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(11) |
EP 0 636 057 B1 |
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EUROPEAN PATENT SPECIFICATION |
| (45) |
Mention of the grant of the patent: |
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28.05.1997 Bulletin 1997/22 |
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Date of filing: 01.03.1993 |
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International application number: |
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PCT/US9301/789 |
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International publication number: |
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WO 9320/976 (28.10.1993 Gazette 1993/26) |
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ABRASIVE ARTICLE
SCHLEIFMITTEL
ARTICLE ABRASIF
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Designated Contracting States: |
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DE ES FR GB IT |
| (30) |
Priority: |
13.04.1992 US 868007
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Date of publication of application: |
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01.02.1995 Bulletin 1995/05 |
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Proprietor: MINNESOTA MINING AND MANUFACTURING COMPANY |
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St. Paul,
Minnesota 55133-3427 (US) |
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| (72) |
Inventors: |
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- LINDHOLM, Gene, O.
Saint Paul, MN 55133-3427 (US)
- STERNER, Mark, L.
Saint Paul, MN 55133-3427 (US)
- TOCCI, Theodore, C.
Saint Paul, MN 55133-3427 (US)
|
| (74) |
Representative: VOSSIUS & PARTNER |
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Siebertstrasse 4 81675 München 81675 München (DE) |
| (56) |
References cited: :
WO-A-91/09705
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US-A- 4 437 269
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- PATENT ABSTRACTS OF JAPAN vol. 8, no. 112 (M-298)(1549) 25 May 1984
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
|
[0001] The present invention relates generally to an abrasive article in which abrasive
grains are bonded to a backing.
[0002] On an abrasive article, indicia in the form of printed information are placed on
the back side, which is the side opposite from the front side. The front side contains
the abrasive grains or grit. The indicia typically includes a grade number, a product
name or other identification. The grade number refers to the average particle size
or the particle size distribution of the abrasive grain. Printing on the back side
of some prior art abrasive articles is incidentally viewable from the front side due
to the substrate being translucent. However, the information is not readable since
it is in a mirror image. Such a product has been sold under the trademark IMPERIAL
MICRO FINISHING FILM by Minnesota Mining and Manufacturing Company of St. Paul, Minnesota.
[0003] Abrasive articles are typically converted into a wide variety of forms such as sheets,
discs, or belts. It is well known to attach the discs or sheets to a backup pad or
support pad during use such as with a pressure sensitive adhesive.
[0004] When the indicia is disposed on the back side of the abrasive article, the information
cannot be seen if the abrasive article is opaque. If the abrasive article is translucent,
only a mirror image of the indicia is seen and it is difficult to discern the indicia.
Information which cannot be read by viewing the front of the abrasive article has
several disadvantages. First, an operator may want to check the particular grade of
an abrasive article if the operator forgets which grade of abrasive article is being
used when the abrasive article is attached to a back-up pad or support pad. Secondly,
if a second operator or new operator uses the same abrasive article, the second or
new operator may not know the particular grade of the abrasive article. In both instances,
the operator has to remove the abrasive article from the pad in order to check the
grade, the product identification, or the manufacturer. Then, if possible, the abrasive
article is remounted on the back of the pad. If not, then a new abrasive article has
to be attached to the pad. Another disadvantage relates to packaging of the abrasive
article. Generally, in order to check the grade of the abrasive article, an abrasive
article has to be removed from the package in order to view the indicia containing
the grade designation.
[0005] The Steinhauser et al. U.S. Patent 3,849,949 discloses a concatenation of coated
abrasive discs in which the non-abrasive side of the disc contains a pressure sensitive
adhesive.
[0006] The Shaw U.S. Patent 4,437,269 discloses an abrasive sheet having indicia carried
on its rear face overlaid by a translucent textile material providing a surface engagable
by hooks. The material being adhered to the indicia and information content remain
discernible through the textile material.
[0007] The Ott U.S. Patent 4,609,581 discloses a coated abrasive sheeting that is adhered
to a backup pad by means of a loop material on the rear surface of the coated abrasive
sheet. The loop material comprises a carrier web with a multiplicity of multi-filament
yarns stitched into the coated abrasive backing with portions of the yarns providing
the loops.
[0008] JP-A-59-19678 is directed to a method of producing a soft offset grinding wheel wherein
letters and patterns appear on a surface of a substrate while grains are attached
to the back of the substrate.
[0009] The present invention includes an abrasive sheet having a substrate with a front
and back side. A layer of abrasive material is adhered to the front side of the substrate.
Indicia are disposed on the substrate and are viewable from the front side of the
substrate through the layer of abrasive material in a non-mirror image readable from
left to right.
[0010] In one preferred embodiment, the indicia are disposed on the back side of a substrate
that is light transmissive. In another preferred embodiment, the indicia are disposed
on the front side of a substrate which may or may not be light transmissive.
[0011] Figure 1 is a cross-sectional view of an abrasive article of the present invention.
[0012] Figure 2 is a perspective view of an abrasive article of the present invention with
indicia being disposed on the front surface thereof.
[0013] Figure 3 is a perspective view of the abrasive article of the present invention with
indicia being disposed on a back surface thereof and readable from the front surface.
[0014] An abrasive article of the present invention is generally indicated at 20 in Figure
1. Abrasive article 20 includes a backing or substrate 22 which has a front side 24
and a back side 26. An abrasive material 28 is bonded to the front side 24 using a
suitable adhesive 25 or other bonding means now known or later developed. Indicia
30 are positioned either on the front side 24 as illustrated in Figure 2 or on the
back side 26 and viewable on the front side 24 as illustrated in Figure 3. In both
instances, the indicia are viewable in a non-mirror image readable from left to right
from the front side of the abrasive article.
[0015] As illustrated in Figure 2, the indicia 30 are applied to the front side 24 of the
substrate 22. The indicia are preferably applied to the substrate 22 prior to adherence
of the abrasive material 28. The indicia 30 are readable in a non-mirror image from
left to right when viewed from the front side of the substrate 22.
[0016] As illustrated in Figure 3, the indicia 30 are positioned on the back side 26 of
the substrate 22. The substrate 22 is light transmissive. By light transmissive is
meant that the substrate is sufficiently transparent so that the indicia are viewable
from the front side 24. Light transmissive substrates may be translucent, clear, transparent,
or lucid. The indicia are applied to the back surface 26 in a mirror image,, and therefore
when viewed from the front side, the indicia are viewable in a non-mirror image readable
from left to right. A layer of colorant may also then be applied to the back side
of the substrate over the indicia with the colorant layer being in a contrasting color
to the indicia to enhance readability.
[0017] The indicia that are applied may include standard information that is typically found
on an abrasive sheet. Such information includes the thickness of the sheet, the grit
size, a product designation number, and manufacturer.
[0018] If the indicia are disposed on the front side 24, the substrate 22 may include either
light transmissive or opaque materials such as paper, fiber, cloth, polymeric film,
non-woven webs and combinations and treated versions thereof. If, however, the indicia
are disposed on the back side 26, then the substrate must be at least translucent.
Examples of such substrates include polymeric films such as polyester film, polyethylene
film, and polypropylene film.
[0019] It is preferred that the front and/or back surface of the polymeric film contain
a primer to increase the adhesion to the adhesive. The primer can be a surface alteration
or chemical type primer. Examples of surface alterations include corona treatment
and scuffing to increase the surface area. Examples of chemical type primers include
ethyl acrylic acid copolymer and aziridine type materials as disclosed in U.S. Patent
4,749,617.
[0020] Preferably, the abrasive grains should also be light transmissive. Examples of typical
abrasive grains used for abrasive material 28 include silicon carbide, aluminum oxide,
white aluminum oxide, ceramic aluminum oxide, cerium oxide, diamond, cubic boron nitride,
boron carbide and mixtures thereof. Although typical abrasive grains are somewhat
opaque, the particles as a layer on the substrate still have light transmissive properties
such that the indicia of the present invention clearly show through the layer of abrasive
grains. Furthermore, in abrasive articles in which the abrasive grains are spaced
from each other (sometimes referred to as "open coat"), the opacity of the individual
abrasive grains is even less of an obstruction to viewing the indicia. Translucent
abrasive grains are preferable such as white aluminum oxide to aid in the readability
of the indicia from the front side of substrate 22.
[0021] The adhesive used to adhere the abrasive material to the substrate is preferably
also light transmissive to aid in the readability of the indicia from the front side
of the substrate 22. Examples of typical adhesives include polyester resins, urethane
resins, acrylate resins, phenolic resins, glue, urea-formaldehyde resins, melamine
resin and mixtures thereof. Such adhesives are applied at a thickness normally used
for adhering abrasive material to a substrate. In one preferred embodiment, polyester
film substrate approximately 70 microns thick was primed with an ethylene acrylic
acid copolymer primer. An abrasive white aluminum oxide in the range of 1 to 100 microns
in particle size was bound with a resole phenolic resin.
[0022] The indicia can be applied using a wide variety of well-known methods, which apply
an ink onto the substrate. Such methods include letterpress printing, lithographic
printing, gravure printing, and screen printing. Letterpress printing is preferably
used. Letterpress printing involves a printing element that consists of a raised surface,
wherein the surface can be a line, a word, a point or any type of figure. In letterpress
printing, the printing ink is applied to the raised surface and then pressed onto
the substrate 22 to cause the printing ink to transfer the specified pattern onto
the substrate 22. In lithographic printing, an indirect image transfer is made where
the inverse of the printing plate is transferred to the substrate 22. Lithographic
printing is also known as offset printing or planographic printing. In gravure printing,
a master tool or roll is engraved with minute wells. The printing ink fills these
wells and the excess printing ink is removed by a doctor blade. The ink in the well
is then transferred to the substrate 22. The size and the shape of the well determines
the pattern on the substrate 22. In screen printing, the printing ink is brushed through
a stencil image on a fine screen and then onto the substrate 22. The stencil image
forms the pattern that is transferred to the substrate 22. More detailed information
on printing techniques is found in
Printing Inks, Kirth-Othmer Encyclopedia of Chemical Technology 19, 110-163 (3d ed. 1982) incorporated
hereinafter by reference.
[0023] The abrasive article 20 is produced into a wide variety of forms such as sheets,
discs, or belts. The discs or sheets are attached to a back-up pad 31 that drives
abrasive article 20 to abrade a work piece (not shown) as illustrated in Figure 1.
The back-up pad is used to support the abrasive article 20 during abrading. The back-up
pad can be made from any material, although it is preferred that the material have
at least some elasticity so that the material flexes during the abrading process.
Examples of suitable materials include metal, rubber such as neoprene rubber, butyl
nitrile rubber, plastics such as thermoplastics including nylon, polypropylene, acrylonitrile
butadiene styrene copolymer, thermosetting plastics, and reinforced plastics, and
polyurethane foam. The back-up pad is generally circular in nature and ranges in diameter
from 1 to 40 cm and preferably in the range of 5 to 25 cm. Generally, the diameter
of the abrasive article is slightly larger than the diameter of the back-up pad. By
slightly larger is meant that the diameter of the abrasive article is between about
0.1 mm to about 2 mm larger than the back-up pad.
[0024] In one embodiment of the present invention, a pressure sensitive adhesive is applied
to the back side 26 of the substrate 22 to allow the abrasive article 20 to be easily
attached to the pad. The pressure sensitive adhesive must have sufficient adhesive
strength to secure the coated abrasive to a support pad during use. Representative
examples of pressure sensitive adhesives suitable for this invention include latex
crepe, rosin, acrylic polymers and copolymers such as polybutylacrylate, polyacrylate
ester, vinyl ethers such as polyvinyl n-butyl ether, alkyd adhesives, rubber adhesives
such as natural rubber, synthetic rubber, chlorinated rubber, and mixtures thereof.
A preferred pressure sensitive adhesive is an isooctylacrylate:acrylic acid copolymer.
[0025] The abrasive article 20 can also be attached to the pad 31 by a hook and loop fastening
system. A hook and loop fastening system typically includes a loop portion 32 and
a hook portion 34. A suitable hook and loop fastening system is sold by Minnesota
Mining and Manufacturing Company of St. Paul, Minnesota. Preferably, the loop portion
is laminated to the back side 26 of the substrate 22. The hook portion is then attached
to the pad 31. The hooks then engage between the loops to attach the abrasive article
to the pad. Of course, the loop portion can be attached to the pad, and the hook portion
can be attached to the substrate. The loop material can be any type of textile material
which has loops projecting therefrom. Examples of suitable textile materials include
cotton, polyester, nylon, rayon, and the like. The loop materials can be multifilament
yarns which are described in detail in Ott U.S. Patent 4,609,581, incorporated hereinafter
by reference. Other types of loop materials are woven or knitted yarns having filament
loops or curls extending from the surface. In one embodiment, the loop material is
an opaque color to improve the readability of the indicia viewed from the front side
of the substrate 22.
[0026] To produce an abrasive sheet material that will withstand a large number of disengagements
from and reengagements with the hooks on the support pad it is necessary to apply
an adhesive coating 36 such as thickened or foamed latex, extruded polymer film, or
hot melt adhesive to adhere the loops to the back side 26. The hot melt adhesive or
other bonding material adhering the loops to the back side 26 may be colored prior
to lamination of the loops to further improve the readability of the indicia from
the front side of the substrate 22.
1. An abrasive article (20) comprising:
a substrate (22) having a front side (24) and a back side (26);
a layer of abrasive material (28) bonded to the front side of the substrate; and
indicia (30) disposed on the substrate, substantially all the indicia being viewable
from the front side of the substrate through the layer of abrasive material in a non-mirror
image readable from left to right.
2. The abrasive article (20) of claim 1 wherein the substrate (22) is light transmissive
and the indicia (30) are disposed on the back side of the substrate.
3. The abrasive article (20) of claim 1 wherein the substrate (22) is opaque and the
indicia (30) are disposed on the front side of the substrate.
4. The abrasive article (20) of any of claims 1 to 3 wherein the layer of abrasive material
(28) is light transmissive.
5. The abrasive article (20) of any of claims 1 to 4 and further comprising:
an adhesive (25) adhering the abrasive material (28) to the front side (24) of the
substrate, the adhesive being light transmissive.
6. The abrasive article (20) of any of claims 1 to 5 and further comprising:
means for releasably attaching the article to a support pad (31).
7. The abrasive article (20) of claim 6 wherein the means for releasably attaching includes
a hook and loop fastener having a first portion (34) containing a plurality of hooks
and a second portion containing a plurality of loops (32) and wherein either the first
or the second portion is attached to the back side of the substrate and wherein then
the other first or second portion is attached to the support pad (31).
8. The abrasive article (20) of claim 7 and wherein the portion of the hook and loop
fastener attached to the substrate is opaque.
9. The abrasive article (20) of claim 7 or 8 and further including:
an adhesive (36) for adhering the portion of the hook and loop fastener to the back
side of the substrate (22).
10. The abrasive article (20) of claim 9 wherein the adhesive is opaque.
11. The abrasive article (20) of any of claims 1, 2 and 4 to 10 wherein the substrate
(22) is a light transmissive polymeric film and the indicia are disposed on the back
side of the polymeric film.
12. The abrasive article (20) of any of the preceding claims and further including a layer
of colorant disposed over the indicia (30), the colorant being in contrasting color
to the indicia.
13. The abrasive article (20) of any of the preceedings claims, wherein the light transmissive
layer of abrasive particles (28) comprises particles selected from the group consisting
essentially of silicon carbide, aluminum oxide, cerium oxide, diamond, cubic boron
nitride and boron carbide.
14. The abrasive article (20) of any of claims 5 to 13, wherein the adhesive (25) is selected
from the group consisting essentially of polyester resin, urethane resin, acrylate
resin, phenolic resin, glue, urea-formaldehyde resins and melamine resin.
15. The abrasive article (20) of any of the preceding claims wherein the substrate comprises
a film selected from the group consisting essentially of polyester film, polyethylene
film and polypropylene film.
16. The abrasive article (20) of any of the preceding claims, wherein the abrasive grains
(28) are adhered to the substrate (22) by a cured adhesive (25).
1. Schleifartikel (20) mit:
einem Substrat (22) mit einer Vorderseite (24) und einer Rückseite (26);
einer mit der Vorderseite des Substrats verbundenen Schleifmaterialschicht (28); und
auf dem Substrat angeordneten Kennzeichen (30), wobei im wesentlichen alle Kennzeichen
von der Vorderseite des Substrats durch die Schleifmaterialschicht als Nicht-Spiegelbild
sichtbar und von links nach rechts lesbar sind.
2. Schleifartikel (20) nach Anspruch 1, wobei das Substrat (22) lichtdurchlässig ist
und die Kennzeichen (30) auf der Rückseite des Substrats angeordnet sind.
3. Schleifartikel (20) nach Anspruch 1, wobei das Substrat (22) opak ist und die Kennzeichen
(30) auf der Vorderseite des Substrats angeordnet sind.
4. Schleifartikel (20) nach einem der Ansprüche 1 bis 3, wobei die Schleifmaterialschicht
(28) lichtdurchlässig ist.
5. Schleifartikel (20) nach einem der Ansprüche 1 bis 4, ferner mit:
einem Haftmittel (25) durch das das Schleifmaterial (28) an der Vorderseite (24) des
Substrats haftet, wobei das Haftmittel lichtdurchlässig ist.
6. Schleifartikel (20) nach einem der Ansprüche 1 bis 5, ferner mit einer Einrichtung
zum lösbaren Anbringen des Schleifartikels an einem Haltekissen (31).
7. Schleifartikel (20) nach Anspruch 6, wobei die Einrichtung zum lösbaren Anbringen
aufweist: eine Haken- und Schlaufenbefestigungseinrichtung mit einem ersten Abschnitt
(34), der mehrere Haken aufweist, und einem zweiten Abschnitt, der mehrere Schlaufen
(32) aufweist, und wobei der erste oder der zweite Abschnitt an der Rückseite des
Substrats und der andere Abschnitt am Haltekissen (31) angebracht ist.
8. Schleifartikel (20) nach Anspruch 7, wobei der am Substrat angebrachte Abschnitt der
Haken- und Schlaufenbefestigungseinrichtung opak ist.
9. Schleifartikel (20) nach Anspruch 7 oder 8, ferner mit:
einem Haftmittel (36) zum Anhaften des Abschnitts der Haken- und Schlaufenbefestigungseinrichtung
an der Rückseite des Substrats (22).
10. Schleifartikel (20) nach Anspruch 9, wobei das Haftmittel opak ist.
11. Schleifartikel (20) nach einem der Ansprüche 1, 2 und 4 bis 10, wobei das Substrat
(22) ein lichtdurchlässiger Polymerfilm ist und die Kennzeichen auf der Rückseite
des Polymerfilms angeordnet sind.
12. Schleifartikel (20) nach einem der vorangehenden Ansprüche, ferner mit einer über
den Kennzeichen (30) angeordneten Färbemittelschicht, die in einer Kontrastfarbe bezüglich
der Kennzeichen ausgebildet ist.
13. Schleifartikel (20) nach einem der vorangehenden Ansprüche, wobei die lichtdurchlässige
Schleifmittelschicht (28) Partikel aufweist, die aus einer Gruppe ausgewählt werden,
die im wesentlichen Siliziumcarbid, Aluminiumoxid, Zeroxid, Diamant, kubischem Bornitrid
und Borcarbid aufweist.
14. Schleifartikel (20) nach einem der Ansprüche 5 bis 13, wobei das Haftmittel (25) aus
einer Gruppe ausgewählt wird, die im wesentlichen Polyesterharz, Urethanharz, Acrylatharz,
Phenolharz, Leim, Harnstoff-Formaldehyd-Harz und Melaminharz aufweist.
15. Schleifartikel (20) nach einem der vorangehenden Ansprüche, wobei das Substrat einen
Film aufweist, der aus einer Gruppe ausgewählt wird, die im wesentlichen Polyesterfilm,
Polyethylenfilm und Polypropylenfilm aufweist.
16. Schleifartikel (20) nach einem der vorangehenden Ansprüche, wobei das Schleifmaterial
(28) durch ein aushärtendes Haftmittel (25) am Substrat (22) angebracht ist.
1. Article abrasif (20) comprenant :
un substrat (22) possédant une face avant (24) et une face arrière (26);
une couche d'un matériau abrasif (28) fixé à la face avant du substrat; et
des indices (30) disposés sur le substrat, essentiellement tous les indices pouvant
être vus à partir de la face avant du substrat à travers la couche de matériau abrasif,
dans une image non réfléchie pouvant être lue de gauche à droite.
2. Article abrasif (20) selon la revendication 1, dans lequel le substrat (22) transmet
la lumière et les indices (30) sont disposés sur la face arrière du substrat.
3. Article abrasif (20) selon la revendication 1, dans lequel le substrat (22) est opaque
et les indices (30) sont disposés sur la face avant du substrat.
4. Article abrasif (20) selon l'une quelconque des revendications 1 à 3, dans lequel
la couche de matériau abrasif (28) transmet la lumière.
5. Article abrasif (20) selon l'une quelconque des revendications 1 à 4, comprenant en
outre :
un adhésif (25) fixant par adhérence le matériau abrasif (28) à la face avant (24)
du substrat, l'adhésif transmettant la lumière.
6. Article abrasif (20) selon l'une quelconque des revendications 1 à 5 et comprenant
en outre :
des moyens pour fixer de façon détachable l'article à un bloc de support (31).
7. Article abrasif (20) selon la revendication 6, dans lequel les moyens de fixation
détachable comprennent un système de fixation à crochets et bouclettes possédant une
première partie (34) contenant une pluralité de crochets, et une seconde partie contenant
une pluralité de bouclettes (32), et dans lequel la première ou seconde partie est
fixée à la face arrière du substrat, et dans lequel l'autre de la première ou seconde
partie est alors fixée au bloc de support (31).
8. Article abrasif (20) selon la revendication 7 et dans lequel la partie du dispositif
de fixation à crochets et bouclettes, fixé au substrat, est opaque.
9. Article abrasif (20) selon la revendication 7 ou 8, et comprenant en outre :
un adhésif (36) pour fixer la partie du dispositif de fixation à crochets et bouclettes
à la face arrière du substrat (22).
10. Article abrasif (20) selon la revendication 9, dans lequel l'adhésif est opaque.
11. Article abrasif (20) selon l'une quelconque des revendications 1, 2 et 4 à 10, dans
lequel le substrat (22) est un film polymère transparent pour la lumière et les indices
sont disposés sur la face arrière du film polymère.
12. Article abrasif (20) selon l'une quelconque des revendications précédentes et comprenant
en outre une couche d'un colorant disposée au-dessus des indices (30), le colorant
ayant une couleur qui contraste avec les indices.
13. Article abrasif (20) selon l'une suelconque des revendications précédentes, dans lequel
la couche, qui transmet la lumière, de particules abrasives (28) comprend des particules
sélectionnées dans le groupe constitué essentiellement par du carbure de silicium,
de l'oxyde d'aluminium, de l'oxyde de cérium, du diamant, du nitrure de bore cubique
et du carbure de bore.
14. Article abrasif (20) selon l'une quelconque des revendications 5 à 13, dans lequel
l'adhésif (25) est choisi dans le groupe constitué essentiellement par une résine
polyester, une résine uréthane, une résine acrylate et une résine phénolique, de la
colle, des résines urée - formaldéhyde et de la résine mélamine.
15. Article abrasif (20) selon l'une quelconque des revendications précédentes, dans lequel
le substrat comprend un film choisi dans le groupe comprenant essentiellement un film
de polyester, un film de polyéthylène et un film de polypropylène.
16. Article abrasif (20) selon l'une quelconque des revendications précédentes, dans lequel
les grains abrasifs (28) sont fixés au substrat (22) au moyen d'un adhésif durci (25).
