(19)
(11) EP 0 653 502 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
09.08.1995 Bulletin 1995/32

(43) Date of publication A2:
17.05.1995 Bulletin 1995/20

(21) Application number: 94308277.6

(22) Date of filing: 10.11.1994
(51) International Patent Classification (IPC)6C23C 22/73, C23C 22/36, C25D 11/36, C23C 22/18, C23C 22/22, C23C 22/13
(84) Designated Contracting States:
DE FR GB

(30) Priority: 11.11.1993 JP 282570/93
11.11.1993 JP 282574/93
27.06.1994 JP 144735/94

(71) Applicants:
  • NIHON PARKERIZING CO., LTD.
    Chuo-ku, Tokyo (JP)
  • TOYOTA JIDOSHA KABUSHIKI KAISHA
    Aichi-ken (JP)

(72) Inventors:
  • Aoyama, Masayuki, c/o Nihon Parkerizing Co., Ltd.
    Chuo-ku, Tokyo (JP)
  • Sudo, Shuntaro, c/o Toyota Jidosha K.K.
    Toyoda-shi, Aichi (JP)
  • Konda, Shigeru, c/o Toyota Jidosha K.K.
    Toyoda-shi, Aichi (JP)
  • Kawaguchi, Hiroshi, c/o Toyota Jidosha K.K.
    Toyoda-shi, Aichi (JP)
  • Tanaka, Atsuo, c/o Toyota Jidosha K.K.
    Toyoda-shi, Aichi (JP)
  • Fukada, Arata, c/o Toyota Jidosha K.K.
    Toyoda-shi, Aichi (JP)

(74) Representative: Hale, Stephen Geoffrey 
J.Y. & G.W. Johnson Furnival House 14/18 High Holborn
London WC1V 6DE
London WC1V 6DE (GB)


(56) References cited: : 
   
       


    (54) Zinc-containing metal-plated composite steel article and method of producing the same


    (57) A zinc-containing metal-plated composite steel article having an enhanced paint-coating property has 0.3 to 3.0 g/m² of a zinc phosphate composite coating layer formed on a zinc-containing metal-plated steel substrate by a cathodic electrolysis treatment or a first chemical conversion treatment and including zinc and phosphorus in a weight ratio Zn/P of 2.504:1 to 3.166:1 and 0.06 to 9.0% by weight of Fe, Co, Ni, Ca, Mg and/or Mn, and a phosphate chemical conversion layer formed on the composite coating layer by a second chemical conversion treatment and including fine phosphate crystals.





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