BACKGROUND OF THE INVENTION
1. Field of the Invention
[0001] The present invention relates to a high-strength aluminum-based alloy having a high
strength, a high ductility and a high specific strength and to a compacted and consolidated
aluminum-based alloy material produced by compacting and consolidating the alloy.
2. Description of the Prior Art
[0002] An aluminum-based alloy having a high strength and a high heat resistance has heretofore
been produced by the liquid quenching process or other similar rapid solidification
processes. In particular, such a rapidly solidified aluminum-based alloy is disclosed
in Japanese Patent Laid-Open No. 275732/1989. A rapidly solidified aluminum-based
alloy is amorphous or microcrystalline and an excellent alloy having a high strength,
a high heat resistance and a high corrosion resistance.
[0003] Although the aluminum-based alloy disclosed in the Japanese Patent Laid-Open No.
275732/1989 is an excellent alloy having a high strength, a high heat resistance and
a high corrosion resistance and is excellent also in the workability when it is used
as a high-strength material, there is room for an improvement when it is used as a
material of which a high toughness and a high specific strength are required.
[0004] The above-described alloy is an alloy having a high strength, a heat resistance and
a high corrosion resistance, and is excellent in the workability when it is prepared
in a powdery or flaky form by the liquid quenching process and subjected as a raw
material to various working processes to give a final product, that is, when a product
is prepared through primary working only. However, when a consolidated material is
formed from the powder or flakes as the raw material and further worked, that is,
subjected to a secondary working, there is room for an improvement in the workability
and retention of excellent properties of the material after the working.
[0005] Accordingly, an object of the present invention is to provide an aluminum alloy having
a high strength, a high heat resistance, a high specific strength and an excellent
toughness while maintaining a strength applicable to a structural member required
to have a high reliability, and to provide a compacted and consolidated material of
an aluminum-based material which enables secondary working (extrusion, machining,
etc.) to be easily conducted and excellent properties inherent in the raw material
to be retained even after the working.
SUMMARY OF THE INVENTION
[0006] In order to solve the above-described problem, the first aspect of the present invention
is directed to a high-strength aluminum-based alloy having a composition represented
by the general formula:
Al
balNi
aM
1b
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo
and a and b are, in atomic %, 5 ≦ a ≦ 10 and 0.1 ≦ b ≦ 5.
[0007] The second aspect of the present invention is directed to a high-strength aluminum-based
alloy having a composition represented by the general formula:
Al
balNi
aM
1bM
2c
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo,
M₂ represents at least one element selected from among Nb, Ta and Hf and a, b and
c are, in atomic %, 5 ≦ a ≦ 10, 0.1 ≦ b ≦ 5 and 0.1 ≦ c ≦ 5.
[0008] The third aspect of the present invention is directed to a high-strength aluminum-based
alloy having a composition represented by the general formula:
Al
balNi
aM
1bQ
d
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo,
Q represents at least one element selected from among Mg, Cu and Zn and a, b and d
are, in atomic %, 5 ≦ a ≦ 10, 0.1 ≦ b ≦ 5 and 0.01 ≦ d ≦ 4.
[0009] The fourth aspect of the present invention is directed to a high-strength aluminum-based
alloy having a composition represented by the general formula:
Al
balNi
aM
1bM
2cQ
d
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo,
M₂ represents at least one element selected from among Nb, Ta and Hf, Q represents
at least one element selected from among Mg, Cu and Zn and a, b, c and d are, in atomic
%, 5 ≦ a ≦ 10, 0.1 ≦ b ≦ 5, 0.1 ≦ c ≦ 5 and 0.01 ≦ d ≦ 4.
[0010] The above-described alloys of the first to fourth aspect are preferably composed
of a matrix of aluminum or a supersaturated aluminum solid solution and, homogeneously
and finely distributed in the matrix, particles made of a stable phase or a metastable
phase of various intermetallic compounds formed from the matrix element and other
alloying elements and/or various intermetallic compounds formed from other alloying
elements themselves.
[0011] The present invention further provides a compacted and consolidated aluminum-based
alloy material having a high strength and obtained by compacting and consolidating
a quench-solidified aluminum-based alloy having a composition represented by any one
of the above-defined general formulae.
[0012] The compacted and consolidated aluminum-based alloy is preferably composed of a matrix
comprised of aluminum or a supersaturated aluminum solid solution, whose average crystal
grain size is 40 to 2000 nm, and, homogeneously distributed in the matrix, particles
made of a stable phase or a metastable phase of various intermetallic compounds formed
from the matrix element and other alloying elements and/or various intermetallic compounds
formed from other alloying elements themselves, the intermetallic compounds having
a mean particle size of 10 to 1000 nm.
[0013] Further, the compacted and consolidated material of the present invention is preferably
produced by melting a material having the above-specified composition, quench-solidifying
the melt into powder or flakes, compacting the resulting powder or flakes, and press
forming and consolidating the compacted powder or flakes into the above-mentioned
structure by conventional plastic working.
BRIEF DESCRIPTION OF THE DRAWINGS
[0014] FIGS. 1 to 5 are each a graph showing the relationship between the change of composition
of the alloy and the properties.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0015] The aluminum-based alloy of the present invention can be produced through the rapid
solidification of a molten metal of an alloy having the above-described composition
by the liquid quench process. The liquid quench process is a process wherein a molten
alloy is rapidly cooled and, for example, the single-roller melt-spinning process,
twin-roller melt-spinning process, in-rotating-water melt-spinning process, etc.,
are particularly useful. In these processes, a cooling rate of about 10² to 10⁸ K/sec
can be attained. In producing a thin ribbon material by the single-roller melt-spinning
process, twin-roller melt-spinning process or the like, a molten metal is injected
through a nozzle into, for example, a copper or steel roll having a diameter of 30
to 300 mm and rotating at a constant speed in the range of from about 300 to 10000
rpm. Thus, various thin ribbon materials having a width of about 1 to 300 mm and a
thickness of about 5 to 500 µm can be easily produced. On the other hand, a fine wire
material can be easily produced by the in-rotating-water melt-spinning process by
injecting a molten metal by means of a back pressure of an argon gas through a nozzle
into a liquid cooling medium layer having a depth of about 1 to 10 cm held by means
of a centrifugal force within a drum rotating at about 50 to 500 rpm. In this case,
the angle of the molten metal ejected through the nozzle to the cooling medium surface
is preferably about 60° to 90°, while the relative speed ratio of the ejected molten
metal to the liquid cooling medium surface is preferably 0.7 to 0.9.
[0016] Instead of using the above-described processes, a thin film can be produced by sputtering,
and a quenched powder can be produced by various atomization processes, such as a
high pressure gas spraying process, or a spray process.
[0017] The alloy of the present invention can be produced by the above-described single-roller
melt-spinning process, twin-roller melt-spinning process, in-rotating-water melt spinning
process, sputtering, various atomization processes, spray process, mechanical alloying
process, mechanical grinding process, etc. Further, if necessary, the mean crystal
grain size and the mean size of the intermetallic compound particles can be controlled
by suitably selecting the production conditions.
[0018] Further, some compositions can provide an unnecessarily fine structure. When the
structure is unnecessarily fine, however, it often becomes impossible to attain a
ductility necessary for the working. In this case, when the resultant structure is
heated, crystals grow above a specified temperature. At that time, various intermetallic
compounds precipitate within the crystals. Thus, it is also possible to produce an
alloy having a crystal grain size and an intermetallic compound particle size suitable
for the present invention also by suitably selecting the heating conditions.
[0019] In the aluminum-based alloy having a composition represented by the general formula
according to the first to fourth aspects, when the values of a, b, c and d are respectively
outside the ranges of from 5 to 10%, from 0.1 to 5%, from 0.1 to 5% and from 0.01
to 4% in terms of atomic %, the alloy becomes so brittle that neither satisfactory
toughness nor high strength can be obtained. In other words, no alloy having properties
contemplated in the present invention can be produced by quenching means on a commercial
scale utilizing the above-described liquid quenching process, etc.
[0020] More precisely, the Ni element combines with Al to form compounds (for example, Al₃Ni),
which are homogeneously dispersed in the Al matrix to improve the strength, rigidity
and heat resistance. In the above-described alloy, when the Ni content is less than
5 atomic %, the matrix cannot be satisfactorily strengthened, while when the Ni content
exceeds 10 atomic %, the ductility becomes poor.
[0021] The M₁ element is at least one element selected from among V, Cr, Mn, Co and Mo and
combines with Al to form compounds, which are homogeneously and finely dispersed in
the Al matrix to increase the strength of the matrix and, at the same time, to improve
the heat resistance. In the above-described alloy, when the M₁ element content is
less than 0.1 atomic %, the matrix is coarsened to lower the strength. On the other
hand, when the M₁ element content exceeds 5 atomic %, the elongation at room temperature
lowers to pause a problem in working.
[0022] The M₂ element is at least one element selected from among Nb, Ta and Hf and, when
it is present together with the M₁ element, the strength of the matrix can be further
increased and the heat resistance. In the above-described alloy, when the M₂ element
content is less than 0.1 atomic %, the matrix is coarsened to lower the strength.
On the other hand, when the M₂ element content exceeds 5 atomic %, the elongation
at room temperature lowers, which causes a problem in working. Further, when importance
is placed on the elongation of the alloy, both the M₁ element content and the M₂ element
content are preferably 5 atomic % or less. Further, in the above-described alloy system,
the addition of the M₂ element in a very small amount with respect to the M₁ element
is particularly useful from the viewpoint of improving the strength and ductility
of the alloy.
[0023] The Q element is at least one element selected from among Mg, Cu and Zn and combines
with Al or between Q elements to form compounds. The addition of the Q element in
a very small amount serves to strengthen the matrix to improve the strength and, at
the same time, can improve the heat resistance, specific strength and specific elasticity.
In the above-described alloy, when the Q element content is less than 0.01 atomic
%, the effect of addition of the Q element cannot be expected. On the other hand,
when the content exceeds 4 atomic %, the strength lowers.
[0024] The compacted and consolidated material of the aluminum-based alloy of the present
invention is preferably produced by quench-solidifying a material having the composition
represented by any one of the general formulae defined above in the first to fourth
aspect, compacting the resultant powder or flakes and subjecting the compacted powder
or flakes to press forming and consolidating by conventional plastic working means.
In this case, the powder or flake as the raw material should have a mean crystal grain
size of 2000 nm or less, and when the intermetallic compounds precipitate, the mean
particle size should be 1000 nm or less. The raw material is heated at a temperature
of 50 to 600°C in the step of compacting and subjected to forming consolidation to
provide the compacted and consolidated material of the present invention.
[0025] The above-described conventional plastic working means should be interpreted in a
broad sense and includes also press forming and powder metallurgy techniques.
[0026] In the above-described general formulae, when the values of a, b, c and d are respectively
limited to 5 to 10%, 0.5 to 5% , 0.5 to 5% and 0.01 to 4% in terms of atomic %, the
material has a higher strength at room temperature to high temperatures (particularly
200°C) than that of the conventional (commercially available) high-strength aluminum
alloys and a ductility capable sufficient to withstanding practical working.
[0027] In the alloy consolidated material of the present invention, Ni element is an element
having a relatively small diffusibility in the Al matrix and, when Ni is finely dispersed
as an intermetallic compound (for example, Al₃Ni) in the Al matrix, it has the effect
of strengthening the matrix and inhibiting the growth of crystal grains. Thus, it
can remarkably improve the hardness and strength of the alloy and stabilize the finely
crystalline phase not only at room temperature but also at high temperatures, thus
imparting heat resistance.
[0028] The M₁ element is an element having a small diffusibility in the Al matrix and forms
various metastable or stable intermetallic compounds, which contributes to the stabilization
of the resultant fine crystalline structure.
[0029] As with the M₁ element, the M₂ element has a small diffusibility in the Al matrix
to form various metastable or stable intermetallic compounds and is present together
with the M₁ element to further contribute to the stabilization of the fine crystalline
structure.
[0030] The Q element combines with Al or another Q element to form compounds to strengthen
the matrix and, at the same time, to improve the heat resistance. Further, it can
improve the specific strength and specific elasticity.
[0031] In the consolidated material of an aluminum-based alloy according to the present
invention, the mean crystal grain size of the matrix is preferably limited to 40 to
2000 nm, because when it is less than 40 nm, the strength is high but the ductility
is insufficient and a mean crystal grain size of 40 nm or more is necessary for attaining
a ductility sufficient for existing working processes, while when it exceeds 2000
nm, the strength lowers so rapidly that no material having a high strength can be
produced. In order to produce a material having a high strength, it is preferable
that the mean matrix crystal grain size be 2000 nm or less.
[0032] The mean particle size of the intermetallic compounds is preferably limited to 10
to 1000 nm, because when it is outside the above-described range, the intermetallic
compounds do not serve as an element for strengthening the Al matrix. Specifically,
when the mean particle size is less than 10 nm, the intermetallic compounds do not
contribute to the strengthening of the Al matrix, and when the intermetallic compounds
are excessively dissolved in the solid solution form in the matrix, there is a possibility
that the material becomes brittle. On the other hand, when the mean particle size
exceeds 1000 nm, the size of the dispersed particles becomes too large to maintain
the strength and the intermetallic compounds cannot serve as a strengthening element.
[0033] When the mean particle size is in the above-described range, it becomes possible
to improve the Young's modulus, high-temperature strength and fatigue strength.
[0034] In the compacted and consolidated material of an aluminum-based alloy according to
the present invention, the mean crystal grain size and the state of dispersion of
the intermetallic compounds can be controlled through proper selection of the production
conditions. When importance is given to the strength, the mean crystal grain size
of the matrix and the mean grain size of the intermetallic compounds are controlled
so as to become small. On the other hand, when importance is given to the ductility,
the mean crystal grain size of the matrix and the mean particle size of the intermetallic
compounds are controlled so as to become large. Thus, compacted and consolidated materials
suitable for various purposes can be produced.
[0035] Further, when the mean crystal grain size of the matrix is controlled so as to fall
within the range of from 40 to 2000 nm, it becomes possible to impart excellent properties
as a superplastic working material.
[0036] The present invention will now be described in more detail with reference to the
following Examples.
Example 1
[0037] Each of the master alloys having a composition (atomic percentage) specified in Table
1 was produced by the melt process in an arc melting furnace, and a thin ribbon (thickness:
20 µm, width: 1.5 mm) was produced therefrom by means of a conventional single-roller
liquid quenching apparatus (a melt spinning apparatus). In this case, the roll was
a copper roll with a diameter of 200 mm, the number of revolutions was 4000 rpm, and
the atmosphere was argon having a pressure of 10⁻³ Torr.
[0038] The ribbons of alloys having the respective compositions specified in Table 1 produced
under the above-described production conditions were examined for their hardness (Hv)
and ductility.
[0039] The hardness is the value (DPN) measured with a microVickers hardness tester under
a load of 25 g. The ductility is expressed in terms of Duc (ductile) when the material
has a ductility on such a level that it is not broken in a 180° adhesion bending test,
while it is expressed in terms of Bri (brittle) when the material has a ductility
on such a level that it cannot be applied to the 180° adhesion bending test.
[0040] The results are given in Table 1.
Table 1
Invention sample No. |
Composition (at.%) |
Hardness Hv (DPN) |
Ductillity |
|
Al |
Ni |
M₁ |
M₂ |
Q |
|
|
1 |
balance |
10 |
Cr=0.6 |
|
|
290 |
Bri |
2 |
balance |
9 |
V=1.6 |
|
|
270 |
Duc |
3 |
balance |
9 |
Mn=0.5 |
|
|
265 |
Duc |
4 |
balance |
8 |
Co=2.5 |
|
|
257 |
Duc |
5 |
balance |
8 |
Cr=1.0 |
Nb=2.0 |
|
260 |
Duc |
6 |
balance |
7 |
Mo=0.5 |
Hf=1.0 |
|
223 |
Duc |
7 |
balance |
6 |
V=0.7 |
|
|
212 |
Duc |
8 |
balance |
5 |
Mn=1.0 |
|
|
198 |
Duc |
9 |
balance |
5 |
W=3.0 |
|
|
187 |
Duc |
10 |
balance |
10 |
V=1.0 Cr=1.5 |
|
Mg=0.2 |
289 |
Bri |
11 |
balance |
9 |
Mn=2.0 |
|
Cu=2.0 |
301 |
Bri |
12 |
balance |
8 |
Cr=0.5 |
|
Mg=1.0, Zn=2.0 |
278 |
Bri |
13 |
balance |
8 |
Cr=3.0 |
Hf=1.0 |
Cu=1.0 |
235 |
Duc |
14 |
balance |
7 |
Cr=1.3 |
Ta=1.0 |
Mg=2.5 |
222 |
Duc |
15 |
balance |
6 |
V=2.2 |
|
Cu=2.5 |
212 |
Duc |
16 |
balance |
5 |
Co=4.0 |
|
Mg=2.0 |
188 |
Duc |
17 |
balance |
8 |
Mn=2.0 |
|
Mg=2.6 |
212 |
Duc |
18 |
balance |
7 |
V=3.2, Co=1.0 |
|
Cu=2.0 |
232 |
Duc |
19 |
balance |
6 |
Mn=2.0 |
|
|
232 |
Duc |
20 |
balance |
5 |
Co=4.2 |
|
|
178 |
Duc |
[0041] As is apparent from Table 1, the alloys of the present invention are materials excellent
in hardness and ductility.
[0042] Further, the thin ribbons produced under the above-described production conditions
were observed under TEM (transmission electron microscopy). As a result, it was found
that all the samples had a fine crystalline structure composed of a matrix of aluminum
or a supersaturated solid solution of aluminum and, homogeneously distributed in the
matrix, particles made of a stable phase or a metastable phase of various intermetallic
compounds formed from the matrix element and other alloying elements and/or various
intermetallic compounds formed from alloying elements themselves.
Example 2
[0043] Aluminum-based alloy powders having respective predetermined compositions (Al
97.5-xNi
xCr
2.5 and Al
92-xNi₈Cr
x) were prepared using a gas atomizing apparatus. The aluminum-based alloy powders
thus produced were filled into a metallic capsule and degassed to prepare billets
for extrusion. These billets were extruded at a temperature of 200 to 550°C by an
extruder. The mechanical properties (tensile strength and elongation) at room temperature
of the extruded materials (consolidated materials) produced under the above-described
production conditions are shown in FIGS. 1 and 2.
[0044] As is apparent from FIG. 1, the tensile strength of the consolidated material at
room temperature rapidly increases when the Ni content is 5 atomic % or more, and
rapidly lowers when the Ni content exceeds 10 atomic %. Further, it is apparent that,
when the Ni content exceeds 10 atomic %, the elongation is small and the minimum elongation
(2%) necessary for general working is obtained when the Ni content is 10 atomic %
or less.
[0045] Further, as shown in FIG. 2, the strength of the consolidated material at room temperature
begins to increase when the Cr content reaches 0.1 atomic %, and rapidly lowers when
the Cr content exceeds 5 atomic %. Further, it is apparent that the elongation lowers
when the Cr content exceeds 5 atomic % and the minimum elongation (2%) necessary for
general working is obtained when the Cr content is 5 atomic % or less.
Example 3
[0046] The procedure of Example 2 was repeated to prepare extruded materials (consolidated
materials) having compositions respectively represented by the formulae Al
98-xNi
xCr₁Nb₁ and Al
91.5-xNi
7.5Cr₁Nb
x. The materials were examined for their mechanical properties (tensile strength and
elongation). The results are shown in FIGS. 3 and 4.
[0047] As is apparent from FIG. 3, the tensile strength of the consolidated material at
room temperature rapidly increases when the Ni content is 5 atomic % or more and rapidly
lowers when the Ni content exceeds 10 atomic %. Further, it is apparent that, when
the Ni content exceeds 10 atomic %, the elongation is small and the minimum elongation
(2%) necessary for general working is obtained when the Ni content is 10 atomic %
or less.
[0048] Further, as shown in FIG. 4, the strength of the consolidated material at room temperature
begins to increase when the Nb content reaches 0.1 atomic %, and rapidly lowers when
the Nb content exceeds 4.5 atomic %. Further, it is apparent that the minimum elongation
(2%) necessary for general working is obtained when the Nb content is 5 atomic % or
less. Further, it is apparent that the strength rapidly lowers when the total content
of Nb and Cr exceeds about 5 atomic %.
Example 4
[0049] The procedure of Example 2 was repeated to prepare extruded materials (consolidated
materials) having a composition represented by the formula Al
9.5-xNi
8.5CO
x. The material was examined for its mechanical properties (tensile strength and elongation).
The results are shown in FIG. 5.
[0050] As is apparent from FIG. 5, the tensile strength of the consolidated material at
room temperature begins to increase when the Co content reaches 0.1 atomic %, and
rapidly lowers when the Co content exceeds 5 atomic %. Further, it is apparent that,
when the Co content exceeds 5 atomic %, the elongation lowers and the minimum elongation
(2%) necessary for general working is obtained when the Co content is 5 atomic % or
less.
Example 5
[0051] The procedure of the Example 2 was repeated to prepare extruded materials (consolidated
materials) having the compositions specified in the left column of Table 2 were prepared
and subjected to measurement of tensile strength at room temperature, tensile strength
at a high temperature (200°C), Young's modulus (modulus of elasticity) and hardness
as shown in the right column of Table 2.
[0052] From the results given in Table 2, it is apparent that the consolidated materials
of the present invention are excellent in the tensile strengths at room temperature
and a high temperature (200°C), Young's modulus and hardness. Further, the tensile
strength is large, and the specific gravity is small, so that it is apparent that
the consolidated materials of the present invention have a high specific strength.
[0053] The consolidated materials listed in Table 1 were subjected to measurement of the
elongation at room temperature to reveal that the elongation exceeds the minimum elongation
(2%) necessary for general working.
[0054] Test pieces for observation under TEM were cut out of the consolidated materials
(extruded materials), including consolidated materials of Examples 2 to 4, produced
under the above-described production conditions and observation was conducted to determine
the crystal grain size of their matrix and particle size of the intermetallic compounds.
All the samples were composed of a matrix of aluminum or a supersaturated aluminum
solid solution having a mean crystal grain size of 40 to 2000 nm and, homogeneously
distributed in the matrix, particles made of a stable phase or a metastable phase
of various intermetallic compounds formed from the matrix element and other alloying
elements and/or various intermetallic compounds formed from other alloying elements
themselves, the intermetallic compounds having a mean grain size of 10 to 1000 nm.

[0055] As described above, the aluminum-based alloy of the present invention has a high
strength and a high heat resistance, which renders it useful as a high specific strength
material and, at the same time, has an excellent workability by virtue of its high
specific elasticity and high toughness. Further, it can be worked while retaining
a sufficient strength applicable to structural materials of which a high reliability
is required.
[0056] Further, the compacted and consolidated material of an aluminum-based alloy according
to the present invention can be easily subjected secondary working (extrusion, cutting,
etc.) and can retain excellent properties inherent in the raw material even after
the working.
1. A high-strength aluminum-based alloy having a composition represented by the general
formula:
AlbalNiaM1b
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo
and a and b are, in atomic %, 5 ≦ a ≦ 10 and 0.1 ≦ b ≦ 5.
2. A high-strength aluminum-based alloy having a composition represented by the general
formula:
AlbalNiaM1bM2c
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo,
M₂ represents at least one element selected from among Nb, Ta and Hf and a, b and
c are, in atomic %, 5 ≦ a ≦ 10, 0.1 ≦ b ≦ 5 and 0.1 ≦ c ≦ 5.
3. A high-strength aluminum-based alloy having a composition represented by the general
formula:
AlbalNiaM1bQd
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo,
Q represents at least one element selected from among Mg, Cu and Zn and a, b and d
are, in atomic %, 5 ≦ a ≦ 10, 0.1 ≦ b ≦ 5 and 0.01 ≦ d ≦ 4.
4. A high-strength aluminum-based alloy having a composition represented by the general
formula:
AlbalNiaM1bM2cQd
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo,
M₂ represents at least one element selected from among Nb, Ta and Hf, Q represents
at least one element selected from among Mg, Cu and Zn and a, b, c and d are, in atomic
%, 5 ≦ a ≦ 10, 0.1 ≦ b ≦ 5, 0.1 ≦ c ≦ 5 and 0.01 ≦ d ≦ 4.
5. A high-strength aluminum-based alloy according to Claim 2 or 4, wherein b and c in
the general formula are, in atomic %, b + c ≦ 5.
6. A high-strength aluminum-based alloy according to any one of Claims 1 to 5, wherein
the aluminum-based alloy is composed of a matrix of aluminum or a supersaturated aluminum
solid solution and, homogeneously and finely distributed in the matrix, particles
made of a stable phase or a metastable phase of various intermetallic compounds formed
from the matrix element and other alloying elements and/or various intermetallic compounds
formed from other alloying elements themselves.
7. A compacted and consolidated aluminum-based alloy, which has been produced by compacting
and consolidating a quench-solidified material having a composition represented by
the general formula:
AlbalNiaM1b
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo
and a and b are, in atomic %, 5 ≦ a ≦ 10 and 0.1 ≦ b ≦ 5.
8. A compacted and consolidated aluminum-based alloy material, which has been produced
by compacting and consolidating a quench solidified material having a composition
represented by the general formula:
AlbalNiaM1bM2c
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo,
M₂ represents at least one element selected from among Nb, Ta and Hf and a, b and
c are, in atomic %, 5 ≦ a ≦ 10, 0.1 ≦ b ≦ 5 and 0.1 ≦ c ≦ 5.
9. A compacted and consolidated aluminum-based alloy material, which has been produced
by compacting and consolidating a quench-solidified material having a composition
represented by the general formula:
AlbalNiaM1bQd
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo,
Q represents at least one element selected from among Mg, Cu and Zn and a, b and d
are, in atomic %, 5 ≦ a ≦ 10, 0.1 ≦ b ≦ 5 and 0.01 ≦ d ≦ 4.
10. A compacted and consolidated aluminum-based alloy, which has been produced by compacting
and consolidating a quench-solidified material having a composition represented by
the general formula:
AlbalNiaM1bM2cQd
wherein M₁ represents at least one element selected from among V, Cr, Mn, Co and Mo,
M₂ represents at least one element selected from among Nb, Ta and Hf, Q represents
at least one element selected from among Mg, Cu and Zn and a, b, c and d are, in atomic
%, 5 ≦ a ≦ 10, 0.1 ≦ b ≦ 5, 0.1 ≦ c ≦ 5 and 0.01 ≦ d ≦ 4.
11. A compacted and consolidated aluminum-based alloy material according to any one of
Claims 7 to 10, wherein the compacted and consolidated material has been produced
by melting a material having a composition represented by the general formula, quench-solidifying
the molten material into powder or flakes, compacting the resultant powder or flakes
and subjecting the compacted powder or flakes to press forming and consolidating the
compacted powder or flakes by conventional plastic working means.
12. A compacted and consolidated aluminum-based alloy material according to any one of
Claims 7 to 11, wherein the compacted and consolidated material is composed of a matrix
of aluminum or a supersaturated aluminum solid solution, whose average crystal grain
size is 40 to 2000 nm, and, homogeneously distributed in the matrix, particles made
of a stable phase or a metastable phase of various intermetallic compounds formed
from the matrix element and other alloying elements and/or various intermetallic compounds
formed from other alloying elements themselves, the intermetallic compounds having
a mean particle size of 10 to 1000 nm.