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<ep-patent-document id="EP92110259B1" file="EP92110259NWB1.xml" lang="en" country="EP" doc-number="0519443" kind="B1" date-publ="19980211" status="n" dtd-version="ep-patent-document-v1-1">
<SDOBI lang="en"><B000><eptags><B001EP>......DE....FRGB..................................</B001EP><B005EP>J</B005EP><B007EP>DIM360   - Ver 2.7 (17 Nov 1997)
 2100000/0</B007EP></eptags></B000><B100><B110>0519443</B110><B120><B121>EUROPEAN PATENT SPECIFICATION</B121></B120><B130>B1</B130><B140><date>19980211</date></B140><B190>EP</B190></B100><B200><B210>92110259.6</B210><B220><date>19920617</date></B220><B240><B241><date>19930518</date></B241><B242><date>19951221</date></B242></B240><B250>en</B250><B251EP>en</B251EP><B260>en</B260></B200><B300><B310>177177/91</B310><B320><date>19910621</date></B320><B330><ctry>JP</ctry></B330></B300><B400><B405><date>19980211</date><bnum>199807</bnum></B405><B430><date>19921223</date><bnum>199252</bnum></B430><B450><date>19980211</date><bnum>199807</bnum></B450><B451EP><date>19970410</date></B451EP></B400><B500><B510><B516>6</B516><B511> 6H 01L  27/148  A</B511></B510><B540><B541>de</B541><B542>Ladungsgekoppelter Bildsensor</B542><B541>en</B541><B542>Charge coupled device image sensor</B542><B541>fr</B541><B542>Détecteur d'image à dispositif couplé de charge</B542></B540><B560><B561><text>EP-A- 0 265 271</text></B561><B561><text>EP-A- 0 435 309</text></B561><B561><text>WO-A-91/03839</text></B561></B560><B590><B598>1A  1B</B598></B590></B500><B700><B720><B721><snm>Nishi, Naoki</snm><adr><str>c/o Sony Corporation,
7-35 Kitashinagawa 6-chome</str><city>Shinagawa-ku,
Tokyo</city><ctry>JP</ctry></adr></B721></B720><B730><B731><snm>SONY CORPORATION</snm><iid>00214021</iid><irf>S92P481EPOOB-Mü</irf><adr><str>7-35 Kitashinagawa 6-chome
Shinagawa-ku</str><city>Tokyo 141</city><ctry>JP</ctry></adr></B731></B730><B740><B741><snm>Müller, Frithjof E., Dipl.-Ing.</snm><iid>00008661</iid><adr><str>Patentanwälte
MÜLLER &amp; HOFFMANN,
Innere Wiener Strasse 17</str><city>81667 München</city><ctry>DE</ctry></adr></B741></B740></B700><B800><B840><ctry>DE</ctry><ctry>FR</ctry><ctry>GB</ctry></B840><B880><date>19921223</date><bnum>199252</bnum></B880></B800></SDOBI><!-- EPO <DP n="1"> -->
<description id="desc" lang="en">
<heading id="h0001">BACKGROUND OF THE INVENTION</heading>
<heading id="h0002">Field of the Invention</heading>
<p id="p0001" num="0001">The present invention relates generally to a solid-state image sensor and, more particularly, to the structure of the sensor elements of a hole accumulation diode construction (HAD construction) of a charge coupled device image sensor (CCD image sensor).</p>
<heading id="h0003">Description of the Prior Art</heading>
<p id="p0002" num="0002">Fig. 3 shows the structure of a CCD image sensor of a known interline transfer system according to WO-A-91/03839. Referring to Fig. 3, the CCD image sensor has an image sensing unit 3 comprising a plurality of sensor elements 1 arranged in vertical and horizontal rows in a two-dimensional arrangement to accumulate electric signal charges corresponding to the quantity of incident light, and a plurality of vertical shift registers (vertical transfer units) 2 each connected to the sensor elements 1 in each vertical row to transfer electric signal charges read from the sensor elements 1 of the corresponding vertical row.</p>
<p id="p0003" num="0003">The electric signal charges produced by the sensor elements 1 through photoelectric conversion are read<!-- EPO <DP n="2"> --> instantaneously in a vertical blanking interval by the vertical shift register. The electric signal charges corresponding to one scanning line among those read by the vertical shift register 2 are transferred to a horizontal shift register 4 in each horizontal blanking interval. The electric signal charges corresponding to one scanning line are transferred sequentially in a horizontal direction by the horizontal shift register 4. An output circuit 5, such as a floating diffusion amplifier (FDA) or the like, is connected to the output end of the horizontal shift register 4. The output circuit 5 detects the electric signal charges obtained by the sensor elements 1 through photoelectric conversion and transferred by the vertical shift registers 2 and the horizontal shift register 4, and converts the electric signal charges into corresponding electric signals and provides television signals.</p>
<p id="p0004" num="0004">As shown in Fig. 4, holes produced in the sensor element 1 by the light received by the sensor element 1 are discharged through a channel stop region 6 to the ground (GND) of the CCD image sensor. Since a p-type region serving as the channel stop region 6 has a low impurity concentration and a small width, the resistance against the the hole current is relatively high. Accordingly, when a large quantity of light falls on the sensor element 1, the surface potential of the sensor element 1 varies and the<!-- EPO <DP n="3"> --> operating characteristics of the sensor element 1 change because the potential of the channel stop region 6 is caused to change by the hole current. Consequently, an extraordinarily large quantity of electric charges is accumulated in the sensor element 1, causing electric signal charges to overflow the vertical shift register 2 (vertical CCD).</p>
<p id="p0005" num="0005">The prior art CCD image sensor is provided with sensor elements 1 having channel stop regions 6 formed in a high impurity concentration to reduce the resistance against the hole current produced through photoelectric conversion. As shown in Figs. 5(A) and 5(B), a p<sup>+</sup>-type channel stop region 7 having a high impurity concentration higher than that of the channel stop region 6 is formed in the inner portion of the channel stop region 6 to reduce the resistance against the hole current. However, when the CCD image sensor is subjected to heat treatment in a semiconductor device fabricating process, the anomalous diffusion of the impurity contained in the p<sup>+</sup>-type channel stop region 7 occurs to spoil the vertical shift register 2 (vertical CCD). Consequently, the effective width of the vertical shift register 2 is reduced and the quantity of electric charges to be dealt with by the vertical shift register 2 is reduced.</p>
<p id="p0006" num="0006">The sensor elements 1 are spoiled likewise by the anomalous diffusion of the impurity contained in the p<sup>+</sup>-type channel stop region 7. Consequently, when an electronic<!-- EPO <DP n="4"> --> shutter operation is performed to discharge the electric signal charges accumulated in the sensor elements 1 into the semiconductor substrate, capacitive coupling is produced to increase the capacitance of the channel stop region 6. Therefore, the overflow barrier will not readily collapse even if the amplitude of a voltage pulse applied to the semiconductor substrate is increased and hence a voltage pulse having a still larger amplitude must be applied to the semiconductor substrate. I.e., the known CCD image sensor comprises an area of sensor elements, each sensor consisting of a hole accumulating layer and a signal accumulating region; vertical transfer registers; channel stop regions including a grounded p-type doping beneath a LOCOS region, each channel stop formed along and on the other side of each vertical row of sensor elements to receive holes produced in the sensor elements; doped regions of the same conductivity type as that of the hole accumulating layer and formed in areas between the sensor elements on each vertical row (= p-doped extensions of the hole accumulating layer under LOCOS regions.</p>
<p id="p0007" num="0007">Further a solid state image sensing device of this kind is described in the earlier European Application EP-A-0 435 309 which is state of the art according to Article 54(3) EPC.</p>
<heading id="h0004">SUMMARY OF THE INVENTION</heading>
<p id="p0008" num="0008">Accordingly, it is an object of the present invention to provide a CCD image sensor capable of suppressing the anomalous increase of the quantity of electric charges to be dealt with by its sensor elements when a large quantity of light falls thereon, without reducing the quantity of electric charges to be dealt with by its vertical transfer registers and without requiring the enhancement of the amplitude of pulses to be applied to its substrate when an electronic shutter operation is performed.<!-- EPO <DP n="5"> --></p>
<p id="p0009" num="0009">A CCD image sensor comprises according to the invention:
<ul id="ul0001" list-style="dash" compact="compact">
<li>a plurality of sensor elements each consisting of a hole accumulating layer and an electric signal charge accumulating region underlying the hole accumulating layer, and arranged in vertical and horizontal rows at intervals;</li>
<li>vertical transfer registers each formed along and on one side of each vertical row of sensor elements to transfer electric signal charges read from the sensor elements on the corresponding vertical row in a vertical direction;</li>
<li>continuous vertical p-doped channel stop regions, each formed along and on the other side of each vertical row of sensor elements to receive holes produced in the sensor elements, and</li>
<li>heavily p-doped HCS-regions, each having a horizontal width smaller than the entire area between adjacent sensor elements but not less than the width of the channel stop region and formed in a portion of the area between the sensor elements near the channel stop region and far from the vertical transfer register so as to connect the hole accumulating layers of the sensor elements in the same vertical row, wherein the impurity concentration of the heavily doped HCS regions is higher than that of the channel stop regions and lower than that of the hole accumulating layers.</li>
</ul></p>
<p id="p0010" num="0010">In the CCD image sensor in accordance with the present invention, the resistance against the hole current is reduced by the additional regions doped in a high impurity concentration in the same type of conduction as that of the hole accumulating layer and formed between the vertical rows of the sensor elements, to use the hole accumulating layer formed on the electric signal charge accumulating regions as passages for holes as well as means for reducing dark current in the sensor elements. Accordingly, the impurity concentration of the channel stop regions needs not be increased, so that the anomalous increase of the quantity of electric charges to be dealt with by the sensor elements when a large quantity of light falls on the CCD image sensor can be suppressed without entailing reduction in the quantity of electric charges to be dealt with by the vertical<!-- EPO <DP n="6"> --> shift registers, and increase in the amplitude of the pulse to be applied to the substrate when an electronic shutter operation is performed.</p>
<heading id="h0005">BRIEF DESCRIPTION OF THE DRAWINGS</heading>
<p id="p0011" num="0011">The above and other objects, features and advantages of the present invention will become more apparent from the following description taken in connection with the accompanying drawings, in which:
<ul id="ul0002" list-style="none" compact="compact">
<li>Fig. 1(A) is a plan view of a sensor element, which corresponds to one picture element, of the image sensing unit of a CCD image sensor in a preferred embodiment according to the present invention;</li>
<li>Fig. 1(B) is a sectional view taken on line Y-Y in Fig. 1(A);</li>
<li>Fig. 2(A) is a sectional view taken on line X-X in Fig. 1(A);</li>
<li>Fig. 2(B) is a sectional view taken on line Y'-Y' in Fig. 1(A);</li>
<li>Fig. 3 is a typical view of a prior art CCD image sensor of an interline transfer system;</li>
<li>Fig. 4 is a plan view of a sensor element, corresponding to one picture element, of the CCD image sensor of Fig. 3;</li>
<li>Fig 5(A) is a sectional view taken on line X-X in Fig.<!-- EPO <DP n="7"> --> 4, showing a portion, corresponding to one picture element, of the image sensing unit of a prior art CCD image sensor; and</li>
<li>Fig. 5(B) is a sectional view taken on line Y-Y in Fig. 4, showing a portion of the image sensing unit corresponding to one picture element.</li>
</ul></p>
<heading id="h0006">DESCRIPTION OF THE PREFERRED EMBODIMENTS</heading>
<p id="p0012" num="0012">A CCD image sensor in a preferred embodiment according to the present invention is a CCD image sensor provided with an image sensing unit of a HAD construction featured by the structure of the sensor elements.</p>
<p id="p0013" num="0013">Referring to Figs. 1(A) to 2(B), a p-type region 12 is formed on an n-type silicon substrate 11. A sensor element 1 consists of a shallow p<sup>+</sup>-type hole accumulating layer 13 formed in the surface of the p-type region 12, and an n-type electric signal charge accumulating region 14 underlying the hole accumulating layer 13. Formed between and contiguously with the hole accumulating layer 13 and the electric signal charge accumulating region 14 is a p-type channel stop region 6.</p>
<p id="p0014" num="0014">As shown in Figs. 1(A) and 1(B), a heavily doped p<sup>+</sup>-type HCS (heavy channel stop) region 19 as an additional region is formed between the adjacent sensor elements 1 in the same vertical row so as to connect the hole accumulating<!-- EPO <DP n="8"> --> layers 13 of the sensor elements 1 in the same vertical row. The impurity concentration of the hole accumulating layer 13 of the sensor element 1 is higher than that of the HCS region 19 in view of avoiding adverse influence on an associated vertical shift register 2.</p>
<p id="p0015" num="0015">The horizontal width, i.e., the size measured along the line X-X, of the HCS region 19 may be not less than the width of the channel stop region 6. As best shown in Fig. 1(A), the HCS region 19 need not be formed in the entire area between the sensor elements 1; the HSC region 19 is formed in a portion of the area between the sensor elements 1. The HCS region 19 is formed in an area near the channel stop region 6 and far from the vertical shift register 2. It is obvious from the construction of the prior art CCD image sensor (Fig. 5(A)) provided with the heavily doped channel stop region 7 in the inner portion of the channel stop region 6 that the resistance against the hole current produced through photoelectric conversion can be reduced if the horizontal width of the HCS region 19 is not less than the width of the channel stop region 6 and that the quantity of electric charges in the vertical shift register is expected to be reduced if the HCS region 19 is formed in an area excessively near to the vertical shift register 2.</p>
<p id="p0016" num="0016">The vertical shift register 2 consists of an n-type<!-- EPO <DP n="9"> --> electric signal charge transfer region 15 formed in the surface of the p-type region 12, and a transfer electrode 16 formed on an insulating layer, not shown, formed of SiO<sub>2</sub> over the surface of the p-type region 12. As best shown in Fig. 1(A) and 1(B), a vertical transfer electrode for the vertical transference of electric signal charges consists of the transfer electrode 16 and a transfer electrode 17 formed of polycrystalline silicon in two layers. A p-type region 18 is formed below the vertical shift register 2, namely, under the electric signal charge transfer region 15, to suppress smear.</p>
<p id="p0017" num="0017">As mentioned above, since the HCS regions 19 are formed additionally between the adjacent sensor elements 1 in the vertical row to use the hole accumulating layer 13 of the sensor element 1 as a passage for holes produced by photoelectric conversion and as means for suppressing dark current in the sensor element 1, a passage having a sufficient capacity can be secured for holes produced by photoelectric conversion and the resistance against the hole current can be reduced to a satisfactorily low extent. Thus, since the channel stop regions need not be heavily doped, problems attributable to the reduction of the quantity of electric charges in the vertical shift registers 2 and the necessity of increasing the amplitude of a pulse to be applied to the silicon substrate 11 in performing an<!-- EPO <DP n="10"> --> electronic shutter operation to discharge the electric signal charges accumulated in the sensor elements 1 to the silicon substrate 11 do not arise, and it is possible to suppress anomalous increase in the quantity of electric charges to be dealt with by the sensor elements 1 when a large quantity of light falls on the CCD image sensor.</p>
<p id="p0018" num="0018">The applicant of the present patent application proposed a CCD image sensor previously in Japanese Patent Application No. Hei 2-309155. This previously proposed CCD image sensor is provided with a hole accumulating layer 13 in common to the sensor elements 1 in each vertical row. In fabricating this CCD image sensor, the hole accumulating layer 13 for the sensor elements 1 must be formed before forming polycrystalline silicon electrodes 16 and 17. The impurity of the highly doped p<sup>+</sup>-type hole accumulating layer 13 diffuses and an n<sup>+</sup>-type layer included in the sensor element 1 disappears when the hole accumulating layer 13 is subjected to heat treatment. Accordingly, the process temperature of processes following the process of forming the hole accumulating layer 13 must be limited to a level that may not cause the diffusion of the impurity of the hole accumulating layer 13, which, however, is very difficult.</p>
<p id="p0019" num="0019">On the other hand, the CCD image sensor of the present invention is provided with the HCS regions 19 between the<!-- EPO <DP n="11"> --> hole accumulating layers 13 of the adjacent sensor elements 1 arranged in a vertical row. Therefore, the sensor elements 1 are not affected significantly by the temperature of the process of forming the HCS regions 19 even if the temperature is relatively high.</p>
<p id="p0020" num="0020">As is apparent from the foregoing description, the CCD image sensor in accordance with the present invention is provided with the additional heavily doped regions of the same type of conduction as that of the hole accumulating layer between the sensor elements arranged in a vertical row. Therefore, a passage having a sufficiently large capacity for holes produced through photoelectric conversion is secured, the resistance against the hole current is reduced to a satisfactorily low extent and hence the impurity concentration of the channel stop regions need not be very high. Accordingly, reduction in the quantity of electric charges to be dealt with by the vertical shift registers due to the diffusion of the impurity of the heavily doped channel stop regions does not occur, the amplitude of the pulse to be applied to the substrate in performing an electronic shutter operation need not be increased and the anomalous increase of the quantity of electric charges to be dealt with by the sensor elements when a large quantity of light falls on the CCD image sensor can be suppressed.<!-- EPO <DP n="12"> --></p>
<p id="p0021" num="0021">Although the invention has been described in its preferred form with a certain degree of particularity, obviously many changes and variations are possible therein.</p>
</description><!-- EPO <DP n="13"> -->
<claims id="claims01" lang="en">
<claim id="c-en-01-0001" num="0001">
<claim-text>A CCD image sensor comprising:
<claim-text>- a plurality of sensor elements (1) each consisting of a hole accumulating layer (13) and an electric signal charge accumulating region (14) underlying the hole accumulating layer (13), and arranged in vertical and horizontal rows at intervals;</claim-text>
<claim-text>- vertical transfer registers (2) each formed along and on one side of each vertical row of sensor elements to transfer electric signal charges read from the sensor elements (1) on the corresponding vertical row in a vertical direction;</claim-text>
<claim-text>- continuous vertical p-doped channel stop regions (6) each formed along and on the other side of each vertical row of sensor elements to receive holes produced in the sensor elements; and</claim-text>
<claim-text>- heavily p-doped heavy channel stop-regions (19), each having a horizontal width smaller than the entire area between adjacent sensor elements but not less than the width of the channel stop region (6) and formed in a portion of the area between the sensor elements near the channel stop region and far from the vertical transfer register (2) so as to connect the hole accumulating layers (13) of the sensor elements (1) in the same vertical row, wherein the impurity concentration of the heavily doped heavy channel stop regions (19) is higher than that of the channel stop regions (6) and lower than that of the hole accumulating layers (13).</claim-text></claim-text></claim>
</claims><!-- EPO <DP n="14"> -->
<claims id="claims02" lang="de">
<claim id="c-de-01-0001" num="0001">
<claim-text>CCD-Bildsensor mit:
<claim-text>- einer Vielzahl von Sensorelementen (1), die jeweils aus einer Löcheransammlungsschicht (13) und einem Ansammlungsbereich (14) für elektrische Signalladungen unter der Löcheransammlungsschicht (13) bestehen und mit Intervallen in vertikalen und horizontalen Reihen angeordnet sind;</claim-text>
<claim-text>- Vertikalübertragungsregistern (2), die jeweils entlang einer Seite jeder vertikalen Reihe von Sensorelementen, und auf dieser, ausgebildet sind, um von den Sensorelementen (1) in der zugehörigen vertikalen Reihe gelesene elektrische Signalladungen in vertikaler Richtung zu übertragen;</claim-text>
<claim-text>- durchgehenden, vertikalen, p-dotierten Kanalstoppbereichen (6), von denen jeder entlang, und auf der anderen Seite, jeder vertikalen Reihe von Sensorelementen ausgebildet ist, um in denselben erzeugte Löcher aufzunehmen; und</claim-text>
<claim-text>- stark p-dotierten Kanalstoppbereichen (19) mit jeweils einer Horizontalbreite, die kleiner ist als das gesamte Gebiet zwischen benachbarten Sensorelementen, jedoch nicht kleiner als die Breite des Kanalstoppbereichs (6), und die in einem Abschnitt des Gebiets zwischen den Sensorelementen nahe dem Kanalstoppbereich und entfernt vom Vertikalübertragungsregister (2) so ausgebildet sind, dass sie die Löcheransammlungsschichten (13) der Sensorelemente (1) in derselben vertikalen Reihe verbinden, wobei die Fremdstoffkonzentration der stark dotierten Kanalstoppbereiche (19) höher als diejenige der Kanalstoppbereiche (6) und niedriger als diejenige der Löcheransammlungsschichten (13) ist.</claim-text></claim-text></claim>
</claims><!-- EPO <DP n="15"> -->
<claims id="claims03" lang="fr">
<claim id="c-fr-01-0001" num="0001">
<claim-text>Capteurs d'image CCD comprenant :
<claim-text>- une pluralité d'éléments de capteur (1) se composant chacun d'une couche d'accumulation de trous (13) et d'une zone d'accumulation de charges de signal électrique (14) sous la couche d'accumulation de trous (13), et disposés dans des rangées verticales et horizontales à des intervalles ;</claim-text>
<claim-text>- des registres de transfert vertical (2) chacun formé le long et d'un côté de chaque rangée verticale d'éléments de capteur pour transférer des charges de signal électrique lues à partir des éléments de capteur (1) sur la rangée verticale correspondant dans une direction verticale ;</claim-text>
<claim-text>- des zones d'arrêt de canal dopées p verticales continues (6) chacune formée le long et de l'autre côté de chaque rangée verticale d'éléments de capteur pour recevoir des trous produits dans les éléments de capteur ; et</claim-text>
<claim-text>- des zones fortement dopées -p (19), ayant chacune une largeur horizontale plus petite que la zone entière entre les éléments de capteur adjacent mais pas inférieure à la largeur de la zone d'arrêt de canal (6) et formés dans une partie de la zone entre les éléments de capteur près de la zone d'arrêt de canal et loin du registre de transfert vertical (2) afin de raccorder les couches d'accumulation de trous (13) des éléments de capteur (1) dans la même rangée verticale, où la concentration d'impureté des zones de fort arrêt de canal fortement dopées (19) est supérieure à celle des zones d'arrêt de canal (6) et inférieure à celle des couches d'accumulation de trous (13).</claim-text></claim-text></claim>
</claims><!-- EPO <DP n="16"> -->
<drawings id="draw" lang="en">
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</drawings>
</ep-patent-document>
