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<!DOCTYPE ep-patent-document PUBLIC "-//EPO//EP PATENT DOCUMENT 1.1//EN" "ep-patent-document-v1-1.dtd">
<ep-patent-document id="EP91114090B1" file="EP91114090NWB1.xml" lang="en" country="EP" doc-number="0472197" kind="B1" date-publ="19941221" status="n" dtd-version="ep-patent-document-v1-1">
<SDOBI lang="en"><B000><eptags><B001EP>......DE....FRGB..................................</B001EP><B005EP>J</B005EP><B007EP>DIM360   - Ver 2.5 (21 Aug 1997)
 2100000/0</B007EP></eptags></B000><B100><B110>0472197</B110><B120><B121>EUROPEAN PATENT SPECIFICATION</B121></B120><B130>B1</B130><B140><date>19941221</date></B140><B190>EP</B190></B100><B200><B210>91114090.3</B210><B220><date>19910822</date></B220><B240><B241><date>19920320</date></B241><B242><date>19930921</date></B242></B240><B250>en</B250><B251EP>en</B251EP><B260>en</B260></B200><B300><B310>223481/91</B310><B320><date>19900824</date></B320><B330><ctry>JP</ctry></B330></B300><B400><B405><date>19941221</date><bnum>199451</bnum></B405><B430><date>19920226</date><bnum>199209</bnum></B430><B450><date>19941221</date><bnum>199451</bnum></B450><B451EP><date>19940406</date></B451EP></B400><B500><B510><B516>5</B516><B511> 5H 01F   7/22   A</B511></B510><B540><B541>de</B541><B542>Hochtemperatur-supraleitende Spule</B542><B541>en</B541><B542>High-temperature superconductive conductor winding</B542><B541>fr</B541><B542>Bobine supra-conductrice à haute température</B542></B540><B560><B561><text>EP-A- 0 045 604</text></B561><B561><text>US-A- 3 281 737</text></B561><B561><text>US-A- 3 813 764</text></B561><B561><text>US-A- 4 499 443</text></B561></B560><B590><B598>1</B598></B590></B500><B700><B720><B721><snm>Sato, Kenichi,
c/o Osaka Works</snm><adr><str>Sumitomo Elec. Ind. Ltd.,
1-3, Shimaya 1-chome</str><city>Konohana-ku,
Osaka</city><ctry>JP</ctry></adr></B721></B720><B730><B731><snm>SUMITOMO ELECTRIC INDUSTRIES, LIMITED</snm><iid>00279014</iid><irf>56 SU 05 81 3</irf><adr><str>5-33, Kitahama 4-chome
Chuo-ku</str><city>Osaka 541</city><ctry>JP</ctry></adr></B731></B730><B740><B741><snm>KUHNEN, WACKER &amp; PARTNER</snm><iid>00100052</iid><adr><str>Patent- und Rechtsanwaltsbüro,
Alois-Steinecker-Strasse 22</str><city>85354 Freising</city><ctry>DE</ctry></adr></B741></B740></B700><B800><B840><ctry>DE</ctry><ctry>FR</ctry><ctry>GB</ctry></B840><B880><date>19920226</date><bnum>199209</bnum></B880></B800></SDOBI><!-- EPO <DP n="1"> -->
<description id="desc" lang="en">
<heading id="h0001">BACKGROUND OF THE INVENTION</heading>
<heading id="h0002">Field of the Invention</heading>
<p id="p0001" num="0001">The present invention relates to a high-temperature superconductive conductor winding, and more specifically, it relates to improvement of properties, particularly the critical current property, of such a high-temperature superconductive conductor winding.</p>
<heading id="h0003">Description of the Background Art</heading>
<p id="p0002" num="0002">A high-temperature superconductive material, which is known as a ceramic superconductor, is coated with a metal and strongly worked into a thin tape by deformation processing. It has been recognized possible to attain a high critical current density by combining such deformation processing with heat treatment.</p>
<p id="p0003" num="0003">In order to apply such a tape-type high-temperature superconducting wire to a coil, for example, it is necessary to wind the wire. In particular, such a tape-type high-temperature superconducting wire is properly wound into the form of a double pancake coil.</p>
<p id="p0004" num="0004">In such a double pancake coil, a single high-temperature wire is adapted to form two coil portions. Therefore, a throughout portion (crossover portion) extending from one coil portion to the other coil portion is required. In<!-- EPO <DP n="2"> --> relation to employment of the tape-type high-temperature superconducting wire, however, it has been recognized that the critical current density is reduced due to shearing stress which is applied to the "throughout portion", since the wire is necessarily twisted at the "throughout portion".</p>
<heading id="h0004">SUMMARY OF THE INVENTION</heading>
<p id="p0005" num="0005">Accordingly, an object of the present invention is to provide a high-temperature superconductive conductor winding obtained by winding a tape-type high-temperature superconducting wire into the form of a double pancake coil, which can suppress generation of shearing stress in a crossover portion, thereby preventing reduction of the critical current density.</p>
<p id="p0006" num="0006">The present invention is directed to a high-temperature ceramic superconductive conductor winding obtained by winding a tape-type high-temperature ceramic superconducting wire, which is combined with a metal, into the form of a double pancake coil. According to the present invention, it is noted that the length of a crossover portion is deeply concerned with the aforementioned shearing stress, as well as the critical current density.</p>
<p id="p0007" num="0007">In the present invention the length of a crossover portion which is provided between pancakes is selected to be at least four times the width of the tape-type high-temperature superconducting wire, in<!-- EPO <DP n="3"> --> order to solve the aforementioned technical problem.</p>
<p id="p0008" num="0008">In the high-temperature superconductive conductor winding according to the present invention, the high-temperature superconducting wire may be covered with an insulating material of an inorganic substance such as mica, glass fiber or quartz fiber, or an organic substance such as tetrafluoroethylene, polyimde resin or formal resin.</p>
<p id="p0009" num="0009">The inventive high-temperature superconductive conductor winding is preferably impregnated with epoxy resin. More preferably, the epoxy resin contains fiber and/or powder.</p>
<p id="p0010" num="0010">A high-temperature superconductor contained in the high-temperature superconducting wire may be divided in a multicore state.</p>
<p id="p0011" num="0011">According to the present invention, the length of the crossover portion is selected to be at least four times the width of the tape-type high-temperature superconducting wire, whereby it is possible to suppress generation of shearing stress at the crossover portion, thereby preventing reduction of the critical current density caused by such shearing stress.</p>
<p id="p0012" num="0012">According to the present invention, the high-temperature superconducting wire is preferably provided with an insulating coat, so that the same can be directly<!-- EPO <DP n="4"> --> wound into a coil with no specific insulating material.</p>
<p id="p0013" num="0013">Further, the high-temperature superconductive conductor winding according to the present invention is preferably impregnated with epoxy resin, so that the winding is resistant against stress which may be applied thereto in preparation of such a winding or during excitation. More preferably, the epoxy resin contains fiber and/or powder, so that the winding is further resistant against the aforementioned stress.</p>
<p id="p0014" num="0014">The high-temperature superconductor which is contained in the high-temperature superconducting wire is preferably divided in a multicore state, so that the high-temperature superconductor is improved in strain resistance and can be wound with no problem after sintering.</p>
<p id="p0015" num="0015">The foregoing and other objects, features, aspects and advantages of the present invention will become more apparent from the following detailed description of the present invention when taken in conjunction with the accompanying drawings.</p>
<heading id="h0005">BRIEF DESCRIPTION OF THE DRAWINGS</heading>
<p id="p0016" num="0016">
<ul id="ul0001" list-style="none">
<li>Fig. 1 is a front elevational view showing a high-temperature superconductive conductor winding 1 according to an embodiment of the present invention; and</li>
<li>Fig. 2 is a top plan view of the high-temperature<!-- EPO <DP n="5"> --> superconductive conductor winding 1 shown in Fig. 1.</li>
</ul></p>
<heading id="h0006">DESCRIPTION OF THE PREFERRED EMBODIMENTS</heading>
<p id="p0017" num="0017">Figs. 1 and 2 illustrate a high-temperature superconductive conductor winding 1 according to an embodiment of the present invention. Fig. 1 is a front elevational view, and Fig. 2 is a top plan view.</p>
<p id="p0018" num="0018">This high-temperature superconductive conductor winding 1 is formed by winding a tape-type high-temperature superconducting wire 2, which is combined with a metal, on a cylindrical spool 3 into the form of a double pancake coil.</p>
<p id="p0019" num="0019">In more concrete terms, the single tape-type high-temperature superconducting wire 2 is wound on the spool 3 from its inner peripheral side to form an upper pancake, i.e., a first coil portion 4. A crossover portion 5, which is connected with the beginning end of the first coil portion 4, is guided to obliquely downwardly extend on the spool 3. The high-temperature superconducting wire 2 is then wound on the outer peripheral surface of the spool 3 from the inner peripheral side inversely to the first coil portion 4, thereby forming a lower pancake, i.e., a second coil portion 6.</p>
<p id="p0020" num="0020">In the aforementioned wound state of the tape-type high-temperature superconducting wire 2, clearances are defined along the first and second coil portions 4 and 6<!-- EPO <DP n="6"> --> due to formation of the crossover portion 5, while spacers 7 and 8 are inserted to absorb such clearances.</p>
<p id="p0021" num="0021">Current-carrying terminals 9 and 10 are mounted on both end portions of the wound high-temperature superconducting wire 2.</p>
<p id="p0022" num="0022">While the spool 3 is simply illustrated in a cylindrical configuration, flanges (not shown) are generally formed on both end portions thereof.</p>
<p id="p0023" num="0023">In this specification, the term "length of the crossover portion" indicates the length of the center line of the crossover portion 5, shown in Fig. 1, in a part exposed from the first and second coil portions 4 and 6.</p>
<p id="p0024" num="0024">Examples which were made to confirm the effect of the present invention are now described in detail.</p>
<heading id="h0007">Example 1</heading>
<p id="p0025" num="0025">Oxides or carbonates containing Bi, Pb, Sr, Ca and Cu were so mixed that these elements were in composition ratios of 1.82:0.43:2.01:2.22:3.03, and this mixture was heat treated to prepare powder having a 2212 phase being composed of Bi, Pb, Sr, Ca and Cu substantially in the ratios of 2:2:1:2, and non-superconducting phases. This powder was degassed under a decompressed atmosphere of 2 Torr at 700°C for 3 hours.</p>
<p id="p0026" num="0026">The as-formed powder was filled into silver pipes.<!-- EPO <DP n="7"> --> 1296 such silver pipes were charged into a large silver pipe of 12 mm in outer diameter and 10 mm in inner diameter, which in turn was drawn into an outer diameter of 1 mm and then rolled into a thickness of 0.18 mm.</p>
<p id="p0027" num="0027">The as-formed tape-type wire was heat treated at 840°C for 50 hours, and then rolled into a tape-type wire of 4 mm in width and 0.15 mm in thickness. This tape-type wire was then heat treated at 840°C for 50 hours.</p>
<p id="p0028" num="0028">This tape-type wire was coated with a formal resin film of 0.1 mm in thickness and wound on a bobbin of 15 mm in outer diameter, to prepare a double pancake coil so that each pancake had ten turns. Some samples of such double pancake coils were prepared with crossover portions of various lengths, to measure J<sub>C,coil</sub>/J<sub>CO</sub> (critical current density in the coil form/critical current density of the wire itself).</p>
<p id="p0029" num="0029">Table 1 shows the results.
<tables id="tabl0001" num="0001"><img id="ib0001" file="imgb0001.tif" wi="109" he="56" img-content="table" img-format="tif"/>
</tables><!-- EPO <DP n="8"> --></p>
<p id="p0030" num="0030">It is clearly understood from Table 1 that the property of the winding was remarkably improved when the length of the crossover portion was at least four times the width of the tape-type wire.</p>
<heading id="h0008">Example 2</heading>
<p id="p0031" num="0031">A tape-type wire of 4.3 mm in width and 0.14 mm in thickness was prepared in a similar manner to Example 1, and coated with a polyimide resin film in place of the formal resin film, to prepare a double pancake coil which was similar to Example 1. According to Example 2, the coil was impregnated with epoxy resin containing glass fiber.</p>
<p id="p0032" num="0032">Table 2 shows results of evaluation of the as-formed samples.
<tables id="tabl0002" num="0002"><img id="ib0002" file="imgb0002.tif" wi="109" he="64" img-content="table" img-format="tif"/>
</tables></p>
<p id="p0033" num="0033">It is understood from Table 2 that the effect of the present invention was further improved when the winding<!-- EPO <DP n="9"> --> was impregnated with epoxy resin.</p>
<heading id="h0009">Example 3</heading>
<p id="p0034" num="0034">A single-core wire was prepared through steps similar to those of Example 1. This wire was rolled into a thickness of 0.18 mm, coated with quartz fiber, and worked into a double pancake coil, which was heat treated at 840°C for 50 hours.</p>
<p id="p0035" num="0035">Also in this case, the coil exhibited an excellent critical current density exceeding 90 % of that of the wire itself when the length of the crossover portion was set to be at least four times the width of the wire.</p>
<p id="p0036" num="0036">Although the present invention has been described and illustrated in detail, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, the scope of the present invention being limited only by the terms of the appended claims.</p>
</description><!-- EPO <DP n="10"> -->
<claims id="claims01" lang="en">
<claim id="c-en-01-0001" num="0001">
<claim-text>A superconducting double pancake coil<br/>
comprising<br/>
a high-temperature ceramic superconductive conductor winding (1) which comprises a tape-type high-temperature ceramic superconducting wire (2) being combined with a metal and wound into the form of a double pancake coil, wherein<br/>
the length of a crossover portion (5) provided between pancakes (4, 6) is at least four times the width of said tape-type high-temperature ceramic superconducting wire (2).</claim-text></claim>
<claim id="c-en-01-0002" num="0002">
<claim-text>A high-temperature ceramic superconductive conductor winding (1) in accordance with claim 1, wherein<br/>
said high-temperature ceramic superconducting wire (2) is provided with an insulating coat.</claim-text></claim>
<claim id="c-en-01-0003" num="0003">
<claim-text>A high-temperature ceramic superconductive conductor winding (1) in accordance with claim 1, wherein<br/>
said winding is impregnated with epoxy resin.<!-- EPO <DP n="11"> --></claim-text></claim>
<claim id="c-en-01-0004" num="0004">
<claim-text>A high-temperature ceramic superconductive conductor winding (1) in accordance with claim 3, wherein<br/>
said epoxy resin contains fiber and/or powder.</claim-text></claim>
<claim id="c-en-01-0005" num="0005">
<claim-text>A high-temperature ceramic superconductive conductor winding (1) in accordance with claim 1, wherein<br/>
a high-temperature ceramic superconductor contained in said high-temperature ceramic superconducting wire (2) is divided in a multicore state.</claim-text></claim>
</claims><!-- EPO <DP n="12"> -->
<claims id="claims02" lang="de">
<claim id="c-de-01-0001" num="0001">
<claim-text>Eine supraleitende Doppelscheibenspule, umfassend:<br/>
eine keramische Hochtemperatur-Supraleiterwicklung (1), welche einen bandförmigen keramischen Hochtemperatursupraleitenden Draht (2) umfaßt, der mit einem Metall verbunden ist und in die Form einer Doppelscheibenspule gewunden ist, wobei<br/>
die Länge eines Kreuzungsbereichs (5), der zwischen den Scheiben (4, 6) zur Verfügung gestellt wird, wenigstens viermal der Breite des bandförmigen keramischen Hochtemperatur-supraleitenden Drahtes (2) entspricht.</claim-text></claim>
<claim id="c-de-01-0002" num="0002">
<claim-text>Eine keramische Hochtemperatur-Supraleiterwicklung (1) gemäß Anspruch 1, wobei<br/>
der keramische Hochtemperatur-supraleitende Draht (2) mit einer isolierenden Schicht versehen ist.</claim-text></claim>
<claim id="c-de-01-0003" num="0003">
<claim-text>Eine keramische Hochtemperatur-Supraleiterwicklung (1) gemäß Anspruch 1, wobei<br/>
die Wicklung mit einem Epoxyharz imprägniert ist.</claim-text></claim>
<claim id="c-de-01-0004" num="0004">
<claim-text>Eine keramische Hochtemperatur-Supraleiterwicklung (1) gemäß Anspruch 3, wobei<br/>
das Epoxyharz Fasern und/oder Pulver enthält.</claim-text></claim>
<claim id="c-de-01-0005" num="0005">
<claim-text>Eine keramische Hochtemperatur-Supraleiterwicklung (1) gemäß Anspruch 1, wobei<br/>
ein keramischer Hochtemperatur-Supraleiter, der in dem keramischen Hochtemperatur-supraleitenden Draht (2)<!-- EPO <DP n="13"> --> enthalten ist, in einen mehradrigen Zustand aufgeteilt ist.</claim-text></claim>
</claims><!-- EPO <DP n="14"> -->
<claims id="claims03" lang="fr">
<claim id="c-fr-01-0001" num="0001">
<claim-text>Une bobine supraconductrice à double galette<br/>
comprenant un enroulement supraconducteur constitué de céramique supraconductrice à haute température critique (1), lequel comprend un fil supraconducteur en céramique supraconductrice à haute température critique (2) ayant la forme d'un ruban, lequel fil est accompagné d'un métal et enroulé pour former une bobine à double galette, dans laquelle<br/>
la longueur de la portion transversale (5) située entre les galettes (4, 6) est d'au moins quatre fois la largeur dudit fil supraconducteur constitué de céramique supraconductrice à haute température critique (2), lequel se présente sous la forme d'un ruban.</claim-text></claim>
<claim id="c-fr-01-0002" num="0002">
<claim-text>Un enroulement supraconducteur à base de céramique supraconductrice à haute température critique (1) selon la revendication 1, dans lequel ledit fil supraconducteur à base de céramique supraconductrice à haute température critique (2), est doté d'un revêtement isolant.</claim-text></claim>
<claim id="c-fr-01-0003" num="0003">
<claim-text>Un enroulement supraconducteur à base de céramique supraconductrice à haute température critique (1) selon la revendication 1, dans lequel ledit enroulement est imprégné de résine époxy.</claim-text></claim>
<claim id="c-fr-01-0004" num="0004">
<claim-text>Un enroulement supraconducteur à base de céramique supraconductrice à haute température critique (1) selon la revendication 3, dans lequel ladite résine époxy contient des fibres et/ou des poudres.</claim-text></claim>
<claim id="c-fr-01-0005" num="0005">
<claim-text>Un enroulement supraconducteur à base de céramique supraconductrice à haute température critique (1) selon la revendication 1, dans lequel un supraconducteur à base de céramique supraconductrice<!-- EPO <DP n="15"> --> à haute température critique constituant ledit fil supraconducteur à base de céramique supraconductrice à haute température critique (2) est constitué de plusieurs brins.</claim-text></claim>
</claims><!-- EPO <DP n="16"> -->
<drawings id="draw" lang="en">
<figure id="f0001" num=""><img id="if0001" file="imgf0001.tif" wi="109" he="205" img-content="drawing" img-format="tif"/></figure>
</drawings>
</ep-patent-document>
