in the form of Trischel pulses. As the distance "d" decreases, both the frequency
of these pulses and the current through the needle array 150 increases. Accordingly,
the ammeter 130 (or a frequency meter) is utilized to send signals to the controller
110 via the signal line 230. These signals are proportional both to the current drawn
by the needle array 150, and to functions of the distance "d". The controller 110
then signals the position control device 210 through a signal line 240 to adjust the
position of the robot arm 220 (and hence needle array 150) until the appropriate current
flow is sensed by the ammeter 130. Apparatus which may be utilized to implement the
position control device 210, is well within the capabilities of one of ordinary skill
in the art.
[0026] In certain applications, it may be desirable to subject the entire portion of the
surface 180, directly below the needle array 150, to a substantially uniform field
(i.e., all points the same electrostatic pressure). Such uniformity would be achieved
by ensuring that, on average, ions are distributed evenly above the surface 180, irrespective
of the instantaneous location of each of the needles 160. One method of effecting
this result would be to rotate the needle array 150 about an axis parallel to the
orientation of the needles 160. In this manner the spatial uniformity of both the
ions produced by the apparatus 100 and of the electric field resulting therefrom would
be enhanced.
[0027] The embodiment of Fig. 3 could be modified in one of at least two ways to allow the
needle array 150 to rotate in the manner prescribed above. One possibility would be
to mechanically alter the robot arm 220 to rotate, as well as vertically position,
the needle array 150. Alternatively, a separate mechanical device may be interposed
between the robot arm 220 and needle array 150 to induce the rotation thereof.
[0028] In addition to smoothing the surface 180, the apparatus 100 of the present invention
may also be used to "texturize" the surface 180. Specifically, as the distance "d"
is reduced ions generated by the needles 160 will not be able to diffuse with substantial
uniformity before being absorbed by the surface 180. That is, ions will be absorbed
by the surface 180 very soon after being generated. As a consequence, the electrostatic
pressure exerted on those areas of the surface 180 directly below each of the needles
160 will become substantially stronger than the pressure applied elsewhere on the
surface 180. For example, if the needle array 150 is fixed a sufficiently short distance
over a particular region of the surface 180 a dimple pattern will emerge thereon mirroring
the arrangement of the needles 160. Similarly, in the event the array 150 is horizontally
translated in close proximity to the surface 180, a pattern of "troughs" will be etched
thereon. In this manner the apparatus 100 may be utilized to impart a desired texture
to the surface 180. Certain designs could of course be recorded on the surface most
effectively by using a single conductive needle rather than the needle array 150.
[0029] Thus the present invention has been described with reference to a particular embodiment
in connection with a particular application. Those having ordinary skill in the art
and access to the teachings of the present invention will recognize additional modifications
and applications within the scope thereof. For example, instruments other than an
array of sharpened needles may be utilized to generate the electric field required
to induce an atmospheric ionic discharge. Similarly, the invention is not limited
to the particular electrical system disclosed herein for supplying an ionization voltage
and controlling the position of the needle array. Those skilled in the art may be
aware of other system configurations which would maintain a relatively constant distance
between the needle array and coating surface. Additionally, charged particles other
than ions may be appropriate for generating electrostatic pressure in alternative
embodiments of the present invention.
[0030] It is therefore contemplated by the appended claims to cover any and all such modifications.
1. A technique for expediting the subsidence of irregularities on a surface of a viscous
coating composition applied to an electrically conductive object comprising the step
of generating electrically charged particles in a volume of space adjacent to said
surface to develop an electric field across said coating composition, said electric
field inducing said charged particles to exert pressure on the surface of said coating.
2. The technique of Claim 1 wherein said step of generating said charged particles includes
the step of precipitating an ionic discharge of a gas included within said volume
of space.
3. The technique of Claim 2 wherein said step of precipitating an ionic discharge includes
the step of applying a voltage to a conductive needle positioned within said gas to
generate ions.
4. The technique of Claim 3 further including the step of translating said needle through
said volume of space.
5. A technique for texturizing a surface of a viscous coating composition applied to
an electrically conductive object comprising the steps of:
a) applying a voltage to an electrically conductive needle positioned within a volume
of space adjacent to said surface, said voltage being of sufficient magnitude to cause
a gas included within said volume of space to be ionized by the electric field produced
by said conductor and
b) translating said conductor within said volume of space such that said ionized gas
causes portions of said coating surface to be displaced, thereby forming a pattern
of texturization.
6. A ripple reduction apparatus for expediting the subsidence of irregularities on a
surface of a viscous coating composition applied to an electrically conductive object
comprising means for generating electrically charged particles in a volume of space
adjacent to said surface to develop an electric field across said coating composition,
said electric field inducing said charged particles to exert pressure on the surface
of said coating.
7. The apparatus of Claim 6 wherein said means for generating said electrically charged
particles includes means for precipitating an ionic discharge of a gas included within
said volume of space.
8. The apparatus of Claim 7 wherein said means for precipitating an ionic discharge includes:
a conductive needle positioned within said volume of space; and
means for applying a voltage to said needle.
9. The apparatus of Claim 8 further including means for translating said needle through
said volume of space.
10. The apparatus of Claim 9 further including:
means for sensing the current through said needle and control means for adjusting
the position of said needle relative to said surface in response to said current.
11. An apparatus for expediting the subsidence of irregularities on a surface of a viscous
coating composition applied to an electrically conductive object comprising:
a voltage source; and
an array of conductive needles, each of said needles being electrically coupled
to said voltage source by an electrically resistive element, for precipitating an
ionic discharge from a gas included within a volume of space adjacent to said surface.
12. The apparatus of Claim 11 further including means for sensing the current through
said array of needles.
13. The apparatus of Claim 12 further including control means for adjusting the position
of said needle relative to said surface in response to said current.
14. The apparatus of Claim 13 further including means for rotating said array of needles.