(19) |
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(11) |
EP 0 555 962 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
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14.12.1994 Bulletin 1994/50 |
(43) |
Date of publication A2: |
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18.08.1993 Bulletin 1993/33 |
(22) |
Date of filing: 20.01.1993 |
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(51) |
International Patent Classification (IPC)5: G01N 30/96 |
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(84) |
Designated Contracting States: |
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DE FR GB IT NL |
(30) |
Priority: |
10.02.1992 US 833334
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(71) |
Applicant: DIONEX CORPORATION |
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Sunnyvale
California 94088-3603 (US) |
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(72) |
Inventors: |
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- Stillian, John R.
Pleasanton,
California 94566 (US)
- Barreto,Victor M.
Santa Clara,
California 95050 (US)
- Friedman, Keith A.
Santa Clara,
California 95051 (US)
- Rabin, Steven B.
Santa Clara,
California 95051 (US)
- Toofan, Mahmood
Dixon,
California 95620 (US)
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(74) |
Representative: Allard, Susan Joyce et al |
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BOULT, WADE & TENNANT
27 Furnival Street London EC4A 1PQ London EC4A 1PQ (GB) |
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(54) |
Ion chromatography system using electrochemical suppression and detector effluent
recycle |
(57) A method of streamlining and lowering the cost of operation of ion chromatography
as well as improving detection limits is disclosed. The apparatus includes chromatographic
separating means (10) through which a sample is eluted in an eluent solution including
an electrolyte. The apparatus includes a sandwich suppressor (11) having a chromatography
effluent compartment separated from a detector effluent compartment by an ion exchange
membrane (17,32,34,36), forming a chromatography effluent flow channel and a detector
effluent channel, respectively. Electrode means (42,44) are disposed in communication
with both flow channels for passing an electric current transverse to the solution
that is passing through them. The chromatography effluent flows through the chromatography
effluent flow channel of the suppressor and through detector (12) which detects resolved
ionic species therein. The effluent from the detector is then recycled through the
detector effluent flow channel and forms a sump for electrolyte ions passing across
the chromatography effluent as well as supplying the water for the electrolysis reaction
generating acid (or base) for suppression.
