(19)
(11) EP 0 577 124 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
21.09.1994 Bulletin 1994/38

(43) Date of publication A2:
05.01.1994 Bulletin 1994/01

(21) Application number: 93110517.5

(22) Date of filing: 01.07.1993
(51) International Patent Classification (IPC)5C21D 8/12
(84) Designated Contracting States:
DE FR GB IT

(30) Priority: 02.07.1992 JP 175790/92
03.08.1992 JP 206795/92
19.08.1992 JP 220500/92
22.10.1992 JP 284787/92
12.11.1992 JP 302728/92
21.12.1992 JP 340746/92

(71) Applicant: NIPPON STEEL CORPORATION
Tokyo 100-12 (JP)

(72) Inventors:
  • Tanaka, Osamu, c/o Nippon Steel Corp. Yawata
    Kitakyushu-shi, Fukuoka (JP)
  • Kuroki, Katsuro, c/o Nippon Steel Corp. Yawata
    Kitakyushu-shi, Fukuoka (JP)
  • Ishiba, Maremizu, c/o Nippon Steel Corp. Yawata
    Kitakyushu-shi, Fukuoka (JP)
  • Masui, Hiroaki, c/o Nippon Steel Corp. Yawata
    Kitakyushu-shi, Fukuoka (JP)
  • Haratani, Tsutomu, c/o Nippon Steel Corp. Yawata
    Kitakyushu-shi, Fukuoka (JP)
  • Nakamura, Yoshio, c/o Nippon Steel Corp. Yawata
    Kitakyushu-shi, Fukuoka (JP)
  • Honma, Hotaka, c/o Nippon Steel Corp. Yawata
    Kitakyushu-shi, Fukuoka (JP)
  • Mishima, Yoichi, c/o Nippon Steel Corp. Yawata
    Kitakyushu-shi, Fukuoka (JP)

(74) Representative: VOSSIUS & PARTNER 
Postfach 86 07 67
81634 München
81634 München (DE)


(56) References cited: : 
   
       


    (54) Grain oriented electrical steel sheet having high magnetic flux density and ultra low iron loss and process for producing the same


    (57) A grain oriented electrical steel sheet having no significant glass film and having a high magnetic flux density and an excellent iron loss property, comprising, in terms of by weight, 2.5 to 4.5% of Si, the steel sheet having, as oxides on its surface, a glass film comprising 0.6 g/m² or less in total of forsterite and spinel composed of MgO, SiO₂ and Al₂O₃ and an insulating coating having a thickness of 6 µm or less, the face tension imparted on the surface of the steel sheet by the coating being in the range of from 0.5 to 2.0 kg/mm². In the final box annealing of the steel sheet after primary recrystallization annealing, use is made of an annealing separator comprising 100 parts by weight of MgO and, added thereto, 2 to 30 parts by weight of at least one member selected from the group consisting of chlorides, carbonates, nitrates, sulfates and sulfides of Li, K, Bi, Na, Ba, Ca, Mg, Zn, Fe, Zr, Sr, Sn, Al, etc., and the heating in the final box annealing is effected in an atmosphere comprising N₂ and H₂ with the nitrogen content being 30% or more at a heating rate of 20°C/hr or less, and a seam or spotty flaw is imparted at an angle of 45 to 90° to the rolling direction of the steel sheet.





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