(19) |
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(11) |
EP 0 479 554 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
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05.05.1993 Bulletin 1993/18 |
(43) |
Date of publication A2: |
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08.04.1992 Bulletin 1992/15 |
(22) |
Date of filing: 01.10.1991 |
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(84) |
Designated Contracting States: |
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AT BE CH DE DK ES FR GB GR IT LI LU NL SE |
(30) |
Priority: |
02.10.1990 US 591812
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(71) |
Applicant: JAMES RIVER CORPORATION OF VIRGINIA |
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Richmond, VA 23217 (US) |
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(72) |
Inventors: |
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- Hollenberg, David Henry
Neenah,
Wisconsin 54956 (US)
- Collins, Stephen Risley
Neenah,
Wisconsin 54956 (US)
- Van Luu, Phuong
Appleton,
Wisconsin 54914 (US)
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(74) |
Representative: Cropp, John Anthony David et al |
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MATHYS & SQUIRE
100 Grays Inn Road London, WC1X 8AL London, WC1X 8AL (GB) |
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(54) |
Crosslinkable creping adhesives |
(57) A method of creping a fibrous web is described which comprises providing to the interface
of a fibrous web and a support surface, preferably a drying surface such as provided
by a Yankee dryer, a creping adhesive comprising a non-self-crosslinkable material
such as a polymer or oligomer having functional groups which are crosslinkable by
ionic crosslinking, and a crosslinking agent which preferably comprises metal cations
having a valency of at least three, and removing the fibrous web from the support
surface by creping. Also provided is a creping adhesive comprising a polymer, oligomer
or mixture thereof having functional groups crosslinkable by cations, a component
providing metal cations having a valency of at least three, and an aqueous solvent
or diluent for the polymer or oligomer. The glass transition temperature and adhesive
strength of the adhesive employed in the invention is readily controllable and the
adhesive is easily removed from dryer surfaces.