| (19) |
 |
|
(11) |
EP 0 552 863 A3 |
| (12) |
EUROPEAN PATENT APPLICATION |
| (88) |
Date of publication A3: |
|
18.08.1993 Bulletin 1993/33 |
| (43) |
Date of publication A2: |
|
28.07.1993 Bulletin 1993/30 |
| (22) |
Date of filing: 05.01.1993 |
|
|
| (84) |
Designated Contracting States: |
|
BE DE ES FR GB IT |
| (30) |
Priority: |
24.01.1992 US 825570
|
| (71) |
Applicant: ETHYL PETROLEUM ADDITIVES, INC. |
|
Richmond,
Virginia 23219-4304 (US) |
|
| (72) |
Inventor: |
|
- Taylor, John Michael
Richmond Heights,
Missouri 63117 (US)
|
| (74) |
Representative: Woods, Geoffrey Corlett et al |
|
J.A. KEMP & CO.
14 South Square
Gray's Inn London WC1R 5LX London WC1R 5LX (GB) |
|
| |
|
| (54) |
High sulfur mineral oil compositions |
(57) Copper corrosiveness of compositions comprising a major amount of a base oil of which
at least 50% by volume is mineral oil that has an inherent sulfur content of at least
0.2 percent by weight is reduced by adding to the oil a small amount of at least one
oil-soluble neutral hydrocarbyl phosphite ester, most preferably triphenyl phosphite.
The addition of phosphite can yield composition exhibiting a copper rod rating of
5 or below in the Cincinnati Milacron Thermal Stability test procedure "A", even though
in the absence of the addition of phosphite, the composition fails the test. The unpredictability
of the invention is shown by the fact that not all high sulfur oils respond to the
treatment, and no explanation for the divergence of results is presently known.