(19)
(11) EP 0 479 554 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
05.05.1993 Bulletin 1993/18

(43) Date of publication A2:
08.04.1992 Bulletin 1992/15

(21) Application number: 91308982.7

(22) Date of filing: 01.10.1991
(51) International Patent Classification (IPC)5B31F 1/12, D21H 17/71
// D21H17/20, D21H17/66
(84) Designated Contracting States:
AT BE CH DE DK ES FR GB GR IT LI LU NL SE

(30) Priority: 02.10.1990 US 591812

(71) Applicant: JAMES RIVER CORPORATION OF VIRGINIA
Richmond, VA 23217 (US)

(72) Inventors:
  • Hollenberg, David Henry
    Neenah, Wisconsin 54956 (US)
  • Collins, Stephen Risley
    Neenah, Wisconsin 54956 (US)
  • Van Luu, Phuong
    Appleton, Wisconsin 54914 (US)

(74) Representative: Cropp, John Anthony David et al
MATHYS & SQUIRE 100 Grays Inn Road
London, WC1X 8AL
London, WC1X 8AL (GB)


(56) References cited: : 
   
       


    (54) Crosslinkable creping adhesives


    (57) A method of creping a fibrous web is described which comprises providing to the interface of a fibrous web and a support surface, preferably a drying surface such as provided by a Yankee dryer, a creping adhesive comprising a non-self-crosslinkable material such as a polymer or oligomer having functional groups which are crosslinkable by ionic crosslinking, and a crosslinking agent which preferably comprises metal cations having a valency of at least three, and removing the fibrous web from the support surface by creping. Also provided is a creping adhesive comprising a polymer, oligomer or mixture thereof having functional groups crosslinkable by cations, a component providing metal cations having a valency of at least three, and an aqueous solvent or diluent for the polymer or oligomer. The glass transition temperature and adhesive strength of the adhesive employed in the invention is readily controllable and the adhesive is easily removed from dryer surfaces.





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