(19)
(11) EP 0 501 539 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
08.09.1993 Bulletin 1993/36

(43) Date of publication A2:
02.09.1992 Bulletin 1992/36

(21) Application number: 92200277.9

(22) Date of filing: 03.02.1992
(51) International Patent Classification (IPC)5C22C 1/10, C22C 1/09
(84) Designated Contracting States:
DE FR GB

(30) Priority: 25.02.1991 US 659967

(71) Applicant: GENERAL MOTORS CORPORATION
Detroit Michigan 48202 (US)

(72) Inventors:
  • Gustafson, Thomas Wesley
    Saginaw, MI 48603 (US)
  • Gerard, Dale Allen
    Warren, MI 48092 (US)
  • Fick, Charles George, III
    Saginaw, MI 48603 (US)
  • Sachdev, Anil Kumar
    Rochester, MI 48307 (US)

(74) Representative: Denton, Michael John et al
Patent Section 1st Floor Gideon House 28 Chapel Street
Luton Bedfordshire LU1 2SE
Luton Bedfordshire LU1 2SE (GB)


(56) References cited: : 
   
       


    (54) Metal matrix composite composition and method


    (57) A method of making a new metal matrix composite material formed from an aluminium-based alloy and a silicon carbide ceramic material is disclosed, in which preferably a porous pre-form (20) of the silicon carbide ceramic material having SiO₂ on the surfaces thereof is placed in an open-top die (24), heated to an elevated temperature in the range of 399°C and 1093°C, and impregnated under pressure with a molten alloy (27) comprising, by weight about 3 to 6 percent copper, about 0.5 to 5 percent magnesium and the balance essentially aluminium. The silicon carbide pre-form (20) impregnated with molten alloy is then cooled at a rate sufficient to sustain supersaturation of the copper and magnesium in the aluminium down to a predetermined temperature. The predetermined temperature is selected so as to permit precipitation in the alloy of a strengthening copper-rich secondary metallic phase containing copper, magnesium and aluminium and consisting essentially of about 40 to 80 percent by weight copper, magnesium in an amount between about 5 and 30 percent by weight, and the balance essentially aluminium. This results in the formation of a metal matrix composite material having a silicon carbide phase, an aluminium-rich primary metallic phase and a copper-rich secondary metallic phase which has the desired composition. The primary metallic phase can contain up to 10 percent of eutectic phase which is generally present as a coarse network or as isolated islands within the primary phase.
    Preferably, cooling occurs immediately after the impregnating step and relatively rapidly to a temperature below about 288°C, where precipitation of the secondary metallic phase occurs. Preferably, the secondary metallic phase comprises a cubically-shaped crystal structure which measures about 40 nanometres on a side.







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