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(11) | EP 0 671 213 A1 |
| (12) | EUROPEAN PATENT APPLICATION |
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| (54) | Process for the recovery of alkylation catalyst |
(57) Process for the recovery of spent fluorinated sulphonic catalyst from acid soluble
oil (ASO) being formed during alkylation of hydrocarbons in presence of the acid catalyst,
comprising steps of
washing the ASO with water and recovering an aqueous solution of the acid catalyst,
neutralizing the acid in the aqueous solution by adding to the solution a basic compound being selected from the group of amino compounds, ammonia and ammonium salts, thereby, forming ammonium salts of the acid catalyst with a melting point at which the obtained acid catalyst salt in a subsequent concentration and drying step is in the form of a melt,
drying the melt, and finally
recovering the acid catalyst by protonisation of the dried melt with sulphuric acid and distilling off the recovered acid catalyst from the sulphuric acid.
washing the ASO with water and recovering an aqueous solution of the acid catalyst,
neutralizing the acid in the aqueous solution by adding to the solution a basic compound being selected from the group of amino compounds, ammonia and ammonium salts, thereby, forming ammonium salts of the acid catalyst with a melting point at which the obtained acid catalyst salt in a subsequent concentration and drying step is in the form of a melt,
drying the melt, and finally
recovering the acid catalyst by protonisation of the dried melt with sulphuric acid and distilling off the recovered acid catalyst from the sulphuric acid.
[0001] The present invention is directed to certain improvements in the alkylation of aliphatic hydrocarbons in the presence of a fluorinated sulphonic acid catalyst.
[0002] More particulary, the invention is related to the recovery of the fluorinated sulphonic acid catalyst acid soluble oil (ASO) in form of a tar from being formed as byproduct during alkylation of hydrocarbons.
[0003] Acid catalyzed alkylation of aliphatic hydrocarbons with olefinic hydrocarbons is a well known process for the preparation of high octane gasoline products. Alkylation of aliphatic hydrocarbons is generally accomplished in the liquid phase by reacting paraffins and olefins in the presence of a strong acid catalyst.
[0004] Utilization of fluorinated sulphonic acids as efficient alkylation catalysts in the alkylation of aliphatic hydrocarbons with olefins, is disclosed in European Patent Application No. 433,954, which by reference is enclosed herein. By the disclosed process, a process stream including a hydrocarbon substrate and an olefinic alkylating agent is reacted by contact with the fluorinated sulphonic acid catalyst in a fixed bed alkylation reactor containing polar contact material. On the contact material is established a reaction zone with the fluorinated sulphonic acid catalyst adsorbed within a confined area of the contact material. In the reaction zone, the process stream is converted at alkylating conditions to a product stream of alkylated hydrocarbons by catalysis of the fluorinated sulphonic acid.
[0005] During the alkylation reaction, the acid catalyst and, consequently, the reaction zone moves as a well-defined band between the ends of the reactor due to interaction with the process stream flowing through and reacting in the zone.
[0006] During migration of the acid catalyst on the contact material, the catalytic activity of the fluorinated sulphonic acid is substantially retained and the acid is still catalytic active when the reaction zone reaches the reactor outlet.
[0007] Although it is possible to reuse the acid catalyst, as it reaches the outlet end of the alkylation reactor by reversing the flow direction of the process stream introduced into the alkylation reactor, small amounts of the acid catalyst will continuously be trapped in ASO byproduct being formed by side reactions during the process. The ASO adsorbs like the acid catalyst as a movable band on the support material adjacent to the reaction zone. It is, thus, possible to withdraw the ASO from the reactor, whenever it reaches one of the ends of the reactor.
[0008] Even if the ASO contains only small amounts of spent acid catalyst, it is desirable to recover the catalyst from the ASO in order to improve the economy of the alkylation process. Conventional methods, like distillation or extraction of the acid directly from the ASO, are not efficient because of strong interaction between the sulphonic acid and basic components in the tar.
[0009] It is, therefore, a principal object of this invention to provide a process for the efficient recovery of fluorinated sulphonic acid catalyst from an alkylation process.
[0010] In the DK patent application No. 0287/93 a recovery process is disclosed, at which spent fluorinated sulphonic acid catalyst is regained by stepwise treating ASO from an alkylation process containing spent catalyst with a proton donating acid to convert the catalyst to its free acid form and then removing the acid by stripping the tar with an inert stripping agent.
[0011] Spent fluorinated sulphonic acid catalyst may quantitatively be recovered by extracting the catalyst containing ASO with water. After extraction with water, it has been shown that the content of fluorinated sulphonic acid catalyst in the extracted ASO is below one ppm. Extracted acid catalyst can be recovered from the aqueous solution by neutralisation with a base, and, subsequently, protonisation in sulphuric acid and distillation of the acid.
[0013] The above process provides an efficient recovery of valuable fluorinated sulphonic acid catalyst. The recovery of the acid after neutralisation with a base, however, represents certain problems. Thus, a number of steps in the further treatment of the obtained salt from the neutralisation step, in particular, drying of the salt complicates the recovery process and diminishes the overall process economy.
[0014] It has now been found that the above disadvantages during drying of recovered acid catalyst salt during recovery of spent alkylation acid catalyst can be avoided by addition of ammonia or organic amino compounds to an aqueous extract of acid containing ASO, whereby salts of the acid catalyst are formed having a melting point at which the salts can be treated in subsequent recovery steps in the liquid phase.
[0015] According to the above observation, this invention provides a process for the recovery of spent fluorinated sulphonic acid catalyst from ASO being formed during alkylation of hydrocarbons in the presence of the acid catalyst, comprising steps of
washing the tar with water and recovering an aqueous phase of the acid catalyst,
adding a basic compound being selected from the group of organic amino compounds, ammonia and ammonium salts and, thereby, forming ammonium salts of the acid catalyst, having a melting point at which the recovered acid catalyst salt in a subsequent concentration and drying step is in the form of a melt, and finally
recovering the acid catalyst by protonisation of the dried melt with sulphuric acid and distillation of the recovered acid catalyst from the sulphuric acid.
[0016] After recovery of the acid catalyst by distilling off the protonated acid catalyst from sulphuric acid, used amino compounds may be recovered by ion exchange with ammonium salt solutions or ammonia.
[0017] When employing ammonia during the recovery process for the formation of ammonium salts, those salts may have an inconvenient high melting point depending on the actual acid catalyst to be recovered. In order to decrease the melting point of the ammonium salts, it is preferred to admix ammonium hydrogen sulphate or alkylammonium hydrogen sulphate, which results in a mixture of salts with a melting point being in the appropriate range for subsequent treatment. The obtained salt mixtures are then dried in form of a melt in liquid phase.
Example
[0021] Thereby, an aqueous phase with the acid catalyst was separated from an oil phase. The oil phase was washed once with water, dried over sodium sulphate and analyzed for trifluoromethanesulphonic acid salts after boiling in ammonia water by ion-chromatographic analysis. The content of acid catalyst was below the detection limit of 0.5 ppm in the oil phase.
[0022] The trifluoromethanesulphonic acid retained in the aqueous phase was recovered by neutralization through addition of adding trimethylamine or triethylamine resulting in a solution of the respective ammonium salts. The melting point of the ammonium salts was:
Et₃NH⁺TfO⁻ (Triethylammoniumtriflate) : 41°C,
Me₃NH⁺TfO⁻ (Trimethylammoniumtriflate) : 140°C.
[0023] 25.1 g (0.10 mole) Et₃NH⁺TfO⁻ were mixed with 25 ml 99.9% sulphuric acid and distilled at 11 mm Hg in a 20 cm Vigreaux column. 14.5 g trifluoromethanesulphonic acid were recovered at 56-60°C giving a recovery of 97%. The remaining 3% of the acid were found in the sulphuric acid remanence.
[0024] 20.9 g (0.10 mole) Me₃NH⁺TfO⁻ were treated with 25 ml 99.9% sulphuric acid and distilled at 10 mm Hg in similar manner as with the triethylammonium salt. At 50-56°C, 15.35 g of a distillate containing 86% trifluoromethanesulphonic acid were obtained corresponding to 13.3 g trifluoromethanesulphonic acid at 89% recovery.
1. Process for the recovery of spent fluorinated sulphonic catalyst from acid soluble
oil (ASO) being formed during alkylation of hydrocarbons in presence of the acid catalyst,
comprising steps of
washing the ASO with water and recovering an aqueous solution of the acid catalyst,
neutralizing the acid in the aqueous solution by adding to the solution a basic compound being selected from the group of amino compounds, ammonia and ammonium salts, thereby, forming ammonium salts of the acid catalyst with a melting point at which the obtained acid catalyst salt in a subsequent concentration and drying step is in the form of a melt,
drying the melt, and finally
recovering the acid catalyst by protonisation of the dried melt with sulphuric acid and distilling off the recovered acid catalyst from the sulphuric acid.
washing the ASO with water and recovering an aqueous solution of the acid catalyst,
neutralizing the acid in the aqueous solution by adding to the solution a basic compound being selected from the group of amino compounds, ammonia and ammonium salts, thereby, forming ammonium salts of the acid catalyst with a melting point at which the obtained acid catalyst salt in a subsequent concentration and drying step is in the form of a melt,
drying the melt, and finally
recovering the acid catalyst by protonisation of the dried melt with sulphuric acid and distilling off the recovered acid catalyst from the sulphuric acid.
2. The process of claim 1, wherein the amino compounds used in the neutralization step
comprises methyl and/or ethylamino compounds.
3. The process of claim 1, wherein the melting point of obtained acid catalyst salt is
further decreased by addition of ammonium hydrogen sulphate.
4. The process of claim 1, wherein the melting point of the acid catalyst salt is further
decreased by addition of alkylammonium hydrogen sulphate with the general formula:
RnH4-n÷HSO₄⁺
where n is between 1 and 3 and R is an alkylgroup.
RnH4-n÷HSO₄⁺
where n is between 1 and 3 and R is an alkylgroup.